• Title/Summary/Keyword: Type 304 SS

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Susceptibility of Stress Corrosion Crack Initiation of Type 304 SS in Simulated Primary Water Environment of PWR (원전 1차 계통수 모사환경에서 Type 304 스테인리스강의 응력부식균열개시 민감도)

  • Sung-Hwan Cho;Sung-Woo Kim;Jong-Yeon Lee
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.20 no.1
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    • pp.25-31
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    • 2024
  • The core shroud of rector vessel internals (RVI) of OPR1000 and ARP1400 is made of Type 304 stainless steel (SS) by bending and welding process that may induce high deformation and residual stress in manufacturing. This work aims to evaluate the susceptibility of stress corrosion crack (SCC) initiation of bent parts of RVI in high temperature primary water environment. For SCC initiation test, tensile specimens were fabricated from the 90 degree bent plate of Type 304 SS (DT specimen), that is an archived part of a Korean APR1400. After the SCC initiation test, the specimen surface was thoroughly examined by optical and scanning electron microscopy, and compared to the specimen fabricated from the as-received plate of Type 304 SS (AR specimen). The surface observation revealed that SCC initiated on the AR specimen surface in typical intergranular (IG) mode, while SCC on the DT specimen occurred in transgrannular mode as well as IG mode. It was also found that the size and number of SCC on the DT specimen were larger than that on the AR specimen. This was attributable to a strain-hardening during the bending process. To compare the susceptibility of SCC initiation, total crack density (TCD) was calculated from the total crack length divided by the measured area of AR and DT specimens. TCD of DT specimen was 4.6 times higher than AR specimen in average, indicating that higher possibility of degradation of bent parts of RVI for a long-term operation.

An Evaluation of the Fracture Behavior for Flash Butt Welding zone by Acoustic Emission Method (AE방법에 의한 Flash Butt 용접부의 파괴거동 평가)

  • 김용수;이하성;강동명
    • Journal of the Korean Society of Safety
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    • v.9 no.1
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    • pp.9-18
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    • 1994
  • In this study, we conducted experimental tests to evaluate fracture behaviors of fresh-butt welded metal by Acoustic Emission technique. We selected similar welding and dissimilar welding process, the one welded for SM45C, SS41 and SUS304 of each material, the other for SM45C and SS41, SM45C and SUS304 and SS41 and SUS304. The fracturing processes of weld metal were estimatied through the fracture toughness test with compact tension specimens and fractography analysis. In ASTM test method E-399, type I curves for materials of this study were obtained by load-cod diagram of fracture toughness test. and 5% offset load( $P_{5}$) was estimated as the estimated crack initial load( $P_{Q}$), The estimated crack initial load( $P_{Q}$) of similar welding materials generally lower than base matal, and then SM45C appeared greatly in decreasing rate of PB, SS41 and SUS304 appeared in order. $P_{Q}$ of dissimilar welding materials were lower than the similar welding materials. $P_{Q}$ of welding of SM45C and SS41 appeared in small, SUS304 and SS41 appeared greatly in dissimilar welding materials. In fracture toughness test, AE counts increased before the inflection point of the slope, decreased after that. It was found that increasing of AE counts were due to the microcrack formation at the crack tip near the $P_{5}$ point through AE data. For welding materials in this study, both low and high AE amplitude appeared simulataneously. It was confirmed that the low AE amplotude was due to formation of micro void, micro crack or micro dimple, the high AE amplitude was caused by microvoid coalescence and quasi-cleavage fracture through analyses of fractograpy.apy.apy.apy.

