• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.11a
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• pp.227-228
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• 2012

In contemporary architectural practice, flat sections and plan drawings are no longer a primary means of representation and communication with participants. A typical building design has an ornamental exterior wall system and a roof system that should have water-proof quality and drainage function. By comparison, distinction between exterior wall and roof are unclear in freeform buildings, and they are integrated into a concept of a building envelope. This study is to propose 3D coordinate control technology for freeform structure by CNC curved tube method in order to develop a BIM-based envelope design and construction method for freeform building. Because a much wider freeform building construction can be achieved with correct 3D data and easy-to-implement in construction field, the proposed 3D coordinate control technology is highly recommended for practical use instead of the conventional CAD system.

• Bulletin of the Korean Chemical Society
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• v.28 no.1
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• pp.89-94
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• 2007

The new pinane derivative containing unique multifused ring system was synthesized. The crystal, molecular and electronic structure of the title compound has been determined. Both pinane ring systems have the same conformation. The five-membered oxazolidine ring exists in twisted chair conformation. The structure is expanded through O-H…O hydrogen bond to semiinfinite hydrogen-bonded chain. The bond lengths and angles in the optimised structure are similar to the experimental ones. The CH3 and CH2 groups (except this of oxazolidine ring) are negatively charged whereas the CH groups are positively charged. The largest negative potential is on the oxygen atoms. The C-N natural bond orbitals are polarised towards the nitrogen atom (ca. 61% at N) whereas the C-O bond orbitals are polarised towards the oxygen atom (ca. 67% at O). It is consistent with the charges on the nitrogen and oxygen atom of oxazolidine ring and the direction of the dipole moment vector (3.08 Debye).

• Journal of the Chungcheong Mathematical Society
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• v.13 no.1
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• pp.1-11
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• 2000

The non-commutative torus $A_{\omega}=C^*(\mathbb{Z}^n,{\omega})$ may be realized as the $C^*$-algebra of sections of a locally trivial $C^*$-algebra bundle over $\widehat{S_{\omega}}$ with fibres $C^*(\mathbb{Z}^n/S_{\omega},{\omega}_1)$ for some totally skew multiplier ${\omega}_1$ on $\mathbb{Z}^n/S_{\omega}$. It is shown that $A_{\omega}{\otimes}M_l(\mathbb{C})$ has the trivial bundle structure if and only if $\mathbb{Z}^n/S_{\omega}$ is torsion-free.

• Journal of the Chungcheong Mathematical Society
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• v.11 no.1
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• pp.151-161
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• 1998

The odd spherical non-commutative tori $\mathbb{S}_{\omega}$ were defined in [2]. Assume that no non-trivial matrix algebra can be factored out of $\mathbb{S}_{\omega}$, and that the fibres are isomorphic to the tensor product of a completely irrational non-commutative torus with a matrix algebra $M_{km}(\mathbb{C})$. It is shown that the tensor product of $\mathbb{S}_{\omega}$ with the even Cuntz algebra $\mathcal{O}_{2d}$ has the trivial bundle structure if and, only if km and 2d - 1 are relatively prime, and that the tensor product of $\mathbb{S}_{\omega}$ with the generalized Cuntz algebra $\mathcal{O}_{\infty}$ has a non-trivial bundle structure when km > 1.

• Proceedings of the Membrane Society of Korea Conference
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• 1995.04a
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• pp.16-20
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• 1995

The spontaneous self-organization of amphiphilic molecules into complex aggregates was undoubtedly an important factor in the emergence of life on earth. We study the parameters governing the self-organization of a simple amphiphilic model system using electron cryomicroscopy of ice-embedded specimens in combination with extensive data analysis. Different stable helices can be generated reproducibly by changing the parameters controlling the molecular aggregation process. The repeating units of the helical aggregates in the micrographs can be found by multivariate statistical image analysis techniques, and these two-dimensional projection images suffice for calculating the three-dimensional density distribution of the fibers. We present a typical structure consisting of a narrow stack of compartmented bilayers twisted into a left-handed helix. Our new techniques directly elucidate the three-dimensional structure of helical assemblies, and can complement or replace diffraction-based approaches.

• Bulletin of the Korean Chemical Society
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• v.22 no.12
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• pp.1350-1360
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• 2001

The synthesis and characterization of very stable Pd(Ⅱ) η1-imine complexes of bis(3,4-dialkyloxybenzylidene-3', 4'-dialkyloxyaniline)dichloropalladium(Ⅱ) with alkyl chain of hexyl (8), octyl (9), decyl (10) and dodecyl (11) groups, a nd of bis(4-ethyloxybenzylidene-4'-ethyloxyaniline)dichloropalladium(Ⅱ) as a model complex are described. The molecular structure with twisted board-like geometry of the complex resulting from the coordination of Pd(Ⅱ) with η1-imine bonding was confirmed by X-ray crystallographic analysis of the model complex. In contrast to the imine ligands, all the complexes with an exception of 11 display a thermally stable monotropic smectic A mesophase without any decomposition of the complex. These results, characterized by a combination of differential scanning calorimetry, optical polarized microscopy, and powder X-ray scattering experiments, are discussed.

