• Title/Summary/Keyword: Ultrasonic reactor

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Effect of Ultrasonic Irradiation on Ozone Nanobubble Process for Phenol Degradation (페놀 분해를 위한 오존 나노기포 공정에서 초음파 조사의 영향)

  • Lee, Sangbin;Park, Jae-Woo
    • Journal of the Korean GEO-environmental Society
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    • v.23 no.3
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    • pp.23-29
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    • 2022
  • In this study, we investigated the ozone nanobubble process in which nanobubble and ultrasonic cavitation were applied simultaneously to improve the dissolution and self-decomposition of ozone. To confirm the organic decomposition efficiency of the process, a 200 mm × 200 mm × 300 mm scale reactor was designed and phenol decomposition experiments were conducted. The use of nanobubble was 2.07 times higher than the conventional ozone aeration in the 60 minutes reaction and effectively improved the dissolution efficiency of ozone. Ultrasonic irradiation increased phenol degradation by 36% with nanobubbles, and dissolved ozone concentration was lowered due to the promotion of ozone self-decomposition. The higher the ultrasonic power was, the higher the phenol degradation efficiency. The decomposition efficiency of phenol was the highest at 132 kHz. The ozone nanobubble process showed better decomposition efficiency at high pH like conventional ozone processes but achieved 100% decomposition of phenol after 60 minutes reaction even at neutral conditions. The effect by pH was less than that of the conventional ozone process because of self-decomposition promotion. To confirm the change in bubble properties by ultrasonic irradiation, a Zetasizer was used to measure the bubbles' size and zeta potential analysis. Ultrasonic irradiation reduced the average size of the bubbles by 11% and strengthened the negative charge of the bubble surface, positively affecting the gas transfer of the ozone nanobubble and the efficiency of the radical production.

Detection of Hydride Blisters in Zirconium Pressure Tubes using Ultrasonic Mode Conversion and Velocity Ratio Method (초음파 모드 변환 및 속도비 방법에 의한 지르코늄 압력관의 수소화물 블리스터 탐지)

  • Cheong, Yong-Moo;Lee, Dong-Hoon;Kim, Young-Suk
    • Journal of the Korean Society for Nondestructive Testing
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    • v.23 no.4
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    • pp.334-341
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    • 2003
  • When the pressure tubes(f are in contact with the calandria tube(CT) in the pressurized heavy water reactor(PHWR), the temperature difference between inner and outer wall of W results in a thermal diffusion of hydrogen (deuterium) and hydride blisters are formed on the outer surface of PT. Because the hydride blisters and zirconium matrix are acoustically continuous, it is not easy to distinguish the blisters from the matrix with conventional ultrasonic method. An ultrasonic velocity ratio method was developed to detect small hydride blisters on the zirconium pressure tube. Hydride blisters were grown in the PT specimen using a steady state thermal diffusion device. The flight times of longitudinal echo and reflected shear echo from the outer surface were measured accurately. The velocity ratio of the longitudinal wave to the shear wave was calculated and displayed using contour plot. Compared to the conventional flight time method of longitudinal wave, the velocity ratio method shows superior sensitivity to detect smaller blisters as well as better images for the blister shapes. Detectable limit of the outer shape of the hydride blisters was conservatively estimated as $500{\mu}m$, with the same specifications of ultrasonic transducer used in the actual PHWR pressure tube inspection.

Estimation of Ultrasonic Energy and Sonochemical Effects in Double-Bath-Type Systems and Heterogeneous Systems (이중 반응기 조건 및 비균일계 조건에서의 초음파 에너지 및 화학적 효과 평가)

  • Lee, Hyeon Jae;Son, Younggyu
    • Journal of Soil and Groundwater Environment
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    • v.22 no.5
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    • pp.40-47
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    • 2017
  • The effects of ultrasound in heterogeneous system were investigated in three kinds of ultrasonic systems including a bath-type system (System #1), a double-bath-type system (System #2), and a double-bath-type system partly filled with glass beads (System #3). The ultrasound energy and its attenuation were quantified using calorimetry and the sound pressure measurement method. The sonochemical effects mainly involved in radical oxidation reactions were quantified using KI dosimetry. It was found that ultrasound energy was significantly attenuated in System #2 and #3 due to the presence of solid materials such as a submerged stainless steel reactor and glass beads. However, in spite of low ultrasound energy status, sonochemical oxidation reactions occurred more violently due to the presence of glass beads in System #3. In addition, calorimetry was more adequate to estimate the total energy status of ultrasound in sonoreactors compared to the sound pressure measurement method.

