• Title/Summary/Keyword: UO2

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Adsorption of U(VI), Fe(II), Sm(III) Ions on OenNen-Styrene DVB Synthetic Resin (OenNen-Styrene DVB 합성수지에 의한 U(VI), Fe(II), Sm(III) 이온들의 흡착)

  • Lee, Chi-Young;Kim, Joon-Tae
    • Journal of environmental and Sanitary engineering
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    • v.22 no.3
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    • pp.77-87
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    • 2007
  • The ion exchange resins have been synthesized from chlormethyl styrene - 1,4 - divinylbenzene(DVB) with 1%, 3%, and 5%-crosslinking and macro cyclic ligand of OenNen-$H_4$ by copolymerization method and the adsorption characteristics of uranium(VI), iron(II) and samarium(III) metallic ions have been investigated in various experimental conditions. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, time, dielectric constant of solvent and crosslink on adsorption of metallic ions were investigated. The uranium ion was showed fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium ${UO_2}^{2+}>Fe^{2+}>Sm^{3+}$ ion. The adsorption was in order of 1%, 3%, and 5% crosslink resin and adsorption of resin decreased in proportion to order of dielectric constant of solvent.

Adsorption of Metal Ions on OenNdien Resin (OenNdien수지에 의한 금속 이온의 흡착)

  • Kang Young-Shik;Rho Gi-Hwan;Kim Joon-Tae
    • Journal of environmental and Sanitary engineering
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    • v.20 no.3 s.57
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    • pp.27-35
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    • 2005
  • The ion exchange resins have been synthesized from chlormethyl styrene - 1,4 -divinyl-benzene(DVB) with $1\%,\;4\%,\;and\;10\%$-crosslinking and macrocyclic ligand of cryptand type by copolymerization method and the adsorption characteristics of uranium(VI), calcium(II) and lutetium(III) metallic ions have been investigated in various experimental conditions. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, time, dielectric constant of solvent and crosslink on adsorption of metallic ions were investigated. The uranium ion was showed fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium $(UO_2^{2+})>calcium(Ca^{2+})>lutetium(Lu^{3+})$ ion. The adsorption was order of $1\%,\;4\%,\;and\;10\%$ crosslink resin and adsorption of resin decreased in proportion to order of dielectric constant of solvents.

Capacity evaluation on the slitting device of the spent fuel rod (사용후핵연료봉 slitting 장치 성능 평가)

  • 정재후;윤지섭;김영환;진재현;김동기
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.1154-1157
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    • 2003
  • The spent fuel slitting device is an equipment developed for the separation of the pellet and hull from the cutting fuel rod with length of 250 mm, and in order to feed UO$_2$ pellet. We have analyzed on the existing technologies for designing and producing of the slitting device in the first year(2001), based on these results, designed and produced the rod slitting device. It has effectively separated the pellet from the hull, but demanded the supplement separation work because of the mixing with pellet and hull in the vessel, and required the condition for the reducing time of the process. In the second year(2002), we have reduced the work time, performed the test and capacity evaluation with the improving device, based these results, and ensured the data demanded for designing of the spent fuel rod slitting device. We have compared with the DUPIC(Direct use of spent PWR fuel in CAND reactors) process, and developed the device for the purpose of reducing over 40 % in comparition with the DUPIC operation time(5 minutes). Based on these results, it will is effectively applied to available data for designing and producing of the hot test facility.

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OPTIMAL PROCESSING AND SYSTEM MANUFACTURING OF A LASER WELDED TUBE FOR AN AUTOMOBILE BUMPER BEAM

  • Suh, J.;Lee, J.H.;Kang, H.S.;Park, K.T.;Kim, J.S.;Lee, M.Y.;Jung, B.H.
    • International Journal of Automotive Technology
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    • v.7 no.2
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    • pp.209-216
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    • 2006
  • A study has been conducted for an optimal processing and an apparatus for manufacturing a laser welded tube for one-body formed bumper beam. The tube dimensions used in calculation were the thickness of 1.4 mm, the diameter of 105.4 mm and the length of 2000 mm. The tube was formed of a cold rolled high strength steel plate(tensile strength of 600 MPa). The two-roll bending method was the optimal tube forming process in comparison with the UO-bending method, the bending method on the press brake, the multi-step continuous roll-forming method and the 3-roll bending method. Monitoring of the welding quality was conducted and the seam tracking along the butt-joint lengthwise to the tube axis was also examined. The longitudinal butt-joint was welded by using a $CO_2$ laser welding machine equipped with a seam tracker and a plasma sensor. The $CO_2$ laser tube welding machine could be used for precise seam tracking and real-time monitoring of the welding quality. As a result, the developed laser welded tube could be used for a one-body formed automobile bumper beam.

