• Title/Summary/Keyword: Ultraviolet stabilizer

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Assesment of Weather ability of Polyester/Polypropylene Geotextile Composites (폴리에스테르/폴리프로필렌 복합형 지오텍스타일의 내후성 평가)

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    • Proceedings of the Korean Geotechical Society Conference
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    • 1999.11c
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    • pp.39-55
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    • 1999
  • Geotextile composites to improve the weather ability were composed of recycled polyester geotextile with carbon black as ultraviolet stabilizer and polypropylene geotextile by needle-punching method, and evaluated physical properties, ultraviolet resistance and chemical stability. Retention ratio of tensile properties of non woven polypropylene geotextiles were decreased about 50% by the exposed condition with ultraviolet but those of geotextile composites were slightly decreased than polypropylene geotextiles. Geotextile composites which have larger weights of polyester geotextile were more stable against ultraviolet. For chemical stability, the changes of tensile properties of geotextile composites were in the range of -20~+10% at the various chemical conditions.

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Improvement of Brightness in UV Curing Type Prism Sheet by Using Aromatic Groups (방향족 도입에 의한 자외선 경화형 프리즘시트의 휘도 개전)

  • Kim, Dong-Ryoul;Kim, Hyung-Il
    • Polymer(Korea)
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    • v.33 no.5
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    • pp.413-419
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    • 2009
  • As the refractive index of the prism layer becomes higher, the optical performance of the prism sheet gets better and the efficiency of the LCD backlight unit is improved. In order to increase the refractive index of the prism layer, the ultraviolet curing type resins were prepared by mixing high refractive index materials containing aromatic groups and the multi-functional reactive diluents. By using 9,9-bis [4-(2-acryloyloxyethoxy)phenyl] fluorene, the refractive index of the prism layer was increased up to 1.58 and the brightness of the backlight unit was improved. Since the light source used in the backlight unit caused the yellowing in the prism sheet and deteriorated the brightness accordingly, the hindered amine light stabilizer was used to improve the yellowing resistance successfully.

Influence of Reducing Agents and Additives on the Synthesis of ZnSe Nanoparticles (ZnSe 나노분말 합성에 미치는 환원제와 첨가제의 영향)

  • Back, Geum Ji;Lee, Da Gyeong;Lee, Min Seo;Song, Ha Yeon;Hong, Hyun Seon
    • Journal of Powder Materials
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    • v.27 no.3
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    • pp.233-240
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    • 2020
  • Nano-sized ZnSe particles are successfully synthesized in an aqueous solution at room temperature using sodium borohydride (NaBH4) and thioglycolic acid (TGA) as the reducing agent and stabilizer, respectively. The effects of the mass ratio of the reducing agent to Se, stabilizer concentration, and stirring time on the synthesis of the ZnSe nanoparticles are evaluated. The light absorption/emission properties of the synthesized nanoparticles are characterized using ultraviolet-visible (UV-vis) spectroscopy, photoluminescence (PL) spectroscopy, and particle size analyzer (PSA) techniques. At least one mass ratio (NaBH4/Se) of the reducing agent should be added to produce ZnSe nanoparticles finer than 10 nm and to absorb UV-vis light shorter than the ZnSe bulk absorption wavelength of 460 nm. As the ratio of the reducing agent increases, the absorption wavelengths in the UV-vis curves are blue-shifted. Stirring in the atmosphere acts as a deterrent to the reduction reaction and formation of nanoparticles, but if not stirred in the atmosphere, the result is on par with synthesis in a nitrogen atmosphere. The stabilizer, TGA, has an impact on the Zn precursor synthesis. The fabricated nanoparticles exhibit excellent photo-absorption/discharge characteristics, suggesting that ZnSe nanoparticles can be alloyed without the need for organic solutions or high-temperature environments.