Laser Peening Application for PWR Power Plants (비등수형 원자로 발전소에의 레이저 피닝 적용기술)

  • Kim, Jong-Do;SANO, Yuji
    • Journal of Welding and Joining
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    • v.34 no.5
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    • pp.13-18
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    • 2016
  • Toshiba has developed a laser peening system for PWRs(pressurized water reactors) as well after the one for BWRs(boiling water reactors), and applied it for BMI(bottom-mounted instrumentation) nozzles, core deluge line nozzles and primary water inlet nozzles of Ikata Unit 1 and 2 of Shikoku Electric Power Company since 2004, which are Japanese operating PWR power plants. Laser pulses were delivered through twin optical fibers and irradiated on two portions in parallel to reduce operation time. For BMI nozzles, we developed a tiny irradiation head for small tubes and we peened the inner surface around J-groove welds after laser ultrasonic testing (LUT) as the remote inspection, and we peened the outer surface and the weld for Ikata Unit 2 supplementary. For core deluge line nozzles and primary water inlet nozzles, we peened the inner surface of the dissimilar metal welding, which is of nickel base alloy, joining a safe end and a low alloy metal nozzle. In this paper, the development and the actual application of the laser peening system for PWR power plants will be described.

The electrical and optical properties of ZnO:Al films Prepared by ultrasonic spray Pyrolysis (초음파 분무법으로 제조한 ZnO:Al 박막의 전기 및 광학적 특성)

  • Lee, Soo-Chul;Moon, Hyun-Yeol;Lee, In-Chan;Ma, Tae-Young
    • Proceedings of the IEEK Conference
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    • 1999.06a
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    • pp.283-286
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    • 1999
  • Transparent conductive aluminum-doped ZnO(AZO) films Were prepared by a ultrasonic spray pyrolysis method at the substrate temperature below 23$0^{\circ}C$. A vertical type hot wall furnace was used as a reactor in the deposition system. Zinc acetate dissolved in methanol was selected as a precursor. The substrate temperature was varied from 18$0^{\circ}C$to 24$0^{\circ}C$. Aluminum (Al) was doped into ZnO films by incorporating anhydrous aluminum chloride (AlCl$_3$) in the zinc acetate solution. The proportion of the Al in the starting solution was varied from 0 wt % to 3.0 wt %. The crystallographic properties and surface morphologies of the films were analyzed by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The resistivity of the films was measured by the Van der Pauw method, and the mobility and carrier concentration were obtained through the Hall effect measurements Transmittance was measured in the visible region. The effects of substrate temperature and aluminum content in the starling solution on the structural and electrical properties of the AZO films are discussed

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Simulation Based Investigation of Focusing Phased Array Ultrasound in Dissimilar Metal Welds

  • Kim, Hun-Hee;Kim, Hak-Joon;Song, Sung-Jin;Kim, Kyung-Cho;Kim, Yong-Buem
    • Nuclear Engineering and Technology
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    • v.48 no.1
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    • pp.228-235
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    • 2016
  • Flaws at dissimilar metal welds (DMWs), such as reactor coolant systems components, Control Rod Drive Mechanism (CRDM), Bottom Mounted Instrumentation (BMI) etc., in nuclear power plants have been found. Notably, primary water stress corrosion cracking (PWSCC) in the DMWs could cause significant reliability problems at nuclear power plants. Therefore, phased array ultrasound is widely used for inspecting surface break cracks and stress corrosion cracks in DMWs. However, inspection of DMWs using phased array ultrasound has a relatively low probability of detection of cracks, because the crystalline structure of welds causes distortion and splitting of the ultrasonic beams which propagates anisotropic medium. Therefore, advanced evaluation techniques of phased array ultrasound are needed for improvement in the probability of detection of flaws in DMWs. Thus, in this study, an investigation of focusing and steering phased array ultrasound in DMWs was carried out using a time reversal technique, and an adaptive focusing technique based on finite element method (FEM) simulation. Also, evaluation of focusing performance of three different focusing techniques was performed by comparing amplitude of phased array ultrasonic signals scattered from the targeted flaw with three different time delays.

Influence of Operating Parameters on Nitrite Accumulation in a Biofilm Reactor and Supplement of External Carbon Source for Denitrification by Sewage Sludge Solubilization (생물막 반응조에서 아질산염 축적에 미치는 운전인자 영향과 하수슬러지 가용화에 의한 탈질반응의 외부탄소원 공급에 관한 연구)

  • Ahn, Hye Min;Lee, Dae Sung
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.1
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    • pp.57-63
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    • 2013
  • A combined process consisted of a biofilm reactor and a continuously stirred-tank reactor (CSTR) was investigated for highly loaded ammonium wastewater treatment via nitrite accumulation. To enhance ammonium oxidizing bacteria over nitrite oxidizing bacteria on the surface of carriers, the biofilm reactor was operated at temperature of $35^{\circ}C$ for more than three months but the influent ammonium (500 mg-N/L) was partially oxidized to nitrite (240 mg-N/L). As pH was increased from 7.5 to 8.0, nitrite accumulation was fully achieved due to the inhibition of nitrite oxidizing bacteria under high free ammonia concentration. The biofilm reactor performance was severely deteriorated at the hydraulic retention time of 12 hr, at which incomplete nitrification of ammonia was observed. Various solubilization methods were applied to sewage sludge for enhancing its biodegradability and the combined method, alkaline followed by ultrasonic, gave the highest solubilization efficiency (58%); the solubilized solution was used as the external carbon source for denitrification reaction in CSTR. FISH analysis showed that the dominant microorganisms on the carriers were ammonium oxidizing bacteria such as Nitrosomonas spp. and Nitrospirar spp. but low amounts of nitrite oxidizing bacteria as Nitrobacter spp. was also detected.

