• 제목/요약/키워드: Two-temperature-stage process

검색결과 135건 처리시간 0.024초

고분자 전해질 연료전지 적용을 위한 DME 자열개질가스 내 CO제거 공정 특성 연구 (Experiment of CO Cleaning Process in DME Autothermal Reformate Gas for PEMFC Application)

  • 최승현;배중면
    • 한국수소및신에너지학회논문집
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    • 제22권4호
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    • pp.474-480
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    • 2011
  • Hydrocarbon is required to be converted to pure hydrogen without carbon monooxide (CO) for polymer exchange membran fuel cell (PEMFC) applications. In this paper, CO cleaning processes as the downstream of Dimethyl ehter (DME) autothermal reforming process were performed in micro-reactors. Our study suggested two kinds of water gas shift (WGS) reaction process: High Temperature shift (HTS) - Low Temperature shift (LTS), Middle temperature shift (MTS). Firstly, using perovskite catalyst for MTS was decreased effieiciency since methanation. Using HTS-LTS the CO concentration was decreased about 2% ($N_2$ & $H_2O$ free) with the reaction temperature of $420^{\circ}C$ and $235^{\circ}C$ for HTS and LTS, respectively. As the final stage of CO cleaning process, preferential oxidation (PROX) was applied. The amount of additional oxygen need 2 times of stoichiometric at $65^{\circ}C$. The total conversion reforming efficiency of 75% was gained.

평평한 금형(金型)의 열응력(熱應力)에 관한 연구(硏究) (A Study on the Thermal Stresses Analysis of the Flat Mould)

  • 민수홍;구본권;김옥삼
    • 한국주조공학회지
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    • 제11권3호
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    • pp.245-253
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    • 1991
  • It is known that the analysis of thermal stresses is substantially important in optimal design of casting mould. In this paper unsteady state thermal stresses generated in ingot and mould during the solidification process are analyzed by the two dimensional thermal elasto-plastic analysis. Distribution of temperature and stress of the mould is calculated using the finite element method and compared with experimental result. The significant results obtained in this study are as follows. At the early stage of the casting process, abrupt temperature change was shown in the vicinity of the inner surface of the mould. The largest temperature gradient is occurred at the corner of the mould. In the thermal stress analysis, compressible stress occurred in the inside wall of the mould where as tensile stress on outside wall. Smaller thermal stress is observed at the rounded corner. It is also observed that the shown is influenced by the thickness of the wall. A fairly good coincidence is found between analytical and experimental results, showing that the proposed analytical methodology is reliable.

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팽창기를 적용한 이산화탄소 냉방시스템의 성능특성에 관한 해석적 연구 (Simulation Study on the Performance Characteristics of a $CO_2$ Cooling System with an Expander)

  • 조홍현;백창현;류창기;김용찬
    • 설비공학논문집
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    • 제19권9호
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    • pp.630-639
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    • 2007
  • A $CO_2$ cycle shows large throttling loss during the expansion process. The application of an expander into the $CO_2$ cycle can reduce the throttling loss and then improve system performance. In this study, the performance of a transcritical $CO_2$ cycle with an expander was analytically investigated in order to improve the cooling performance of the system. The expander was applied to the single-stage and two-stage compression cycles. The performance was analyzed with the variations of compressor frequency, outdoor temperature, and expander efficiency. The single-stage and two-stage compression cycles with the expander showed COP improvement of 25% and 32%, respectively, over the single-stage cycle with an EEV.

양돈폐수처리시 실규모 이단 혐기성공정의 성능 및 메탄회수 (Methane Recovery and Performances of Full-scale Two-stage Anaerobic Process Treating Piggery Wastewater)

  • 정진영;정윤철;강신현;정형숙
    • 한국물환경학회지
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    • 제21권3호
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    • pp.256-262
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    • 2005
  • The purpose of this study is to investigate the performances of organic removal and methane recovery by using a full scale two-phase anaerobic system. The full scale two-phase anaerobic process was consists of an acidogenic anaerobic baffled reactor (ABR) and a methanognic upflow anaerobic sludge blanket (UASB) reactor. The volumes of acidogenic and methanogenic reactors were designed to $28.3m^3$ and $75.3m^3$. The two-phase anaerobic system represented 60-82% of COD removal efficiency when the influent COD concentration was in the range of 7,150 to 16,270 mg/L after screening (average concentration is 10,280 mg/L). After steady-state, the effluent COD concentration in the methanogenic reactor showed $2,740{\pm}330 mg/L$ by representing average COD removal efficiency was $71.4{\pm}8.1%$ when the operating temperature was in the range of $19-32^{\circ}C$. The effluent SCOD concentration was in the range of 2,000-3,000 mg/L at the steady state while the volatile fatty acid concentration was not detected in the effluent. Meanwhile, the COD removal efficiency in the acidogenic reactor showed less than 5%. The acidogenic reactor played key roles to reduce a shock-loading when periodic shock loading was applied and to acidify influent organics. Due to the high concentration of alkalinity and high pH in the effluent of the methanogenic reactor, over 80% of methane in the biogas was produced consistently. More than 70% of methane was recovered from theoretical methane production of TCOD removed in this research. The produced gas can be directly used as a heat source to increase the reactor temperature.

