• Title/Summary/Keyword: UV Radiation

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FIR Observations and Simple LVG Modeling Results of L1448-MM

  • Lee, Jin-Hee;Lee, Jeong-Eun;Lee, Seok-Ho;DIGIT Team, DIGIT Team
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.1
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    • pp.82.2-82.2
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    • 2012
  • We present Herschel-PACS observations of L1448-MM, a Class 0 protostar with a prominent outflow, part of the DIGIT Key Program (PI: N. Evans). We detect numerous emission lines including CO and $H_2O$ rotational transitions, OH transitions, and [OI] forbidden transitions at wavelengths from 55 to 210 ${\mu}m$. The $H_2O$, [OI], mid-J CO (J < 23), and OH emission distributes along the outflow direction although high-J CO and other OH emission peaks at the central spatial pixel. According to our simple excitation analysis, CO seems to have two temperature components of warm and hot, which might be attributed to the PDR and shock, respectively. After exploring a wide range of physical conditions with a non-LTE LVG code, RADEX, we found that either shock alone or the combination of PDR and shock can explain the observations. The relative fraction of observed line luminosities suggest that L1448-MM is shielded from the UV radiation because $H_2O$ and CO are the dominant coolants rather than OH and [OI]. In addition, our observed fluxes match better with C-shock models rather than J-shocks. The non-LTE LVG model supports that the IR pumping process is important for OH transitions because the OH line ratios are fitted much better when the dust thermal continuum is included.

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Antioxidative Activity of Securinega suffruticosa Extract (광대싸리 줄기 추출물의 항산화 활성)

  • Park, Soo-Nam;Kim, Jai-Hyun;Ahn, You-Jin
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.3
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    • pp.269-278
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    • 2009
  • In this study, the anti oxidative effects, inhibitory effects on elastase, and components of Securinega suffruticosa extracts were investigated. The free radical (1,1-diphenyl-2-picrylhydrazyl, DPPH) scavenging activities ($FSC_{50}$) and reactive oxygen species ROS) scavenging activities ($OSC_{50}$) of extract/fractions from Securinega suffruticosa were measured. The aglycone fraction ($9.04\;{\pm}\;0.51\;{\mu}g/mL$) and 50 % ethanol extract ($1.05\;{\pm}\;0.41\;{\mu}g/mL$) showed the most effective scavenging activities. The protective effects on the rose-bengal sensitized photohemolysis of human erythrocytes were investigated. The aglycone fraction exhibited the most prominent cellular protective effect (${\tau}_{50},\;102.77\;{\pm}\;5.37$ min at $10{\mu}g/mL$). The inhibitory effect of ethyl acetate fraction on tyrosinase were of examined ($210.0\;{\pm}\;1.02\;{\mu}g/mL$). The inhibitory effect of aglycone fraction on elastase were also investigated ($17.6\;{\pm}\;1.26\;{\mu}g/mL$). These results indicate that extract/fractions of Securinega suffruticosa can function as antioxidants in biological systems, particularly skin exposed to UV radiation by scavenging $^1O_2$ and other ROS, and protect cellular membranes against ROS. Securinega suffruticosa extract could be used as a new cosmeceutical ingredient for whitening and anti-wrinkle products.

The photocatalytic activities of nano-titanium dioxide on the cotton fabrics for self-cleaning properties