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An optimized condition for corrosion protection of Type 304 Films prepared by unbalanced magnetron sputtering in 3.5% NaCl solution

  • Yoo, Ji-Hong;Ahn, Seung-Ho;Kim, Jung-Gu;Lee, Sang-Yul
    • Journal of the Korean institute of surface engineering
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    • v.34 no.5
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    • pp.465-474
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    • 2001
  • Type 304SS coatings were performed at 200$\square$ onto AISI 1045 carbon steel substrate using unbalanced magnetron sputtering (UBMS) with an austenitic AISI 304 stainless steel (SS) target of 100mm diameter. The total deposition pressure in the active Ar gas was 2$\times$10$^{-3}$ Torr. Coatings were done at various target power densities and bias voltages. Chemical compositions of metallic elements of the coatings were measured by energy dispersive X-rays spectroscopy (EDS). The structure and the morphology of Type 304SS coatings were investigated by means of X-ray diffraction (XRD) and scanning electron microscopy (SEM). Corrosion properties of the coated specimens were examined using electrochemical polarization measurements and electrochemical impedance spectroscopy in a deaerated 3.5% NaCl solution. The porosity rate was obtained from a comparison of the dc polarization resistance of the uncoated and coated substrates. Scratch adhesion testing was used to compare the critical loads for different coatings. XRD results showed that the sputtered films exhibit a ferritic b.c.c. $\alpha$-phase. Potentiodynamic polarization curves indicated that all samples had much higher corrosion potential and better corrosion resistance than the bare steel substrate. The corrosion performance increased with increasing power density and the adhesion was enhanced at the bias voltage of -50V. An improvement in the corrosion resistance can be obtained with a better coating adhesion. Finally, an optimized deposition condition for corrosion protection was found as $40W/cm^2$ and -50V.

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Experimental Study on the Development of a Seismic Reinforcement Method for Reinforced Concrete Columns using High-tensile Alloy Materials (고인장 합금재를 활용한 철근콘크리트 기둥의 내진보강공법 개발에 관한 실험적 연구)

  • Do-Yeon Kim;Il-Young Jang
    • Journal of the Society of Disaster Information
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    • v.20 no.2
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    • pp.411-418
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    • 2024
  • Purpose: This study aims to develop brand new bolt fastening type of seismic retrofit using high tensile alloy materials for existing reinforced concrete columns. Method: A T-type cross-sectional seismic retrofit made of SUS304 and SS275, and the high-tensile bolt of SCM435 was analyzed for the effect of material properties on seismic performance through bending test. Result: The experiment using SUS304 shows a 7% higher maximum strength and 22% higher yield strength and shows a higher compressive stress of 360MPa. In addition, the change in the neutral axis is also smaller. Conclusion: Seismic retrofit using SUS304 is considered to be better in terms of yield strength, tensile strength, neutral axis change, and ductility, and it is considered necessary to experiment with RC column real experiments in future studies.

The Corrosion Behavior of Cold-Rolled 304 Stainless Steel In Salt Spray Environments (염분분사환경에서 냉연 304 스테인레스강의 부식거동)

  • Chiang, M.F.;Young, M.C.;Huang, J.Y.
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.9 no.2
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    • pp.93-98
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    • 2011
  • Saline corrosion is one of the major degradation mechanisms for stainless steel type 304 (SS304) dry storage cask during the spent fuel interim storage period. Slow strain rate test (SSRT) and neutral salt spray test (NSS) were performed at $85^{\circ}C$ and $200^{\circ}C$ with 0.5 wt% sodium chloride mist sprayed on the cold-rolled SS304 specimens of different degrees of reduction in this study. The weight changes of the NSS specimens tested at $85^{\circ}C$ for 2000 hours differed greatly from those at $200^{\circ}C$. The weight loss of NSS specimens was not significant at $85^{\circ}C$ but the weight gain decreased gradually with increasing the cold-rolled reduction. The yield strength (YS) and ultimate tensile stress (UTS) values obtained from the SSRT tests for lightly cold-rolled specimens in the salt spray environment at $85^{\circ}C$ and $200^{\circ}C$ are slightly lower than in air. But for those with 20% reductions, the specimen strengths were no longer changed by the saline corrosion. The preliminary results demonstrated that the quality and performance of cold-rolled SS304 is acceptable for fabrication of dry storage casks. However, more work on the corrosion behavior of cold-rolled stainless steel in the saline atmosphere is needed to better understand its long-term performance.

