• Elastomers and Composites
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• v.56 no.4
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• pp.243-249
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• 2021

The demand for truck bus radial (TBR) tires with enhanced fuel efficiency and wear resistance have grown in recent years. In addition, as the issue of particulate matter and air pollution increases, efforts are being made to reduce the generation of particulate matter. In this study, we investigated the effect of varying the content of butadiene rubber (BR) on the properties of the rubber compounds and the amount of particulate matter in the TBR tire tread compound. Furthermore, we utilized carbon black in the NR/BR blend compounds owing to its excellent compatibility, and we used silica in the ENR-25/BR blend compounds because it can interact chemically with epoxide groups. The NR/BR blend compounds and the ENR-25/BR blend compounds were evaluated by varying their BR content between 20 phr and 30 phr. The results showed that the ENR-25/BR blend compounds had superior wear resistance than the NR/BR blend compounds. This was caused by the interaction between silica and ENR. In addition, it was confirmed that the increased wear resistance as the BR content increased. Furthermore, compared to the NR/BR blend compounds, ENR-25/BR blend compounds exhibited a lower tan 𝛿 value at 60℃ because silica was used as filler. This indicates a higher fuel efficiency. The measurement results for wear particulate matter showed that as increasing the BR content resulted in generation of less wear particulate matter. This was caused by the increased wear resistance. Moreover, the ENR-25/BR blend compounds with excellent filler-rubber interaction exhibited lower quantities of generated wear particulate matters as compared to the NR/BR blend compounds.

• Elastomers and Composites
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• v.34 no.2
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• pp.156-176
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• 1999

Rubber chemicals such as accelerators, antidegradants, vulcanizing agents, processing agents and retarders are very important to the production and protection of tires and rubber goods. The use of accelerators and antidegradants are evaluated in various tire components. This paper will focus on how to vulcanize tires economically and maintain the physical properties of each tire component without severe degradation due to oxygen, heat and ozone. Also, new non-nitrosoamine accelerators and non-staining antiozonants will be discussed. Lastly, the future requirements of antidegradants and accelerators in the tire industry will be reviewed. Tires have been vulcanized with Sulfenamides as primary accelerators and either Guamdine's or Thiurams as secondary accelerators to achieve proper properties at service conditions. However, interior components such as the carcass can be vulcanized with Thiazoles as a primary accelerator to cure faster than the external components. Using the combination of Sulfenamide with secondary accelerators in a tire tread compound and the combination of a Thiazole and Guanidine in a carcass compound will be presented with performance data. Uniroyal Chemical and another Rubber Chemical Manufacturer have developed, "Tetrabenzyl Thiuram Disulfide," (TBzTD) as a non-Nitrosoamine accelerator, which could replace Nitrosoamine generating Thiurams. This new accelerator has been evaluated in a tread compound as a secondary accelerator. Also, Flexsys has developed N-t-butyl-2-benzothiazole Sulfenamide (TBSI) as a non-Nitrosoamine accelerator which could replace 2-(Morpholinothio) -benzothiazole (MBS), a scorch delayed Sulfendamide accelerator. TBSI has been evaluated in a Natural Rubber (NR) belt skim compound vs. MBS. An optimum low rolling resistant cure system has been developed in a NR tread with Dithiomorpholine (DTDM). Also, future requirements for developing accelerators will be discussed such as the replacement of DTDM and other stable crosslink systems. Antidegradants are divided into two different types for use in tire compounds. Internal tire compounds such as apex, carcass, liner, wire breaker, cushion, base tread and bead compounds are protected by antioxidants against degradation from oxygen and heat due to mechanical shear. The external components such as sidewall, chafer and cap tread com-pounds are protected from ozone by antiozonants and waxes. Various kinds of staining and non-staining antioxidants have been evaluated in a tire carcass compound. Also, various para-phenylene diamine antiozonants have been evaluated in a tire sidewall compound to achieve the improved lifetime of the tire. New non-staining antiozonants such as 2, 4, 6-tris-(N-1, 4-dimethylpentyl-p-phenylene diamine) 1, 3, 5 Trizine (D-37) and un-saturated Acetal (AFS) will be discussed in the tire sidewall to achieve better appearance. The future requirements of antidegradants will be presented to improve tire performance such as durability, better appearance and longer lasting tires.