• Bulletin of the Korean Chemical Society
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• v.13 no.6
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• pp.613-620
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• 1992

The solvent-dependent photophysical properties of 2-biphenylcarboxylic acid (2BPCA) and 4-biphenylcarboxylic acid(4BPCA), which have a pre-twisted conformation in the ground state, have been investigated. The fluorescence spectra of 4BPCA show vibrational structure with a non-mirror image to the absorption spectra in nonpolar solvent while those of 2BPCA show no structure even in nonpolar solvents. As the solvent polarity increases, the fluorescence spectra become diffuse and broad with a strong red shift resulting in the large Stokes shift. The large fluorescence Stokes shift of BPCA's in polar solvent is also partially due to an intramolecular charge transfer (ICT) interaction in the excited state, as demonstrated by the large dipole moment in the excited state (7.6-10.6 D). The fluorescence decay behaviors of BPCA's (decay-times and their pre-exponential factors) also depend on solvent polarity in agreement with the solvent-dependent properties of the steady-state fluorecence. The data have been discussed in terms of change in the excited-state potential energy surface with respect to change of the dihedral angle of biphenyl moiety.

• International Journal of Industrial Entomology and Biomaterials
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• v.40 no.1
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• pp.6-15
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• 2020

Silk has attracted the attention of numerous research groups because of its unique properties as a biomedical material. Recently, studies on the biomedical application of silk cocoon, such as membranes for guided bone regeneration, have been conducted. As a preliminary study on silkworm cocoons, the morphological structure and crystallinity of cocoon of nine silkworm varieties with different sides are examined in this study. The morphological structure of the silkworm cocoon is shown to be dependent on silkworm variety and the cocoon layer (i.e. outside or inside). It is also shown that the silk filaments of the out layer are more bent and twisted compared to those of the inner layer. Furthermore, the crystallinity of the outer surface of all silkworm cocoons is found to be higher than that of the inner surface, regardless of the silkworm variety. Lastly, it is shown that the crystallinity index of the cocoon depends on the silkworm variety, implying that the structure of the cocoon varies with silkworm variety.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.6
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• pp.2292-2299
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• 2010

The wear and abrasion mechanism of conventional PET/Cotton fabric which is used as a lining layer for thermotherapy massager was elaborately investigated in order to increase the life-span of the fabrics for Thermotherapy Massager. Based on the destruction mechanism, the feasible PET fabrics were prepared and its anti-wearing performance was evaluated. It is revealed that the wearing destruction is mainly caused by the repeat abrasion on a specific part of folded fabric as well as abrasion itself. Therefore, it is necessary that the prevention of fabric folding while massager is running is essential and the recovery from the crease on a fabric is also necessary to solve this problem. Covered elastic yarn, high twisted yarn, change of fabric structure or different fiber were utilized to prepare the possible alternatives. As a result, the anti-wearing performance of the fabrics are greatly improved to have about 2 times and 1.5 times longer life-span for the fabric with covered elastic yarn and high twisted yarn, respectively.

• Textile Coloration and Finishing
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• v.25 no.3
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• pp.223-231
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• 2013

This research has a main focus on providing fundamental data for on-the-spot industrial fields by comparing and contrasting physical properties of fluffy spun-like material. The fluffy spun-like yarn is developed as fluffy yarn similar to natural spun-like yarn by treating polyester(FDY and + type shaped DTY) with ATY machine. In this experiment, using ATY machine for raw material texturing, we produced two fluffy yarns: (i) + type shaped(50d/36f, DTY) as core yarn and 100d/192f FDY as effect yarn[ATY(D)], (ii) FDY(75/36) as core yarn and 100d/192f FDY [ATY(F)] as effect yarn. After producing thous yarns, we twisted them with 500T/M, 700T/M, 1000T/M, respectively. produced yarns through this process were used as the samples for this experiment. Even though the shrinkage of fluffy yarn ATY(F) and ATY(D) becomes high as treated temperature rises and treated time lengthens, it is more affected by treated temperature then by treated time. In this experiment, produced fluffy yarn[ATY(D)] shows a little high values for temperature, but almost same values for higher temperatures. When we compare ATY(F) with ATY(D) fluffy yarn shows more natural fluffy yarn surface structure like natural cotton. The shrinkage of 700T/M twisted ATY(D) fluffy yarn show about 11% under treated temperature $180^{\circ}C$ and treated time 30min, and about 7% under $120^{\circ}C$ and 30min, respectively. But the shrinkage of 1000T/M fluffy yarn shoes about 9% and 6% under same conditions. Regarding treated time, tenacity and initial modulus of ATY(D) fluffy yarn rise high until 30min, but do not show much increase above 30min. Regarding treated temperature, tenacity and initial modulus of it rise high aboyer $140^{\circ}C$.