• Title/Summary/Keyword: Ultra-fine

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Grinding Kinetics of Calcite, Pyrophyllite and Talc During Stirred Ball Milling - Consideration of Selection Function (교반 볼밀에 의한 방해석, 납석, 활석의 분쇄 시 분쇄속도론에 관한 연구 - 선택함수의 고찰)

  • Choi, Hee-Kyu;Kim, Seong-Soo;Hwang, Jin-Yeon
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.2 s.52
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    • pp.135-145
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    • 2007
  • The needs for the ultra fine particles have been increased in preparation field of raw powders such as fine ceramics and high functional products. In this study, a series of wet grinding experiments were carried out on inorganic powders such as calcite, pyrophyllite and talc by a stirred ball mill. The particle size distribution of ground products of each test material fur a given grinding time was found to be expressed by the grinding rate (selection function) which was obtained from the grinding kinetics analysis. The median diameter decreased from 6.49 to $0.47{\mu}m$ in calcite, and decreased from 3.91 to $1.14{\mu}m$ in pyrophyllite. However, in talc, median diameter was decreased a little bit from 10.30 to $6.67{\mu}m$. The grinding rate changing on calcite and pyriphyllite were similar at the same conditions. However, in the case of talc, it was observed that the grinding rate was not increased compared to other samples.

Binderless Consolidation of Fine Poly-Si Powders for the Application as Photovoltaic Feedstock (태양전지(太陽電池) 원재료(原材料)로 사용(使用)하기 위한 폴리실리콘 미세분말(微細粉末)의 무점결제(無粘結劑) 성형(成形))

  • Shin, Je-Sik;Kim, Dae-Suk;Kim, Ki-Young;Shon, In-Jin;Moon, Byung-Moon
    • Resources Recycling
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    • v.18 no.1
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    • pp.38-43
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    • 2009
  • In this study, binderless consolidation processes of ultra foe Si powder, by-products of making high purity poly-Si in the current method, were systematically investigated for use as economical solar-grade feedstock. The average diameter of the silicon powder was $7.8{\mu}m$. The main contaminants of the fine silicon powder were $SiO_2$ type oxide and humidity. The chemical pretreatment using the HF solution was observed to be effective for the improvement of the compactability of the silicon powder and the density ratio and the strength of the silicon powder compacts. The yield of the binder-free consolidation process increased by 20% under a vacuum condition. In as-received state, the silicon powder were not pure enough to be used as solar grade feed-stock material. After the dry chemical treatments, a sufficiently high purity above solar-grade was able to be achieved.

Study on The Synthesis of The Ultra-Fine (Ni, Zn)-ferrite by The Hydrothermal Method and its $CO_2$ Decomposition (수열합성법에 의한(Ni, Zn)-Ferrites의 초미세분말 합성공정 및 $CO_2$분해 특성 연구)

  • Kim, Jeong-Sik;An, Jeong-Ryul;Ryu, Ho-Jin
    • Korean Journal of Materials Research
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    • v.10 no.3
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    • pp.223-226
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    • 2000
  • The oxygen deficient ferrites $(Ni_x,\; Zn_{1-x})Fe_2O_{4-{\delta}}$ can decompose $CO_2$ as C and $O_2$ at a low temperature of about $300^{\circ}C$. Ultra powders of $(Ni_x,\; Zn_{1-x})Fe_2O_4$ for the $CO_2$ decomposition were prepared by the hydrothermal methods. The XRD result of synthesized ferries showed the spinel structure of ferrites and ICP-AES and EDS quantitative analyses showed the composition similar with the starting molar ratios of the mixed solution prior to reaction. The BET surface area of the synthesized(Ni, Zn)-ferrites was above $110\textrm{m}^2/g$ and its particle size was very as small as about 5~10 nm. The $CO_2$ decomposition efficiency of the oxygen deficient ferrites($(Ni_x,\;Zn_{1-x})Fe_2O_{4-{\delta}}$) was almost independent with composition and the $CO_2$ decomposition efficiency of ternary (Ni, Zn)-ferrites was better than of binary Ni-ferrites.