How to quantify the similarity of 2D distributions: Comparison of spatial distribution of Dark Matter and Intracluster light

  • Yoo, Jaewon;Ko, Jongwan;Sabiu, Cristiano G.;Chun, Kyungwon;Shin, Jihye;Hwang, Ho Seong;Smith, Rory;Kim, Hyowon
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.2
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    • pp.67.4-68
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    • 2021
  • In studying the dynamical evolution of galaxy clusters, one intriguing approach is to compare the spatial distributions of various components, such as the dark matter, the member galaxies, the gas, and the intracluster light (ICL; the diffuse light from stars, which are not bound any individual cluster galaxy). If we find a visible component whose spatial distribution coincides with the dark matter distribution, then we could draw a dark matter map without requiring laborious weak lensing analysis. Furthermore, if the component traces the dark matter distribution better for more relaxed galaxy cluster, we could use the similarity as a dynamical stage estimator of the galaxy cluster. We present a novel new methodology to quantify the similarity of two or more 2-dimensional spatial distributions. We apply the method to a sample of galaxy clusters at different dynamical stages simulated within N-cluster Run, which is an N-body simulation using the galaxy replacement technique. Among the various components (stellar particles, galaxies, ICL), the velocity defined ICL+ brightest cluster galaxy (BCG) component traces the dark matter best. Between the sample galaxy clusters, the relaxed clusters show stronger similarity of the spatial distribution between the dark matter and ICL+BCG than the dynamically young clusters.

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Modification of conventional X-ray diffractometer for the measurement of phase distribution in a narrow region

  • Park, Yang-Soon;Han, Sun-Ho;Kim, Jong-Goo;Jee, Kwang-Yong;Kim, Won-Ho
    • Analytical Science and Technology
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    • v.19 no.5
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    • pp.407-414
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    • 2006
  • An X-ray diffractometer for spatially resolved X-ray diffraction measurements was developed to identify phase in the narrow (micron-scaled) region of high burn-up fuels and some nuclear materials. The micro-XRD was composed of an X-ray microbeam alignment system and a sample micro translation system instead of a normal slit and a fixed sample stage in a commercial XRD. The X-ray microbeam alignment system was fabricated with a microbeam concentrator having two Ni deposited mirrors, a vertical positioner, and a tilt table for the generation of a concentrated microbeam. The sample micro translation system was made with a sample holder and a horizontal translator, allowing movement of a specimen at $5{\mu}m$ steps. The angular intensity profile of the microbeam generated through a concentrator was symmetric and not distorted. The size of the microbeam was $4,000{\times}20{\mu}m$ and the spatial resolution of the beam was $47{\mu}m$ at the sample position. When the diffraction peaks were measured for a $UO_2$ pellet specimen by this system, the reproducibility ($2{\Theta}={\pm}0.01^{\circ}$) of the peaks was as good as a conventional X-ray diffractometer. For the cross section of oxidized titanium metal, not only $TiO_2$ in an outer layer but also TiO near an oxide-metal interface was observed.

Development of X-ray Image Processing Technology for Nondestructive Measurement of the Coating Thickness in the Simulated TRISO-coated Fuel Particle (모의 TRISO 핵연료입자 코팅층 두께 비파괴 측정을 위한 X-선 영상처리기술 개발)

  • Kim Woong-Ki;Lee Young-Woo;Park Ji-Yeon;Ra Sung-Woong
    • Proceedings of the Korea Information Processing Society Conference
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    • 2006.05a
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    • pp.669-672
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    • 2006
  • 고온가스냉각 원자로에서는 고온 안정성 및 핵분열생성물 차단 성능이 우수한 TRISO(tri-tsotropic) 핵연료를 사용하고 있다. TRISO 핵연료 입자는 직경이 약 1 mm인 구 형태로 입자의 중심에는 직경 $0.5{\mu}m$의 핵연료 커널(kernel)이 포함되며 커널 외곽을 코팅 층이 에워싸고 있다. 이 코팅 층은 완충(buffer) PyC(pyrolytic carbon) 층, 내부 PyC 층, SiC 층, 그리고 외부 PyC 층으로 구성되어 있다. 각 코팅 층의 두께는 수십${\sim}$${\mu}m$ 범위이며, 본 연구에서는 각 코팅 층의 두께를 비파괴적으로 측정하기 위하여 마이크로포커스 X-선 발생장치와 고해상도 X-선 평판(flat panel) 검출기로 구성된 정밀한 X-선 래디오그래피 장치를 구성하고, $UO_2$ 핵물질 대신에 $ZrO_2$를 커널로 사용한 모의 TRISO 핵연료 입자에 대한 래디오그래피 영상을 획득한 후 디지털 영상처리기술을 이용하여 코팅 층 사이의 경계선이 구분 가능하도록 영상을 개선하고 디지털 영상처리 알고리즘을 개발하여 코팅 층의 두께를 측정하였다.

