• Title/Summary/Keyword: Ultrafiltration system

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Separation Purification Characteristics of Rinsing Solution in Semiconductor Process using Bigh Performance Polymer Membranes ( I ) (기능성 고분자막을 이용한 반도체 공정 세정액의 분리정제특성 (I))

  • Lee Jae-Dal;Hong Young-Ki;Ro Duck-Kil;Bae Kie-Seo
    • Textile Coloration and Finishing
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    • v.17 no.3 s.82
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    • pp.34-42
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    • 2005
  • In this work, a practical separation performance was investigated on aqueous alcohol solutions, especially for iso-propyl alcohol (IPA), which is usually used during the semi- conductor rinsing process. The removal of various substances from waste aqueous IPA solutions was carried out by microfiltration with $0.1\~1{\mu}$m pore size of mean diameter as a pre-filter. Permeability and molecular weight cut-off of the functional polysulfone(PSf) ultrafiltration membrane to purify waste aqueous IPA solutions were measured through the ultrafiltration test. The solute rejection of PSf membrane had $92\%$ in 1,000ppm aqueous PEG solution with PEG molecular weight 10,000, the molecular weight cut-off had 10,000. The IPA concentration on the $CMPA-K^+$ membrane performance using pervaporation module system could be increased from $95.04 wt\%$ to more than $98.50wt\%$ in about 9hr at operation temperature of $70^{\circ}C$ using the pervaporation module system.

Treatment of Tapioca Starch Wastewater By Anaerobic Digestion Coupled With Membrane Separation Process (혐기성 소화 및 막분리에 의한 Tapioca 전분의 폐수처리)

  • ;S. Vigneswaran
    • KSBB Journal
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    • v.6 no.2
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    • pp.135-141
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    • 1991
  • This study thus looks into two treatment processess : i) Anaerobic digester coupled with hollow fibre membrane unit. Treatment of starch waste with anaerobic digester-membrane system was studied. $0.17\m^2$ area of hollow fibre membrane unit of known pore size was immersed into laboratory-scale anaerobic digestion system. The pore size of membrane was varied from 0.03 to $\0.15mu$m. The hydraulic retention time of anaerobic digester was varied from 1.5 to 10 days. The effect of hydraulic retention time on treatment efficiency was significant while effect of membrane size was not significant. The gas production was about 0.74㎥/kg COD treated. The COD removal efficient was about 80-95% depending on the hydraulic retention time. ii ) Crossflow ultrafiltration as post treatment to anaerobic filter. The effluent from anaerobic filter, which had a total COD in the range of 4,500-5,200 mg/L was treated by crossflow ultrafiltration units. The study conducted with different membrane pore size indicated that membrace with 1,000,000 molecular weight cut-off size gave a higher COD removal efficiency in the range of 83-87% while giving a study flux of $120-130 L/\m^2$.h. A study was conducted to see the long term clogging effect of membrane also.

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Permeation Behavior of Semiconductor Rinsing Wastewater Containing Si Particles in Ultrafiltration System -I. Permeation Characteristics of Polysulfone Flat Plate Membrane- (Si 입자를 함유한 반도체 세정폐수의 한외여과 특성[I] -Polysulfone 평판막에 의한 투과분리-)

  • 곽순철;이석기;전재홍;남석태;최호상
    • Membrane Journal
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    • v.8 no.2
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    • pp.102-108
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    • 1998
  • Permeation behavior of the semiconductor rinsing wastewater containing Si particles was examined by ultrafiltration using the polysulfone plate membrane. The permeation flux was gradually decreased with time. It was due to the growth of cake deposited on the membrane surface and the pore plugging by Si particles. Permeation flux of cross flow type was 1.4 times higher than that of the dead end flow type. Nitrogen back flushing which is the removing method of membrane fouling was superior to the water sweeping. With nitrogen back flushing, the decrease of permeation flux due to the fouling was recovered about 85 % to the initial flux in the flat plate membrane system. The rejection rate of Si particles was about 90 % and the size of Si particle in the permeate was about 70 nm.