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Electron Microscopical Observation of Transglutaminase-treated Ultra High Temperature Milk Sedimiment (Transglutaminase로 처리한 초고온 살균유 침전물의 전자현미경적 관찰)

  • Moon, Jeong-Han;Hong, Youn-Ho
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.8
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    • pp.1359-1366
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    • 2004
  • Ultra high temperature treated (UHT) skim milk and colloidal calcium phosphate-free skim milk were treated with microbial transglutaminase (TGase), ultracentrifuged at various rates, lyophilized, and observed for morphological properties with a scanning electron microscope (SEM). UHT skim milk showed small holes of associated micelles at lower centrifugal rates, and became thick and irregular, and fine particles were associated regularly at higher centrifugal rates. When UHT skim milk with TGase was incubated for 1 hour, casein micelles aggregated and broadened as centrifugation rate increased. When UHT skim milk with TGase was incubated for 8 hours, casein micelles were associated irregularly to large aggregates and widened. Colloidal calcium phosphate-free skim milk with TGase incubated for 1 hour and separated by two-step centrifugation showed aggregated lump, while the milk incubated for 8 hours with TGase was associated with broadened, compact, and regular layers as the centrifugation rate increased. Such phenomena were caused by heat treatment, protein crosslinking reaction catalyzed by TGase and conformational changes of casein molecules, and could be dependent on reaction time, temperature and ultracentrifugation rate.

A Study on Durability Characteristics for Plungers of Conventional Ceramic and Surface Modification by Powder Coating Using High Velocity Oxygen Fuel Thermal Spray (기존 세라믹 및 초고속 용사 분말피막 표면개질 플런저의 내구성 특성에 관한 연구)

  • Bae, Myung-whan;Park, Byoung-ho;Jung, Hwa
    • Transactions of the Korean Society of Automotive Engineers
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    • v.24 no.3
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    • pp.285-293
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    • 2016
  • The high velocity oxygen fuel(HVOF) thermal spray is a kind of surface modification techniques to produce the sprayed coating layer. This process is to form the coating layer after spraying the powder to molten or semi-molten state by the ultra-high speed at the high-temperature heat source and conflicting with a substrate. The efficiency of thermal spraying is dropped, however, because the semi-molten powder in a spray process become a factor that degrades the mechanical property by the formed pore within the coating layer. Therefore, it is necessary to melt completely the thermal spray powder in order to produce the coating layer with an optimal adhesive force. In this study, to improve the wear resistance, corrosion resistance and heat resistance, the plungers of high-speed and ultra-high pressure reciprocating hydraulic pumps used in ironworks are manufactured with STS $420J_2$ and are coated by the powders of WC-Co-Cr and WC-Cr-Ni including the WC of high hardness using a HVOF thermal sprayer developed in this laboratory. These are called by the surface-modified plungers. The surface roughness, hardness, and surface and cross-sectional microstructure of these two surface-modified and conventional ceramic plungers are measured and compared before operation with after operation for 100 days. It is found that the values of centerline average surface roughness and maximum height for conventional ceramic plunger are 9.5 to 10.8 and 5.2 to 5.7 times higher than those of surface-modified ones coated by WC-Co-Cr and WC-Cr-Ni because the fine tops and bottoms on surface roughness curve of conventional ceramic plunger are approximately 100 times higher than those of surface-modified ones. In addition, the pores and scratches in the surface microstructure are considerably formed in the order of conventional ceramic, WC-Cr-Ni and WC-Co-Cr surface-modified plungers. The greater the WC content of high hardness powder is less the change in the plunger surface.