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A Study on the Mitigation of Vapor Explosions with Tin-Water Sytem (주석-물 시스템의 증기폭발 완화에 대한 연구)

  • Shin Y.S.;Kim J.H.;Hong S.W.;Song J.H.;Kim H.D.
    • Proceedings of the KSME Conference
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    • 2002.08a
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    • pp.397-400
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    • 2002
  • Vapor explosion is one of the most important problems encountered in severe accident management of nuclear power plants. In spite of many efforts, a lot of questions still remain. So, KAERI launched a real experimental program called TROI using $UO_{2}$ and $ZrO_{2}$ to investigate the vapor explosion. Besides TROI tests, a small-scale experiment with molten-tin/water system was performed to quantify the characteristics of vapor explosion and to understand the phenomenology of vapor explosion. A vapor explosion was observed while the amount of air bubble and water temperature were systematically varied The mass and temperature of tin are $50\;g\;and\;150^{\circ}C$, respectively. Water temperature is set to $24^{\circ}C\;and\;50^{\circ}C$. The void fraction of air bubble ranges from $0\;to\;10\;{\%}$. The strength of vapor explosion was measured using dynamic pressure sensors attached in reactor tube wall. as a function of void fraction. In addition, a high speed video filming up to 1,000 flame/sec was taken in order to visually investigate the behavior of the vapor explosion .

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The Influence of Water Depth and Melt Composition on a Steam Explosion in Severe Accidents in a Nuclear Reactor (원자로에서 중대사고시 냉각수의 수심과 용융물 성분이 증기폭발에 미치는 영향)

  • Kim, Jong-Hwan;Park, Ik-Kyu;Hong, Seong-Wan;Min, Beong-Tae;Song, Jin-Ho;Kim, Hee-Dong
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.414-419
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    • 2003
  • In the recent TROI experiments, melts of zirconia and two different compositions of corium were used to observe the occurrence of a steam explosion when it came into contact with water at two different depths. The compositions of the corium were 70 : 30 and 80 : 20 in weight percent of $UO_{2}$ and $ZrO_{2}$, and the mass of the corium was about 10kg. The depth of water in the interaction vessel was 67cm and 130cm. A steam explosion did not occur in the interaction between 80 : 20 corium melt and water at 130cm depth, while steam spikes were observed in the interactions between corium melts of two different compositions and water at 67cm depth. A strong steam explosion occurred in the interaction between 5.43kg of zirconia melt and water at 67cm depth. This fact shows that the explosivity of zirconia is much greater than that of corium.

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RADIATION MONITORING SYSTEM FOR ADVANCED SPENT FUEL CONDITIONING PROCESS FACITLITY

  • Kook Dong-Hak;Choung Won-Myung;Lee Eun-Pyo;You Gil-Sung;Cho Il-Je;Kwon Kie-Chan;Lee Won-Kyoung;Ku Jeoung-Hoe
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11b
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    • pp.149-155
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    • 2005
  • The $ACP^1$ is under development for effective management of spent fuel by converting $UO_2$ into U-metal. For demonstration of this process, $\alpha-\gamma$ type new hotcell was built in the $IMEF^2$ basement. To secure against radiation hazard, this facility needs radiation monitoring system which will observe the entire operating area before the hotcell and service area at back of it. This system consists of 7 parts; Area Monitor for $\gamma$-ray, Room Air Monitor for particulate and iodine in both area, Hotcell Monitor for hotcell inside high radiation and rear door interlock, Duct Monitor for particulate of outlet ventilation, Iodine Monitor for iodine of outlet duct, CCTV for watching workers and material movement, Server for management of whole monitoring system. After installation and test of this, radiation monitoring system will be expected to assist the successful ACP demonstration.

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