• Journal of Electrochemical Science and Technology
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• v.11 no.3
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• pp.291-309
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• 2020

Chromium was electrodeposited from deep eutectic solvents-based Cr³⁺ electrolytes on HB-pencil graphite electrode. Factors influencing the electrochemical behavior and the processes of Cr nucleation and growth were explored using cyclic voltammetry and chronoamperometry techniques, respectively. Cr³⁺ reduction was found to occur through an irreversible diffusion-controlled step followed by another irreversible one of impure diffusional behaviour. The reduction behavior was found to be greatly affected by Cr³⁺ concentration, temperature, and type of hydrogen bond donor used in deep eutectic solvents (DESs) preparation. A more comprehensive model was suggested and successfully applied to extract a consistent data relevant to Cr nucleation kinetics from the experimental current density transients. The potential, the temperature, and the hydrogen bond donor type were estimated to be critical factors controlling Cr nucleation. The nucleation and growth processes of Cr from either choline chloride/ethylene glycol (EG-DES) or choline chloride/urea (U-DES) deep eutectic solvents were evaluated at 70℃ to be three-dimensional (3D) instantaneous and diffusion-controlled, respectively. However, the kinetics of Cr nucleation from EG-DES was found to be faster than that from U-DES. Cr nucleation was tending to be instantaneous at higher temperature, potential, and Cr³⁺ concentration. Cr nuclei electrodeposited from EG-DES were characterized at different conditions using scanning electron microscope (SEM). SEM images show that high number density of fine spherical nuclei of almost same sizes was nearly obtained at higher temperature and more negative potential. Energy dispersive spectroscopy (EDS) analysis confirms that Cr deposits were obtained.

• International Journal of Fluid Machinery and Systems
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• v.5 no.3
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• pp.109-116
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• 2012

Water hammer pumps can effectively use the water hammer phenomenon for water pumping. They are capable of providing an effective fluid transport method in regions without a well-developed social infrastructure. The results of experiments examining the effect of the geometric form of water hammer pumps by considering their major dimensions have been reported. However, these conventional studies have not fully evaluated pump performance in terms of pump head and flow rate, common measures of pump performance. The authors have focused on the effects on the pump performance of various geometric form factors in water hammer pumps. The previous study examined how the hydrodynamic characteristics was affected by the inner diameter ratio of the drive and lift pipes and the angle of the drive pipe, basic form factors of water hammer pumps. The previous papers also showed that the behavior of water hammer pump operation could be divided into four characteristic phases. The behavior of temporal changes in valve chamber and air chamber pressures according to the air volume in the air chamber located downstream of the lift valve was also clarified in connection with changes in water hammer pump performance. In addition, the effects on water hammer pump performance of the length of the spring attached to the drain valve and the drain pipe angle, form factors around the drain valve, were examined experimentally. This study focuses on the form of the lift valve, a major component of water hammer pumps, and examines the effects of the size of the lift valve opening area on water hammer pump performance. It also clarifies the behavior of flow in the valve chamber during water hammer pump operation.

• Journal of the Korean Institute of Intelligent Systems
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• v.8 no.2
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• pp.9-20
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• 1998

In this paper, a new distance relaying scheme is proposed. Artificial neural networks are applied to the distance relaying system composed of pattern recognition based. The proposed distance relaying scheme has two blocks of pattern recognition stages to estimate the fundamental frequency and to classify the fault types. In the first block, a filtering method using neural networks called a neural networks mapping filter(NMF) is presented to efficiently extract the features. And in the sec'ond block, the estimator called neural networks fault pattern estimator(NFPE) is also presented to classify the fault types by the extracted effective features obtained from NMF. Each block of these applied schemes is trained by back-propagation algorithm of multilayer perceptron and show the fast and accurate pattern recognition by ability of multilayer neural networks. The test result of this approach are obtained the good performance from the fault transient wave signals of EMTP(e1ectromagnetic transients program) in the various fault conditions of power systems.

• Journal of the Korean Electrochemical Society
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• v.4 no.2
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• pp.70-76
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• 2001

The present work describes the capabilities of laser beam deflection (LBD) technique for the analysis of the stresses developed during hydrogen diffusion through Pd foil electrode. First, we explain briefly the elasto-diffusive (Gorsky effect) and diffusion-elastic phenomena. A model for the diffusion-elastic phenomenon is theoretically derived from the solution of the Fick's equation for given initial and boundary conditions, Vegard's second law and Hooke's law. Second, we introduce how to apply the principle of LBD technique to the study on the stresses generated during hydrogen diffusion. From the comparison of the deflection transients numerically calculated with those experimentally measured, we finally discuss the change in the tensile deflection with time in terms of hydrogen concentration profile transient and hydrogen diffusivity.

