• Bulletin of the Korean Chemical Society
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• v.20 no.11
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• pp.1281-1287
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• 1999

The low-lying electronic states of diazirine and 3,3'-dimethyldiazirine have been studied by high level ab initio quantum chemical methods. The equilibrium geometries of the ground state and the first excited singlet and triplet states have been optimized using the Hartree-Fock (HF) and complete active space SCF (CASSCF) methods, as well as using the Møller-Plesset second order perturbation (MP2) theory and the single configuration interaction (CIS) theory. It was found that the first excited singlet state is of 1 B1 symmetry resulting from the n- π* transition, while the first excited triplet state is of 3 B2 symmetry resulting from the π- π* transition. The harmonic vibrational frequencies have been calculated at the optimized geometry of each electronic state, and the scaled frequencies have been compared with the experimental frequencies available. The adiabatic and vertical transition energies from the ground electronic state to the low-lying electronic states have been estimated by means of multireference methods based on the CASSCF wavefunctions, i.e., the multiconfigurational quasidegenerate second order perturbation (MCQDPT2) theory and the CASSCF second-order configuration interaction (CASSCF-SOCI) theory. The vertical transition energies have also been calculated by the CIS method for comparison. The computed transition energies, particularly by MCQDPT2, agree well with the experimental observations, and the electronic structures of the molecules have been discussed, particularly in light of the controversy over the existence of the so-called second electronic state.

• Journal of Astronomy and Space Sciences
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• v.34 no.3
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• pp.207-212
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• 2017

During the last glacial-interglacial transition, there were multiple intense climatic events such as the Bølling-Allerød warming and Younger Dryas cooling. These events show abrupt and rapid climatic changes. In this study, the climate events and cycles during this interval are examined through wavelet analysis of Arctic and Antarctic ice-core $^{18}O$ and tropical marine $^{14}C$ records. The results show that periods of ~1383-1402, ~1029-1043, ~726-736, ~441-497 and ~202-247 years are dominant in the Arctic region, whereas periods of ~1480, ~765, ~518, ~311, and ~207 years are prominent in the Antarctic TALDICE. In addition, cycles of ~1019, ~515, and ~209 years are distinct in the tropical region. Among these variations, the de Vries cycle of ~202-209 years, correlated with variations in solar activity, was detected globally. In particular, this cycle shows a strong signal in the Antarctic between about 13,000 and 10,500 yr before present (BP). In contrast, the Eddy cycle of ~1019-1043 years was prominent in Greenland and the tropical region, but was not detected in the Antarctic TALDICE records. Instead, these records showed that the Heinrich cycle of ~1480 year was very strong and significant throughout the last glacial-interglacial interval.

• Journal of the Korean housing association
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• v.16 no.5
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• pp.117-125
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• 2005

Since Mapo Apartment was introduced as a new urban housing type in the early sixties, apartment has been a typical urban housing in our country. In these days, according to various life-styles and new attitudes about the quality of life, apartment has been developed in various types like high rise residential complex and apartments with special themes. This study has been focused on the transition of modem urban housing in France. The origin of a word, apartment, has been defined and history of apartment in French urban life has been analyzed focusing on the common space and community facilities. Representative apartments in the 18th, 19th and 20th century were selected and comparatively analyzed. Especially in the 19th century, urban housing for working class had been a major concern among the communist and the bourgeoisie and has its own characteristics relative to each other. The characteristics shown in the apartment by the communist in France have been followed in the Korean apartments since 1960's, then the recent trends are rapidly changing in the housing market in Korea. Thus, the findings of this study can be very useful to understand the recent changes of diverse housing types in our society and also be very helpful to prospect our urban housing types in the future according to the changes of new lift styles.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.41 no.7
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• pp.588-595
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• 2013

Airborne SAR system is the imaging Radar system that is loaded on a manned or unmanned aircraft, which is in charge of high quality image acquisition and moving target detection. This paper describes the operational requirements for the Airborne SAR system and suggests the operational concept to satisfy the requirements. To be specific, it describes the interface with airborne system, state definition and transition, operation mode based on mission definition file, fault management, and data storing and transmission concept. Finally, it gives the ground test results to verify the SAR system operational concept.

