• 제목/요약/키워드: UV Measurement

검색결과 571건 처리시간 0.027초

Determination of the Dissociation Constant of Thymol Blue with Diode-Laser/Fiber-Optic Thermal Lensing Spectroscopy

  • 김성호;노영순
    • Bulletin of the Korean Chemical Society
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    • 제19권8호
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    • pp.822-824
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    • 1998
  • The simple and convenient measurement of the dissociation constant of an indicator, thymol blue, was achieved by using a portable diode-laser/fiber-optic thermal lensing spectroscopy, which consisted of a visible diode laser, a photodiode, and an optical fiber. It gives comparable results to the cited value obtained from a conventional UV/VIS spectroscopy.

과산화수소/자외선/산소 처리를 이용한 베르베린 염료 및 염직물의 퇴화거동 연구 (Study on the Degradation Behavior of Berberine Dye and Berberine Dyed Silk using Hydrogen Peroxide/UV/Oxygen Treatment)

  • 안춘순
    • 복식문화연구
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    • 제20권2호
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    • pp.238-250
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    • 2012
  • This study examined the degradation behavior of SB(standard berberine) dye and SB dyed silk using HPLC-MS instrument after degradation in the hydrogen peroxide/ultraviolet ray radiation/oxygen system up to 9 days and 40 hours respectively. In the degraded samples, berberine was detected at 5.2 min in the SB dye and 5.3 min in the SB dyed silk with its molecular ion=336 and the UV spectra of quaternary alkaloid. Degradation product 3(m/z=102) newly appeared after 5 day degradation treatment with continued increase till the end of degradation treatment. The amount of berberine in the degraded dye decreased with degradation progression. In the silk dyeings, berberine was detected only up to 21 hour degradation sample. The amount of berberine decreased dramatically during the first 6 hours of degradation treatment. The CIELAB color measurement of the silk dyeings showed dramatic change in the b* value, near zero in the 40 hour degraded silk. CIELAB and Munsell color measurements were in agreement with the HPLC-MS results of the dyed silk in the change of berberine content that the degraded silk became white and lost yellow color.

UV Laser Raman Scattering을 이용한 정적 연소기내 분사된 연료의 정량적 당량비 측정에 관한 연구 (A Study on Quantitative Measurements of Equivalence Ratio in Constant Volume Chamber Using UV Laser Raman Scattering)

  • 진성호;허형석;김경수;박경석
    • 한국분무공학회지
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    • 제3권4호
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    • pp.35-42
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    • 1998
  • Laser Raman scattering method has been applied to measure equivalence ratio of methane/air and propane/air mixture in constant volume combustion chamber. We used high power KrF excimer laser$(\lambda=248nm)$ and a high gain ICCD camera to capture low intensity Raman signal. Raman shifts and Ram cross-sections of $H_2,\;O_2,\;N_2,\;CO_2,\;CH_4\;and\;C_3H_8$ were measured precisely. Our results showed an excellent agreement with other groups. Mole fraction measurement of $O_2\;and\;N_2$ from air showed that $O_2\;:\;N_2$ = 0.206 : 0.794. We used constant volume combustion chamber and gas injector which is operated at $5\sim10barg$. Methane and propane are used as a fuel. 50 Raman signal are obtained and ensemble averaged for measurement of equivalence ratio. Our measured results showed that the equivalence ratio of fuel/air mixture is reasonable at ${\pm}5%$ error range.

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자외선 수직형 LED 제작을 위한 Indium Tin Oxide 기반 반사전극 (Indium Tin Oxide Based Reflector for Vertical UV LEDs)

  • 정기창;이인우;정탁;백종협;하준석
    • 한국재료학회지
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    • 제23권3호
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    • pp.194-198
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    • 2013
  • In this paper, we studied a p-type reflector based on indium tin oxide (ITO) for vertical-type ultraviolet light-emitting diodes (UV LEDs). We investigated the reflectance properties with different deposition methods. An ITO layer with a thickness of 50 nm was deposited by two different methods, sputtering and e-beam evaporation. From the measurement of the optical reflection, we obtained 70% reflectance at a wavelength of 382 nm by means of sputtering, while only 30% reflectance resulted when using the e-beam evaporation method. Also, the light output power of a $1mm{\times}1mm$ vertical chip created with the sputtering method recorded a twofold increase over a chip created with e-beam evaporation method. From the measurement of the root mean square (RMS), we obtained a RMS value 1.3 nm for the ITO layer using the sputtering method, while this value was 5.6 nm for the ITO layer when using the e-beam evaporation method. These decreases in the reflectance and light output power when using the e-beam evaporation method are thought to stem from the rough surface morphology of the ITO layer, which leads to diffused reflection and the absorption of light. However, the turn-on voltage and operation voltage of the two samples showed identical results of 2.42 V and 3.5 V, respectively. Given these results, we conclude that the two ITO layers created by different deposition methods showed no differences in the electric properties of the ohmic contact and series resistance.

