• Title/Summary/Keyword: Transient absorption

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Development of Fast-Response CO2 Analyzer and Analysis of Engine-out Emission during Cold Start of SI Engine (고속응답 CO2 분석기의 제작 및 이를 이용한 SI엔진에서의 실시간 배기가스 분석에 관한 연구)

  • Song, Hyun-Soo;Park, Kyoung-Seok;Park, Dong-Sun;Min, Kyoung-Doug
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.2
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    • pp.133-140
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    • 2009
  • A fast-response $CO_2$ analyzer has been developed for measuring the $CO_2$ concentration during transient condition of a SI engine. The analyzer consists of the non-dispersive infrared absorption method, electrical chopping system and water cooling system. The analyzer has good repeatability, linearity and permissible drift characteristic. Besides, it showed 18ms of a response to measure the $CO_2$ concentration. The fast-response $CO_2$ analyzer was applied to a single cylinder SI engine and the $CO_2$ emission was examined during engine start. Simultaneously, the standard exhaust gas analyzer, which has slow response time, was used for confirming the accuracy of the exhaust gas analysis using the fast-response $CO_2$ analyzer. The developed analyzer showed much faster responsive characteristic than that of a standard analyzer and made cycle by cycle exhaust gas analysis possible. The transient engine operating characteristics will be estimated from the $CO_2$ concentration of engine-out emissions and engine operating variables.

SORET, HALL CURRENT, ROTATION, CHEMICAL REACTION AND THERMAL RADIATION EFFECTS ON UNSTEADY MHD HEAT AND MASS TRANSFER NATURAL CONVECTION FLOW PAST AN ACCELERATED VERTICAL PLATE

  • VENKATESWARLU, M.;LAKSHMI, D. VENKATA;RAO, K. NAGA MALLESWARA
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.20 no.3
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    • pp.203-224
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    • 2016
  • The heat and mass transfer characteristics of the unsteady hydromagnetic natural convection flow with Hall current and Soret effect of an incompressible, viscous, electrically conducting, heat absorbing and optically thin radiating fluid flow past a suddenly started vertical infinite plate through fluid saturated porous medium in a rotating environment are taken into account in this paper. Derivations of exact analytical solutions are aimed under different physical properties. The velocity, concentration and temperature profiles, Sherwood number and Nusselt number are easily examined and discussed via the closed forms obtained. Soret effect and permeability parameter tends to accelerate primary and secondary fluid velocities whereas hall current, radiation and heat absorption have reverse effect on it. Radiation and heat absorption have tendency to enhance rate of heat transfer at the plate. The results obtained here may be further used to verify the validity of obtained numerical solutions for more complicated transient free convection fluid flow problems.

Study on the Electron Injection of Newly Synthesized Organic Sensitizer in Dye-Sensitized Solar Cell

  • Gang, Tae-Yeon;Lee, Do-Gwon;Go, Min-Jae;Kim, Gyeong-Gon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.310-310
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    • 2010
  • Electronic and photovoltaic characteristics of two sensitizers (TA-BTD-CA and TA-BTD-St-CA), composed of a different $\pi$-conjugation in the linker group, have been investigated by theoretical and experimental methods. The electronic structure, transition dipole moment and oscillator strengths of two sensitizers have been scrutinized by using density functional theory (DFT) and time-dependent DFT (TD-DFT) method. The LUMO level and the oscillator strength of TA-BTD-St-CA was higher than that of TA-BTD-CA, which may facilitate the electron injection process as well as increase the absorption coefficient. The relative efficiencies of the electron injection from the excited sensitizer to nanocrystalline TiO2 and SnO2 films have also been investigated by nanosecond transient absorption spectroscopy. The relative electron injection efficiency of TA-BTD-St-CA exhibited similar injection efficiency for two different semiconductors. However, in the case of TA-BTD-CA sensitizer, electron injection into SnO2 was approximately three times larger than that into TiO2. This enhancement of electron injection of TA-BTD-CA for the SnO2 is due to the increment of the driving force caused by positive shift of conduction band of semiconductor, which was also confirmed from the investigation for the photovoltaic characteristics according to the electrolyte additive, such as LiI additive.