• Korean Institute of Interior Design Journal
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• v.15 no.3 s.56
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• pp.65-74
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• 2006

This study is intended to analyze the way of incorporating the effect of natural light into the architectural space design by Le Cobusier. The composition of modem architectural space is significantly different from that of classical architecture. Such transition is attributable to the change of tectonic method which was supported by the development of new materials and structural systems. In addition, the effect of natural light systems which is one of the main elements in architectural space has undergone significant changes in modern ages. Moreover, Le Corbusier introduces the new concept of natural light in his works. By bringing the above two trends together, this study analyzed the way how Le Cobusier applied light effect in his works. Specifically, findings regarding the 'traffic flow in the space' with the light, 'elevation effect' with the 'Brise soleil' in Le Cobusier's works were presented. And also the way of lighting the object in the space was presented.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.33 no.5
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• pp.50-56
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• 2005

The objective of this study is to find the optimal thrust condition and wing loading of a vertical take-off and landing (VTOL) fixed-wing aircraft through a single engine failure analysis during landing approach and an analysis of transition flight. The aircraft analysis modules used in the study are based on the aircraft synthesis program. To achieve the computing infrastructure for aircraft design and analysis, the EMDIOS was employed as a design framework, which is a semi-completed application program and ready to customize. Simulation results reveal the most critical height at the event of single engine failure is approximately 40 ft. And, in order to avoid a significant loss in altitude during the transition, the thrust to weight ratio must be kept high, while both the engine tilt speed and the wing loading must be kept low, as confirmed by the analysis results.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.42 no.7
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• pp.535-543
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• 2014

A computational simulation for a nonslender BWB UCAV configuration with rounded leading edge and span of 1.0m was performed to analyze its aerodynamic characteristics. The freestream is 50m/s over -4 to 26 degree A.o.A.s. Reynolds number based on the mean chord length is $1.25{\times}10^6$. 3D multi block hexahedral grids are used which allow good grid quality and ease to capture boundary layer. ${\gamma}-Re_{\theta}$ model as well as $k-{\omega}$ SST model is employed to assess the effect of transition for flow behavior. Drag and lift of the UCAV were well predicted while $C_M$ is under predicted at high angle of attacks and influenced by the turbulence models strongly. After assessing pressure distribution, skin friction lines and velocity field around the UCAV configuration, it was found that transition effect should be considered to enhance the prediction of aerodynamic behavior by a vortical flowfield.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.37 no.12
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• pp.1184-1191
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• 2009

In order to reduce the download around the Smart UAV(SUAV) at Transition mode, flow control using synthetic jet has been performed. Many of the complex tilt rotor flow features are captured including the leading and trailing edge separation, and the large region of separated flow beneath the wing. Based on the results of part 1 of the present work, synthetic jet is located at 0.01c, $0.95c_{flap}$ and it is operated with the non-dimensional frequency of 0.5, 5 to control the leading edge and trailing edge separation. Consequently, download is substantially reduced compared to with no control case at transition mode using leading edge jet only. The present results show that the overall flight performance and stability of the SUAV can be remarkably improved by applying the active flow control strategy based on synthetic jet.

• International Journal of Aeronautical and Space Sciences
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• v.6 no.2
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• pp.84-96
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• 2005

Helical tip vortex is known as stable vortex structure, however the specific frequency component of far wake perturbation induces the vortex pairing in hover and axial flight. It is expected that the tip vortex pairing phenomena may happen in transition flight and very low advance ratio flight so that inflow may be most nonuniform in the low advance ratio flight. The objectives of this paper are that a tip-vortex instability during the transition from hover into very low advance ratio forward flight is numerically predicted to understand a physics by using a time-marching free-wake method. To achieve the objectives, numerical method is firstly validated in typical axial and forward flights cases. Present scheme with trim routine can predict airloads and inflow distribution of forward flight with good accuracy. Then, the transition flight condition is calculated. The rotor used in this wake calculation is a small-scale AH-1G model. By using a tip-vortex trajectory tracking method, the tip-vortex pairing process are clearly observed in transient flight($\mu$=0.03) and disappears at a slightly higher advance ratio($\mu$=0.05). According to the steady flight simulation at $\mu$=0.03, it is confirmed the tip-vortex pairing process is continued in the rear part of rotor disk and not occurs in the front part. Time averaged inflow in this case is predicted as smooth distribution.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.44 no.6
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• pp.477-483
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• 2016

Velocity profiles of laminar, transition and turbulent boundary layers were investigated by using Particle Image Velocimetry(PIV) measurements on the flat plate at Mach 2.96. The Schlieren visualization and PIV measurements are also used to confirm whether the oblique shock wave generated from the leading edge affects the flow field over the flat plate. The laminar velocity profile measured from the experiment was well matched with the compressible Blasius solution. The velocity profile of the transition boundary layer was well correlated with the theoretical turbulent velocity profile from near the wall and the transition began from Re = $1.41{\times}106$. For the turbulent boundary layer, considering compressibility effects, the Van Driest-transformed velocity satisfies the incompressible log-law. It is found that the log region is extended farther in the wall-normal direction compared to the log region in incompressible boundary layer.