• Title/Summary/Keyword: Ultraviolet (UV) curing

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A Study on the dynamic viscoelasticity of UV curing polymer and alkyd resin composite materials (UV경화성 수지와 Alkyd수지 복합재료의 경화거동과 동적 점탄성에 관한 연구)

  • 정원식;최정병;김용욱
    • Journal of the Korean Graphic Arts Communication Society
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    • v.16 no.3
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    • pp.29-41
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    • 1998
  • The ultraviolet(UV)-curable materials wildly have been used as a ink and coating materials. A according to measure UV polymerization phase separation of acryl groups 2,3,4-functional monomer, a few experiments were performed gel fraction, dynamic viscosity of alkyd resin blend system. Dependence of photoiniator concentration and various monomer, alkyd resin content investigated structural changes of films cured by UV irradiation. Curing rate measured UV irradiation under $25^{\circ}C$, cell gap 7cm and film thickness 100${\mu}{\textrm}{m}$. In results, it was through that the viscoelastic properties of films cured with increasing the ratios of monomer/alkydresin contents are network polymer in properties such as viscoelasticity.

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Comparative analysis of strain according to the deposition of a constant temperature water bath of a denture-base artificial tooth produced using three-dimensional printing ultraviolet-curing resin (3D 프린팅용 광경화 수지를 사용하여 제작한 의치상용 인공치아의 항온수조 침적에 따른 변형률 비교 분석)

  • Kim, Dong-Yeon;Lee, Gwang-Young;Kim, Jae-Hong;Yang, Cheon-Seung
    • Journal of Technologic Dentistry
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    • v.42 no.3
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    • pp.202-207
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    • 2020
  • Purpose: This study is a comparative analysis of the strain according to deposition in a constant temperature water bath after manufacturing ultraviolet (UV)-cured artificial teeth. Methods: As a control group, 10 ready-made artificial teeth were selected as the first molar on the right side of the maxilla (RT group). Silicone was used as a duplicate of the artificial denture teeth. Experimental teeth were prepared in two groups using the prepared silicone mold. In the first experimental group, the UV-cured resin was injected into the negative silicone, followed by irradiation with a UV-curing machine for 5 minutes (5M group). In the second experimental group, the UV-cured resin was injected into the negative silicone, and then irradiated for 30 minutes using a UV-curing machine (30M group). The one-way ANOVA was performed, and post-test was analyzed by Tukey. Results: When immersed in a water bath for 15 days, it was found to be -0.3% in the RT group, -0.6% in the 5M group, and -0.7% in the 30M group. The results revealed -0.2% in the RT group, 0.2% in the 5M group, and -0.2% in the 30M group when they were in the bath for 30 days. Conclusion: In the water bath, the swelling was greater when deposited for 1 to 15 days, but was less when deposited for 15 to 30 days.

Comparison of polymerization by time of light curing for dental 3D printing (치과 3D 프린팅용 광중합 시간에 따른 중합도 비교)

  • Kim, Dong-Yeon;Lee, Gwang-Young
    • Journal of Technologic Dentistry
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    • v.44 no.3
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    • pp.76-80
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    • 2022
  • Purpose: The purpose of this study is to analyze the depth according to curing using photocurable resin for dental three-dimensional printing. Methods: A stainless mold with a height of 4 mm was prepared. Ultraviolet (UV) polymerization resin was injected into the mold. Photocuring was then performed for 5 minutes using a photopolymerizer, and the height was measured using a digital measuring instrument (first group). Second, light polymerization was also performed outside the mold for 5 minutes, and the height was measured using a digital measuring instrument. Third, light polymerization was further performed for 5 minutes, and the height was measured using a digital measuring instrument. Statistical analysis was performed with the Kruskal-Wallis test, which is a nonparametric test (α=0.05). Results: The third group had the largest measurement length, whereas the first group had the smallest. However, the difference between groups was not statistically significant (p>0.05). The color of the first group was different from that of the second and third groups. Conclusion: All of the 4-mm-thick photocured specimens had a curing reaction, but the part that was not directly irradiated with UV did not show its original color.