Confocal Scanning Laser Microscope (CSLM)을 이용한 신규 미백 효과 측정 연구 (New Measurement of Whitening Effects by Using Confocal Scanning Laser Microscope (CSLM))

  • 김명기;조석철;남개원
    • 대한화장품학회지
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    • 제41권3호
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    • pp.279-285
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    • 2015
  • 여성의 얼굴에 과색소침착이 발생하는 것은 불안감, 특히 미적인 요소에 있어서 많은 고민을 유발한다. 피부의 흑화는 자외선(UV)에 대하여 이를 방어하기 위한 기작으로 멜라닌의 양과 밀접한 관계가 있다. 이러한 피부의 구성성분을 관찰하기 위해, confocal scanning laser microscope (CSLM)은 피부에 직접 현미경 검사를 실시하여 어떠한 조직의 변화 없이 피부를 실시간으로 관찰할 수 있는 비침습적 이미지 장치이다. 본 연구에서는 자외선 조사를 통해 유도된 하박 내측 피부의 과색소침착을 유도하여, 다른 피부색을 평가하는 측정기기와 상관성을 분석하여, CSLM을 이용한 새로운 미백 평가방법을 제시하였다. CSLM을 활용한 미백 효능 평가법은 소비자가 보다 이해하기 쉽도록 미백 제품을 평가하는데 유용할 것으로 생각된다.

자외선복사의 측정과 분석 (The Measurement and Analysis for Ultraviolet Radiation)

  • 한종성;김홍범;김훈
    • 조명전기설비학회논문지
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    • 제19권2호
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    • pp.7-12
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    • 2005
  • 광원의 복사에너지가 물질에 입사하면, 그 물질의 고유한 특성에 따라 그 에너지의 일부는 흡수되고 나머지는 반사되거나 투과된다. 물질을 구성하는 분자가 빛을 흡수하면 그 빛의 파장에 따른 복사에너지에 의하여 열적 반응이나 광화학적 반응을 일으킨다. 특히 자외선복사에 의한 광화학적 작용은 물질의 변퇴색과 같은 광화학적 열화를 초래한다. 물질에 손상이 일어나면 그 물질의 가치상실 뿐 아니라, 손상된 것을 다시 복원하기 쉽지 않기 때문에 이에 대한 적절한 조명 환경을 마련하여 손상의 최소화나 보존에 많은 노력을 기울여야 한다. 본 연구에서는 자외선에 의한 광화학적 손상과 그 방호에 대하여 살펴보고, 전시조명용으로 많이 사용되는 인공광원과 자연주광을 대상으로, 이들 광원들이 방출하는 복사조도와 자외선을 포함하는 광복사량을 측정하고 그 결과를 분석하였다.

합금도금강판 내식성 향상을 위한 UV 경화형 유무기 하이브리드 코팅 (Improvement of anti-corrosive property for alloy plated steel sheet by UV curable organic-inorganic hybrid coatings)

  • 박종원;이경황;나현주;박병규;남영섭;홍신협
    • Corrosion Science and Technology
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    • 제12권1호
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    • pp.27-33
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    • 2013
  • According to its merits about high curing speed and low emission of volatile organic compounds, UV curable inorganic-organic coating technology has been developed as an alternative for toxic and carcinogenic chromate-based treatments for years. It is consistently observed that ultra-thin films offer excellent corrosion protection as well as paint adhesion to metals. Based on the tetra-ethylorthosilicate(TEOS) and methacryloxypropyl trimethoxysilane(MPTMS), inorganic sol was synthesized and formed hybrid networks with UV curable acrylic monomer, 6-hexanediol diacrylate(HDDA), trimethylolpropane triacrylate(TMPTA), pentaerylthritol triacrylate(PETA). Several methods were used to test their properties such as salt spray test, potentiodynamic measurement, tape peel test, etc. It was shown that anti-corrosive property and stability of storage were affected by the molecular ratios of inorganic and organic compounds. It was not only the stability of storage, but had a excellent anti-corrosive, paint adhesive, and anti-solvent properties in a final molar ratios of 0.6/0.04/0.86/0.005 (TEOS/MPTMS/Acetone/HNO3) and 0.08/0.106/0.081/0.02 (TMPTA/HDDA/PETA/photo initiator).

Hazards Caused by UV Rays of Xenon Light Based High Performance Solar Simulators

  • Dibowski, Gerd;Esser, Kai
    • Safety and Health at Work
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    • 제8권3호
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    • pp.237-245
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    • 2017
  • Background: Solar furnaces are used worldwide to conduct experiments to demonstrate the feasibility of solar-chemical processes with the aid of concentrated sunlight, or to qualify high temperature-resistant components. In recent years, high-flux solar simulators (HFSSs) based on short-arc xenon lamps are more frequently used. The emitted spectrum is very similar to natural sunlight but with dangerous portions of ultraviolet light as well. Due to special benefits of solar simulators the increase of construction activity for HFSS can be observed worldwide. Hence, it is quite important to protect employees against serious injuries caused by ultraviolet radiation (UVR) in a range of 100 nm to 400 nm. Methods: The UV measurements were made at the German Aerospace Center (DLR), Cologne and Paul-Scherrer-Institute (PSI), Switzerland, during normal operations of the HFSS, with a high-precision UV-A/B radiometer using different experiment setups at different power levels. Thus, the measurement results represent UV emissions which are typical when operating a HFSS. Therefore, the biological effects on people exposed to UVR was investigated systematically to identify the existing hazard potential. Results: It should be noted that the permissible workplace exposure limits for UV emissions significantly exceeded after a few seconds. One critical value was strongly exceeded by a factor of 770. Conclusion: The prevention of emissions must first and foremost be carried out by structural measures. Furthermore, unambiguous protocols have to be defined and compliance must be monitored. For short-term activities in the hazard area, measures for the protection of eyes and skin must be taken.