• Proceedings of the Korean Information Science Society Conference
• /
• 2001.10c
• /
• pp.535-537
• /
• 2001

IPv6 초기 도입단계에서는 IPv4와 IPv6 (Internet protocol version 6)의 혼용이 예상됨에 따라 초기 IPv6 네트워크는 기존 IPv4와의 연동 및 호환을 위해 트랜지션 (transition) 메커니즘과 상호공존 (coexistence mechanism) 메커니즘을 필요로 한다. 이를 위해 다양한 트랜지션 메커니즘들이 제안되고 있는데 크게 터널링 (tunneling)과 변환 (translation) 방식으로 구분할 수 있다. 본 논문은 이러한 메커니즘 중에서 터널링을 이용한 DSTM (dual stack transition mechanism)을 분석한 후 제안된 DSTM의 각 연결별 임시 IPv4 주소할당에 대한 비합리적인 문제점을 개선한 모델을 제시하였다. 본 논문예서 제안한 모델은 기존의 NAT (network address translation) 방식과 유사하게 단일 IPv4 주소와 포트 넘버를 이용하여 각 연결을 식별할 수 있도록 한다. 그리고 DSTM 시스템 구현을 위한 효율적인 알고리즘 설계를 통해 IPv4 패킷을 IPv6 패킷으로 캡슐화 (encapsulation)하여 전송할 수 있는 인터페이스를 구현하여 결과를 분석하였다.

• Proceedings of the Korean Society of Marine Engineers Conference
• /
• 2006.06a
• /
• pp.291-292
• /
• 2006

This experimental study investigates the wake flow behind the flow characteristics around staggered tube arrays. In this experiment, the principal aim is to investigate the transition mechanism of the large vortex generating process in the wake having unique vortex shedding pattern. The detailed visualization is carried out using the PIV measurement. The transition mechanism of the large generating vortex is clarified by showing the streak lines. the vorticity and the statistical fluctuating velocity distributions.

• Bulletin of the Korean Chemical Society
• /
• v.32 no.12
• /
• pp.4179-4184
• /
• 2011

The nucleophilic substitution reactions of bis(2,6-dimethylphenyl) chlorophosphate (5), containing the four ortho-methyl substituents, with X-pyridines are investigated kinetically in MeCN at $65.0^{\circ}C$. The free energy correlations for substituent X variations in the nucleophiles exhibit biphasic concave upwards with a breakpoint at a X = 3-Cl. Unusual positive ${\rho}_X$ (= +5.40) and negative ${\beta}_X$ (= -0.83) values are obtained with the weakly basic pyridines. The pyridinolysis rate of 5 is hundreds times slower compared to that of bis(phenyl) chlorophosphate because of the steric hindrance of the four ortho-methyl substituents in the two phenyl rings. Ion-pair mechanism is proposed and positive ${\rho}_X$ and negative ${\beta}_X$ values are substantiated by an imbalance of the transition state.

• International Journal of Precision Engineering and Manufacturing
• /
• v.9 no.2
• /
• pp.11-17
• /
• 2008

Critical erosion kinetic energy models for radial/median cracks and lateral cracks in a workpiece are established in this study. We used experimental results to demonstrate that the fracture erosion resistance and erosion machining number could be used to evaluate the brittle fracture resistance and machinability of a workpiece. Erosion kinetic energy models were developed to predict brittle fracture and ductile shear, and a critical erosion kinetic energy model was developed to predict the transition from brittle fracture to ductile shear. These models were verified experimentally.

• Proceeding of EDISON Challenge
• /
• 2014.03a
• /
• pp.183-195
• /
• 2014

Kinetically constrained models (KCM) have attracted interest as models that assign dynamic origins to the interesting dynamic properties of supercooled liquid. Signs of dynamic heterogeneity in the crossover model that linearly interpolates between the FA-like symmetric constraint and the East model constraint by asymmetric parameter b were investigated using Monte Carlo technique. When the asymmetry parameter was decreased sufficiently, smooth fragile-to-strong dynamic transition was observed in terms of the relaxation time, diffusion constant, Stokes-Einstein violation, and dynamic length scale. Competition between energetically favored symmetric relaxation mechanism and entropically favored asymmetric relaxation mechanism is behind such transition.

