• Title/Summary/Keyword: UV and thermal aging

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A Study on the Age Degradation Kinetics of Pole Transformer Oil (주상변압기 절연유의 경년열화반응 속도론에 관한 연구)

  • 남영우
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.11 no.1
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    • pp.99-105
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    • 1997
  • In the paper, aging of insulating oil in pole transformer has been studied by performing accelerated thermal aging test. Dissolved gases were extracted by air bubbling method. Concentration of dissolved gases were modified by extraction ratio of each gases in insulating oil. Aging of insulating materials were proceeded by thermal degradation and oxidation reaction. Both of the reactions followed zeroch order kinetics. Formation rate equations for hydrocarbons, carbon oxides, and hydrogen were derived. It was conformed by gas analysis and UV-Visible spectrophotometric method that iron core and copper coil in pole transformer act as catalyst during the aging process.

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전기집진기술의 현황과 장래전망(I)

  • 고명삼;이달우
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.11 no.1
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    • pp.24-33
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    • 1997
  • In this paper, aging of insulating oil in pole transformer has been studied by performing accelerated thermal aging test. Dissolved gases were extracted by air bubbling method. Concentration of dissolved gases were modified by extraction ratio of each gases in insulting oil. Aging of insulting materials were proceeded by thermal degradation and oxidation reaction. Both of the reactions followed zeroth order kinetics. Formation rate equations for hydrocarbons, carbon oxides, and hydrogen were derived. It was conformed by gas analysis and UV-visible spectrophotometric method that iron core and copper coil in pole transformer act as catalyst during the aging process.

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Resistance Activity of Kyung-Ok-Ko on Thermal Stress in C. elegans (경옥고(瓊玉膏)의 열 스트레스에 의한 피부노화 억제 활성)

  • Won-Seok Jung;Sung-Young Cho;Hyun-Woo Cho;Hee-Woon Lee;Young‐IL Jeong;Hee-Taek Kim;Young-Bob Yu
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.37 no.1
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    • pp.17-28
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    • 2024
  • Objectives : This study was conducted to reveal the scientific mechanism of the anti-skin aging activity of Kyung-Ok-Ko(KOK), which is highly useful as a Korean traditional medicine and functional food. Methods : The skin wrinkle and aging inhibitory activity of KOK was confirmed through in vitro experiments of human dermal fibroblast neonatal cell(HDFn) and in vivo of C. elegans, and hairless mouse(SKH-1). Results : The amount of the C-terminus of the collagen precursor in the HDFn cell culture medium treated with KOK using an enzymes-linked immunoassay kit. The group treated with KOK 200㎍/㎖ was a 28.3% increase of collagen precursor compared to the control group. KOK showed inhibitory activity of MMP-1 compared to the control group at a concentration of 200㎍/㎖. In addition, KOK 200㎍/㎖ showed significant inhibitory activity of thermal stress and an oxidative stress compared to the control group in C. elegans. Furthermore, KOK showed a concentration-dependent(100mg/kg and 500mg/kg) anti-wrinkle formation effect in UV-irradiated hairless mouse(SKH-1). Additionally, when KOK was administered to UV-irradiated hairless mice, an increase in procollagen -1 and -3 genes expression was observed, and mmp-1 and mmp-9 genes, which increase collagen decomposition, decreased with the administration of KOK. Conclusions : The skin aging inhibition mechanism of Kyung-Ok-Ko(KOK) is presumed to be achieved through suppressing thermal stress and oxidative stress, suppressing mmp-1 and mmp-9 genes, and increasing procollagen-1 and procollagen-3.

Effects of UV and Ozone on the Weathershed for Polymer Insulators (폴리머애자 갓 재료에 미치는 자외선 및 오존의 영향)

  • 이병성;한재홍;한용희;한상옥;윤여숭
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.63-66
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    • 1999
  • The effects of UV and ozone on the weathershed materials for 5 polymer insulators were investigated. This study was carried by material characterizations such as surface microstructure, thermal property, chemical structure and contact angle. The aged specimens are compared with new ones. In case of UV, the chalking of fillers and cracking of surface were increased with the increase of UV radiation time. In case of ozone, aged specimens are not different from new ones. From this study, It can be concluded that UV has more effect on the surface properties of weathershed materials than ozone.

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Effect of Electrical Properties on the EPDM- $Al(OH)_3$ Composite by UV Accelerated weathering (Al(OH)3가 EPDM의 자외선 촉진열화에 미치는 전기적 특성평가)

  • Shim, Dae-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.243-247
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    • 2003
  • The effect of accelerated weathering(UV) on three type of ethylene propylene diene monomer(EPDM) composite used for higher voltage insulator were investigated by weather-emoter. For weatherability of EPDM composite, surface resistance, dielectric breakdown strength, change of contact angle, surface composition were measured according to UV accelerated weathering time. From the resort of the measurement of surface resistivity, contact angle of EPDM composite decreased and showed chalking and cracking phenomenon when UV weathweing time was for 1500 h and 2000 h. The analysis of surface atomic composition indicated that surface aluminiu(Al) content was detected due to chalking phenomenon after 1500 h of UV weathering, Oxygen content of all composite increased due to the oxidation.