A Study on the Fundamental Properties of Ultra Rapid Hardening Mortar using Coal-Ash (잔골재 대체재로서 석탄회를 이용한 초속경 보수모르타르의 기초적 특성에 관한 연구)

  • Lee, Gun-Cheol;Oh, Dong-Uk;Kim, Young-Geun;Cho, Chung-Ki
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.1
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    • pp.128-135
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    • 2011
  • In this study, in order to develop ultra rapid hardening mortar(URHM) for tunnel repairs using bottom ash of low recycle ratio and Admixture as Eco concept, fundamental properties of URHM on temperature condition of construction field were performed. Test result, URHM of three types for fluidity and setting time were as in the following : B > C > A. Those for low temperatures were later than the standard condition. Compressive, bending and bond strength were similar with three types as follow. In compressive strength, initial strength of the low were smaller than the standard but the low in the long-term were similar with the standard. On the contrary to this, bending strength were similar in initial strength but the low in the long-term were smaller than the standard. The low in bond strength was average 35% less than the standard. Length changes was as in the following : A > C > B. the low is two times much as the standard but the case using blast furnace slag particles noticeably reduced length changes. Water absorption coefficient and water vapor resistance were as in the following : C > A > B. In case of URHM added bottom ash, water absorption coefficient and water vapor resistance were increased because bottom ash is porous material.

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Counting and Localizing Occupants using IR-UWB Radar and Machine Learning

  • Ji, Geonwoo;Lee, Changwon;Yun, Jaeseok
    • Journal of the Korea Society of Computer and Information
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    • v.27 no.5
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    • pp.1-9
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    • 2022
  • Localization systems can be used with various circumstances like measuring population movement and rescue technology, even in security technology (like infiltration detection system). Vision sensors such as camera often used for localization is susceptible with light and temperature, and can cause invasion of privacy. In this paper, we used ultra-wideband radar technology (which is not limited by aforementioned problems) and machine learning techniques to measure the number and location of occupants in other indoor spaces behind the wall. We used four different algorithms and compared their results, including extremely randomized tree for four different situations; detect the number of occupants in a classroom, split the classroom into 28 locations and check the position of occupant, select one out of the 28 locations, divide it into 16 fine-grained locations, and check the position of occupant, and checking the positions of two occupants (existing in different locations). Overall, four algorithms showed good results and we verified that detecting the number and location of occupants are possible with high accuracy using machine learning. Also we have considered the possibility of service expansion using the oneM2M standard platform and expect to develop more service and products if this technology is used in various fields.

Exposure status of welding fumes for operators of overhead traveling crane in a shipyard (대형조선소 천장크레인 운전원의 용접흄 노출 실태)

  • Lee, Kyeongmin;Kim, Boowook;Kwak, Hyunseok;Ha, Hyunchul
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.25 no.3
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    • pp.301-311
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    • 2015
  • Objectives: Operators of overhead traveling crane in a ship assembly factory perform work to transmit large vessel blocks to an appropriate working process. Hazardous matters such as metal dusts, carbon monoxide, carbon dioxide, ozone, loud noise and fine particles are generated by variable working activities in the factory. The operators could be exposed to the hazardous matters during the work. In particular, welding fumes comprised of ultra fine particles and heavy metals is extremely hazardous for humans when exposing a pulmonary through respiratory pathway. Occupational lung diseases related to welding fumes are increasingly on an upward tendency. Therefore, the objective of this study is to assess properly unknown occupational exposure to the welding fumes among the operators. Methods: This study intended to clearly determine an equivalence check whether or not chemical constituents and composition of the dusts, which existed in the driver's cab, matched up with generally known welding fumes. Furthermore, computational fluid dynamics program(CFD) was used to identify a ventilation assessment in respect of a contamination distribution of welding fumes in the air. The operators were investigated to assess personal exposure levels of welding fumes and respirable particulate. Results: The dust in an operation room were the same constituents and composition as welding fumes. Welding fumes, which caused by the welding in a floor of the factory, arose with an ascending air current up to a roof and then stayed for a long time. They were considered to be exposed to the welding fumes in the operation room. The personal exposure levels of welding fumes and respirable particulate were 0.159(n=8, range=0.073-0.410) $mg/m^3$ and 0.138(n=8, range=0.087-0.178) $mg/m^3$, respectively. They were lower than a threshold limit value level($5mg/m^3$) of welding fumes. Conclusions: These findings indicate that an occupational exposure to welding fumes can exist among the operators. Consequently, we need to be keeping the operators under a constant assessment in the operator process of overhead traveling crane.

