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Synthesis and Emulsification of Polyurethane Anionomer (음이온성 폴리우레탄의 합성 및 에멀젼화에 관한 연구)

  • Ann, Choun-Kee;Jin, Je-Yong;Lee, Gyung-Won;Choi, Sei-Young
    • Elastomers and Composites
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    • v.34 no.5
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    • pp.399-406
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    • 1999
  • Polyurethane (PU) prepolymers were synthesized from polytetramethylene ether glycol (PTMG), 4,4'-diphenylmethane diisocyanate (MDI), toluene 2,4-diisocyanate (TDI) and isophoron diisocyanate (IPDI). After chain extention using dimethyol propionic acid (DMPA), aqueous polyurethane anionomers were prepared from triethyl amine (TEA) as a neutralizer. The effect of the content of chain extender and the degree of neutralization on the state of emulsification, adhesive strength, viscosity, glass transition temperature and physical properties of emulsion cast film were investigated using UTM, Viscometer and DSC.

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Study on the Synthesis of Polyurethane Cationomers and Their Mechanical Properties (양이온성 폴리우레탄의 합성 및 기계적 특성에 관한 연구)

  • Ann, Choun-Kee;Jin, Je-Yong;Choi, Sei-Yong
    • Elastomers and Composites
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    • v.33 no.3
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    • pp.177-184
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    • 1998
  • Polyurethane(PU) prepolymers were synthesized from polytetramethylene ether glycol(PTMG), with 4,4'-diphenylmethane diisocyanate(MDI), toluene 2,4-diisocyanate (TDI) and isophoron diisocyanate(IPDI). After chain extention using n-methyl-diethanol amine(n-MDEA), aqueous polyurethane cationomers were prepared by addition of glycolic acid(GA) as a quaternizer. The effect of the content of chain extender and the degree of neutralization on the stability of emulsion, adhesive strength, viscosity, glass transition temperature and physical properties of emulsion cast film were investigated using UTM, viscometer and DSC.

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Feasibility Study on the Use of Vegetable Oil (Natural Ester) in Malaysia Power System Transformers

  • Suleiman, Abubakar A.;Muhamad, Nor Asiah Binti
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.3
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    • pp.113-116
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    • 2014
  • Power transformer insulation oil is critical to the useful life of the transformer. Although mineral base insulation oil is the most common type of transformer insulation oil in use, environmental and safety concerns has encouraged the development of biodegradable alternatives. Today, $Envirotemp^{(R)}\;FR3^{TM}$ is in commercial use and this study is aimed at ascertaining the possibility of applying the oil in Malaysia power transformers. A sample of $Envirotemp^{(R)}\;FR3^{TM}$ was tested to measure and compare the technical (including electrical, chemical and physical) properties of the oil according to Malaysian standards. The study found that the oil sample had better qualities, such as higher dielectric strength, lower dissipation factor, higher flash and fire points, higher moisture absorption capability, and less dissolved gases composition amongst others. However, it was also ascertained that further development in this area could be hindered due to Malaysia's lack of standards for biodegradable oil.

Preparation and Characterization of ACF Using Lyocell Adopting Surface Modification Process (리오셀 표면개질공정을 도입한 ACF 제조 및 특성)

  • Jo, Young Hyuk;Jin, Young Min;Lee, Soon Hong
    • Journal of the Korean Society of Safety
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    • v.31 no.1
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    • pp.66-73
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    • 2016
  • Lyocell fibers were used as a precursor in order to improve yield and strength of cellulose-based precursor while manufacturing activated carbon fiber(ACF). Lyocell fibers as a precursor for the preparation of ACF were surface-modified by reaction with 3-aminopropyltriethoxysilane(APTES) and pre-treated with KOH and H3PO4. Using aforementioned precursor, ACFs were prepared by a series of stabilization, carbonization and activation process at high temperatures. On each process, FT-IR, TGA, UTM and SEM were used to observe fibers' physical properties including structure and porous surfaces. FT-IR results proved that surface modification was achieved during stabilization, carbonization and activation process. TGA results during carbonization process found that surface modified fibers with APTES 0.02 mol(A2) showed higher thermostability, and extended pre-treatment increased yield. Especially, yield was found to have an increase of 10~20 wt% with surface modification during activation process. UTM results showed that tensile strength has the same order of concentration of APTES after surface modification, however, was found to show lower tensile strength than lyocell fibers after stabilization process. SEM results revealed that more homogeneous porosity control could be proceed after modifying the surface for the effective removal of hazardous substances.

Evaluation of the seismic performance of special moment frames using incremental nonlinear dynamic analysis

  • Khorami, Majid;Khorami, Masoud;Motahar, Hedayatollah;Alvansazyazdi, Mohammadfarid;Shariati, Mahdi;Jalali, Abdolrahim;Tahir, M.M.
    • Structural Engineering and Mechanics
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    • v.63 no.2
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    • pp.259-268
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    • 2017
  • In this paper, the incremental nonlinear dynamic analysis is used to evaluate the seismic performance of steel moment frame structures. To this purpose, three special moment frame structure with 5, 10 and 15 stories are designed according to the Iran's national building code for steel structures and the provisions for design of earthquake resistant buildings (2800 code). Incremental Nonlinear Analysis (IDA) is performed for 15 different ground motions, and responses of the structures are evaluated. For the immediate occupancy and the collapse prevention performance levels, the probability that seismic demand exceeds the seismic capacity of the structures is computed based on FEMA350. Also, fragility curves are plotted for three high-code damage levels using HASUS provisions. Based on the obtained results, it is evident that increase in the height of the frame structures reduces the reliability level. In addition, it is concluded that for the design earthquake the probability of exceeding average collapse prevention level is considerably larger than high and full collapse prevention levels.9.

