• Title/Summary/Keyword: U-Product

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Hydrogen production by catalytic decomposition of propane-containing methane over N330 carbon black in a fluidized bed (유동층 반응기에서 N330 카본 블랙 촉매를 이용한 프로판을 포함한 메탄의 촉매분해에 의한 수소 제조)

  • Lee, Seung-Chul;Lee, Kang-In;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.761-764
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    • 2009
  • The thermocatalytic decomposition of methane is an environmentally attractive approach to $CO_2$-free production of hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbon from the reactor. The usage of carbon black was reported as stable catalyst for decomposition of methane. Therfore, carbon black (DCC-N330) is used as catalyst. A fluidized bed reactor made of quartz with 0.055 m I.D. and 1.0 m in height was selected for the thermo-catalytic decomposition. The porpane-containg methnae decomposition reaction was operated at the temperature range of 850-900 $^{\circ}C$ methane gas velocity of 1.0 $U_{mf}$ and the operating pressure of 1.0 atm. In this work, propane was added as reactant to make methane conversion higher. Therefore we compared with methane conversion and pre-experiment methane conversion that using only methane as reactant. The carbon black, after experiment, was measured in particle size and surface area and analyzed surface of the carbon black by TEM.

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Hydrogen production by catalytic decomposition of methane over carbon black catalyst in a fluidized bed on pressurized bench-scale condition (가압유동층 반응기에서 카본블랙 촉매를 이용한 메탄의 촉매분해에 의한 수소제조)

  • Seo, Hyung-Jae;Lee, Seung-Chul;Lee, Gang-In;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.791-793
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    • 2009
  • Hydrogen has been recognized of the energy source for the future, in terms of the most environmentally acceptable energy source. A pressurized fluidized bed reactor made of carbon steel with 0.076 m I.D. and 1.0 m in height was employed for the thermocatalytic decomposition of methane to produce amount of $CO_2$ - free hydrogen with validity from a commercial point of view. The fluidized bed was proposed for withdrawing of product carbons from the reactor continuously. The methane decomposition rate with the carbon black N330 catalyst was rapidly reached a quasi-steady state and remained for several hour. The methane thermocatalytic decomposition reaction was carried out at the temperature range of 850 - 950 $^{\circ}C$, methane gas velocity of 2.0 $U_{mf}$ and the operating pressure of 1.0 -3.0 bar. Effect of operating parameters such as reaction temperature, pressure on the reaction rates was investigated and predicted the effect of a change in conditions on a chemical equilibrium thermodynamically, according to Le Chatelier's principle.

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Hydrogen production by catalytic decomposition of propane over carbon black catalyst in a fluidized bed (유동층 반응기에서 카본블랙 촉매를 이용한 프로판의 촉매 분해에 의한 수소생산 연구)

  • Nam, Woo-Seok;Jung, Jae-Uk;Yoon, Ki-June;Lee, Dong-Hyun;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.388-391
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    • 2006
  • A fluidized bed reactor made of quartz with 0.055m I.D. and 1.0m in height was employed for the thermocatalytic decomposition of propane to produce $CO_2-free$ hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor The propane decomposition rate used carbon black DCC-N330, Hi-900L as a catalyst. The propane decomposition reaction was carried out at the temperature range of $600-800^{\circ}C$, propane gas velocity of $1.0U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature on the reaction rates was investigated. Resulting production in our experiment were not only hydrogen but also several by products such as methane, ethylene, ethane, and propylene.

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Analysis of the Rate of Sensitization to Food Allergen in Children with Atopic Dermatitis (아토피피부염 환아의 식품 알레르겐에 대한 감작률 분석을 통한 식품알레르기의 고찰)