• YAKHAK HOEJI
• /
• v.24 no.3_4
• /
• pp.151-157
• /
• 1980

Color transition mechanism of shikonin as an acid-alkali indicator was studied. It was confirmed that the presence of phenolic hydroxy radical was essential for the color change of shikonin. But in accordance with shikonin sodium salt (blue color), which was presumed to make chelation as six membered rings. Shikonin in alkaline solution, by dissociated phenolic protons of naphthoquinone nucleous, converted to the corresponding anion and instead of disappearance tautomerization, electron delocalization occurred and an additional pair of nonbonding electrons in the anion was available for interaction with .phi. electron system of the ring with further extension of the conjugation. It was responsible for its blue color(corresponding color: orange) with needs less energy difference (${\phi}{\rarw}{\phi}^{*}$) because of conjugation extension. Shikonin sodium salt seems to have similar nuclear structure as shikonin anion.

• Proceedings of the Korean Society of Marine Engineers Conference
• /
• 2001.05a
• /
• pp.135-139
• /
• 2001

This experimental study investigates the wake flow behind a pair of cylinders displaced normal to a free stream. In this experiment, the principal aim is to investigate the transition mechanism of the large vortex generating process in the wake having unique vortex shedding pattern. associated with the gap difference between the cylinders. The detailed visualization is carried out using the PIV measurement. The transition mechanism of the large generating vortex is clarified by showing the streak lines. the vorticity and the statistical fluctuating velocity distributions.

• Bulletin of the Korean Chemical Society
• /
• v.28 no.6
• /
• pp.936-940
• /
• 2007

The aminolyses of diphenyl phosphinic chloride (1) with substituted anilines in acetonitrile at 55.0 oC are investigated kinetically. Large Hammett ρ X (ρnuc = ?4.78) and Bronsted β X (βnuc = 1.69) values suggest extensive bond formation in the transition state. The primary normal kinetic isotope effects (kH/kD = 1.42-1.82) involving deuterated aniline (XC6H4ND2) nucleophiles indicate that hydrogen bonding results in partial deprotonation of the aniline nucleophile in the rate-limiting step. The faster rate of diphenyl phosphinic chloride (1) than diphenyl chlorophosphate (2) is rationalized by the large proportion of a frontside attack in the reaction of 1. These results are consistent with a concerted mechanism involving a partial frontside nucleophilic attack through a hydrogen-bonded, four-center type transition state.

• Bulletin of the Korean Chemical Society
• /
• v.18 no.4
• /
• pp.390-394
• /
• 1997

Nucleophilic substitution reactions of 2-thiopheneethyl benzenesulfonates (2-TEB) and 3-thiopheneethyl benzenesulfonates (3-TEB) with anilines and N,N-dimethylanilines (DMA) are investigated in acetonitrile at 60.0 ℃. The cross-interaction constants ρxz determined for the reactions with anilines are large negative (- 0.50) which are comparable to those for the similar predominantly frontside-attack SN2 reactions of 1-phenylethyl (1-PEB), 2-phenylethyl (2-PEB) and cumyl benzenesulfonates. A large negative ρxz value (- 0.4∼- 0.8) is considered to provide a mechanistic criterion for the frontside-attack SN2 mechanism with a four-center transition state. In agreement with this proposal the kinetic isotope effects, kH/kD, involving deuterated aniline nucleophiles are all greater than one reflecting partial N-H(D) bond cleavage in the transition state. The MO theoretical reactant structures of 1-PEB, 2-PEB and 2-TEB based on the PM3 calculation show that the benzene ring blocks the backside nucleophile approach to the reaction center carbon (Cα) enforcing the frontside-attack SN2 mechanism.

• Bulletin of the Korean Chemical Society
• /
• v.20 no.11
• /
• pp.1269-1276
• /
• 1999

Metallocenes, whether using a cocatalyst or not, act as catalysts in ethylene polymerization. The positive charge on the transition metal of a metallocene might have an important role in polymerization as an active site in our model approach. Using semiempirical calculations in the absence of cocatalyst, we show one of the possibilities that the positive charge on a metallocene might be more easily transferred through the Cp ring of a ligand to the ethylene than to transfer directly from the transition metal to the ethylene. In these calculations, the charge on titanium in an eight C2H4 system is transferred and a polymer chain is produced. This reaction takes place only when ethylenes are arranged in a particular direction with respect to the ring, but does not take place for ethylenes near Ti or Cl atoms. The same mechanism is shown for a metallocene ligand which is sterically hindered or where the Cp ring is replaced by fluorenyl. These results suggest an entirely new polymerization mechanism in the absence of a cocatalyst in which the Cp ring is the active site.