Numerical analysis of tilted angle shear connectors in steel-concrete composite systems

  • Khorramian, Koosha;Maleki, Shervin;Shariati, Mahdi;Jalali, Abdolrahim;Tahir, M.M.
    • Steel and Composite Structures
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    • v.23 no.1
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    • pp.67-85
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    • 2017
  • This study investigates numerically the behavior of tilted angle shear connectors embedded in solid concrete slabs. Two different tilted angle connectors were used, titled angle with 112.5 and 135 degrees between the angle leg and steel beam flange. A nonlinear finite element model was developed to simulate and validate the experimental push-out tests. Parametric studies were performed to investigate the variations in concrete strength and connector's dimensions. The results indicate that the ultimate strength of a tilted angle shear connector is directly related to the square root of the concrete compressive strength. The effects of variations in the geometry of tilted angle connectors on the shear capacity are discussed in details. Based on the numerical analyses, two equations are proposed to estimate the ultimate capacity of tilted angle shear connectors of 112.5 and 135 degrees in the defined range of parameters.

A Study on the Property Changes by Trihydric Alcohol Addition Reaction and Polyurethane Dispersion Synthesis for Buffalo Leather Coatings (Buffalo Leather 코팅에 대한 수분산 폴리우레탄의 합성 및 3가 알콜 첨가에 의한 물성변화 연구)

  • Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.4
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    • pp.623-630
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    • 2015
  • Prepared polyurethane resin for buffalo leather coating on surface was synthesized with addition reaction glycerol which had different mole ratio. Mechanical properties of the synthesized polyurethane resin were measured by the SEM, FT-IR, UTM. Growing concerns in the evnironment-friendly polymer resin, we have synthesized low late obtained solvent water dispersion resin to be coating on buffalo leather. The increase of aliphatic trihydric alcohol glycerol mole %, abrasion resistance and tensile strength had demonstrated reduce properties. On the contrary, elongation and flexibility properties had highly increased. In the result of toluene solvent resistance, there was no effect of increased or decreased by the ratio of glycerol mole %.

Mechanical Properties and Synthesis of Polyurethane Dispersion by Glycerol for Vegetable Leather Surface Coatings (Vegetable Leather 표면코팅에 대한 Glycerol을 이용한 수분산 폴리우레탄의 합성 및 기계적 특성)

  • Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.100-107
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    • 2015
  • Prepared polyurethane resin for vegetable leather coating on surface was synthesized with glycerol which had different mole ratio. Mechanical properties of the synthesized polyurethane resin were measured by the SEM, FT-IR, UTM. Growing concerns in the evnironment-friendly polymer resin, we have synthesized low late obtained solvent water dispersion resin to be coating on vegetable leather. The increase of aliphatic trihydric alcohol glycerol mole %, abrasion resistance and tensile strength had highly stronger in intensity and longer durability. On the contrary, demonstrated reduce properties of elongation and flexibility. In the result of toluene solvent resistance, there was no effect of increased or decreased by the ratio of glycerol mole %.

Synthesis and Properties of Polyester System Polyurethane without Solvent (무용제 반응에 의한 폴리에스테르계 폴리우레탄의 합성 및 특성)

  • Kwak Noh-Seok;Yang Yun-Kyu;Jeong Boo-Young;Hwang Taek-Sung
    • Polymer(Korea)
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    • v.29 no.4
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    • pp.344-349
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    • 2005
  • Polyurethanes(PUs) were synthesized by reaction of isophorone diisocyanate, acetylbutyl citrate, and 3 types of polycaprolactone diol. Their structures were confirmed by FT-IR and NMR spectrometer. And, their thermal and mechanical properties were measured by TGA ud UTM. The effective network chain lengths ($\bar{M}_c$), measured by compressive modulus apparatus, were about $8000\~24000$ g/mol. As crosslinking density and amount of hard segment increased, tensile strength increased and elongation decreased. As the crosslinking density of PUs increased, thermal property inproved. When the ratio of NCO/OH is 1.1, maximum crosslinking density was achieved.

Small Scale Map Projection and Coordinate System Improvement in Consideration of Usability and Compatibility

  • Choi, Byoung Gil;Na, Young Woo;Jung, Jin Woo
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.34 no.2
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    • pp.171-183
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    • 2016
  • Small-scale maps currently used are made by scanning and editing printed maps and its shortcoming is accumulated errors at the time of editing and low accuracy. TM projection method is used but its accuracy varies. In addition, small-scale maps are made without consideration of usability and compatibility with other scale maps. Therefore, it is necessary to suggest projection and coordinates system improvement methods in consideration of usability and compatibility between data. The results of this study reveal that in order to make the optimum small-scale map, projection that fits the purpose of map usage in each scale, coordinate system and neat line composition should be selected in consideration of interrelation and compatibility with other maps. Conic projection should be used to accurately illustrate the entire country, but considering usability and compatibility with other maps, traversing cylindrical projection should be used instead of conic projection. For coordinates system of the small-scale map, Universal Transverse Mercator (UTM-K) based on the World Geodetic System should be used instead of conventional longitude and latitude coordinate system or Transverse Mercator.