  • Metanawin, Siripan;Metanawin, Tanapak;Panutumrong, Praripatsaya;Hathaiwaseewong, Sunee;Chaichalermvong, Tirapong
    • International Journal of Advanced Culture Technology
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    • v.3 no.1
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    • pp.129-137
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    • 2015
  • The study of photocatalysis of nano titanium dioxideon the cotton fabrics have been investigatedthrough self-cleaning properties. The mini-emulsion technique was employed to prepare the encapsulation of titanium dioxide nano particles in polystyrene beads prior used. The mini-emulsion was coated on the cotton fabrics using Pad-dry method.The loading amount of TiO2particles into the mini-emulsion were various from 1%wt to 40%wt. The particles sizes of the TiO2-encapsulated polystyrene mini-emulsion were investigated by dynamic light scattering. It was noticed that the particle size of the mini-emulsion was in the range of 100- 200 nm. The morphology of treated cotton fabrics were investigated using scanning electron microscopy. The crystal structure of TiO2-encapsulated PS mini emulsion which coated on cotton fabrics were examined by X-ray diffraction spectroscopy. In order to investigate the photocatalytic activities of TiO2 through the selfcleaning characteristics of the cotton fabrics, colorant stains were created on the samples. Coffee stains were used as colorant organic stains. The result shown that the coffee stained on the cotton fabrics significantly showed the improving of the self-cleaning properties under UV radiation.

Synthesis of Hyaluronic Acid Scaffold for Tissue Engineering and Evaluation of Its Drug Release Behaviors (히아루론산을 이용한 조직공학용 Scaffold의 제조와 약물 방출 거동에 관한 연구)

  • Nam, Hye-Sung;Kim, Ji-Heng;An, Jeong-Ho;Chung, Dong-June
    • Polymer(Korea)
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    • v.25 no.4
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    • pp.476-485
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    • 2001
  • In this study, we tried to design and synthesize using natural polymers (hyaluronic acid and sodium alginate) and also to make some kinds of scaffolds as sponge type for reducing the burst effect of loaded drug from them. Photo-dimerizable group was incorporated to hyaluronic acid and degradable hydrogel was prepared by the UV radiation of the polymer. The pore size and its distribution of scaffold were controlled by changing microsphere production conditions such as solution concentration and spraying pressure. It was found that drug release behavior from synthesized scaffolds was affected by hybridization of two naturally originated polymers (cinnamoylated tetrabutylammonium hyaluronate: CHT and cinnamolylated sodium alginate: CSA) and the obtained scaffolds were degraded in fairly long time (about 2 months) under in vitro environment. Therefore, we expect that obtained scaffolds can be applicable for the tissue regeneration scaffolds in the fields of orthopaedic surgery.

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Cytotoxicity of Ultra-pure TiO2 and ZnO Nanoparticles Generated by Laser Ablation

  • Jeong, Minju;Park, Jeong Min;Lee, Eun Jeong;Cho, Yea Seul;Lee, Chunghyun;Kim, Jeong Moo;Hah, Sang Soo
    • Bulletin of the Korean Chemical Society
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    • v.34 no.11
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    • pp.3301-3306
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    • 2013
  • This paper aims to address the cellular toxicity of ultra-pure titanium dioxide ($TiO_2$) and zinc oxide (ZnO) nanoparticles (NPs) frequently employed in sunscreens as inorganic physical sun blockers to provide protection against adverse effects of ultraviolet (UV) radiation including UVB (290-320 nm) and UVA (320-400 nm). In consideration that the production and the use of inorganic NPs have aroused many concerns and controversies regarding their safety and toxicity and that microsized $TiO_2$ and ZnO have been increasingly replaced by $TiO_2$ and ZnO NPs (< 100 nm), it is very important to directly investigate a main problem related to the intrinsic/inherent toxicity of these NPs and/or their incompatibility with biological objects. In the present study, we took advantage of the laser-assisted method called laser ablation for generation of $TiO_2$ and ZnO NPs. NPs were prepared through a physical process of irradiating solid targets in liquid phase, enabling verification of the toxicity of ultra-pure NPs with nascent surfaces free from any contamination. Our results show that $TiO_2$ NPs are essentially non-poisonous and ZnO NPs are more toxic than $TiO_2$ NPs based on the cell viability assays.

An optimized microwave-assisted extraction method for increasing yields of rare ginsenosides from Panax quinquefolius L.

