• Title/Summary/Keyword: Transport temperature

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Microstructure and Electrical Properties of (YNdSm)-Ba-Cu-O High Tc Composite Superconductors by Zone Melting Process (존멜팅법으로 제조한 (YNdSm)-Ba-Cu-O계 고온복합초전도체의 미세구조 및 전기적 특성)

  • Kim, So-Jung;Lee, Sang-Heon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.2
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    • pp.110-113
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    • 2016
  • (YNdSm)-Ba-Cu-O system high Tc composite superconductors were directionally grown by zone melting process, having large temperature gradient, in air atmosphere. Cylindrical green rods of $(YNdSm)_{1.8}Ba_{2.4}Cu_{3.4}O_x$ [(YNS)1.8]composite oxides by CIP (cold isostatic pressing) method using rubber mold were fabricated. The microstructure and superconducting properties were investigated by XRD, TEM and SQUID magnetometer. The size of nonsuperconducting $(YNdSm)_2BaCuO_5$ inclusions of the melt-textured (YNS)1.8 sample with $CeO_2$ additive were remarkably reduced and uniformly distributed within the superconducting (YNS)1.8 matrix. (YNS)1.8 samples, with / without $CeO_2$ additive, showed an onset $T_c{\geq}90K$ and sharp superconducting transition. The critical current density $J_c$ value of the (YNdSm)1.8 superconductor with $CeO_2$ additive were 840 A, $1.2{\times}104A/cm^2$ in 77 K, 0 Tesla by direct current transport method.

Fabrication of Molybdenum Silicide-based Composites with Uniformly Dispersed Silicon Carbide (탄화 규소가 균일 분산된 규화 몰리브데넘계 복합재의 제조)

  • Choi, Won June;Park, Chun Woong;Kim, Young Do;Byun, Jong Min
    • Journal of Powder Materials
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    • v.25 no.5
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    • pp.402-407
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    • 2018
  • Molybdenum silicide has gained interest for high temperature structural applications. However, poor fracture toughness at room temperatures and low creep resistance at elevated temperatures have hindered its practical applications. This study uses a novel powder metallurgical approach applied to uniformly mixed molybdenum silicide-based composites with silicon carbide. The degree of powder mixing with different ball milling time is also demonstrated by Voronoi diagrams. Core-shell composite powder with Mo nanoparticles as the shell and ${\beta}-SiC$ as the core is prepared via chemical vapor transport. Using this prepared core-shell composite powder, the molybdenum silicide-based composites with uniformly dispersed ${\beta}-SiC$ are fabricated using pressureless sintering. The relative density of the specimens sintered at $1500^{\circ}C$ for 10 h is 97.1%, which is similar to pressure sintering owing to improved sinterability using Mo nanoparticles.

Random Sequence Analysis of the Genomic DNA of Methanopyrus kandleri and Molecular Cloning of the Gene Encoding a Homologue of the Catalytic Subunit of Carbon Monoxide Dehydrogenase

  • Shin, Hyun-Seock;Ryu, Jae-Ryeon;Han, Ye-Sun;Choi, Yong-Jin;Yu, Yeon-Gyu
    • Journal of Microbiology and Biotechnology
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    • v.9 no.4
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    • pp.404-413
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    • 1999
  • Methanopyrus kandleri is a hyperthermophilic methanogen that represents one of the most heat-resistant organisms: the maximum growth temperature of M. kandleri is $110^{\circ}C$. A random sequence analysis of the genomic DNA of M. kandleri has been performed to obtain genomic information. More than 200 unique sequence tags were obtained and compared with the sequences in the GenBank and PIR databases. About 30% of the analyzed tags showed strong sequence similarity to previously identified genes involved in various cellular processes such as biosynthesis, transport, methanogenesis, or metabolism. When statistics relating to the frequency of codons were examined, the sequenced open reading frames showed highly biased codon usage and a high content of charged amino acids. Among the identified genes, a homologue of the catalytic subunit of carbon monoxide dehydrogenase (CODH) that reduces $CO_2$ to CO was cloned and sequenced in order to examine its detailed gene structure. The cloned gene includes consensus promoters. The amino acid sequence of the cloned gene shows a strong homology with the CODH genes from methanogenic Archaea, especially in the presumed binding sites for Fe-S centers.