On-Road Investigation of PM Emissions of a City-Buses Fuelled by Diesel, CNG, and LPG Using a Mobile Emission Laboratory (이동형 배출가스 측정시스템(MEL)을 이용하여 디젤, CNG, LPG 시내버스에서 배출되는 입자상 물질 평가)

  • Lee, Seok-Hwan;Kim, Hong-Suk;Park, Jun-Hyuk;Yoon, Jun-Kyu
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.4
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    • pp.409-416
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    • 2011
  • A mobile emission laboratory (MEL) was designed to measure the amount of traffic pollutants with high temporal and spatial resolution under real conditions. Equipment for gas-phase measurements of quantity of CO, NOx, $CO_2$, and THC and for the measurement of the number density and size distribution of fine and ultra-fine particles by a FMPS and a CPC were placed in a mini-van. The exhaust of different type of vehicles can be sampled by MEL. This paper describes the construction and technical details of the MEL and presents data from the experiment in which a car chases city buses fuelled by diesel, CNG, and LPG. The diameters of most particles in the exhaust of the diesel city bus were less than 300 nm and most of the particles had a diameter of 30-60 nm. However, most particles in the exhaust of the CNG and LPG city buses were nanoparticles (diameter: less than 50 nm).

Size-resolved Source Apportionment of Ambient Particles by Positive Matrix Factorization at Gosan, Jeju Island during ACE-Asia (PMF 분석을 이용한 ACE-Asia 측정기간 중 제주 고산지역 입자상 물질의 입경별 발생원 추정)

  • Moon K.J.;Han, J.S.;Kong, B.J.;Jung, I.R.;Cliff Steven S.;Cahill Thomas A.;Perry Kelvin D.
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.5
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    • pp.590-603
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    • 2006
  • Size-and time-resolved aerosol samples were collected using an eight-stage Davis rotating unit for monitoring (DRUM) sampler from 23 March to 29 April 2001 at Gosan, Jeju Island, Korea, which is one of the super sites of Asia-Pacific Regional Aerosol Characterization Experiment(ACE-Asia). These samples were analyzed using synchrotron X-ray fluorescence for 3-hr average concentrations of 19 elements including Al, Si, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, As, Se, Br, Rb, and Pb. The size-resolved data sets were then analyzed using the positive matrix factorization(PMF) technique to identify possible sources and estimate their contributions to particulate matter mass. PMF analysis uses the uncertainty of the measured data to provide an optimal weighting. Twelve sources were resolved in eight size ranges($0.09{\sim}12{\mu}m$) and included continental soil, local soil, sea salt, biomass/biofuel burning, coal combustion, oil combustion, municipal incineration, nonferrous metal source, ferrous metal source, gasoline vehicle, diesel vehicle, and volcanic emission. The PMF result of size-resolved source contributions showed that natural sources represented by local soil, sea salt, continental soil, and volcanic emission contributed about 79% to the predicted primary particulate matter(PM) mass in the coarse size range ($1.15{\sim}12{\mu}m$) while anthropogenic sources such as coal combustion and biomass/biofuel burning contributed about 58% in the fine size range($0.56{\sim}2.5{\mu}m$). The diesel vehicle source contributed mostly in ultra-fine size range($0.09{\sim}0.56{\mu}m$) and was responsible for about 56% of the primary PM mass.