• Title/Summary/Keyword: Two Difference Voltage

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Polarity-tuned Gel Polymer Electrolyte Coating of High-voltage LiCoO2 Cathode Materials

  • Park, Jang-Hoon;Cho, Ju-Hyun;Kim, Jong-Su;Shim, Eun-Gi;Lee, Yun-Sung;Lee, Sang-Young
    • Journal of the Korean Electrochemical Society
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    • v.14 no.2
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    • pp.117-124
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    • 2011
  • We demonstrate a new surface modification of high-voltage lithium cobalt oxide ($LiCoO_2$) cathode active materials for lithium-ion batteries. This approach is based on exploitation of a polarity-tuned gel polymer electrolyte (GPE) coating. Herein, two contrast polymers having different polarity are chosen: polyimide (PI) synthesized from thermally curing 4-component (pyromellitic dianhydride/biphenyl dianhydride/phenylenediamine/oxydianiline) polyamic acid (as a polar GPE) and ethylene-vinyl acetate copolymer (EVA) containing 12 wt% vinyl acetate repeating unit (as a less polar GPE). The strong affinity of polyamic acid for $LiCoO_2$ allows the resulting PI coating layer to present a highly-continuous surface film of nanometer thickness. On the other hand, the less polar EVA coating layer is poorly deposited onto the $LiCoO_2$, resulting in a locally agglomerated morphology with relatively high thickness. Based on the characterization of GPE coating layers, their structural difference on the electrochemical performance and thermal stability of high-voltage (herein, 4.4 V) $LiCoO_2$ is thoroughly investigated. In comparison to the EVA coating layer, the PI coating layer is effective in preventing the direct exposure of $LiCoO_2$ to liquid electrolyte, which thus plays a viable role in improving the high-voltage cell performance and mitigating the interfacial exothermic reaction between the charged $LiCoO_2$ and liquid electrolytes.

Relative Influence of Surface and Interfacial Defects in Hydrothermally Grown Nanostructured ZnO (수열 합성된 나노구조를 갖는 ZnO 에 대한 표면 및 계면 결함의 상대적인 영향)

  • Park, Cheolmin;Lee, Jihye;So, Hye-Mi;Chang, Won Seok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.10
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    • pp.831-835
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    • 2014
  • The relative concentration of surface and interfacial defects in hydrothermally grown ZnO nanostructures was investigated by a comparison of two samples having different growth temperatures via bias voltage sweep rate under laser illumination of 405 and 355 nm. The current of small ZnO nanostructures (growth temperature of $75^{\circ}C$) decreased when induced more slowly bias voltage sweep rate under the laser illumination. In contrast, the current of large ZnO nanostructures (growth temperature of $90^{\circ}C$) increased. This difference in currents indicates the relation of relative defects concentration between surface and interfacial defects of ZnO nanostructure. Our experimental approach has potential applicability in the analysis of influence on defects in ZnO devices.

A Study on Production of Nitrogen Oxides in Plasma Reactors

  • Lim, Gye-Gyu
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.E3
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    • pp.91-99
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    • 2001
  • Plasma reactor was used to generate a high potential difference between two surfaces of concentric pyrex tubes by electrical current. The annular gap of the reactor was calculated by trial and error from the breakdown voltage equation and set at 0.45 cm. The overall objective of this research was to know the effects of the frequency, humidity, and residence time on the formation of nitrogen oxides in a plasma reactor. The primary voltage varied from 50 to 90 volts and the frequency was varied in increments of 10 Hz from 60 to 650 Hz at the primary voltage of 90. The increase in the secondary voltage was not linear but exponential at high frequencies. At a maximum concentration of about 745 ppm, the frequency and secondary voltage was 600 Hz and 4,200 volts, respectively. All tests for the effects of humidity on NO$_{x}$ production were performed at the optimal setting of 90 colts and 600 Hz frequency. Since the NO$_{x}$ production was not an one dimensional phenomenon, competing reactions were assumed to occur in the discharge chamber. The sharp peak concentration of 1,810 ppm was observed at 38% of relative humidity, The enhanced production was choked off, and the production rate rapidly dropped to 3 ppm at above 40% of relative humidity. It is assumed that the corona attacks the most vulnerable molecules in the reaction chamber before attacking other more lightly bonded molecules, possibly at humidities above 38% and the optimized 90 volt setting. Thus, there was not enough energy left after attacking all water molecules to decompose an appreciable amount of $N_2$. If nitrogen breakdown does not occur, then oxides of nitrogen are not likely to be produced.ced.