Identification of nonregular indication according to change of grain size/surface geometry in nuclear power plant (NPP) reactor vessel (RV)-upper head alloy 690 penetration

  • Kim, Kyungcho;Kim, Changkuen;Kim, Hunhee;Kim, Hak-Joon;Kim, Jin-Gyum;Jhung, Myungjo
    • Nuclear Engineering and Technology
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    • v.49 no.7
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    • pp.1524-1536
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    • 2017
  • During the fabrication process of reactor vessel head penetration (RVHP), the grain size of the tube material can be changed by hot or cold work and the inner side of the tube can also be shrunk due to welding outside of the tube. Several nonregular time-of-flight diffraction (TOFD) signals were found because of deformed grains. In this paper, an investigation of nonregular TOFD indications acquired from RVHP tubes using experiments and computer simulation was performed in order to identify and distinguish TOFD signals by coarse grains from those by Primary Water Stress Corrosion Crack (PWSCC). For proper understanding of the nonregular TOFD indications, microstructural analysis of the RVHP tubes and prediction of signals scattered from the grains using Finite Element Method (FEM) simulation were performed. Prediction of ultrasonic signals from the various sizes of side drilled holes to find equivalent flaws, determination of the size of the nonregular TOFD indications from the coarse grains, and experimental investigation of TOFD signals from coarse grain and shrinkage geometry to identify PWSCC signals were performed. From the computer simulation and experimental investigation results, it was possible to obtain the nonregular TOFD indications from the coarse grains in the alloy 690 penetration tube of RVHP; these nonregular indications may be classified as PWSCC. By comparing the computer simulation and experimental results, we were able to confirm a clear difference between the coarse grain signal and the PWSCC signal.

Synthetic Phase Tuning Technique for the Transduction of a Specific Ultrasonic Torsional Mode in a Pipe (배관에서의 특정 비틀림 초음파 모드 송수신을 위한 합성 위상 조절 기법)

  • Kim, Hoe Woong;Kwon, Young Eui;Joo, Young Sang;Kim, Jong Bum;Kim, Yoon Young
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.23 no.3
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    • pp.249-257
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    • 2013
  • This study newly presents a synthetic phase tuning technique to suppress the unwanted torsional mode while enhancing the desired torsional mode in a pipe. Specifically, we aim at the enhancement of the first torsional mode and the suppression of the undesired, second torsional mode. Earlier efforts were to enhance the desired wave mode only in the hope that the enhancement results in the suppression of the unwanted wave mode. Unlike these efforts, the suggested technique makes the complete cancellation of the unwanted wave mode but it is shown to enhance the desired first mode for torsional wave problems. In the present study, the synthetic phase tuning is developed for the cancellation of the unwanted wave mode, meaning that the number of necessary experimental equipments is reduced. Simulation and experiment were carried out to check the effectiveness of the proposed method. As an application of the suggested technique, we investigated the reflection and mode conversion characteristics of the first torsional mode according to the step thickness variation in a stepped pipe.

Mechanized Ultrasonic Testing for PWR Reactor Pressure Vessel (가압경수로 원자로 압력용기 자동초음파검사)

  • Park, Moon-Ho;Kim, Jae-Hee
    • Journal of the Korean Society for Nondestructive Testing
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    • v.17 no.2
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    • pp.114-121
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    • 1997
  • 가압경수로 원자로 압력용기 비파괴검사를 위해 지금까지 계속 사용하여 온 기존의 고정식 매니플레이터 방식의 원자로 자동초음파검사장비는 최근 급속도로 발전한 전자산업 및 컴퓨터 등으로 인해 기본 설계 개념부터 달리하는 소형.경량화된 수중 이동형 원자로 검사 장비 형태로 바뀌어 가고 있다. 따라서, 본 해설에서는 현재까지 국내외 알려진 각종 소형 원자로 압력용기 자동초음파검사장비 및 고정식 매니플레이터 방식의 원자로 압력용기 자동초음파검사장비를 분석하여 기술하였으며, 현재 국내 원자로 압력용기 용접부검사를 위해 개발중인 RYSIS 장비 및 검사 기술 수준을 진단해보고 앞으로의 방향을 제시하였다.

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