Crevice Corrosion Properties of PWR Structure Materials Under Reductive Decontamination Conditions (환원제염조건에서 가압경수로 구조재료의 틈부식 특성)

  • Jung, Jun-Young;Park, Sang Yoon;Won, Hui Jun;Choi, Wang Kyu;Moon, Jei Kwon;Park, So Jin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.3
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    • pp.199-209
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    • 2014
  • Crevice corrosion tests were conducted to examine the corrosion properties of HYBRID (HYdrazine Base Reductive metal Ion Decontamination) which was developed to decontaminate the PWR primary coolant system. To compare the corrosion properties of HYBRID with commonly existing decontamination agents, oxalic acid (OA) and citric oxalic acid (CITROX) were also examined. Type 304 Stainless Steel (304 SS) and Alloy 600 which are major components of the primary coolant system in Pressurized Water Reactor (PWR) were evaluated. Crevice corrosion tests were conducted under very aggressive conditions to confirm quickly the corrosion properties of primary coolant system structure components which have high corrosion resistance. Pitting and IGA were occurred in crevice surface under OA and CITROX conditions. But localized corrosion was not observed under HYBRID condition. Very low corrosion rate of less than $1.3{\times}10^{-3}{\mu}m/h$ was observed under HYBRID condition for both materials. On the other hand, under OA condition, Alloy 600 indicated comparatively uniform corrosion rate of $4.0{\times}10^{-2}{\mu}m/h$ but 304 SS indicated rapid accelerated corrosion in lower case than pH 2.0. In case of HYBRID condition, general corrosion and crevice corrosion were scarcely occurred. Therefore, material integrity of HYBRID in decontamination of primary coolant system in pressurized water reactor (PWR) reactor was conformed.

Macro and Micro-electrochemical Characteristics on Dissimilar Welding Metal of Double Wall Gas Pipe for Duel Fuel Engine (이중 연료 엔진용 이중벽 가스 배관 이종 용접부의 매크로 및 마이크로 전기화학적 특성)

  • Kim, Seong-Jong;Park, Jae-Cheul;Han, Min-Su;Jang, Seok-Ki
    • Corrosion Science and Technology
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    • v.9 no.6
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    • pp.331-337
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    • 2010
  • This study compared the macro and micro electrochemical characteristics at the local area of welding metal on dissimilar welding parts for type 304 stainless steel (SS) and type 316L SS. The materials are used for double wall gas pipe of duel fuel engine for a ship. The various potentiodynamic experiments were performed several times in 10% ${H_2C_2O_2}{\cdot}{H_2O}$ solution using macro and micro methods, respectively. The micro electrochemical experiments conducted to resolve at local area on cross-section of dissimilar welding materials by micro-droplet cell device. The micro-droplet cell techniques can be used almost electrochemical experiments to resolve corrosion characteristics of the limited electrode area of the metallic surface between wetted spot of working electrode and tip of sharpened capillary tube. The results of macro electrochemical experiments show that resistance of active dissolution reaction at welding zone was high due to low current density by formation of passivation protection film at passive region. According to the micro electrochemical experiment, the corrosion current density of welding zone and bond zone were relatively high.

