• 제목/요약/키워드: Transition rate

검색결과 1,277건 처리시간 0.023초

고용착 GMA 용접의 Arc 안정성 및 용적이행 현상에 미치는 보호gas의 영향 (Effect of Shielding gas Composition on Arc Stability and Transfer mode of High deposition GMA Welding)

  • 경규담;천홍정;이정헌;강봉용;김희진
    • Journal of Welding and Joining
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    • 제15권1호
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    • pp.109-115
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    • 1997
  • The arc stability and the metal transfer mode of high deposition GMA welding were investigated using various compositions of shielding gas with two types of filler, ie solid wire and metal cored wire. As for a solid wire, the transfer mode changed from axial spray to rotational spray with increasing wire feed rate (welding current) and the transition current was different with the gas composition. The gas composition also affected the apparent stability of rotating arc. As for a metal cored wire, on the other hand, no transition occurred and thus spray transfer mode could be applied with the welding current over 500A (deposition rate over 300g/min). Looking for the development of high deposition GMA welding process, above results were discussed in two different ways, one is to elevate the transition current, the other is to stabilize the rotational transfer mode.

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Zr계 벌크 비정질 합금의 과냉 액상 영역에서의 점성 유동 현상 연구 (A Study on Viscous Flow of the Zr-based Bulk Metallic Glass in an Undercooled Liquid State)

  • 이광석;하태권;장영원
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2004년도 춘계학술대회 논문집
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    • pp.265-268
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    • 2004
  • In this present study, mechanical properties of the Zr-Ti-Cu-Ni-Be bulk metallic glass are characterized by compression test over a wide range of temperatures and strain rates. Three different types of deformation behavior have been identified as a result, viz., Newtonian viscous flow, non-Newtonian flow and brittle fracture without plastic deformation. A transition state theory is applicable fur the flow stress - strain rate curve that contains the transition from Newtonian to non-Newtonian flow. Based on the relationship between viscosity and strain rate within undercooled liquid state, we can easily obtain the experimental deformation map and suggest the boundaries among different deformation behavior of this alloy.

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압전성 $KAlSiO_4$ 단결정 육성 및 상변화 (Crystal Growth and Phase Transition of Piezoelectric $KAlSiO_4$)

  • 오광석;박봉모;정수진;이태근;박병규;김호성
    • 한국세라믹학회지
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    • 제33권3호
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    • pp.362-370
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    • 1996
  • Kalsilite (KAlSiO4) system undergoes a displacive phase transition from hexagonal phase with p63 space group to the phase with P63mc at 886$^{\circ}C$. The flux composition having kalsilite :K2O:B2O3=1:2:2 has enabled the growth of hexagonal kalsilite with the size of 0.5~1 mm at a slow cooling rate (0.3$^{\circ}C$/hr). On decreasing the cooling rate the size has increased and pyramidal (1011) faces are newly developed with the shape of (0001) and (1010) faces. Upon stirring (1011) faces are degraded. The space group of O1 and O2 are P21221 and C2221 respectively. Their orthorombic modification O1 and O2 are synthesized at relatively low and high temperature respectively.

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Delignification Kinetics of Trema orientalis (Nalita) in Kraft Pulping

  • Jahan, M. Sarwar;Rubaiyat, A.;Sabina, R.
    • 펄프종이기술
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    • 제39권5호
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    • pp.7-11
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    • 2007
  • Kraft pulping of Trema orientalis (Nalita) was studied in order to find kinetic data for delignification. Pulping runs were carried out in the temperature range of $160-180\;^{\circ}C$ under constant and well-defined conditions. The delignification was found to be first order with respect to residual lignin and was chemically controlled. The rate of delignification reaction was increased 1.11-1.23 for $10\;^{\circ}C$ temperature increase in the range of $160-180\;^{\circ}C$ range. A mean value of 93% of lignin was removed at the transition between bulk and residual delignification. The influence of cooking temperature on the rate constant was expressed by an Arrhenius-type equation. The obtained activation energy of the delignification reaction was 6,164 cal/mol. The transition point between bulk and residual phase was shifted to lower lignin and carbohydrate yield with the increase of temperature.

Theoretical Investigation of the Vibrational Relaxation of NO(${\upsilon}=1-7$) in Collisions with $O_{2}\;and\;N_{2}$

  • Jongbaik Ree
    • Bulletin of the Korean Chemical Society
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    • 제14권1호
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    • pp.47-52
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    • 1993
  • The vibrational relaxation rate constants of NO(v = 1-7) by $O_2\;and\;N_2$ have been calculated in the temperature range of 300-1000 K using the solution of the time-dependent Schrodinger equation. The calculated relaxation rate constants by $O_2$ increase monotonically with the vibrational energy level v, which is compatible with the experimental data, while those by $N_2$ are nearly independent of v in the range of $3.40 {\pm}1.60{\times}10_{-16} cm^3$/molecule-sec at 300 K. Those for NO(v) + $N_2$ are about 2-3 orders of magnitude smaller than those for NO(v) + $O_2$, because the latter is an exothermic processes while the former an endothermic. Relaxation processes can be interpreted by single-quantum V-V transition. The contributions of V-T/R transition and double-quantum V-V transition to the relaxation are negligible over the entire temperature range.