  • Yao, Hua;Li, Xuwen;Liu, Ying;Wu, Qian;Jin, Yongri
    • Journal of Ginseng Research
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    • v.40 no.4
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    • pp.415-422
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    • 2016
  • Background: Rare ginsenosides in Panax quinquefolius L. have strong bioactivities. The fact that it is hard to obtain large amounts of rare ginsenosides seriously restricts further research on these compounds. An easy, fast, and efficient method to obtain different kinds of rare ginsenosides simultaneously and to quantify each one precisely is urgently needed. Methods: Microwave-assisted extraction (MAE) was used to extract nine kinds of rare ginsenosides from P. quinquefolius L. In this article, rare ginsenosides [20(S)-Rh1, 20(R)-Rh1, Rg6, F4, Rk3, 20(S)-Rg3, 20(R)-Rg3, Rk1, and Rg5] were identified by high performance liquid chromatography (HPLC)-electrospray ionization-mass spectrometry. The quantity information of rare ginsenosides was analyzed by HPLC-UV at 203 nm. Results: The optimal conditions for MAE were using water as solvent with the material ratio of 1:40 (w/v) at a temperature of $145^{\circ}C$, and extracting for 15 min under microwave power of 1,600 W. Seven kinds of rare ginsenosides [20(S)-Rh1, 20(R)-Rh1, Rg6, F4, Rk3, Rk1, and Rg5] had high extraction yields, but those of 20(S)-Rg3 and 20(R)-Rg3 were lower. Compared with the conventional method, the extraction yields of the nine rare ginsenosides were significantly increased. Conclusion: The results indicate that rare ginsenosides can be extracted effectively by MAE from P. quinquefolius L. in a short time. Microwave radiation plays an important role in MAE. The probable generation process of rare ginsenosides is also discussed in the article. It will be meaningful for further investigation or application of rare ginsenosides.

Tailoring the properties of spray deposited V2O5 thin films using swift heavy ion beam irradiation

  • Rathika, R.;Kovendhan, M.;Joseph, D. Paul;Pachaiappan, Rekha;Kumar, A. Sendil;Vijayarangamuthu, K.;Venkateswaran, C.;Asokan, K.;Jeyakumar, S. Johnson
    • Nuclear Engineering and Technology
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    • v.52 no.11
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    • pp.2585-2593
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    • 2020
  • Swift heavy ion (SHI) beam irradiation can generate desirable defects in materials by transferring sufficient energy to the lattice that favours huge possibilities in tailoring of materials. The effect of Ag15+ ion irradiation with energy 200 MeV on spray deposited V2O5 thin films of thickness 253 nm is studied at various ion doses from 5 × 1011 to 1 × 1013 ions/㎠. The XRD results of pristine film confirmed orthorhombic structure of V2O5 and its average crystallite size was found to be 20 nm. The peak at 394 cm-1 in Raman spectra confirmed O-V-O bonding of V2O5, whereas 917 cm-1 arise because of distortion in stoichiometry by a loss of oxygen atoms. Raman peaks vanished completely above the ion fluence of 5 × 1012 ions/㎠. Optical studies by UV-Vis spectroscopy shows decrement in transmittance with an increase in ion fluence up to 5 × 1012 ions/㎠. The red shift is observed both in the direct and indirect band gaps until 5 × 1012 ions/㎠. The surface topography of the pristine film revealed sheath like structure with randomly distributed spherical nano-particles. The roughness of film decreased and the density of spherical nanoparticles increased upon irradiation. Irradiation improved the conductivity significantly for fluence 5 × 1011 ions/㎠ due to band gap reduction and grain growth.

