• Title/Summary/Keyword: U- 10wt.%Mo

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EPMA를 이용한 사용후 PWR 핵연료 PCI 영역 분석

  • Jeong, Yang-Hong;Yu, Byeong-Ok;Baek, Seung-Je;An, Sang-Bok;Ryu, U-Seok
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2009.11a
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    • pp.311-312
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    • 2009
  • 가압 경수로에서 53,000 MWd/tU으로 연소된 사용후 핵연료의 PCI 영역에 대해 방사선 차폐형 성분 분석기기( Shielded EPMA)를 사용하여 반경방향에 대한 성분분포를 분석하였다. PCI 영역에서 산화층의 두께는 13um 이었으며, 핵분열생성물의 침투 두께는 시료에서 약 10 um 이내로 나타났다. 이 두께에 침투된 핵종의 총 농도는 1~2 wt%로 관찰되었다. 주요핵종은 Cs 0.5~0.7 wt%, Mo 0.2~0.3 wt%, Pd, Ru, Nd, Ce등이 0.1~0.2 wt% 로 관찰되었다.

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SCANNING ELECTRON MICROSCOPY ANALYSIS OF FUEL/MATRIX INTERACTION LAYERS IN HIGHLY-IRRADIATED U-Mo DISPERSION FUEL PLATES WITH Al AND Al-Si ALLOY MATRICES

  • Keiser, Dennis D. Jr.;Jue, Jan-Fong;Miller, Brandon D.;Gan, Jian;Robinson, Adam B.;Medvedev, Pavel;Madden, James;Wachs, Dan;Meyer, Mitch
    • Nuclear Engineering and Technology
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    • v.46 no.2
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    • pp.147-158
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    • 2014
  • In order to investigate how the microstructure of fuel/matrix-interaction (FMI) layers change during irradiation, different U-7Mo dispersion fuel plates have been irradiated to high fission density and then characterized using scanning electron microscopy (SEM). Specifially, samples from irradiated U-7Mo dispersion fuel elements with pure Al, Al-2Si and AA4043 (~4.5 wt.%Si) matrices were SEM characterized using polished samples and samples that were prepared with a focused ion beam (FIB). Features not observable for the polished samples could be captured in SEM images taken of the FIB samples. For the Al matrix sample, a relatively large FMI layer develops, with enrichment of Xe at the FMI layer/Al matrix interface and evidence of debonding. Overall, a significant penetration of Si from the FMI layer into the U-7Mo fuel was observed for samples with Si in the Al matrix, which resulted in a change of the size (larger) and shape (round) of the fission gas bubbles. Additionally, solid fission product phases were observed to nucleate and grow within these bubbles. These changes in the localized regions of the microstructure of the U-7Mo may contribute to changes observed in the macroscopic swelling of fuel plates with Al-Si matrices.

Geochemical Characteristics of Black Slate and Coaly Slate from the Uranium Deposit in Deokpyeong Area (덕평리 지역 우라늄광상의 흑색점판암과 탄질점판암의 지구화학적 특성)

  • Shin, Dong-Bok;Kim, Su-Jeong
    • Economic and Environmental Geology
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    • v.44 no.5
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    • pp.373-386
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    • 2011
  • Geochemical study was performed on black slates and interbedded U-bearing coaly slates in Deokpyeongri area, the representative uranium mineralized district of the Ogcheon Metamorphic Belt, to discuss the genetic environments of the uranium deposit. REE concentration (254 ppm) of the black slates is higher than that (169 ppm) of the coaly slates and NASC-normalized REE patterns of the coaly slates show remarkable positive Eu anomaly. l11e redox-sensitive trace elements such as V, Cr, Co, Ni, Mo and U in the coaly slates are highly enriched compared to the black slates, especially for V of 24 times, Mo of 62 times, and U of 60 times. In additions, Pd and Pt are also enriched in the coaly slates. Positive Eu anomaly and the noticeable enrichment of the elements listed above compared to those of NASC indicate that those elements were not derived from common seawater but deposited under high temperature and reducing environment of submarine hydrothermal activities. Wide compositional ranges of major elements ($SiO_2/Al_2O_3$: 3.98~11.88, $Al_2O_3/Na_2O$: 25.6~139.06, $K_2O/Na_2O$: 6.80~46.85) also suggest that the source rocks of the sediments are mixtures of sedimentary rocks and igneous rocks. Higher sulfur contents in the coaly slates, 2.6 wt.%, than those in the black slates, 0.6 wt.% also indicates that the former was influenced by hydrothermal activities containing much sulfur. These geochemical characteristics are similar to the genetic environments of South China type PGE deposits (Mo-Ni-Zn-PGE) which is geotectonically correlated with the Ogcheon Metamorphic Belt and is known as sedimentary-exhalative deposits. In conclusions, the uranium and other metallic elements mineralization seems to have occurred in the sedimentary basin that was affected by submarine hydrothermal activities and rich in organic materials under oxygen-poor environments as well.