레이놀즈 수의 시간 증가율에 따른 난류 채널유동의 변화 (Effects of the Temporal Increase Rate of Reynolds Number on Turbulent Channel Flows)

  • 정서윤;김경연
    • 대한기계학회논문집B
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    • 제40권7호
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    • pp.435-440
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    • 2016
  • 레이놀즈 수의 시간 증가율이 벽면난류 구조에 미치는 영향을 난류 채널유동에 대한 직접수치모사를 수행하여 조사하였다. 완전 발달된 $Re_{\tau}=180$의 난류 채널유동이 가속을 받게 되어 평균속도로 무차원화된 레이놀즈 수가 5600에서 13600까지 선형적으로 변화하게 된다. 다양한 가속 시간에 대한 계산을 수행하여 벽면난류에 대한 가속율의 효과를 파악하였다. 유량의 증가율이 큰 경우에는 우회 천이와 유사한 현상이 발견되었으며, 유량의 증가율이 낮은 경우에는 우회 천이 현상이 거의 나타나지 않았다. 본 연구 결과는 초기 레이놀즈 수와 최종 레이놀즈 수의 비 보다는 레이놀즈 수의 시간 증가율이 채널 내 과도유동에서의 우회 천이 현상 발생에 주요인자 임을 제시한다.

Pharmaceutical studies on the polymorphism of hydrochlorothiazide

  • Kim, Bong-Hee;Kim, Johng-Kap
    • Archives of Pharmacal Research
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    • 제7권1호
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    • pp.47-52
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    • 1984
  • Four polymorphic forms (I, II, III and IV) of hydrochlorothiazide have been characterized on the basis of x-ray diffractometry and differential thermal analysis. Form I was obtained by crystallization from N, N-dimethylformamide and Form II was crystallized from hot methanol. Form III was precipitated from sodium hydroxide aqueous solution by treatment with hydrochloric acid and Form IV was crystallized from 50% methanol. The metastable form I was a most stable form among four polymorphs, which was stable more than ten months at room temperature. The thermodynamic parameters such as heat of solution, enthalpy, entropy, free energy difference and transition temperature were determined by the measurement of intrinsic dissolution rate. The transition temperature and the heat of transition between the metastable Form I an Form II were determined to be $299.15^{\circ}$K and 5.03 Kcal/mole, respectively and free energy difference ($\delta$ F) was 302. 13 cal/mole. Diuretic action of these four polymorphic forms was also evaluated by monitoring the difference in urinary excretion of sodium, potassium and magnesium in rats.

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LPMOCVD 법으로 증착된 TiO$_2$ 박막의 특성 (Properties of TiO$_2$ Thin Film Deposited by LPMOCVD)

  • 이하용;박용환;고경현;박정훈;홍국선
    • 한국세라믹학회지
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    • 제36권9호
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    • pp.901-908
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    • 1999
  • Effects of LPMOCVD process parameters on the properties of TiO2 thin film were investigated. Depositions were made in the range of temperature 300-67$0^{\circ}C$ with various TTIP(Titanium Tetraisopropoxide) concentrations by contrlling bubbler temperature(40-8$0^{\circ}C$) and/or flow rate(30-90 sccm). Post annealing treatments were carried out at 500-80$0^{\circ}C$ range in the air. Films deposited at 40$0^{\circ}C$ have denser morphology than those of films deposited at 50$0^{\circ}C$ and $600^{\circ}C$ due to slower deposition rate. Bubbler temperature can affect on the deposition rate in mass transfer controlled regime such as 50$0^{\circ}C$ or higher but not below 50$0^{\circ}C$ where surface reaction rate becomes important. On the contrary for films deposited above 50$0^{\circ}C$ flow rate can raise deposition rate but eventually saturate it at the 50 sccm and above due to retarded adhesion of decomposed species. But for films deposited at 40$0^{\circ}C$ deposition rate increases stadily with flow rate. As the film becomes more porous A(200) texture can not be developed and AnataselongrightarrowRutile transition kinetics increases.

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Korea's Demographic Transition and Long-Term Growth Projection Based on an Overlapping Generations Model

  • KWON, KYOOHO
    • KDI Journal of Economic Policy
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    • 제39권2호
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    • pp.25-51
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    • 2017
  • This paper employs an Overlapping Generations Model to quantify the impacts of Korea's demographic transition toward an older population on the total output growth rate. The model incorporates the projected population through 2060 according by Statistics Korea. The effects of the low fertility and increased life expectancy rates are studied. The model is considered suitable for analyzing the effects of demographic changes on the Korean economy. Under the assumption that the TFP growth rate will not slow considerably in the future, remaining at 1.3% per annum, the gross output growth rate of the Korean economy is projected to slow to 1.1% per annum in the 2050s, from 4.0% in the 2000s. The shrinking workforce due to the decline in fertility plays a significant role in the deceleration of the Korean economy. The increased life expectancy rate is expected to mitigate the negative effect, but the magnitude of its effect is found to be limited.

고밀도 자기기록 채널을 위한 연속적인 천이의 제한을 갖는 코드 (Consecutive transition limited code for high-density magnetic recording channel)

  • 이주현;이재진
    • 한국통신학회논문지
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    • 제28권12C호
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    • pp.1177-1181
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    • 2003
  • 연속적인 천이의 제한을 갖는 변조 코드는 고밀도 자기기록 채널에서 사용하기 위한 채널 코드 중의 하나이다. 특히, 채널로 입력되는 코드열이 연속적인 천이를 2회 이하로 허용할 경우, 채널 출력에 대한 검출 성능이 월등히 향상될 수 있으나, 이와 반대로 코드율은 현저히 감소되는 단점이 있다. 따라서, 본 논문에서는 각 코드워드에서는 연속되는 천이 길이의 제한(j)을 2로 제한하면서, 코드워드가 연결되는 부분에서는 j=3까지 허용하는 코드율이 7/8인 런-길이 제한 (RLL) 코드를 제안하였다. 이때, 제안한 코드의 연속적인 ‘0’의 개수(k)는 7로 제한된다.