  • 한영신;정상진;조영연;최혜미;안강모;이상일
    • Korean Journal of Community Nutrition
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    • v.9 no.1
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    • pp.90-97
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    • 2004
  • The purpose of this study was to determined the rate of sensitization to food allergen in children with Atopic Dermatitis (AD) in Korea. A total of 3,783 patients (male = 1983, female = 1800) with AD (age under 18 years) who had visited Samsung Medical Center from 1998 to 2003 were enrolled in the study. Food hypersensitivity was measured by specific IgE to egg, cow's milk, soy, peanut, wheat, buckwheat, beef, pork, chicken, shrimp, crab, salmon, mackerel, etc. Specific IgE levels > 0.7 kU/L. by Captured Allergen Product (CAP) assay were considered positive. Chi-square test at p value < 0.05 was used to examine the difference of the prevalence by sex and age. The rate of sensitization to multiple food allergens was 31.2% and decreased with age. Hypersensitivity to egg showed highest prevalence, which was 24.3%, compared to the prevalence of other foods. High prevalence of hypersensitivity to milk. wheat, soy, peanut, crab or shrimp was observed (11.6- 17.7%). Low prevalence of hypersensitivity to beef, pork, tuna or chicken was observed (1.9-3.5%). Children aged under 3 years had significantly higher prevalence of hypersensitivity to egg, milk, soy and beef than children aged at least 3 years. Our results stress the need for examination of food hypersensitivity aimed at identified and limited each food allergen among children with AD caused by food to help patients outgrow their food allergy.

Long-term Sulfur Emissions and Environmental Kuznets Curves: Comparison and Implications

  • Huang, Zheng;Tonooka, Yutaka;Sekiguchi, Kazuhiko;Wang, Qingyue;Sakamoto, Kazuhiko
    • Asian Journal of Atmospheric Environment
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    • v.3 no.1
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    • pp.19-26
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    • 2009
  • The environmental Kuznets curve hypothesis assumes an inverted U-shaped relationship between environmental damage and income, and such curves have been used to study how economic growth affects the environment. In this study, we analyzed data for gross domestic product (GDP) per capita and for sulfur emissions in the industrialized countries of the United Kingdom, United States of America, and Japan, as well as data for the developing country of China, to determine the relationship between emissions and income in these countries. Attempts by these countries' governments to incorporate environmental policy considerations into the income-environment relationship were also examined. The potential role of the environmental Kuznets curve as a policy tool was investigated. We determined that, at least in the case of sulfur emissions, policies and institutions significantly reduced environmental degradation in the industrialized countries studied. Furthermore, the environmental Kuznets curve can reliably predict the future relationship between environmental impact and GDP for developing countries.

Identification of the Vibrio vulnificus cadC and Evaluation of Its Role in Acid Tolerance

  • Rhee, Jee-Eun;Ju, Hyun-Mok;Park, U-Ryung;Park, Byoung-Chul;Choi, Sang-Ho
    • Journal of Microbiology and Biotechnology
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    • v.14 no.5
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    • pp.1093-1098
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    • 2004
  • An open reading frame encoding CadC, consisting of 526 amino acids, was identified from the upstream region of the Vibrio vulnificus cadBA operon. The deduced amino acid sequences of the cadC were 22 to 78% similar to those reported from other Enterobacteriaceae. Functions of cadC gene on acid tolerance were assessed by comparing acid tolerances of V. vulnificus and its isogenic mutant, whose cadC gene was inactivated by allelic exchanges. The results demonstrated that the gene product of cadC contributes to acid tolerance of V. vulnificus, and that its contribution is dependent on prior exposure of cells to moderately acidic pH. The cellular level of cadB and cadA transcripts decreased in the cadC mutant, indicating that CadC exerts its effect on acid tolerance of V. vulnificus by enhancing the expression of cadBA in a pH-dependent manner.

Potential Yeast from Indonesian Wild Forest Honey Showing Ability to Produce Lipase for Lipid Transesterification

  • Palilu, Prayolga Toban;Kasiamdari, Rina Sri;Ilmi, Miftahul
    • Microbiology and Biotechnology Letters
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    • v.47 no.4
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    • pp.555-564
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    • 2019
  • Biodiesel is produced through the transesterification process in the presence of alcohol and a catalyst that catalyzes the conversion of triglycerides to esters and glycerol compounds. A more optimal product conversion can be achieved using enzymes, such as lipase. Lipase is reported to be produced in osmophilic yeasts due to the low water content in their natural habitats. Wild forest honey is one of the osmophilic natural habitats in Indonesia. However, lipase-producing yeast has not been reported in the Indonesian honey. In this study, we screened the lipase-producing yeasts isolated from wild forest honey collected from Central Sulawesi. The production profile and activity of lipase were determined at different pH values and temperatures. One promising yeast was isolated from the honey, which was identified as Zygosaccharomyces mellis SG 1.2 based on ITS sequence. The maximum lipase production (24.56 ± 1.30 U/mg biomass) was achieved by culturing the strain in a medium containing 2% olive oil as a carbon source at pH 7 and 30℃ for 40 h. The optimum pH and temperature for lipase activity were 6 and 55℃, respectively. The enzyme maintained 80% of its activity upon incubation at 25℃ for 4 h. However, the enzyme activity decreased by more than 50% upon incubation at 35 and 40℃ for 2 h. This is the first study to report the lipase producing capability of Z. mellis. Further studies are needed to optimize the enzyme production.

