• Title/Summary/Keyword: Ultra-high-performance

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Improved Calibration for the Analysis of Emerging Contaminants in Wastewater Using Ultra High Performance Liquid Chromatography and Time-of-Flight Mass Spectrometry

  • Pellinen, Jukka;Lepisto, Riikka-Juulia;Savolainen, Santeri
    • Mass Spectrometry Letters
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    • v.9 no.3
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    • pp.77-80
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    • 2018
  • The focus of this paper is to present techniques to overcome certain difficulties in quantitative analysis with a time-of-flight mass spectrometer (TOF-MS). The method is based on conventional solid-phase extraction, followed by reversed-phase ultra high performance liquid chromatography of the extract, and mass spectrometric analysis. The target compounds included atenolol, atrazine, caffeine, carbamazepine, diclofenac, estrone, ibuprofen, naproxen, simazine, sucralose, sulfamethoxazole, and triclosan. The matrix effects caused by high concentrations of organic compounds in wastewater are especially significant in electrospray ionization mass spectroscopy. Internal-standard calibration with isotopically labeled standards corrects the results for many matrix effects, but some peculiarities were observed. The problems encountered in quantitation of carbamazepine and triclosan, due to nonlinear calibration were solved by changing the internal standard and using a narrower mass window. With simazine, the use of a quadratic calibration curve was the best solution.

Flexural behavior of UHPC-RC composite beam

  • Wu, Xiangguo;Lin, Yang
    • Steel and Composite Structures
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    • v.22 no.2
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    • pp.387-398
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    • 2016
  • In order to evaluate the effects of U shape ultra high performance concrete (UHPC) permanent form on the behaviors of Reinforced Concrete (RC) beam, a full scale RC composite beam is designed and tested with U shape UHPC permanent form and a reference RC beam with same parameters is tested simultaneously for comparison. The effects of the permanent form on the failure mode, cracking strength, ultimate capacity and deformation are studied. Test results shows that the contributions of the U shape UHPC permanent form to the flexural cracking behaviors of RC beam are significant. This study may provide a reference for the design of sustainable RC beam with high durable UHPC permanent form.

Strength Characteristics of Ultra High Performance Concrete at early age

  • Kim, Sung-Wook;Park, Jung-Jun;Ryu, Guem-Sung;Koh, Kyoung-Taek;Hong, Ki-Nam
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.563-564
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    • 2009
  • Ultra-High Performance Concrete (UHPC) compared to normal concrete is exhibiting extremely high strength characteristics with compressive strength and tensile strength reaching 200MPa and 15MPa, respectively. The mechanical characteristics of UHPC can be thus exploited advantageously in the construction of structure through the reduction of the cross-sectional area and fabrication of slim and light-weight of the structural members. In the case where the structural member is made of UHPC, the occurrence of crack can be prevented by releasing the restraint provided by the form in due time. This research performs parametric study of the failure characteristics of concrete such as failure energy and softening curve suggested by the viscous crack model approximating the failure of concrete. The scope of this research contains the results of tests performed to investigate the strength of UHPC during early elapsed time.

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Impact resistant properties of Kagome truss reinforced composite panels

  • Choi, Jeong-Il;Park, Se-Eon;Lee, Sang-Kyu;Kim, Gyu-Yong;Hwang, Jae-Seung;Lee, Bang Yeon
    • Advances in concrete construction
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    • v.12 no.5
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    • pp.391-398
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    • 2021
  • This paper presents an experimental study exploring impact resistant properties of Kagome truss reinforced composite panels. Three types of panels with different materials and reinforcements, i.e., ultra-high-performance mortar, steel fiber, and Kagome truss, were designed and manufactured. High-velocity projectile impact tests were performed to investigate the impact response of panels with dimensions of 200 mm×200 mm×40 mm. The projectile used in the testing was a steel slug with a hemispherical front; the impact energy was 1 557 J. Test results showed that the Kagome truss reinforcement was effective at improving the impact resistance of panels in terms of failure patterns, damaged area, and mass loss. Synergy effects of a combination of Kagome truss and fiber reinforcements for the improvement of impact resistance capacity of ultra-high-performance mortar were also observed.

Effect of environmentally friendly materials on steel corrosion resistance of sustainable UHPC in marine environment

  • Tahwia, Ahmed M.;Elgendy, Gamal M.;Amin, Mohamed
    • Structural Engineering and Mechanics
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    • v.82 no.2
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    • pp.133-149
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    • 2022
  • This study investigates the resistance of sustainable ultra-high performance concrete (UHPC) on steel reinforcement corrosion. For enhancing the sustainability of UHPC, concrete mixes were prepared with ordinary Portland cement main binder, and mixes with moderate to high percentages of blast furnace cement (CEM III), fly ash (FA), and slag cement as partial replacements of the full quantity of the used cement. Linear polarization resistance technique was employed to estimate the electrochemical behavior of the concrete specimens. Results showed that the compressive strength and the resistance of steel to corrosion in marine environments can be enhanced by improving the sustainability of UHPC through incorporation of CEM III, FA, and slag cement. FA replacement of up to 50% with the addition of 15% SF content produced better compressive strength and steel corrosion resistance than slag cement whether with the use of ordinary Portland cement or blast furnace cement as the main binder.