Geochemical Behavior, Dispersion and Enrichment of Environmental Toxic Elements in Coaly Metapelites and Stream Sediments at the Hoenam Area, up the Taecheong Lake, Korea (대청호 상류, 회남일대에 분포하는 탄질 변성니질암과 하상 퇴적물의 환경유해원소에 관한 지화학적 거동, 분산 및 부화)

  • Lee, Chan Hee;Lee, Hyun Koo
    • Economic and Environmental Geology
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    • v.30 no.3
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    • pp.209-222
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    • 1997
  • The Hoenam area, up the Taecheong lake, composed mainly of low grade coal-bearing metapelites within the Ogcheon Supergroup. These coal formations are developed discontinuously several hundred meters and swelling from 10 to 300 cm along the host metapelites. Although the formations have been mined for coal, but already mined out, and the formations were higher content (mean value of 42 samples) of environmental toxic elements as As (13 ppm). Ba (1.81 wt. %), Cd (2 ppm), Cr (188 ppm), Cu (87 ppm), Mo (214 ppm), Pb (25 ppm), Sb (3 ppm), Se (12 ppm), U (55 ppm), V (2124 ppm) and Zn (234 ppm) than the host metapelites and the NASC. The Al, Ti, Mg, K and Na contents in stream sediments derived from the Hando and Bugook mine area were highly concentrations than the samples from the Samseongjeil mine area. The mean value (wt. %) of Fe (10.07), Mn (0.15), Ca (0.84), P (0.18) and Ba (0.77) influenced by the Samseongjeil mine were higher than the other mine drainage sediments. The mean content (ppm) of environmental toxic elements in drainage sediments from the Samseongjeil mine were taken As (2083), Cu (447), Mo (202), Ni (720), Pb (42), U (250), V (1070) and Zn (2632), which are extremely high concentrations against NASC and EPA. Characteristics of elemental behavior and dispersion of the all toxic elements are the same as increased with increasing U, V, and Cu. Rare earth elements in the sediments are enriched with LREE (La, Ce and Nd) from the drainage on strong concentration of toxic elements. The pH of stream water is neutral, but pH of the sediments ranged from 4.92 to 6.93 (mean 6.22), those are slightly acid in the Hando mine area. Major elements in the host rocks at the Hoenam area are mostly depleted especially Ca, excepting Ti and Ba, normalized with NASC. The sediments were highly enriched of Ti, Fe, Mg, Mn and Ba, but depleted of Al, K, Ca, Na and P on the basis of host rocks and NASC. Minor and environmental toxic elements in the host rocks were strongly enriched all elements (As, Cd, Mo, Se, D, V and Zn), excepting Co, Ni and Sr. Enrichment index (mean value) about toxic elements (As, Cr, Cu, Fe, Ni, Pb and Zn) of the sediments in this area have taken 41.35 (Hando mine drainage; 2.73, Samseongjeil mine drainage; 113.14 and Bugook mine drainage; 8.19), those are seriously contaminated by environmental toxic elements.

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Effects of Fatty Acids and Vitamin E Supplementation on Behavioral Development of the Second Generation Rat

  • Hwang, Hye-Jin;Um, Young-Sook;Chung, Eun-Jung;Kim, Soo-Yeon;Park, Jung-Hwa;Lee, Yang-Cha-Kim
    • Preventive Nutrition and Food Science
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    • v.7 no.3
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    • pp.265-272
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    • 2002
  • In this study, we examined the effects of dietary fatty acids on the fatty acid composition of phospholipid fractions in regions of the brain and on behavioral development in rats. The Sprague Dawley rats were fed the experimental diets 3~4 wks prior to the conception. Experimental diets consisted of 10% fat(wt/wt) which were from either safflower oil (SO, poor in $\omega$3 fatty acids), mixed oil MO, P/M/S ratio : 1:1.4:1, $\omega$6/$\omega$3 ratio = 6.3), or mixed oil supplemented with vitamin E (+500 mg/kg diet). At 3 and 9 weeks of age, frontal cortex (FC), corpus striatum (CS), hippocampus (H), and cerebellum (CB) were dissected from the whole brain. The fatty acid content was determined in the different phospholipid fractions: phosphatidylcholine (PC), phosphatidyl-serine (PS), and phosphatidylethanolamine (PE) in the rat brain regions. In the visual discrimination test, the order of the cumulative errors made in Y-water maze test were SO > MO > ME. This suggested that the balanced diet supplemented with vitamin I had the most beneficial effect on learning ability. The overall characteristics of correlation between fatty acids and behavior development were that the frequency of cumulative errors were negatively correlated significantly with monounsaturated fatty acids (MUFAs), ie., 18:1 $\omega$9 and 22:1 $\omega$9. Docosa-hexaenoic acid (22:6 $\omega$3) of PS in frontal cortex (FC) was negatively correlated with the number of errors made in the Y-water maze test.22:5 $\omega$6 PS in hippocampus (H), PC and PE in corpus striatum (CS), PC in cerebellum (CB) were positively correlated with cumulative errors. And these errors were negatively correlated with 20:4 $\omega$ 6 of PE in corpus striatum (CS) and PC in cerebellum (CB). Especially, O1eic acid (18:1 u 9) in all phospholipid fractions (PC, PS, PE) of hippocampus was negatively correlated with the number of errors. These findings demonstrate that the MUFAs were might be essential for proper brain development, especially in hippocampus which is generally thought to be the regions of memory and learning.