Electroluminescent Properties of White Light-Emitting Device Using Photoconductive Polymer and Anthracene Derivatives (광전도성 고분자와 안트라센 유도체를 이용한 백색 전계발광소자의 발광 특성)

  • Lee Jeong-Hwan;Choi Hee-Lack;Lee Bong
    • Korean Journal of Materials Research
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    • v.15 no.8
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    • pp.543-547
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    • 2005
  • Organic electroluminescence devices were made from 1,4-bis-(9-anthrylvinyl)benzene (AVB) and 1,4-bis-(9-aminoanthryl)benzene (AAB) anthracene derivatives. Device structure was ITO/AVB/PANI(EB)/Al (multi-layer device) and ITO/AAB:DCM/Al(single-layer device). In these devices, AVB, polyaniline(emeraldine base) (PANI(EB)) and AAB were used as the emitting material. 4-(dicyanomethylene)-2-methyl-6-p-(dimethylamino)styryl-4H -pyran(DCM) was used as red fluorescent dopant. We studied change of fluorescence wavelength with concentration of DCM doped in AAB. The ionization potential (IP) and optical band gap (Eg) were measured by cyclic voltammetry and UV-visible spectrum. We compared with difference of emitting wavelength between photoluminescence and electroluminescence spectrum. In case of the multi-layer device, PANI and AVB EL spectra have similar wave pattern to each PL spectrum and when PAM and AVB were used at the same time, and multi-layer device showed that a balanced recombination and radiation kom PANI and AVB. In case of the single-layer device, with the increase of DCM concentration, the blue emission decreases and red emission increases. This indicates that DCM was excited by the energy transfer from AAB to DCM or the direct recombination at the dopant sites due to carrier trapping, or both. The device with $1.0wt\%$ DCM concentration gave white light.

Polarization of Rayleigh Scattered Lyα in Active Galactic Nuclei

  • Chang, Seok-Jun;Lee, Hee-Won;Yang, Yujin
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.70.3-70.3
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    • 2016
  • Active galactic nuclei (AGNs) typically show a non-thermal continuum locally represented by a power-law and many prominent emission lines in the UV and optical regions. AGNs are classified by two types, where Type I AGNs exhibit both broad and narrow lines and only narrow lines are observed in Type 2 AGNs. The unification models of AGNs invoke the existence of a molecular torus just outside of the broad line region. In the presence of a high column HI region associated with the molecular torus, we propose that significant fraction of broad line photons near Lyman series can be scattered by atomic hydrogen in the torus. In particular, $Ly{\alpha}$ being the strongest emission line, strong linear polarization may develop around $Ly{\alpha}$ through Rayleigh scattering. We adopt a Monte Carlo technique to investigate the polarized transfer of $Ly{\alpha}$ in a thick HI region with the shape of a torus. We consider the range of HI column density N_HI = 1020-23 with fixed geometric parameters of the torus such as the inner and outer radii and the height. We present the polarized spectra and angular distribution of Rayleigh scattered radiation around $Ly{\alpha}$. We find that the $Ly{\alpha}$ core part is polarized in the direction perpendicular to the symmetry axis whereas in the far wing part it is polarized in the parallel direction. It is concluded that the unification of AGNs implies that $Ly{\alpha}$ can be uniquely polarized through Rayleigh scattering.

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Isolation of Lipase Producing Yeast and Optimization of Cultivation Condition (Lipase 생산 효모균주의 분리 및 배양조건 최적화)

  • 박명훈;류현진;오경근
    • KSBB Journal
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    • v.19 no.2
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    • pp.148-153
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    • 2004
  • Lipase catalyzes the hydrolysis of glycerides into fatty acids and glycerol. The study of microbial lipases has been stimulated in resent years. It is due to the potential uses of lipases in esterification of oils to glycerol, alcohols and carbohydrates. Development of lipase producing yeast has been focused concerning to the utilization of yeast culture for animal feed. In this study, yeast like cells was isolated from a waste oil and sludge. A strain having higher lipase activity was selected by random mutagenesis using UV-radiation. The optimal cultivation conditions in submerged culture were examined in terms of lipase production. 2.0% of high fructose syrup, 1,0% of CSL, and 1.0% of olive oil were selected as the nutritional media for the production of lipase. The maximum lipase activity of 1.12 U/ml and viable cell number of 8.8${\times}$10$\^$7/ cells/mL were obtained at 27$^{\circ}C$ with an initial pH of 5.0.