하수2차처리수의 재이용을 위한 후탈질공정의 평가 (Performance Evaluation of Tertiary Post-denitrification Processes for the Reuse of Secondary Effluent from Wastewater Treatment Plant)

  • 이찬호;윤주환;이윤석;이한샘;안동근
    • 한국물환경학회지
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    • 제23권5호
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    • pp.642-649
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    • 2007
  • The effectiveness of add-on tertiary treatment processes for the polishing of the effluent of a biological nutrient removal (BNR) system from a modified $A^2/O$ process has been examined under the field condition with pilot-scale plants. The add-on treatment processes of 1) combined biofilm anoxic reactor and sand filtration, and 2) two-stage denitrification filter had been operated with various operating conditions. The experimental results indicated that two-stage denitrification filter could produced a better polished tertiary effluent. Filtration rate of $150m^3/m^2{\cdot}d$ for the 2-stage denitrifying filter could decrease the nitrate removal probably due to shorter detention time that caused insufficient reaction for denitrification. Two stage denitrification filter operated with M/N ratio of 3.0 and filtration rate of $100m^3/m^2{\cdot}d$ produced the tertiary effluent with nitrate and SS concentraitons of 2.8 mg/L and 2.3 mg/L, respectively. When the operating temperature reduced $30^{\circ}C$ to $18^{\circ}C$, $NO_3{^-}-N$ removal efficiency decreased from 73% to 68%.

코인된 솔더 범프를 형성시킨 PCB 기판을 이용한 플립 칩 접속 (Flip Chip Assembly on PCB Substrates with Coined Solder Bumps)

  • 나재웅;백경욱
    • 한국마이크로전자및패키징학회:학술대회논문집
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    • 한국마이크로전자및패키징학회 2002년도 추계기술심포지움논문집
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    • pp.21-26
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    • 2002
  • Solder flip chip bumping and subsequent coining processes on PCB were investigated to solve the warpage problem of organic substrates for high pin count flip chip assembly by providing good co-planarity. Coining of solder bumps on PCB has been successfully demonstrated using a modified tension/compression tester with height, coining rate and coining temperature variables. It was observed that applied loads as a function of coined height showed three stages as coining deformation : (1) elastic deformation at early stage, (2) linear increase of applied load, and (3) rapid increase of applied load. In order to reduce applied loads for coining solder bumps on PCB, effects of coining process parameters were investigated. Coining loads for solder bump deformation strongly depended on coining rates and coining temperatures. As coining rates decreased and process temperature increased, coining loads decreased. Among the effect of two factors on coining loads, it was found that process temperature had more significant effect to reduce applied coining loads during the coining process. Lower coining loads were needed to prevent substrate damages such as micro-via failure and build-up dielectric layer thickness change during applying loads. For flip chip assembly, 97Pb/Sn flip chip bumped devices were successfully assembled on organic substrates with 37Pb/Sn coined flip chip bumps.

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2단 승온 캐스케이드 히트펌프의 성능 특성에 관한 연구 (Study on the Performance of a Cascade Heat Pump with Two-stage Water Heating Process)

  • 장한별;최종민
    • 한국지열·수열에너지학회논문집
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    • 제12권4호
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    • pp.27-32
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    • 2016
  • It is estimated that only heating and cooling take about one third of the total energy consumption worldwide. However, the conventional heating and cooling systems have low efficiencies. Also, boilers and electric heaters that are mostly used to generate both domestic and industrial hot water are inefficient and high energy consumers. For this reason, cascade heat pumps which are known to be very energy efficient and have less environmental impact are being promoted to replace conventional heating, cooling and hot water systems. In this study, a newly designed cascade heat pump by two-stage water heating method has been experimentally investigated. By adopting the auxiliary heat exchanger, the performance of the system was increased. The performance enhancement rate of the system could be maximized by adjusting the low stage compressor speed rather than the high stage compressor speed. The performance of the system with the auxiliary heat exchanger was enhanced by 16.5%.