• Molecules and Cells
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• v.26 no.6
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• pp.558-565
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• 2008

Although the fertilizing ability of spermatozoa is greatly reduced after freezing, complete understanding of alterations induced by cryopreservation has not been elucidated. The present study evaluates the effects of cryopreservation on the $Ca^{2+}$ handling of boar spermatozoa using several sperm activators. Intracellular $Ca^{2+}$ signals from single spermatozoa were measured using confocal $Ca^{2+}$ imaging of unfrozen samples and of other spermatozoa after having been frozen. Elevation of the external $K^{2+}$ concentration elicited a three times larger $Ca^{2+}$ increase in fresh spermatozoa than in cryopreserved spermatozoa. Caffeine elicited $Ca^{2+}$ transients with some oscillations in the fresh spermatozoa, but not in the thawed spermatozoa. Depletion of the $Ca^{2+}$ store with thapsigargin induced a rapid rise in $Ca^{2+}$ in the control but generated a smaller increase of $Ca^{2+}$ after thawing. Exposure to progesterone induced a biphasic rise of the $Ca^{2+}$ level in the fresh spermatozoa only. Sperm viability was reduced by cryopreservation. Resting $Ca^{2+}$ levels in fresh and cryopreserved spermatozoa were similar. Longer incubation (2.5 h) of thawed spermatozoa partly recovered the $Ca^{2+}$ response to the interventions. These results suggest that cryopreservation reduces the responsiveness of spermatozoa to depolarization, modulators of the internal $Ca^{2+}$ store and progesterone in terms of the $Ca^{2+}$ signal, thus providing a possible mechanism for reduced fertility observed in cryopreserved boar spermatozoa.

• Molecules and Cells
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• v.25 no.2
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• pp.216-223
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• 2008

It has been reported that bone marrow (BM)-side population (SP) cells, with hematopoietic stem cell activity, can transdifferentiate into cardiomyocytes and contribute to myocardial repair. However, this has been questioned by recent studies showing that hematopoietic stem cells (HSCs) adopt a hematopoietic cell lineage in the ischemic myocardium. The present study was designed to investigate whether BM-SP cells can in fact transdifferentiate into functional cardiomyocytes. Phenotypically, BM-SP cells were $19.59%{\pm}9.00\;CD14^+$, $8.22%{\pm}2.72\;CD34^+$, $92.93%{\pm}2.68\;CD44^+$, $91.86%{\pm}4.07\;CD45^+$, $28.48%{\pm}2.24\;c-kit^+$, $71.09%{\pm}3.67\;Sca-1^+$. Expression of endothelial cell markers (CD31, Flk-1, Tie-2 and VEGF-A) was higher in BM-SP cells than whole BM cells. After five days of co-culture with neonatal cardiomyocytes, $7.2%{\pm}1.2$ of the BM-SP cells expressed sarcomeric ${\alpha}$-actinin as measured by flow cytometry. Moreover, BM-SP cells co-cultured on neonatal cardiomyocytes fixed to inhibit cell fusion also expressed sarcomeric ${\alpha}$-actinin. The co-cultured BM-SP cells showed neonatal cardiomyocyte-like action potentials of relatively long duration and shallow resting membrane potential. They also generated calcium transients with amplitude and duration similar to those of neonatal cardiomyocytes. These results show that BM-SP cells are capable of functional cardiomyogenic differentiation when co-cultured with neonatal cardiomyocytes.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.29 no.6 s.237
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• pp.671-686
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• 2005

The transient nature and complex geometries of two-phase gas-liquid flows cause fundamental difficulties when measuring flow velocity using an electromagnetic flowmeter. Recently, a current-sensing flowmeter was introduced to obtain measurements with high temporal resolution (Ahn et al.). In this study, current-sensing flowmeter theory was applied to measure the fast velocity transients in slug flows. The velocity fields of axisymmetric gas-liquid slug flow in a vertical pipe were obtained using Volume-of-Fluid (VOF) method, and the virtual potential distributions for the electrodes of finite size were also computed using the finite volume method for simulating slug flow. The output signal prediction for slug flow was carried out from the velocity and virtual potential (or weight function) fields. The flowmeter was numerically calibrated to obtain the cross-sectional liquid mean velocity at an electrode plane from the predicted output signal. Two calibration parameters are proposed for this procedure: a flow pattern coefficient and a localization parameter. The flow pattern coefficient was defined by the ratio of the liquid resistance between the electrodes for two-phase flow with respect to that for single-phase flow, and the localization parameter was introduced to avoid errors in the flowmeter readings caused by liquid acceleration or deceleration around the electrodes. These parameters were also calculated from the computed velocity and virtual potential fields. The results can be used to obtain the liquid mean velocity from the slug flow signal measured by a current-sensing flowmeter.