A study on the curing characteristics of multi-concentrating UV-LED Curable Coating (다중 집광성 UV-LED 경화형 코팅의 경화특성에 관한 연구)

  • Jung, Chan-Gwon;Kim, Beom-Su;Park, Dae-Hee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.10
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    • pp.339-345
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    • 2018
  • We investigated the curing properties of cured coatings for a multi-focal UV-LED. The coatings are for LEDs that operate at multiple UV wavelengths, unlike conventional single-wavelength UV-LEDs. Using UV-LED light sources with wavelengths of 365, 395, 420, and 450 nm, we analyzed the optical characteristics such as the direction of light flux and light source. We also analyzed the curing characteristics at each UV-LED wavelength to optimize the LED for composite wavelengths. The curing performance state was predicted through computer simulation for when the multiple wavelengths of UV light sources are superimposed, and then actual LEDs were designed and fabricated. To improve the internal high-speed curing, a multi-spot module was fabricated, in which each LED is condensed, and multiple wavelengths are synthesized and condensed at the same position. The adhesive strength, surface hardness, and internal hardness of the curing agent were tested by varying the wavelength combination conditions. The surface hardening and internal hardening were compared and analyzed using a hardness tester and FT-IR analyzer. As a result, the characteristics of the surface and internal hardness were improved by a multi-spot method in which four wavelengths were overlapped in a UV-LED rather than a single wavelength.

A Study on Ulraviolet-cut Ability of Silk Fabric Dyed with Natural Dyestuffs (천연염재의 자외선 차단성능 연구)

  • 김월순;최인려
    • The Research Journal of the Costume Culture
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    • v.12 no.1
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    • pp.1-11
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    • 2004
  • This study was carried out on the process of natural dye substances which can flock ultraviolet rays without producing harmful substances by pollution, germs, etc. While making human body safe in contact, extracting Gardenia, Sappan wood, Radix scutellariae, Cromwell, Mugwort, Gallnut, Lac. Those are used for curing diseases, dyeing silk cloth with those extracts, and examining the color fastness, Ultraviolet protection. From this study, the following conclusion was produced. Brightness was lower in pre-mordanting than in post. And color difference showed that Radix scutellariae was the highest. Aluminum-mordanting showed a higher color difference than Fe. Colorfastness to washing was high in all samples, and the degree of color-changing by washing was the highest in the sample dyed by gardenia, pre-mordanted gallnut showed the highest degree. Colorfastness to perspiration was the highest in gardenia. UV-A test showed that all samples a high rate of 85% or higher compared with test white cloth. Especially, post-mordanted radix scutellariae, pre-mordanted gallnut and post-mordanted sappanwood showed a superior blocking rate.

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Effects of UV Initiator on Properties of Polymer-Modified Asphalt (자외선 경화제가 고분자개질아스팔트의 물성에 미치는 영향에 관한 연구)

  • Kang, Hyun-Seung;Hong, Young-Keun
    • Elastomers and Composites
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    • v.45 no.3
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    • pp.217-222
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    • 2010
  • Paved roads are suffered from the permanent plastic deformation in hot summer and cracks in cold winter, which are detrimental to safe driving. This leads to necessity of modification of asphalt to resist those deformation. In this study, two kinds of modifiers were examined; organic polymers and a photoinitiator which is activated by ultraviolet lay. The mechanical and rheololgical properties of modified asphalts were examined using UTM and rheometer. Results showed that the properties were varied depending on the types of polymer and irradiation time. UV irradiation increased the tensile strength and storage modulus of thermoplastic polymer-modified asphalt, however UV was not effective on thermoset polymer. According to long term ultraviolet curing test, properties of the polymer/photoinitiator-modified asphalt did not decrease, but rather increase for 20 years. This indicates that the useful life of the asphalt could be extended by addition of photoinitiator.