Assessment of Resistance to Application Environment of Geotextile Composites (복합형 지오텍스타일의 적용환경에 대한 저항성 평가)

  • Jeon, Han-Yong;Lyoo, Won-Seok;Ghim, Han-Do;Chung, Chin-Gyo;Cho, Bong-Gyun
    • Journal of the Korean Geosynthetics Society
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    • v.2 no.3
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    • pp.25-38
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    • 2003
  • Geotextile composites to improve the resistance to the application environment were manufactured of recycled polyester geotextile with carbon black as ultraviolet stabilizer and polypropylene geotextile by needle-punching method. Mechanical properties, ultraviolet resistance and chemical stability were evaluated. Retention ratio of tensile properties of polypropylene geotextiles were decreased about 50% with the exposed condition by ultraviolet but those of geotextile composites showed the slightly decrease. Geotextile composites which have larger weights of recycled polyester geotextile were more stable against ultraviolet. For chemical stability, the changes of tensile strength values of geotextile composites were in the range of -20~+10% at the various chemical conditions.

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Synthesis of Zr0.73Y0.27O1.87 Crystals by the Bridgman-Stockbager Method

  • Kim, Won-Sa;Yu, Young-Moon;Lee, Jin-Ho
    • Journal of the Korean earth science society
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    • v.23 no.1
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    • pp.52-58
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    • 2002
  • A colorless and transparent zirconium oxide ($Zr_{0.73}Y_{0.27}O_{1.87}$) crystal has been synthesized by the Bridgman-Stockbager method. The gem-quality material is produced by adding 20${\sim}$25 wt.% $Y_2O_3$ (stabilizer) and 0.04 wt.% $Nd_2O_3$ (decolorising agent) to the $ZrO_2$ powder. It shows a vitreous luster with a slight oily appearance. Under a polarizing microscope, it shows isotropic nature with no appreciable anisotropism. Mohs hardness value and specific gravity is measured to be 8${\sim}$$8{\frac{1}{2}}$ and 5.85, respectively. Under ultraviolet light it shows a faint white glow. The crystal structure of yttria-stabilized zirconia with 0.27 at.% Y has been re-investigated, using single crystal X-ray diffraction, and confirmed to be a cubic symmetry, space group $Fm{\overline{3}}m$ ($O^5_h$) with a=5.1552(5) ${{\AA}}$, V=136.99(5) ${{\AA}}^3$, Z=4. The stabilizer atoms randomly occupy the zirconium sites and there are displacements of oxygen atoms with amplitudes of ${\Delta}/a{\sim}$0.033 and 0.11 along <110> and <111> from the ideal positions of the fluorite structure, respectively.

Pigment Influence of High Density Polyethylene Electrical Strength (고밀도 폴리에틸렌의 전계 세기의 영향)

  • Choi, Yong-Sung;Wee, Sung-Dong;Hwang, Jong-Sun;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04c
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    • pp.50-53
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    • 2008
  • In this work, the $TiO_2$ pigment influence in HDPE dielectric strength was analyzed. Chemical and structural characterizations were made to identify changes during the processing and your influence in the electrical properties. Formulations containing 0, 0.5, 1, 2.5, 4 and 6 of titanium dioxide were processed by extrusion and injection molding with stabilization-antioxidants, ultraviolet stabilizers and plasticizers. The electrical strength tests were analyzed by the statistical distribution of Weibull, and the maximum likelihood method. The high concentrations present lower values to electrical strength. The $\beta$ parameter could be using to insulator particles dispersion. The $TiO_2$ concentration variation shows that these incorporations implicate strength values increase has a maximum (5,35MV/cm). High pigment concentration induces a little falls in property values. Observing the $\beta$ parameter, minimum experiment electric field (Ebmin) and electric strength value, found that the best electric perform formulation was the formulation with 2.5% $TiO_2$ weight.

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Effects of Zeolites on Thermal Stability of Poly(vinyl chloride) (폴리염화비닐(PVC)의 열안정성에 제올라이트가 미치는 영향)

  • Xu, Jiayou;Liang, Qinghua;Xian, Xiumei;Li, Kaidan;Liu, Jie
    • Polymer(Korea)
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    • v.39 no.1
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    • pp.1-5
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    • 2015
  • The effects of zeolite on the thermal stability of poly(vinyl chloride) (PVC) were investigated by the static thermal stability test, pyrolysis experiment and ultraviolet spectrum. The results showed that the porous zeolite could absorb hydrogen chloride (HCl), which suppressed the catalysis of HCl on thermal degradation of PVC, thus improved the thermal stability of PVC. The oxidizing acid which was loaded on zeolite had oxidated on the double bond that formed during the dehydrochlorination of PVC. This process could prohibit the growth of the conjugated polyene and improved the color of PVC. Hence, zeolite might be possible to come up with a high performance thermal stabilizer.