Shear behavior of a demountable bolted connector in steel-UHPC lightweight composite structures

  • Gu, Jin-Ben;Wang, Jun-Yan
    • Structural Engineering and Mechanics
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    • v.81 no.5
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    • pp.551-563
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    • 2022
  • Bolted connector could be an alternative to replace the conventional welded headed stud in steel-ultra high performance concrete (UHPC) lightweight composite structures. In this paper, a novel demountable bolted shear connector, consisting of a high-strength bolt (HSB) and a specially-designed nut which is pre-embedded in a thin UHPC slab, is proposed, which may result in the quick installation and disassembly, due to the mountable, demountable and reusable features. In order to study the shear behavior of the new type of bolted shear connector, static push-out tests were conducted on five groups of the novel demountable bolted shear connector specimens and one group of conventional welded headed stud specimen for comparison. The effect of the bolt shank diameter and aspect ratio of bolt on failure mode, shear stiffness, peak slip at the steel-UHPC interface, shear strength and ductility of novel bolted connectors is investigated. Additionally, design formula for the shear strength is proposed to check the suitability for assessment of the novel demountable bolted shear connectors.

Effect of Superplasticizer on Setting Time and compressive strength of Ultra High Performance Concrete (고성능 감수제 종류에 따른 초고성능 섬유보강 콘크리트의 응결 및 압축강도에 미치는 영향)

  • Baek, Sung-Jin;Hyun, Seung-Yong;kim, Jong;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.65-66
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    • 2022
  • In this study, the setting characteristics of the high range water reducing agent to minimize the retardation of UHPC were confirmed to minimize the setting time in the hardening of UHPC. As a result of the study, there was a slight change depending on the difference in the type of Superplasticizer, K > P > D = S > E in the order of condensation promotion, and E > S = D = K > P on the 28th day.

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Bit Interleaver Design of Ultra High-Order Modulations in DVB-T2 for UHDTV Broadcasting (DVB-T2 기반의 UHDTV 방송을 위한 초고차 성상 변조방식의 비트 인터리버 설계)

  • Kang, In-Woong;Kim, Youngmin;Seo, Jae Hyun;Kim, Heung Mook;Kim, Hyoung-Nam
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.39A no.4
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    • pp.195-205
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    • 2014
  • The ultra-high definition television (UHDTV) has been considered as a next generation broadcsating service. However the conventional digital terrestrial transmission system cannot afford the required transmission data rate of UHDTV, and thus adopting ultra-high order constellation, such as 4096-QAM, into the conventional DTT systems has been studied. In particular, when the ultra-high order constellation is adopted into the digital video broadcasting-2nd generation terrestrial (DVB-T2) unequal-error protection (UEP) properties of a codeword of an error correction coding and ultra-high order constellations should be properly matched by bit mapper in order to enhance the decoding performance. Because long codeword results in a heavy computational complexity to design the bit mapper, the DVB-T2 divided it into cascaded blocks, the bit interleaver and the bit-to-cell DEMUX, and there have been many researches related to each block. However, there are few published study related to design methodology of bit interleaver. In this respect, this paper proposes a design methodology of the bit interleaver and presents bit interleavers of 1024-QAM and 4096-QAM according to the proposed design algorithm. The newly designed interleavers improved the decoding performance of the error correction coding by maximally 0.6 dB SNR over both of AWGN and random fading channel.

A Fundamcntal Study on the Propertice of High Performance Concrete using High Flowable Portland Cement (고유동포틀랜드시멘트를 이용한 고성능콘크리트의 기초적 특성에 관한연구)

  • 홍성윤;김병권;박춘근;조동원
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.10a
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    • pp.45-49
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    • 1995
  • The fundamental properties of High Performance Concrete(HPC) were studied using high flowable portland cement which was developed at the Sangyong Cement Ind. Co.,Ltd. The results obtained are as follows. (1)The slump of HPC using high flowable portland cement maintains for 120min. (2)Ultra high strength greater than 800kg/$\textrm{cm}^2$ can be designed without using silica fume and other additives. (3)The value of drying shrinkage and adiabatic temperature rise of HPC are less than those of concrete made with OPC.

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The rapid determination of PAHs in foods using ultra high performance liquid chromatography (UHPLC를 이용한 식품 중의 PAHs 신속분석법)

  • Ha, Jae-Ho;Shin, Dong-Bin;Hwang, Jin-Bong;Seo, Hye-Young;Ito, Masahito;Nakagawa, Hiroaki
    • Analytical Science and Technology
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    • v.24 no.4
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    • pp.266-274
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    • 2011
  • Using a Hitachi LaChrom Ultra 2000U, a reverse phase ultra high performance liquid chromatography (u-HPLC) method was developed for the rapid quantification of 14 PAHs in foods. The proposed method for PAH analysis is based on solid phase extraction (SPE) cartridges; the determination was carried out by u-HPLC with fluorimetric detection. The method was very sensitive; PAH concentration levels were in a low ${\mu}g$/kg range and could be detected and quantified. Six samples of food were analyzed. Among PAHs, PHE was found in most of samples, the concentration ranging from 2.5 to 19.9 ${\mu}g$/kg. The contents of benzo[c]fluorine (BCL), pyrene (PYR), benzo[a]anthracene (BaA), chrysene (CHR), benzo[b]fluoranthene (BbF), benzo[k]fluoranthene (BkF) were low at the '${\mu}g$/kg' level or were less than LOD.