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Clarification of Apple Vinegar by Ultrafiltration and Flux Charcateristics (한외여과를 이용한 사과식초의 청징화와 투과특성)

  • Kim, Soon-Dong;Chung, Ho-Duck;Choi, Yong-Hee;Youn, Kwang-Sup
    • Applied Biological Chemistry
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    • v.43 no.1
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    • pp.24-28
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    • 2000
  • This study was conducted to evaluate the effect of ultrafiltration (UF) process variables on permeate flux and membrane resistance and to clarify apple vinegar for quality improvement. Apple vinegar was clarified in a laboratory ultrafiltration system with hollow fiber membrane made of polysulfone and MWCO 30,000 and 10,000. The permeate flux increased with the increase of flow rate and the optimum pressure was $1.5\;kgf/cm^2$ in this system. The turbidity of clarified apple vinegar treated UF largely decreased. pH and acidity of treated samples showed the same level as those of untreated apple vinegar. The permeate flux continuously declined while the fouling material accumulated on the membrane as the operation time increased. Resistance decreased with lower pressure, which could be explained by expansion of pore size at lower pressure and minor compaction of the polarized layer at lower pressure.

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A Pilot-Scale Microfiltration/Ultrafiltration system for Drinking Water Treatment (상수처리를 위한 파일롯 규모의 정밀여과/한외여과 시스템)

  • Kim, Hanseung;Oh, Jeongik;Kim, Chunghwan
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.6
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    • pp.770-777
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    • 2004
  • Three pilot-scale membrane systems were operated using lake water as influent in this study. Microfiltration (MF) membrane with pore size of 0.01 m was used in Systen I of which filtration mode was set at constant pressure of $1kgf/cm^2$. Ultrafiltration (UF) membranes with molecular cutoff (MWCO) of 80,000 and 13,000 were used in System II-1 and II-2, respectively. Constant flow mode was applied at the range between 0.7 and $1.5m^3/m^2{\cdot}d$ (average of $1.1m^3/m^2${\cdot}d) for System II-1 and between 0.37 and $1.65m^3/m^2{\cdot}d$ (average of $1.18m^3/m^2{\cdot}d$) for System II-2. In System I, the flux changed from $1m^3/m^2{\cdot}d$ to $0.2m^3/m^2{\cdot}d$ during the operation time of 5 months. System II showed recovery of 94% under the allowable maximum pressure of $3kgf/cm^2$ during the same operation period. From these results, the efficient operation was observed in constant flow mode with respect to filtration time and recovery. Average filtrate turbidity showed 0.0071 NTU in System I and 0.0054 NTU in System II, which implied that high turbidity removal was obtained in both MF and UF systems with no significant difference between MF and UF. From the fact that membrane flux depends largely on membrane type and operation mode, a guideline of optimum design and operation should be suggested for application of membrane systems to full scale water treatment.

Technical Feasibility for Hollow-Fiber Ultrafiltration Water Treatment System and its Economic Aspects (중공사형 한외여과막 수처리 공정의 기능성과 막을 사용한 수처리공정의 경제성에 관한 연구)

  • Wang, Jin-Soo;Kim, Byung-Jick;Choi, Soo Hyoung
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.12-18
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    • 1999
  • This research was undertaken to do the technical and economical feasibility study of membrane water treatment system. For the technical feasibility study, batch water treatment system using UF(ultrafiltration) was set up and several experiments were carried out. The performance of the UF membrane was tested in terms of turbidity. The experimental results showed that the UF membrane process produced less than 1 NTU water regardless of input water turbidity. For the economical feasibility study, the cost model was analyzed and programmed for simulation. Also costs of the membrane water treatment and the conventional treatment were evaluated. The simulation results showed that the unit production cost increased when design flow or permeate flow decreased. The production cost of membrane water treatment system was lower than that of the conventional system. Both technical and economical feasibility study showed that the UF membrane water purification system was a very competitive water purification process.