The Study of Thermal Effect Suppression and Wavelength Dependence of Azobenzene-coated FBG for UV Sensing Application (UV광 측정용 아조벤젠 코팅된 FBG의 열적 효과 제거 및 파장 의존성에 대한 연구)

  • Choi, Dong-Seok;Kim, Hyun-Kyoung;Ahn, Tae-Jung
    • Korean Journal of Optics and Photonics
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    • v.22 no.2
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    • pp.67-71
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    • 2011
  • In the paper, we have demonstrated an azobenzene-coated fiber Bragg grating (FBG) for monitoring ultraviolet light (UV) intensity in remote measurement. The elasticity of the coated azobenzene polymer is changed by the UV light, which induces a center wavelength change corresponding to the change of the FBG's grating period. The wavelength shift resulting from both UV light and other light with the wavelength out of the UV range was about 0.18 nm. In order to improve the accuracy of the measurement, the center wavelength shift caused by radiant heat of the light source was sufficiently removed by using a thermal filter. The amount of the center wavelength shift was consequently reduced to 0.06 nm, compared to the result without the thermal filter. Also, the FBGs coated by using azobenzene polymer were produced by two different methods; thermal casting and UV curing. Considering temperature dependence, UV curing is more suitable than thermal casting in UV sensor application of the azobenzene-coated FBG. In addition, we have confirmed the wavelength dependence of the optical sensor by means of four different band pass filters. Thus, we found out that the center wavelength shift per unit intensity is 0.029 [arb. unit] as a maximum value at 370 nm wavelength region and that the absorption spectrum of the azobenzene polymer was very consistent with the wavelength dependence of the azobenzene-coated FBG.

The Effect of EVA Sheet Gel Content Depending on Curing Condition for Photovoltaic Module (PV모듈용 EVA Sheet의 Curing조건에 따른 Gel Content 특성)

  • Kang, Gi-Hwan;Kim, Kyung-Soo;Park, Kyung-Eun;Kim, Hyun-Il;Yu, Kwon-Jong
    • Proceedings of the KIEE Conference
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    • 2006.07b
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    • pp.1155-1156
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    • 2006
  • In this paper, we analyzed the effect of EVA Sheet Gel Content depending on curing condition for photovoltaic module. Gel Content was measured by manufacturing Glass/EVA Sheet/Back Sheet scheme at several curing temperature and curing time. And the surface analysis of EVA Sheet depending on process condition could be observed using SEM(Scanning Electron Microscope). Through this experiment, we could confirm that there are differences on Gel Content of EVA Sheet and surface configuration depending on curing temperature and curing time. To find out the optical characteristic dependency on curing condition, Class/EVA Sheet/Glass scheme was fabricated. The optical transmittance of EVA Sheet at visible wavelength was enhanced 5% when compared to Glass/Glass scheme. And the transmittance of $130^{\circ}C$/4min, $110^{\circ}C$/4min, $160^{\circ}C$/6min process condition was higher at ultraviolet wavelength range. These curing conditions could be regarded as the best process for suppression the discoloration speed of EVA Sheet under UV light.

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Preparation and Properties of UV Curable Urethane Acrylates for Ink Binder (Ink Binder용 UV 경화형 조성물의 제조 및 특성)

  • Park, Hyun-Ju;Han, Chang-Duk;Oh, Sang-Taek
    • Journal of Adhesion and Interface
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    • v.14 no.4
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    • pp.167-174
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    • 2013
  • In this study, Ultraviolet (UV) curable urethane acrylates for ink binder was prepared by reaction of IPDI, polyether polyol and HEA. The UV curing behavior of compositions with HEA/PETA ratio on UV irradiation time was investigated by FT-IR spectrophotometer, probe tack tester and Photo-DSC. Conversion % and gel content were increased with increasing UV irradiation time, but probe tack was decreased. Storage modulus, tensile strength and decomposition temperature were increased as PETA content increased. In case of HEA/PETA ratio was 30/70, adhesion property of UV-cured composition on PMMA sheet was excellent.