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Emission Characteristics of Elemental Constituents in Fine Particulate Matter Using a Semi-continuous Measurement System (준 실시간 측정시스템을 이용한 미세입자 원소성분 배출특성 조사)

  • Park, Seung-Shik;Ondov, John M.
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.2
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    • pp.190-201
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    • 2010
  • Fine particulate matter < $1.8{\mu}m$ was collected as a slurry using the Semicontinuous Elements in Aerosol Sampler with time resolution of 30-min between May 23 and 27, 2002 at the Sydney Supersite, Florida, USA. Concentrations of 11 elements, i.e., Al, As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Se, and Zn, in the collected slurry samples were determined off-line by simultaneous multi-element graphite furnace atomic absorption spectrometry. Temporal profiles of $SO_2$ and elemental concentrations combined with meteorological parameters such as wind direction and wind speed indicate that some transient events in their concentrations are highly correlated with the periods when the plume from an animal feed supplement processing facility influenced the Sydney sampling site. The peaking concentrations of the elemental species during the transient events varied clearly as the plume intensity varied, but the relative concentrations for As, Cr, Pb, and Zn with respect to Cd showed almost consistent values. During the transient events, metal concentrations increased by factors of >10~100 due to the influence of consistent plumes from an individual stationary source. Also the multi-variate air dispersion receptor model, which was previously developed by Park et al. (2005), was applied to ambient $SO_2$ and 8 elements (Al, As, Cd, Cr, Cu, Fe, Pb, and Zn) measurements between 20:00 May 23 and 09:30 May 24 when winds blew from between 70 and $85^{\circ}$, in which animal feed processing plant is situated, to determine emission and ambient source contributions rates of $SO_2$ and elements from one animal feed processing plant. Agreement between observed and predicted $SO_2$ concentrations was excellent (R of 0.99; and their ratio, $1.09{\pm}0.35$) when one emission source was used in the model. Average ratios of observed and predicted concentrations for As, Cd, Cr, Pb, and Zn varied from $0.83{\pm}0.26$ for Pb to $1.12{\pm}0.53$ for Cd.

Effect of Glucose, Its Analogs and Some Amino Acids on Pre-steady State Kinetics of ATP Hydrolysis by PM-ATPase of Pathogenic Yeast (Candida albicans)

  • Bushra, Rashid;Nikhat, Manzoor;M., Amin;Luqman A., Khan
    • Animal cells and systems
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    • v.8 no.4
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    • pp.307-312
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    • 2004
  • Fast kinetics of transient pH changes and difference spectrum formation have been investigated following mixing of ADP/ATP with partially purified plasma membrane PM-ATPase of the pathogenic yeast Candida albicans in the presence of five nutrients: glucose, glutamic acid, proline, lysine, and arginine and two analogs of glucose: 2-deoxy D-glucose and xylose. Average $H^+$- absorption to release ratio, indicative of population of ATPase undergoing complete hydrolytic cycle, was found to be 0.27 for control. This ratio varied between 0.25 (proline) to 0.36 (arginine) for all other compounds tested, except for glucose. In the presence of glucose, $H^+$- absorption to release ratio was exceptionally high (0.92). While no UV difference spectrum was observed with ADP, mixing of ATP with ATPase led to a large conformational change. Exposure to different nutrients restricted the magnitude of the conformational change; the analogs of glucose were found to be ineffective. This suppression was maximal in the case of glucose (80%); with other nutrients, the magnitude of suppression ranged from 40-50%. Rate of $H^+$- absorption, which is indicative of E~P complex dissociation, showed positive correlation with suppression of conformational change only in the case of glucose and no other nutrient/analog. Mode of interaction of glucose with plasma membrane $H^+$-ATPase thus appears to be strikingly distinct compared to that of other nutrients/analogs tested. The results obtained lead us to propose a model for explaining glucose stimulation of plasma membrane $H^+$-ATPase activity.

Pharmacodynamic Study of Silkworm Powder in Mice Administered to Maltose, Sucrose and Lactose (누에분말 추출물의 이당류 경구투여에 대한 동력학적 연구)

  • Ryu, Kang-Sun;Lee, Heui-Sam;Kim, Sun-Yeou
    • Journal of Sericultural and Entomological Science
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    • v.41 no.1
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    • pp.9-13
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    • 1999
  • The experiment was carried out to investigate the absorption profile of blood glucose in mice administered to silkworm powder MeOH extract. The mice was injected to oral load of maltose, sucrose and lactose(2 g/kg) and silkworm powder MeOH extract at the same time. After injecting the sample, blood glucose concentration was measured at 0, 30, 60, 120, 180 and 240 minutes. Blood glucose lowering effect of silkworm powder for loading maltose was 69% in postprandial 30 minutes. After the postprandial 60 minutes, the glucose was absorbed slowly. Total amount of blood glucose absorption in mice administered to maltose were 560.7 mg/dl during 240 minutes. That of silkworm powder MeOH extract marked 534.7 mg/dl. Total amount of blood glucose from oral loading sucrose reached to 508.9 mg/dl. That of loading silkworm powder MeOH extract were 468.8. But, silkworm powder was not inhibited lactose absorption. As a above results, silkworm powder inhibits the transient rising of blood glucose after postprandial 30 minuts through inhibition of ${\alpha}$-glucosidases. In case of starvation silkworm powder don't promote the hypoglycemia. In addition, silkworm powder induces the delay absorption of glucose without loss of it.