LABORATORY STUDIES ON MIC OF AISI TYPE 304 STAINLESS STEEL USING BACTERIA ISOLATED FROM A W ASTEWATER TREATMENT SYSTEM

  • Sreekumari, Kurissery R.;Kyozo, Hirotani;Katsuya, Akamatsu;Takashi, Imamichi;Yasushi, Kikuchi
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.260-265
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    • 2002
  • Microbiologically influenced Corrosion (MIC) is one of the most deleterious effects of metal microbe interactions. When a fresh metal surface comes in contact with a non-sterile fluid, biofilm formation is ensued. This might result in the initiation of corrosion. The sites and materials where MIC is implicated are versatile. Industries such as shipping, power generation, chemical etc are reported to be affected. The rapid and unexpected failure of AISI type 304 stainless steel was investigated in the laboratory by simulation studies for a period of 4 months. Slime and water samples from the failure site were screened for corrosion causing bacteria. Both aerobic and anaerobic nora were enumerated and identified using PCR techniques. Pseudomonas sp. and Bacillus sp. were the most common aerobic bacteria isolated from the water and slime samples, whilst sulfate reducing bacteria (SRB) were the major anaerobic bacteria. The aerobic bacteria were used for the corrosion experiments in the laboratory. Coupon exposure studies were conducted using a very dilute (0.1%V/V) nutrient broth medium. The coupons after retrieval were observed under a Scanning Electron Microscope (SEM) for the presence of MIC pits. Compared to sterile controls, metal coupons exposed to Pseudomonas sp and Bacillus sp. showed the initiation of severe pitting corrosion. However, amongst these two strains, Psudomonas sp. caused pits in a very short span of 14 days. Towards the end of the experiment, severe pitting was observed in both the cases. The detailed observation of pits showed they vary both in number and shapes. Whilst the coupons exposed to Bacillus sp. showed widely spread scales like pits, those exposed to Pseudomonas sp. showed smaller and circular pits, which had grown in number and size by the end of the experiment. From these results it is inferred that the rapid and unexpected failure of 304 SS might be due to MIC. Pseudonwnas sp. could be considered as the major responsible bacteria that could initiate pits in the metallic structures. As the appearance of pits was different in both the tested strains, it was thought that the mechanisms of pit formation are different. Experiments on these lines are being continued.

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A Study on the Prediction of Die Wear using Wear Model (마멸모델을 이용한 금형마멸 예측에 관한 연구)

  • Park, Jong-Nam
    • Design & Manufacturing
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    • v.7 no.1
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    • pp.28-33
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    • 2013
  • During the cold forming, due to high working pressure acting on the die surface, failure mechanics must be considered before die design. One of the main reasons of die failure in industrial application of metal forming technologies is wear. The mechanisms of wear are consisted of adhesion, abrasion, erosion and so on. Die wear affects the tolerances of formed parts, metal flow, and costs of process. The only way to control these failures is to develop a prediction method on die wear suitable in the design state in order to optimize the process. The wear system is used to analyse 'operating variables' and 'system structure'. In this study, with AISI D2, AISI 1020, AISI 304SS materials, a series of the wear experiments of pin-on-disk type to obtain the wear coefficients from Archard's wear model and the upsetting processes are carried out to observe the wear phenomenon during the cold forming process. The analysis of upsetting processes are performed by the rigid-plastic finite element method. The result of the analysis is used to investigate the die wear the processes, and the analysis simulated die wear profiles are compared with the experimental measured die wear profiles.

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Evaluation of Exposure to Pyrethroid Pesticides according to Sprayer Type using Biological Monitoring (생물학적 모니터링을 이용한 분무기 형태에 따른 피레스로이드 농약 노출량 평가)

  • Song, Jae Seok;Choi, Hong Soon;Yu, Ho Young;Park, Byung Gon;Kwon, Daeho
    • The Korean Journal of Pesticide Science
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    • v.20 no.4
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    • pp.300-304
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    • 2016
  • The aim of this study were to evaluate the exposure level of pyrethroid pesticide according to spraying machine type. The urinary metabolites of pyrethroid pesticide in apple farmers were analyzed to determine the exposure level of pyrethroid pesticide. The result shows that, the spraying volume was greater in SS sprayer group than in power sprayer group. But multi variate analysis which adjust spraying volume and field area, there were no difference of urinary metabolites between two sprayer machine. To make more accurate model of pesticide exposure, the factors influencing pesticide exposure should be determined and further study should be done.