자동차의 안정성을 고려한 고인성 충격흡수 강재로서 TRIP 형 복합상강의 기계적 성질 및 그 특성 (The Mechanical Properties and Characteristics of TRIP-assisted Multiphase Steels in High Toughness for Autombile Safety)

  • 이기열
    • 한국자동차공학회논문집
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    • 제8권4호
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    • pp.141-148
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    • 2000
  • As the steel plates used for automobile safety the TRIP-assisted multiphase steels are being introduced to automobile industry with respect to their remarkable mechanical properties for the combination of high strength and large elongation. This multiphase structure is generated by two stage heat treatment (intercritical annealing & isothermal treatment) The metastable retained austenite can be transformed to martensite when plastically deformed which results in TRIP effect. Actually the microstructure of TRIP-assisted steels consist of a fine dispersite. There present discussion deals with bainite reaction kinetics of austenite in the process o f two stage heat treatment. In relation to bainite transformation the characteristics of bainite reaction is found to be influenced by the bainite tempering temperature and also by the relative rate in which carbides precipitate within residual austenite.

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프로세스 압축기 틸팅패드 저널베어링의 비정상 고온거동 트러블슈팅 (Abnormal High-Temperature Behavior Troubleshooting of Process Compressor Tilting Pad Journal Bearing)

  • 이안성;이운실;최동훈
    • Tribology and Lubricants
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    • 제33권2호
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    • pp.37-44
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    • 2017
  • A DE-side LBP tilting pad journal bearing of a 1-stage overhung heat-pump compressor in a propylene process exhibited abnormal high-temperature behavior. Its temperature had been relatively high at $78^{\circ}C$ from the beginning of operation. In 2014, after three years of operation, it increased suddenly and reached $103^{\circ}C$. Installing a varnish removal equipment and others managed to stabilize the temperature at $95^{\circ}C$. We undertook a troubleshooting approach for reviewing the comprehensive status and integrity of the temperature design of the bearing. We performed lubrication and heat-balance analysis, based on the design engineering data and documents supplied by the OEM. For the base design data of DE-side TPJB, evaluating the effects of key design variables on bearing metal temperature showed that firstly, increasing the bearing clearance and supply oil flow-rate, and next, changing the oil type, and finally, increasing the machined pad clearance and offset, are more effective in reducing the bearing metal temperature. Furthermore, a clarification meeting with the OEM revealed that an incorrect decision had been made to decrease the bearing clearance to eliminate the SSV harshness issue, while not maintaining a sufficient oil flow-rate. We conducted a detailed retrofit design analysis, wherein we increased the oil flow-rate and bearing clearance by decreasing the preload. We predicted that the bearing temperature would decrease to $63^{\circ}C$ from $75.7^{\circ}C$ even at the rerate condition. Finally, after installing and operating a retrofit replacement bearing in 2015, the bearing temperature stabilized at a low temperature of $65^{\circ}C$. Currently (January. 2017), two year later, the bearing metal temperature remains at $65^{\circ}C$. Therefore, we can conclude that the abnormal high-temperature behavior of the bearing has been resolved completely.

Two-Stage Fermentation for 2-Ketogluconic Acid Production by Klebsiella pneumoniae

  • Sun, Yuehong;Wei, Dong;Shi, Jiping;Mojovic, Ljiljana;Han, Zengsheng;Hao, Jian
    • Journal of Microbiology and Biotechnology
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    • 제24권6호
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    • pp.781-787
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    • 2014
  • 2-Ketogluconic acid production by Klebsiella pneumoniae is a pH-dependent process, strictly proceeding under acidic conditions. Unfortunately, cell growth is inhibited by acidic conditions, resulting in low productivity of 2-ketogluconic acid. To overcome this deficiency, a two-stage fermentation strategy was exploited in the current study. During the first stage, the culture was maintained at neutral pH, favoring cell growth. During the second stage, the culture pH was switched to acidic conditions favoring 2-ketogluconic acid accumulation. Culture parameters, including switching time, dissolved oxygen levels, pH, and temperature were optimized for the fed-batch fermentation. Characteristics of glucose dehydrogenase and gluconate dehydrogenase were revealed in vitro, and the optimal pHs of the two enzymes coincided with the optimum culture pH. Under optimum conditions, a total of 186 g/l 2-ketogluconic acid was produced at 26 h, and the conversion ratio was 0.98 mol/mol. This fermentation strategy has successfully overcome the mismatch between optimum parameters required for cell growth and 2-ketogluconic acid accumulation, and this result has the highest productivity and conversion ratio of 2-ketogluconic and produced by microorganism.