• International Journal of Railway
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• v.1 no.3
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• pp.83-88
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• 2008

Since the 1990's the fleet of the Dutch Railways showed a dramatic decrease in wheel tyre life. This lifetime reduction led to an unacceptable increase in life cycle costs. Therefore Lloyd's Register Rail has proposed to NedTrain to investigate the possibilities of improving the wheel tyre life. Three improvements were determined as most promising and relatively easy to achieve: - Profile optimisation for Rolling Contact Fatigue (RCF) reduction - a new wheel profile has been developed with a better resistance against rolling contact fatigue of the wheel tread. The profile has been implemented on single deck intercity trains and shows an increase in wheel tyre life of 30%. - Selection of improved wheel tyre materials - combining information from literature and experiences of manufacturers five alternative wheel tyre materials have been selected and are now being tested in practice. - Optimisation of the maintenance strategy - an alternative, preventative maintenance regime has been developed. With this Scraping regime, during short term maintenance every wheel is reprofiled. Higher mileages are reached and savings on life cycle costs up to 50% and more have been achieved. Unplanned maintenance goes down with $30{\sim}60%$. The results from field tests, using a reference group for comparison, and preliminary results after implementation show that the increase in wheel tyre life that is achieved with this project is significant. The results will continue to be monitored using the asset management tool 'Wheel Watch', that was specially developed for this project and is also described in this paper.

• Transactions of the Korean Society of Automotive Engineers
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• v.18 no.3
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• pp.43-52
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• 2010

In this study, the shapes of the wheel and rail are represented by using 3-dimensional surface functions with surface parameters and a 3-dimensional wheel-rail contact analysis is presented. A whole numerical solution of wheel-rail contact at tread and flange including 2-point contacts can be achieved with the proposed numerical algorithm. Kinematic characteristics such as variances of vertical displacement and roll angle, and variance of wheel radius difference for arbitrary yaw and lateral displacement of wheelset, are determined for the KTX wheel-rail pair as an example. The condition of yaw and lateral displacement occurring 2-point contacts to analyze derailment are compared between standard and worn wheels. Differences of contact characteristics between curved and straight rails are also analyzed.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2012.04a
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• pp.298-304
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• 2012

The development of low rolling resistance tire with weight reduction in tire and vehicle may induce high level of tire/road noise, especially the rumble road noise on rough road. In this paper, the design factor for good rumble noise is considered in view of tire and vehicle. For the 3 mid-sized sedans, the rumble noise is very sensitive to the test vehicle. And it is concluded that the tire with high tread part stiffness and low sidewall part stiffness shows best rumble noise performance, and the rumble noise is in trade-off relation with cavity resonance noise. So, it is desirable to select and change proper construction design factors to have good tire/vehicle rumble noise.

• Proceedings of the KSR Conference
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• 2003.10c
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• pp.22-27
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• 2003

The running safety of the rolling stock depends on the design characteristics and the contact condition between wheel and railway. In this study, the effect of the conicity of wheel tread on the running safety is analyzed. The modal analysis results in $0.5\~0.6Hz$ natural frequency with lateral modes. However, the frequency analysis for the running simulation shows the frequency components near 1Hz. The running simulation shows that the KTX with GV40 wheel has less lateral vibration than that of XP55 as the KTX goes higher speed.