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Calcium Absorption Accelerating Effect of Chitosnn Oligosaccharides prepared by Ultrafiltration Membrane Enzymatic Reactor (한외여과막 효소반응기를 이용하여 제조한 키토산 올리고당의 칼슘흡수 촉진효과)

  • JEON You-Jin;KIM Gyu-Hyung;PARK Pyo-Jam;KIM Se-Kwon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.32 no.3
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    • pp.247-251
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    • 1999
  • In spite of various bio-functionalities of chitosan, the effects in vivo were still ambiguous because of its low absorption on organism. Therefore, chitosan oligosaccharides (COSs) are necessary to elucidate for an efficient utilization in vivo. COSs were prepared from chitosan using ultrafiltration membrane enzymatic reactor system with MWCO (molecular weight cut-off) 3,000 Da of membrane. Calcium absorption accelerating effect using COSs was examined by two methods, in vitro and in vivo. In vitro experiment, calcium absorption by the addition of COSs in a mixture solution of calcium and phosphate was higher approximately $50\%$ than that by control. In vivo using rats, group taken the diet contained $1\%$ COSs anil calcium chloride decreased about $75\%$ of calcium content excreted from feces, and then, showed about $15\%$ increase in breaking force of femur. These results demonstrated that COSs definitely involved in calcium metabolism in vivo.

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Process Development of Wastewater Containing Silicon Fine Particles by Ultrafiltration for Water Reuse -III. Permeation Characteristics of Pilot Scale Hollow Fiber Membrane Modules- (한외여과에 의한 Si 미립자 함유폐수 재이용 공정개발(III) -Pilot-Scale 중공사막 모듈에 의한 투과 특성)

  • 전재홍;함용규;이석기;박영태;남석태;최호상
    • Membrane Journal
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    • v.9 no.3
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    • pp.185-192
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    • 1999
  • The ultrafiltration characteristics of wafer processing wastewater produced from semicon¬ductor industry was investigated for wastewater reuse. Using the pilot-scale ultrafiltration system con¬taining poly sulfone hollow fiber membranes (MWCO : 10,000, 20,000, 30,(00), the membrane performance, such as flux, rejection rate and concentration factor for flux was examined. The SDhs, turbidity, electrical conductivity and concentration of Si particles were measured, and the possibility of permeate reuse was validated from the experimental results. It was shown that the flux was recovered by the sweeping with air and water effectively. The permeate flux of 30,000 MWCO membrane was about 5 times higher than that of 10,000 and 20,000 MWCO membranes. The concentration of Si particle in the saw wastewater was analyzed 3.8-5.6 mg/$\ell$ and that of Si particle in the permeate was analyzed less than 0.2${\mu}g$/$\ell$. This means the rejection of silicon particle was over 96%.

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Textile Wastewater Treatment by MF-UF Combined Membrane Filtration (MF-UF 분리막 복합공정에 의한 염색가공 폐수처리)

  • Yang, Jeongmok;Park, Chulhwan;Lee, Byunghwan;Kim, Sangyong
    • Clean Technology
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    • v.12 no.3
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    • pp.151-156
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    • 2006
  • Combined membrane process of ceramic microfiltration (MF) and polymer ultrafiltration (UF) was optimized for the removal of color and total organic carbon (TOC) from textile wastewater. Membrane regeneration was performed for the efficient operation by backflushing and chemical cleaning. Flux of 10.3% increased by the pulse backflushing of 1 second every 2 minutes in ceramic microfiltration. Membrane regeneration of 97% was obtained by chemical cleaning with 0.1% sodium hydroxide in polymer ultrafiltration. The removal efficiency of TOC, color and SS (suspended solid) were 84.6%, 97.4% and 100%, respectively. The combined process was found to be suitable for the removal of color and residual organics from textile wastewater.

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Effect of Coagulation in Coagulation/Ultrafiltration Hybrid System in Water Treatment Process (정수처리용 응집.한외여과 혼성공정에서 응집 효과에 관한 연구)

  • Moon, Seong-Yong;Lee, Sang-Hyub;Kim, Seung-Hyun;Yoon, Cho-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.8
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    • pp.837-843
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    • 2005
  • Coagulation influence was evaluated as the pretreatment for ultrafiltration. Coagulation was expected to improve water quality, reduce membrane fouling and increase backwash effect. Continuous operation of UF was employed in order to investigate the influence of coagulation. Alum, PACS and Ferric chloride were used as coagulants separately. From the result of the research, coagulation can improve the treated water quality greatly. Organic removal was increased more than turbidity and showed an improvement of 30.6% at most. All three coagulants presented conspicuous reduction of membrane fouling, among which PACS was the most effective with long term run. Backwash effect differed with different coagulants while Ferric chloride turned out to be the most effective one. The optimum dosage of coagulant resulted in the highest backwash efficiency.