• Nuclear Engineering and Technology
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• v.38 no.2
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• pp.185-194
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• 2006

Transient operations for an integral type reactor, SMART-P, have been experimentally investigated using a thermal-hydraulic integral test facility, VISTA (Experimental Verification by Integral Simulation of Transients and Accidents), in order to verify the system design and performance of the SMART-P, a pilot plant of SMART. The VISTA facility was subjected to various accident conditions such as feedwater increase and decrease, loss of coolant flow, and control rod withdrawal accidents in order to elucidate the thermal-hydraulic responses following such accidents and finally to verify the system design of the SMARTP. Full functional control logics have been implemented in the VISTA facility in order to control the required control action for an accident simulation. As one of the sensitivity tests to verify the PRHRS performance, the effects of the initial water level in the compensation tank are experimentally investigated. When the initial water level is 16%, the water is quickly drained and nitrogen gas is then introduced into the PRHR system, resulting in deterioration of the PRHRS performance. It is thus found that nitrogen ingression should be prevented to ensure stable PRHRS operation.

• Journal of KSNVE
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• v.6 no.2
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• pp.163-177
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• 1996

An investigation on thermohydraulic stability of flow oscillations in the CANada Deuterium Uranium-600(CANDU-6) heat transport system has been conducted. Flow oscillations in reactor coolant loops, comprising two heat sources and two heat sinks in series, are possibly caused by the response of the pressure to extraction of fluid in two-phase region. This response consists of two contributions, one arising from mass and another from enthalpy change in the two-phase region. The system computer code used in the investigation os SOPHT, which is capable of simulating steady states as well as transients with varying boundary conditions. The model was derived by linearizing and solving one-dimensional, homogeneous single- and two-phase flow conservation equations. The mass, energy and momentum equations with boundary conditions are set up throughout the system in matrix form based on a node-link structure. Loop stability was studied under full power conditions with interconnecting the two compressible two phase regions in the figure-of-eight circuit. The dominant function of the interconnecting pipe is the transfer of mass between the two-phase regions. Parametric survey of loop stability characteristics, i. e., damping ratio and period, has been made as a function of geometrical parameters of the interconnection line such as diameter, length, height and orifice flow coefficient. The stability characteristics with interconnection line has been clarified to provide a simple criterion to be used as a guide in scaling of the pipe.

• Journal of the Microelectronics and Packaging Society
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• v.12 no.4 s.37
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• pp.331-338
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• 2005

The rapid advances in high power light sources and arrays as encountered in incandescent lamps have induced dramatic increases in die heat flux and power consumption at all levels of high power LED packaging. The lifetime of such devices and device arrays is determined by their temperature and thermal transients controlled by the powering and cooling, because they are usually operated under rough environmental conditions. The reliability of packaged electronics strongly depends on the die attach quality, because any void or a small delamination may cause instant temperature increase in the die, leading sooner or later to failure in the operation. Die attach materials have a key role in the thermal management of high power LED packages by providing the low thermal resistance between the heat generating LED chips and the heat dissipating heat slug. In this paper, thermal transient characteristics of die attach in high power LED package have been studied based on the thermal transient analysis using the evaluation of the structure function of the heat flow path. With high power LED packages fabricated by die attach materials such as Ag paste, solder paste and Au/Sn eutectic bonding, we have demonstrated characteristics such as cross-section analysis, shear test and visual inspection after shear test of die attach and how to detect die attach failures and to measure thermal resistance values of die attach in high power LED package. From the structure function oi the thermal transient characteristics, we could know the result that die attach quality of Au/Sn eutectic bonding presented the thermal resistance of about 3.5K/W. It was much better than those of Ag paste and solder paste presented the thermal resistance of about 11.5${\~}$14.2K/W and 4.4${\~}$4.6K/W, respectively.