Proliferation of Tricholoma matsutake Mycelial Mats in Pine Forest Using Mass Liquid Inoculum

  • Lee, Won-Ho;Han, Sang-Kuk;Kim, Beom-Seok;Shrestha, Bhushan;Lee, Soo-Yong;Ko, Cheol-Soon;Sung, Gi-Ho;Sung, Jae-Mo
    • Mycobiology
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    • v.35 no.2
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    • pp.54-61
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    • 2007
  • Two isolates of Tricholoma matsutake T-008 and T-034, preserved in Entomopathogenic Fungal Culture Collection (EFCC) of Korea, were used in the present study. The isolates had 100% Bootstrap homology with Tricholoma matsutake U62964 and T. matsutake AB188557 and AF309538 preserved in Gene Bank of NCBI. Mycelial growth of T. matsutake was highest in TMM and MYA at $25^{\circ}C$. The highest dry wt. of mycelium was obtained after 65 days of culture, when 6 mycelial discs were inoculated in 100 ml of broth in 250 ml shaking flask. Mycelial mats were observed in clumped condition at the inoculation sites of pine forest after two weeks of inoculation. After 5 months of inoculation, mycelia mats were observed growing inside soil and walls of a few inoculation sites, while mycelial mats growth up to $5{\sim}8$ cm were observed in the roots of pine tree after 6 months. The survival rate of the inoculum was about 40% of the total inoculation sites. The survival rate was found below 20% when the mycelium was inoculated in the summer. The reasons for low survival rates of the mycelium were mainly due to dry season and the soil-borne small animals such as earthworm and mole. After one year of inoculation, no external difference was observed between the artificially inoculated mycelia and the naturally existing mycelia of T. matsutake. The present study showed that fruiting bodies of T. matsutake could be produced by artificial inoculation under the appropriate environmental conditions.

MODIFICATION OF METAL MATERIALS BY HIGH TEMPERATURE PULSED PLASMA FLUXES IRRADIATION

  • Vladimir L. Yakushin;Boris A. Kalin;Serguei S. Tserevitionov
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2000.05a
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    • pp.1-1
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    • 2000
  • The results of the modification of metal materials treated by high temperature pulst:d plasma fluxes (HTlPPF) with a specific power of incident flux changing in the $(3...100)10^5{]\;}W/cm^2$ range and a pulse duration lying from 15 to $50{\;}\mu\textrm{s}$ have been presented. The results of HTPPF action were studied on the stainless steels of 18Cr-l0Ni, 16Cr- 15Ni, 13Cr-2Mo types; on the structural carbon steels of (13...35)Cr, St. 3, St. 20, St. 45 types; on the tool steels of U8, 65G, ShHI5 types, and others; on nickel and high nickel alloy of 20Cr-45Ni type; on zirconium- and vanadium-base alloys and other materials. The microstructure and properties (mechanical, tribological, erosion, and other properties) of modified materials and surface alloying of metals exposed to HTPPF action have been investigated. It was found that the modification of materials by HTPPF resulted in a simultaneous increase of several properties of the treated articles: microhardness of the surface and layers of 40...60 $\mu\textrm{m}$ in depth, tribological characteristics (friction coefficient, wear resistance), mechanical properties ({\sigma_y}, {\;}{\sigma_{0.2}}.{\;}{\sigma_r}) on retention of the initial plasticity ($\delta$), corrosion resistance, radistanation erosion under ion irradiation, and others. The determining factor of the changes observed is the structural-phase modification of the near-surface layers, in particular, the formation of the fine cellular structure in the near-surface layers at a depth of $20{\;}{\mu\textrm{m}}$ with dimension of cells changing in the range from 0.1 to $1., 5{\;}\mu\textrm{m}$, depending on the kind of material, its preliminary treatment, and the parameters of plasma fluxes. The remits obtained have shown the possibility of purposeful surface alloying of metals exposed to HTPPF action over a depth up to 20...45 $\mu\textrm{m}$ and the concentration of alloying element (Ni, Cr, V) up to 20 wt.%. Possible industrial brunches for using the treatment have been also considered, as well as some results on modifying the serial industrial articles by HTPPF.

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