Statistical division of compressive strength results on the aspect of concrete family concept

  • Jasiczak, Jozef;Kanoniczak, Marcin;Smaga, Lukasz
    • Computers and Concrete
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    • v.14 no.2
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    • pp.145-161
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    • 2014
  • The article presents the statistical method of grouping the results of the compressive strength of concrete in continuous production. It describes the method of dividing the series of compressive strength results into batches of statistically stable strength parameters at specific time intervals, based on the standardized concept of "concrete family". The article presents the examples of calculations made for two series of concrete strength results, from which sets of decreased strength parameters were separated. When assessing the quality of concrete elements and concrete road surfaces, the principal issue is the control of the compressive strength parameters of concrete. Large quantities of concrete mix manufactured in a continuous way should be subject to continuous control. Standardized approach to assessing the concrete strength proves to be insufficient because it does not allow for the detection of subsets of the decreased strength results, which in turn makes it impossible to make adjustments to the concrete manufacturing process and to identify particular product or area on site with decreased concrete strength. In this article two independent methods of grouping the test results of concrete with statistically stable strength parameters were proposed, involving verification of statistical hypothesis based on statistical tests: Student's t-test and Mann - Whitney - U test.

First Moment Closure Simulation of Floating Turbulent Premixed Flames in Stagnation Flows (정체 유동장에 떠있는 난류 예혼합 화염의 일차 모멘트 닫힘 모사)

  • Lee, Eun-Ju;Huh, Kang-Y.
    • 한국연소학회:학술대회논문집
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    • 2000.05a
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    • pp.122-132
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    • 2000
  • Computational fluid dynamic simulation is performed for the floating turbulent premixed flames stabilized in stagnation flows of Cho et al. [1] and Cheng and Shepherd [2]. They are both in the wrinkled flamelet regime far from the extinction limit with $u'/S^{0}_{L}$ less than unity. The turbulent flux is given in the first moment closure as a sum of the classical gradient flux due to turbulent motions and the countergradient flux due to thermal expansion. The parameter $N_{B}'s$ are greater than unity with the countergradient flux dominant over the gradient flux. The countergradient flux is assumed to be zero in $\bar{c}<0.05$. The flame surface density is modeled as a symmetric parabolic function with respect to $\bar{c}$. The product of the maximum flame surface density and the mean stretch factor is considered as a tuning constant to match the flame location. Good agreement is achieved with the measured $\tilde{w}$ and $\bar{c}$ profiles along the axis in both flames.

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Purification and Characteristics of Pullulanase from Bacillus cereus subsp. mycoides (Bacillus cereus subsp. mycoides가 생산하는 Pullulanase의 정제와 특성)

  • Chung, Man-Jae;Woo, Jeong-Suk;Cho, Dae-Sun;Lee, Myong-Yur;Park, Nam-Kyu
    • Microbiology and Biotechnology Letters
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    • v.22 no.1
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    • pp.73-79
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    • 1994
  • The optimum cultural temperature and time for the pullulanase production by Bacillus cereus subsp. mycoides were 35$\circ $C and 48 hrs, respectively. The addition of egg albumin and casein to the basal medium increased the enzyme production. The enzyme was purified by ammonium sulfate fractionation and DEAE-cellulose column chromatography. specific activity of the purified enzyme was 82.37 U/mg protein and yield of theenzyume activity was 62.1%. The purified enzuyme showed a single band on ployacrylamide disc gel electrophoresis and its molecular weight was estimated to be 66.,000 by SDS-polyacrylamide disc gel electrophoresis. The isoelcular point for the purified enzyme was pH 5.0. The optimum temperature and pH were 50$\circ $C and pH 6.5, respectively. The purified enzyme was stable below 40$\circ $C and in the pH range of 6.5~10.0 The pullulanase activity was greatly inhited by Ag$^{+}$, Hg$^{2+}$ and EDTA, and its heat stability was increased by the addition of Ca$^{2+}$. The tydrolysis product with the enzyme on pullulan was maltotriose.

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