• Elastomers and Composites
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• v.44 no.3
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• pp.232-243
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• 2009

The specialized and diversified synthetic and compounding technologies are used to meet the requirements for the advanced high performance tire tread materials with better balance of fuel economy(rolling resistance), safety(wet traction) and wear resistance. These techniques involve the methodology for the improvement of chemical and physical interaction between filler and the rubber matrix using coupling agents as well as a variety of chemically-modified solution SBRs. The research trends about the high performance functional SBRs and coupling agents which can interact with the surface of fillers and their working mechanism were investigated in the conventional carbon black-filled rubber and silica-filled SBR systems developed recently as "green tire".

• Elastomers and Composites
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• v.56 no.4
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• pp.234-242
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• 2021

The demand for truck bus radial (TBR) tires with enhanced fuel efficiency and wear resistance have grown in recent years. In addition, as the issue of particulate matter and air pollution increases, efforts are being made to reduce the generation of particulate matter. In this study, the properties of epoxidized natural rubber (ENR) containing a silica-friendly functional group were evaluated by considering it as a base rubber and varying the silica ratio in this binary filler system. The results showed that the wear resistance of the NR/BR blend compound decreased as the silica ratio increased. In contrast, the ENR/BR blend compound exhibited an increase in wear resistance as the silica ratio was increased. In particular, the ENR-50/BR blend compound showed the best wear resistance due to the presence of several epoxide groups. Furthermore, we observed that for tan 𝛿 at 60℃, higher epoxide content resulted in the higher T_g of the rubber, indicating a higher tan 𝛿 at 60℃. On the other hand, it was confirmed that increasing the silica ratio decreased the value of tan 𝛿 at 60℃ in all compounds. In addition, we measured the amount of wear particulate matters generated from the compound wear. These measurements confirmed that in the binary filler system, regardless of the filler type, the quantity of the generated wear particulate matters as the filler-rubber interaction increased. In conclusion, the silica filled ENR/BR blend compound exhibited the lowest generation of wear particulate matters.

• Elastomers and Composites
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• v.48 no.3
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• pp.201-208
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• 2013

In this study, effect of different amounts of sulfur and vulcanization accelerators in the acrylonitrile styrene-butadiene rubber (AN-SBR)/silica compounds on the properties of tire tread compound were studied. As a result, cure rate and degree of cross-linking of the compounds were increased due to enhanced cross-linking reactivity by the increased amounts of sulfur and vulcanization accelerators. Also, abrasion resistance and the mechanical properties such as hardness and modulus of the compounds were improved by enhanced degree of cross-linking of the compounds. For the dynamic properties, tan ${\delta}$ value at $0^{\circ}C$ was increased due to the increase of glass transition temperature ($T_g$) by enhanced degree of cross-linking of the compound, and tan ${\delta}$ value at $60^{\circ}C$ was decreased. Initial cure time ($t_1$) showed the linear relationship with tan ${\delta}$ value at $60^{\circ}C$. This result is attributed that reduced initial cure time ($t_1$) of compounds by applying increased amount of curatives can form cross-linking in early stage of vulcanization that may suppress development of filler network. This result is verified by observation on the surface of annealed compounds using AFM (atomic force microscopy). Consequently, decreased initial cure time is considered a very important parameter to reduce tan ${\delta}$ at $60^{\circ}C$ through reduced re-agglomeration of silica particles.

• The Journal of the Acoustical Society of Korea
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• v.14 no.2
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• pp.80-91
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• 1995

A theoretical models has been prepared which describes the noise generated by tire/road interaction for the tire structure-borne sound analysis. The model begin with a set of thin shell equations describing the motion of the belt of a radial ply tire, as drived by Bohm('mechanisms of the belted tire', Igeniur-Archiv, XXXV, 1966). Structural quantities required for these equations are derived from material properties of the tire. The rolling shape of a tire is computed from the steady-state limit of these equations. Vibrational response of the tire is treated by the full dependent shell equations. The force input at the tire/road interface is calculated on the basis of tread geometry and distribution of contact patch pressure. Radiation of noise is calculated by a simpson integral. Using the programs, the effect on noise of various tire design variations is computed and discussed. Trends which lead to quiet tire design are identified.