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A SPECTROSCOPIC STUDY OF THE OPTICAL PROPERTIES OF VARIOUS PAPERS MADE FROM RECLAIMED FIBRES

  • Ingegerd Forsskahl;Carola Olkkonen;Henrik Tylli
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.04b
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    • pp.296-301
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    • 1999
  • Different papers such as toilet and towel tissue, newsprint and copy paper made from reclaimed fibres were characterized using UV-VIS reflectance and fluorescence spectroscopy. The emission properties of the extracts of the papers were also evaluated. Photochemical irradiation at ambient temperatures, and thermal aging of the copy papers at 105$^{\circ}C$ and 150$^{\circ}C$ were performed. Post-colour numbers (PC) were calculated from the reflectance values measured from the corresponding UV-VIS reflectance spectra. Light absorption coefficient spectra were calculated before and after irradiation, and the changes in absorption coefficient were related to the content of chromophores in the papers. Photochemical and thermal discolouration of the copy papers, similar to that of virgin fibres, was readily observed. The influence of changes in the concentrations of fluorescent brightening agents and dyes on the spectral properties was also assessed. Photostabilization studies of the copy papers were performed with the use of polymer additives polyethylene glycol (PEG) and polytetrahydrofuran (PTHF).

Synthesis, Curing and Properties of Silicone-Epoxies

  • Huang, Wei;Yuan, Youxue;Yu, Yunzhao
    • Journal of Adhesion and Interface
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    • v.7 no.4
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    • pp.39-44
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    • 2006
  • A new kind of silicone-epoxy composite is reported in this research. The silicone-epoxy resin was synthesized by the hydrosilylation of tetramethycyclotetrasiloxane and 4-vinyl-1-cyclohexene 1,2-epoxy with a high reaction yield. It was found that the obtained silicone-epoxy resin shows a high reactive activity to the aluminum complex-silanol catalyst. The resin could be cured under the catalysis of $(Al(acac)_3/Ph_2Si(OH)_2$ at a concentration below 0.1 wt% to give a hard cured resin showing excellent optical clarity, UV resistance and thermal stability. It was also found that the Si-H groups facilitated the curing reaction and the silicone-epoxy resin bearing Si-H group could be cured effectively even if $Ph_2Si(OH)_2h$ was absent. Moreover, the UV resistance and thermal stability were improved significantly by the introduction of Si-H groups. This is possibly due to the reductive property of Si-H groups which can annihilate radical and peroxide effectively. This kind of silicone-containing epoxy composite might have very promising applications as optical resin, optical adhesive and encapsulation materials for electronic devices.

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Temperature Characteristics and Annealing Process of the Waveguide Bragg Grating (광도파로 브래그 격자의 온도특성과 열처리 공정)

  • 한준모;서영진;백세종;노흥렬;임기건;최두선
    • Transactions of Materials Processing
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    • v.13 no.3
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    • pp.205-210
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    • 2004
  • The waveguide Bragg gratings have been fabricated by the phase-mask method. An excimer laser with maximum 600mJ output pulse energy and uniform phase masks have been used. Hydrogen loading is often used for enhancing the uv photosensitivity of the core, however, the resultant gratings show significant aging effect. In the present study, high temperature thermal annealing process has been investigated to obtain thermal gratings and process parameters are deduced.

Inter-lamina Shear Strength of MWNT-reinforced Thin-Ply CFRP under LEO Space Environment

  • Moon, Jin Bum;Kim, Chun-Gon
    • Composites Research
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    • v.30 no.1
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    • pp.7-14
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    • 2017
  • In this paper, the inter-lamina shear strength (ILSS) of multi-wall carbon nanotube (MWNT) reinforced carbon fiber reinforced plastics (CFRP) and thin-ply composites were verified under low earth orbit (LEO) space environment. CFRP, MWNT reinforced CFRP, thin-ply CFRP and MWNT reinforced thin-ply CFRP were tested after aging by using accelerated ground simulation equipment. The used ground simulation equipment can simulate high vacuum ($2.5{\times}10^{-6}torr$), atomic oxygen (AO, $9.15{\times}10^{14}atoms/cm^2{\cdot}s$), ultraviolet light (UV, 200 nm wave length) and thermal cycling ($-70{\sim}100^{\circ}C$) simultaneously. The duration of aging experiment was twenty hours, which is an equivalent duration to that of STS-4 space shuttle condition. After the aging experiment, ILSS were measured at room temperature ($27^{\circ}C$), high temperature ($100^{\circ}C$) and low temperature ($-100^{\circ}C$) to verify the effect of operation temperature. The MWNT and thin-ply shows good improvement of ILSS at ground condition especially with the thin-ply. And after LEO exposure large degradation of ILSS was observed at MWNT added composite due to the thermal cycle. And the degradation rate was much higher under the high temperature condition. But, at the low temperature condition, the ILSS was largely recovered due to the matrix toughening effect.

Study on Coloring and Aging Pattern of Bongchae used for Conservation Treatment of Paper Cultural Properties (지류문화재의 보채에 쓰이는 봉채의 채색 및 열화 양상 연구)

  • Song, Jung Won;Kim, Myoung Nam;Lee, Jang Jon
    • Journal of Conservation Science
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    • v.35 no.5
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    • pp.416-429
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    • 2019
  • Bongchae is primarily employed for toning, which is the last step in the conservation treatment of paper's cultural properties. The objective of this study is to identify the coloring patterns of four types of Bongchae(Bonram, Gamboge, Yeonji, and Daeja) and determine the associated color change patterns through accelerated aging experiments. By examining the coloring patterns, it is observed that Yeonji, Bonram, and Daeja are painted as particles, whereas Gamboge indicates a close state of coating. Results obtained from X-ray diffraction analysis of Bongchae indicate that the presence of quartz, calcite, and pyrophyllite can be equally detected in Bonram, Yeonji, and Daeja. Additionally, the presence of goethite is also detected in Daeja. Gamboge becomes discolored from yellow to orange color during wet thermal aging, and Gamboge and Yeonji become decolorized during UV irradiation aging. Hence, cultural properties of paper colored with Gamboge can be predicted to become discolored to orange color by alkalis and can be darkened by UV rays because the decolorization of Gamboge and Yeonji occurs preferentially.