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Analysis of Flow through High Pressure Bypass Valve in Power Plant (발전소용 고압 바이패스 밸브 내부 유동해석)

  • Cho, An-Tae;Kim, Kwang-Yong
    • The KSFM Journal of Fluid Machinery
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    • v.10 no.6
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    • pp.17-23
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    • 2007
  • In the present work, flow analysis has been performed in the steam turbine bypass control valve (single-path type) for two different cases i.e., case with steam only and case with both steam and water. The numerical analysis is performed by solving three-dimensional Reynolds-averaged Navier-Stokes (RANS) equations. The shear stress transport (SST) model and $k-{\varepsilon}$ model are used to each different case as turbulence closure. Symmetry condition is applied at the mid plane of the valve while adiabatic condition is used at the outer wall of the cage. Grid independency test is performed to find the optimal number of grid points. The pressure and temperature distributions on the outer wall of the cage are analyzed. The mass flow rate at maximum plug opening condition is compared with the designed mass flow rate. The numerical analysis of multiphase mixing flow(liquid and vapor) is also performed to inspect liquid-vapor volume fraction of bypass valve. The result of volume fraction is useful to estimate both the safety and confidence of valve design.

Synthesis of Forsterite with High Q and Near Zero TCf for Microwave/Millimeterwave Dielectrics

  • Ohsato, Hitoshi;Ando, Minato;Tsunooka, Tsutomu
    • Journal of the Korean Ceramic Society
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    • v.44 no.11
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    • pp.597-606
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    • 2007
  • With the advent of ubiquitous age, the high quality dielectric materials have been required for the wireless communications available to the millimeterwave as well as microwave frequencies. The utilizable region for the frequency has been expanding to the millimeter-wave region because of the shortage of radio frequency (RF) resources. These high frequencies would be expected for ultra high speed LAN, ETS and car anti-collision system on the intelligent transport system (ITS) and so on. Silicates are good candidates for microwave/millimeterwave dielectrics, because of their low dielectric constant ${\epsilon}_r$ and high quality factor (High Q). Forsterite ($Mg_2SiO_4$) is one of the silicates with low ${\epsilon}_r$ of 6.8 and Q f of 240000 GHz. In this paper, we reviewed following three categories for synthesis of forsterite: (1) Synthesis of high Q forsterite (2) Adjust the temperature coefficient of resonant frequency $TC_f$ (3) Diffusion of $SiO_{4^-}$ and Mg-ions on the formation of forsterite.

Influence of Oxygen Supply Method on the Performance of IGCC Plants (IGCC 플랜트에서 산소공급방식이 성능에 미치는 영향)

  • Ahn, Ji-Ho;Kim, Tong-Seop
    • Journal of Hydrogen and New Energy
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    • v.23 no.3
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    • pp.264-273
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    • 2012
  • In this paper, two types of integrated gasification combined cycle (IGCC) plants using either an air separation unit (ASU) or an ion transport membrane (ITM), which provide the oxygen required in the gasification process, were simulated and their thermodynamic performance was compared. Also, the influence of adopting a pre-combustion $CO_2$ capture in the downstream of the gasification process on the performance of the two systems was examined. The system using the ITM exhibits greater net power output than the system using the ASU. However, its net plant efficiency is slightly lower because of the additional fuel consumption required to operate the ITM at an appropriate operating temperature. This efficiency comparison is based on the assumption of a moderately high purity (95%) of the oxygen generated from the ASU. However, if the oxygen purity of the ASU is to be comparable to that of the ITM, which is over 99%, the ASU based IGCC system would exhibit a lower net efficiency than the ITM based system.

Synthesis and Characterization of Di and Triblock Copolymers Containing a Naphthalene Unit for Polymer Electrolyte Membranes (고분자전해질 막을 위한 나프탈렌 단위를 포함하는 디 및 트리 블록공중합체의 합성 및 특성분석)