Study on Quality Criteria for Transparent Soundproof Panels(2) - Sound Insulation Characteristics and Evaluation of Weatherability (투명방음판의 품질기준 설정에 관한 연구(2) - 음향 특성 및 내후성 평가)

  • Chang, Taesun;Kim, Chulhwan;Hwang, Cheolho
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.22 no.11
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    • pp.1099-1105
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    • 2012
  • Transparent noise barrier panels have the advantages of transmitting light to nearby residents and allowing drivers to orientate themselves by providing views of the surrounding area. To develop guidelines on quality criteria for transparent soundproof panels, their sound transmission loss and weatherability were experimentally investigated. In Korea, the sound transmission loss of noise barrier panels should be more than 25 dB at 500 Hz and 30 dB at 1000 Hz. The transmission loss tests of transparent panels were performed in accordance with KS F 2808. Typically, plastic materials suffer from color changes when exposed to ultraviolet(UV) light over extended periods. Therefore, weathering of plastics is one of the most important properties for outdoor applications. Protection against UV radiation and weathering is usually accomplished by using UV stabilizer additives or coatings. Transparent materials for soundproof panels were examined through accelerated weathering tests and their weathering resistances were evaluated from changes in yellowness index.

Characterization of Yttrium Doped Zinc Oxide Thin Films Fabricated by Spin-coating Method (스핀코팅법에 의해 제조되어진 Yttrium이 도핑된 ZnO 막의 특성)

  • Kim Hyun-Ju;Lee Dong-Yun;Song Jae-Sung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.5
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    • pp.457-460
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    • 2006
  • Y doped zinc oxide (YZO) thin films were deposited on F doped $SnO_2$ (FTO) glass substrate by sol-gel method using the spin-coating system. A homogeneous and stable solution was prepared by dissolving acetate in the solution added diethanolamine as sol-gel stabilizer. YZO films were obtained after preheated on the hot-plate for 5minute before each coating; the number of coating was 3 times. After the coating of last step, annealing of YZO films performed at $450^{\circ}C$ for 30 minute. In order to confirming of a ultraviolet ray interruption and down-conversion effects, optical properties of YZO films, transmission spectrum and fluorescent spectrum were used. Also, for understanding the obtained results by experiment, the elestronic state of YZO was calculated using the density functional theory The results obtained by experiment were compared with calculated structure. The detail of electronic structure was obtained by the discrete variational Xa (DV-Xa) method, which is a sort of molecular orbital full potential method. The density of state and energy levels of dopant element were shown and discussed in association with optical properties.

Stabilization to Sunlight of Natural Coloring Matter by Soluble Methyl-Hesperidin (수용성 메틸-헤스페리딘에 의한 천연색소의 빛에 대한 안정화)

  • Woo, Dong-Ho
    • Korean Journal of Food Science and Technology
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    • v.32 no.1
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    • pp.50-55
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    • 2000
  • Soluble methyl-hesperidin (MH) powder was prepared from crude MH, and was investigated on the stabilization to sunlight of natural coloring matter. Soluble MH powder was added to riboflavin, bixin, and paprika oleoresin solutions at concentration of 0.1 or 0.2%(w/w), and the absorbance of respective solutions was analyzed by spectrophotometer after exposing to sunlight for $10{\sim}24$ hr. While coloring matter solutions without MH was faded completely with lapse of time, addition of MH retarded to fade natural coloring matters. According as amount of MH added increased, MH showed more excellent stabilizing effect on the coloring matters. Especially, vitamin C with soluble MH showed remarkable synergistic effect in paprika oleoresin solution during the exposure to sunlight for 8 hr. Consequently, it was found that MH plays a role as excellent stabilizer of natural coloring matters to ultraviolet of sunlight.

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