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A Design of Novel Instrumentation Amplifier Using a Fully-Differential Linear OTA (완전-차동 선형 OTA를 사용한 새로운 계측 증폭기 설계)

  • Cha, Hyeong-Woo
    • Journal of the Institute of Electronics and Information Engineers
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    • v.53 no.1
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    • pp.59-67
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    • 2016
  • A novel instrumentation amplifier (IA) using fully-differential linear operational transconductance amplifier (FLOTA) for electronic measurement systems with low cost, wideband, and gain control with wide range is designed. The IA consists of a FLOTA, two resistor, and an operational amplifier(op-amp). The principal of the operating is that the difference of two input voltages applied into FLOTA converts into two same difference currents, and then these current drive resistor of (+) terminal and feedback resistor of op-amp to obtain output voltage. To verify operating principal of the IA, we designed the FLOTA and realized the IA used commercial op-amp LF356. Simulation results show that the FLOTA has linearity error of 0.1% and offset current of 2.1uA at input dynamic range ${\pm}3.0V$. The IA had wide gain range from -20dB to 60dB by variation of only one resistor and -3dB frequency for the 60dB was 10MHz. The proposed IA also has merits without matching of external resistor and controllable offset voltage using the other resistor. The power dissipation of the IA is 105mW at supply voltage of ${\pm}5V$.

Quench Characteristics of Resistive SFCL Elements in series (직렬 연결된 초전도 한류기의 퀜치 및 한류 특성)

  • Hyun, Ok-Bae;Choi, Hyo-Sang;Kim, Hye-Rim;Lim, Hae-Ryong;Kim, In-Seon
    • Proceedings of the KIEE Conference
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    • 2000.07b
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    • pp.663-665
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    • 2000
  • We fabricated resistive superconducting fault current limiters (SFCL) based on YBCO thin films grown on 2-inch diameter saphire substrates Two SFCLs with nearly identical properties were connected in series to investigate the simultaneous quench. There was a slight difference in the rate of voltage increase between two SFCL units when they were operated independently. This difference. however, resulted in significantly unbalanced power dissipation between the units. This imbalance was removed by connecting a shunt resistor to an SFCL in parallel. The appropriate values of the shunt resistances were $80{\Omega}$ at $75 V_{rms}$. $100{\Omega}$ at $100 V_{rms}$ and $110{\Omega}$ at $120 V_{rms}$, respectively. Increased power input at high voltages also reduced the initial imbalance in power dissipation. but with increase in film temperature to higher than 200 K.

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Operating Characteristics of Superconducting Fault Current Limiters Connected in Series by Shunt Resistors (직렬연결된 초전도 한류기의 분로저항에 의한 동작특성)

  • Hyun, Ok-Bae;Choi, Hyo-Sang;Kim, Hye-Rim;Lim, Hae-Ryong;Kim, In-Seon
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.49 no.11
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    • pp.737-741
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    • 2000
  • We fabricated resistive superconducting fault current limiters (SFCL) based on YBCO thin films grown on 2-inch diameter $Al_2O_3$ substrates. Two SFCLs with nearly identical properties were connected in series to investigate simultaneous quench. There was a slight difference in the rate of voltage increase between two SFCL units when they were operated independently. This difference resulted in significantly imbalanced power dissipation between the units. This imbalance was removed by connecting a shunt resister to an SFCL in parallel. The appropriate values of shunt resistance were 80 ${\Omega}$ at 75 $V_rms$ and 110 ${\Omega}$ at 120 $V_rms$, respectively. Increased power input at high voltages also reduced the initial imbalance in power dissipation, but with increase in film temperature to higher than 200 K.

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Fundamental Study of Energy Harvesting using Thermoelectric Module on Road Facilities (열전소자를 활용한 도로구조물에서의 에너지 하베스팅 기초 연구)

  • Lee, Jae-Jun;Kim, Dae-Hoon;Lee, Kang-Hwi;Lim, Jae-Kyu;Lee, Seung-Tae
    • International Journal of Highway Engineering
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    • v.16 no.6
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    • pp.51-57
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    • 2014
  • PURPOSES : An conventional method for electric power generation is converting thermal energy into mechanical energy then to electrical energy. Due to environmental issues such as global warming related with $CO_2$ emission etc., were the limiting factor for the energy resources which resulting in extensive research and novel technologies are required to generate electric power. Thermal energy harvesting using thermoelectric generator is one of energy harvesting technologies due to diverse advantages for new green technology. This paper presents a possibility of application of the thermoelectric generator's application in the direct exchange of waste solar energy into electrical power in road space. METHODS : To measure generated electric power of the thermoelectric generator, data logger was adopted as function of experimental factors such as using cooling sink, connection methods etc. Also, the thermoelectric generator、s behavior at low ambient temperature was investigated as measurement of output voltage vs. elapsed times. RESULTS : A few temperature difference between top an bottom of the thermoelectric generator is generated electric voltage. Components of an electrical circuit can be connected in various ways. The two simplest of these are called series and parallel and occur so open. Series shows slightly better performance in this study. An installation of cooling sink in the thermoelectric generator system was enhanced the output of power voltage. CONCLUSIONS : In this paper, a basic concepts of thermoelectric power generation is presented and applications of the thermoelectric generator to waste solar energy in road is estimated for green energy harvesting technology. The possibility of usage of thermoelectric technology for road facilities was found under the ambient thermal gradient between two surfaces of the thermoelectric module. An experiment results provide a testimony of the feasibility of the proposed environmental energy harvesting technology on the road facilities.