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Femtosecond Coherent Spectroscopic Study of Zn(II)porphyrin Using Chirped Ultrashort Pulses

  • Yoon, Min-Chul;Song, Jae-Kyu;Cho, Sung;Kim, Dong-Ho
    • Bulletin of the Korean Chemical Society
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    • v.24 no.8
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    • pp.1075-1080
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    • 2003
  • We have investigated femtosecond coherent vibrational motions of Zn(II)-5,15-diphenylporphyrin in toluene using chirp-controlled ultrashort pulses. The oscillatory features superimposed on the temporal profiles of the pump-probe transient absorption signal are affected by the chirping and energy of excitation pulses. Using chirp- and excitation energy-controlled femtosecond pulses, we are able to obtain information on the structural changes between the electronic ground and excited states based on a comparative analysis of the Fouriertransformed frequency-domain spectra retrieved from the oscillatory components with the ground state resonance Raman spectra and normal mode calculations.

A Study on the Keyhole Dynamics According to Polarization of Laser (레이저의 편광을 고려한 키홀 거동 해석에 관한 연구)

  • Cho, Jung-Ho;Na, Suck-Joo
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.1307-1311
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    • 2007
  • Three-dimensional transient keyhole profile is numerically analyzed for the case of stationary laser keyhole welding. Volume of fluid (VOF) method is adopted to track the free surface of molten metal based on the three governing equations which are continuity, momentum and energy equations. Multiple reflections of laser beam at the keyhole walls are also included in analysis through a real-time ray tracing technique. In this simulation, especially, polarization of laser is considered as an energy absorption mechanism following the Fresnel reflection theory. Both cases of linearly and circularly polarized beam are simulated and compared. The results show that the theoretically generated keyhole is asymmetrically stretched along the direction of polarization which is already observed experimentally before.

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A Study on the Deterioration Progress of Railway Arresters (철도용 피뢰기의 열화진전에 관한 연구)

  • Kil Gyung-Suk;Han Ju-Seop;Han Moon-Seob
    • Proceedings of the KSR Conference
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    • 2004.06a
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    • pp.1393-1395
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    • 2004
  • Arresters are the best protective device on electrical power systems against transient overvoltages generated by lightning and/or switching operation. Nonetheless, arresters will be deteriorated due to absorption of moisture in the environments of its use, repetition in the protective operation to overvoltages, and some defects at manufacturing. It is therefore important to estimate the electrical characteristic changes of ZnO blocks. In this paper, an accelerated deterioration test by a standard lightning impulse current was carried out to extract parameters needed for diagnosing arrester deterioration, and leakage current components were measured. Total energy applied to the ZnO blocks at each time is 1,050[J] in 8/20[${\mu}s$] impulse current. From the experimental results, we proposed electrical parameters and leakage current level to diagnose arrester soundness.

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Low-Velocity Impact Characterizations of 3D Orthogonal Woven Composite Plate (3D 직교 직물 복합재료의 충격 거동 및 특성에 관한 수치해석)

  • 지국현;김승조
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.10a
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    • pp.170-174
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    • 2002
  • In this study, the material characterization and the dynamic behavior of 3D orthogonal woven composite materials has been studied under transverse central low-velocity impact condition by means of the micromechanical model using finite elements. To build up the micromechanical model considering tow spacing and waviness, an accurate unit structure is stacked in x-y-z direction repeatedly. First, the mechanical properties of 3D orthogonal woven composites are obtained by means of virtual experiment using full scale Finite Element Analysis based on the DNS concepts, and the computed elastic properties are validated by comparison to available experimental results[9]. Second, using the implementation of this validated micromechanical model, 3D transient finite-element analysis is performed considering contact and impact, and the impact behavior of 3D orthogonal woven composite is investigated. A comparison study will be carried out in terms of energy absorption capabilities.

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