  • KIM, AERHAN
    • Journal of Hydrogen and New Energy
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    • v.27 no.6
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    • pp.660-669
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    • 2016
  • A fluorinated-sulfonated, hydrophobic-hydrophilic copolymer was planed subsequently synthesized using typical nucleophilic substitution polycondensation reaction. A novel AB and ABA (or BAB) block copolymers were synthesized using sBCPSBP (sulfonated 4,4'-bis[4-chlorophenyl)sulfonyl]-1,1'-biphenyl), DHN (1,5-dihydroxynaphthalene), DFBP (decafluorobiphenyl) and HFIP (4,4'-hexafluoroisopropylidenediphenol). All block copolymers were easily cast and made into clear films. The structure and synthesized copolymers and corresponding membranes were analyzed using GPC (gel permeation chromatography), $^1H$-NMR ($^1H$ nuclear magnetic resonance) and FT-IR (Fourier transform infrared). TGA (Thermogravimetric analysis) and DSC (differential scanning calorimetry) analysis showed that the prepared membranes were thermally stable, so that elevated temperature fuel cell operation would be possible. Hydrophobic/hydrophilic phase separation and clear ionic aggregate block morpology was confirmed in both triblock and diblock copolymer in AFM (atomic force microscopy), which may be highly related to their proton transport ability. A sulfonated BAB triblock copolymer membrane with an ion-exchange capacity (IEC) of 0.6 meq/g has a maximum ion conductivity of 40.3 mS/cm at $90^{\circ}C$ and 100% relative humidity.

Effect of transport current properties on connecting of YBCO Coated Conductor having stabilizer layer and BSCCO tape (안정화 층을 갖는 YBCO Coated Conductor와 BSCCO 선재의 결합이 과전류 통전 특성에 미치는 영향)

  • Kim, Min-Ju;Du, Ho-Ik;Yim, Seong-Woo;Park, Chung-Ryul;Choi, Byung-Hwan;Doo, Seung-Gyu;Kim, Yong-Jin;Han, Byoung-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.290-291
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    • 2008
  • Recently High Temperature Superconductor(HTS) Tape is limelight of the applied superconducting machines. Mainly used superconducting tape are BSCCO tape and YBCO coated tape. These superconducting tape are applied such as SMES, superconducting generator and MAGLEV. Actually superconductor tape's experimental gauge is short. For this reason, experiment was conducted. Firstly length of 50cm BSCCO, YBCO Coated conductor@Cu and YBCO coated conductor@sus are prepared. and flow the over-current. Secondly, BSCCO and Coated conductor connected with lenth of 25cm and flow the over-current. Coupled line of HTS tape was compared with single line of HTS tape and these overcurrent characteristics was investigated.

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Properties of the Exciton Blocking Layer in Organic Photovoltaic cell (유기 광기전력 소자의 엑시톤 억제층 특성)

  • Oh, Hyun-Seok;Lee, Ho-Shik;Park, Yong-Phil;Lee, Won-Jae;Kim, Tae-Wan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04b
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    • pp.20-21
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    • 2008
  • Photovoltaic effects in organic solar cell were studied in a cell configuration of ITO/PEDOT:PSS/CuPd(20nm)/$C_{60}$(40nm)/BCP/Al(150nm) at room temperature. Here, the BCP layer works as an exciton blocking layer. The exciton blocking layer must transport electrons from the acceptor layer to the metal cathode with minimal increase in the total cell series resistance and should absorb damage during cathode deposition. Therefore, a proper thickness of the exciton blocking layer is required for an optimized photovoltaic cell. Several thicknesses of BCP were made between $C_{60}$ and Al. And we obtained characteristic parameters such as short-circuit current, open-circuit voltage, and power conversion efficiency of the device under the illumination of AM 1.5.

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An Analytic Study on the Creep Properties for Fibers Mixed of High Strength Concrete (고강도 콘크리트의 섬유 혼입에 따른 크리프 특성 분석에 관한 연구)

  • Park, Hee-Gon;Kwon, Hae-Won;Lee, Bo-Hyeong;Bae, Yeoun-Ki;Lee, Jae-Sam;Jung, Sang-Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.11a
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    • pp.81-85
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    • 2009
  • In the recent years, the high strength concrete has increasingly been used according to extending market of tall buildings. However, Ministry of Land, transport and Maritime Affairs was established by law with an alternative plan after June 2008 because of the weakness of high strength concrete accompanied spalling phenomena in fire. The mix design of concrete has to properly meet standards which are the spalling resistance of concrete and limited temperature of steel reinforcement. The fire proof concrete mixed fiber has widely been used to meet spalling safety on the many construction sites, the most researches about the fire proof concrete mixed fiber had being carried out focused on fire resistance, compressive strength and cast in place of concrete. But the most important thing is column shortening used the fire proof concrete within the vertical members. In this paper, the fire proof concrete filled spalling safety standards was experimented by required material when the column shortening is revised between normal concrete and fire proof concrete mixed fiber and then the results have done a comparative analysis. Also, The paper aimed to indicate a basic data for revision of column shortening of fire proof concrete.

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