A STUDY OF THE STRESS TRANSMISSION OF VARIOUS ARTIFICIAL TEETH AND DENTURE BASE MATERIALS TO THE UNDER-LYING SUPPORTING TISSUES (인공치와 의치상의 재질에 따른 의치상 하부 지지조직에의 응력전달에 관한 연구)

  • Chung, Hyun-Gun;Chung, Moon-Kyu;Lee, Ho-Yong
    • The Journal of Korean Academy of Prosthodontics
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    • v.27 no.2
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    • pp.79-100
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    • 1989
  • The Purpose of this study was to investigate material differences in stress transmission among various artificial teeth and denture base materials. For this study, a two-dimensional finite element model and a two-dimensional photoelastic model of a mandible with complete denture were made. A resin tooth and a porcelain tooth were used as artificial teeth, and a resin base, a metal lined base, and a soft-liner lined base were used as denture bases. An occlusal load was applied and principal stresses generated in the supporting tissues were compared. To test the impact stress transmission, strain gauge attached to the denture base specimens made of the different materials were made in thick and thin groups. Voltage outputs from hitting the specimen with a steel ball were compared. The results were as follows : 1. In FEM, increasing the mucosal thickness reduced the maximum principal stresses in the supporting tissues, but altering the tooth materials and the base materials induced no difference in the stresses. 2. In photoelastic model study, no difference in fringe order among the specimens were observed, but the thick mucosa group and the soft-liner lined group revealed a more uniform distribution of the load. 3. In strain measuring, the impact force transmission was highest in the soft-liner lined group, and was the lowest in the metal lined group(p<0.01). 4. In the thin group using the resin base, the porcelain tooth showed higher impact stress transmission than the resin tooth(p<0.01), but no difference was observed between them in the thick group. In the soft-liner lined group, the porcelain tooth showed higher impact stress transmission than the resin tooth(p<0.01), but no difference was observed between them in the metal lined group. 5. The thick group showed lower impact stress transmission than the thin group(p<0.01).

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An Optimal Combination of Illumination Intensity and Lens Aperture for Color Image Analysis

  • Chang, Y. C.
    • Agricultural and Biosystems Engineering
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    • v.3 no.1
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    • pp.35-43
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    • 2002
  • The spectral color resolution of an image is very important in color image analysis. Two factors influencing the spectral color resolution of an image are illumination intensity and lens aperture for a selected vision system. An optimal combination of illumination intensity and lens aperture for color image analysis was determined in the study. The method was based on a model of dynamic range defined as the absolute difference between digital values of selected foreground and background color in the image. The role of illumination intensity in machine vision was also described and a computer program for simulating the optimal combination of two factors was implemented for verifying the related algorithm. It was possible to estimate the non-saturating range of the illumination intensity (input voltage in the study) and the lens aperture by using a model of dynamic range. The method provided an optimal combination of the illumination intensity and the lens aperture, maximizing the color resolution between colors of interest in color analysis, and the estimated color resolution at the combination for a given vision system configuration.

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Simulation for the analysis of distortion and electrical characteristics of a two-dimensional BJT (2차원 BJT의 전기적 특성 및 왜곡 해석 시뮬레이션)

  • 이종화;신윤권
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.4
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    • pp.84-92
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    • 1998
  • A program was developed to analyze the electrical characteristics and harmonic distrotion in a two-dimensional silicon BJT. The finite difference equations of the small signal and its second and thired harmonics for basic semiconductor equations are formulated treating the nonlinearity and time dependence with Volterra series and Taylor series. The soluations for three sets of simultaneous equations were obtained sequantially by a decoupled iteration method and each set was solved by a modified Stone's algorithm. Distortion magins and ac parameters such as input impedance and current gains are calculated with frequency and load resistance as parameters. The distortion margin vs. load resistancecurves show cancellation minima when the pahse of output voltage shifts. It is shown that the distortionof small signal characteristics can be reduced by reducing the base width, increasing the emitter stripe length and reducing the collector epitaxial layer doping concentration in the silicon BJT structure. The simulation program called TRADAP can be used for the design and optimization of transistors and circuits as well as for the calculation of small signal and distortion solutions.

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