• 한국광학회지
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• 제4권3호
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• pp.347-353
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• 1993

펌프-촉침 방법을 이용한 피코초 순간 흡광 속도분광기를 제작하고 피코초 순간 흡광 분광을 측정하는 다른 방법들과 비교하였다. 제작된 피코초 순간 흡광 속도분광기는 모드 록킹된 cw 색소 레이저에서 발생된 펌프 펄스와 촉침 펄스 사이의 지연시간 변화에 따른 시료의 순간 투과도를 잡금 증폭기를 사용하여 측정하였다. 이 속도분광기를 사용하여 측정된 순간 흡광 및 바닥 상태의 표백 재생 속도 곡선들을 보여주었다. 단일 파장에서 발광 또는 비발광 계의 순간 흡광 혹은 바닥 상태의 표백 재생의 아주 좋은 속도 곡선을 얻을 수 있었다.

• 한국광학회지
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• 제2권4호
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• pp.209-213
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• 1991

최근들어 극초단 광학펄스를 생성하고 증폭하는 기술의 발달로 인하여 시분해 레이저 분광학에 많은 영향을 끼치게 되었다. 그 중에서도 응용성이 넓은 순간흡수분광학장치를 본 연구실에서 개발하였다. 이 기술은 고출력 레이저 펄스를 이용하여 white light continuum pulse를 생성시켜 이를 조사빔으로 이용하고, pump pulse는 원래 상태의 레이저를 이용하는 것이다. 순간흡수율 변화를 여러 파장에서 측정가능하도록 photodiode array를 이용하였으며, pump와 probe pulse의 시간차이에 의한 순간흡수율 변화를 색소의 일종인 DDI를 이용하여 측정하였다.

• 대한기계학회논문집B
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• 제26권12호
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• pp.1729-1737
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• 2002

A mathematical model for the prediction of carbon-dioxide absorption rate during the transient state of rotary type absorber is developed. The rotary type absorber operates using a fast rotating porous structure and clean water. The model for the transient state rotary type absorbers is based on the steady state model of packed tower absorber. The paper manipulates the operating data of an arbitrary quasi-steady state condition of rotary type absorber for the determination of the coefficients involved in the model developed. The prediction accuracy is evaluated from the measured data of rotary type absorber operated under fast transient state. The measured data include the mole fraction of carbon dioxide in mixed gas and the pressure of absorber. The relative error in carbon dioxide prediction is estimated to be 20% at maximum. The model is successfully applied for the prediction of the behavior of a closed cycle diesel engine.

• 한국광학회:학술대회논문집
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• 한국광학회 1990년도 제5회 파동 및 레이저 학술발표회 5th Conference on Waves and lasers 논문집 - 한국광학회
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• pp.172-176
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• 1990

A high resolution picosecond absorption kinetic spectrometer utilizing dye emission and a streak camera is presented and compared with other methods of picosecond transient absorption measurements. Typical transient absorption and bleach recovery kinetics measured with this spectrometer are shown. Single wavelength transient absorption or ground state bleach recovery kinetics are determined on the basis of a single laser shot, so that the samples are relatively free frm decomposition by irradiation. Excellent kinetics may be obtained from the near UV to the near IR and are not subject to interference from luminescence of samples. The sensitivity of this spectrometer is very high and it is reasonably easy and convenient to set up and use.

• Rapid Communication in Photoscience
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• 제3권4호
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• pp.73-75
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• 2014

Novel diphenylphenanthrenes (DPPs) were prepared by a photocyclization method, and the substituent effects of the phenyl groups on the photophysical properties of the phenanthrene chromophore were investigated based on measurements of fluorescence yields, lifetimes, and transient absorption. Fluorescence activities in DPPs are increased by introducing phenyl rings that can enhance the transition moment along the short axis of the phenanthrene skeleton. Intersystem crossing from the fluorescent states to the triplet manifolds is shown to be operative through the triplet-triplet absorption spectra obtained by laser photolysis techniques.

• Bulletin of the Korean Chemical Society
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• 제6권4호
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• pp.234-238
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• 1985

The photoisomerization of 5-styryl-1,3-dimethyluracil is studied with nanosecond laser flash photolysis technique at room temperature. The laser flash photolysis of E-isomer produces the transient absorption spectrum regarded as the triplet-triplet absorption, but the transient absorption of Z-isomer does not show the typical decay curve, probably due to the facile photocyclization reaction during the laser flash photolysis. Using the energy transfer method on nanosecond laser spectroscopy, the energy of the lowest triplet state for E isomer is estimated to lie between 41.8 and 47 kcal/mol. The triplet lifetime for E-isomer obtained from the decay curve of the transient absorption is ca. 93ns. The $S_1 → T_1$ intersystem crossing of E-isomer on direct excitation is relatively inefficient at room temperature supporting the singlet mechanism for direct photoisomerization.

• Bulletin of the Korean Chemical Society
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• 제33권11호
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• pp.3879-3882
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• 2012

• Bulletin of the Korean Chemical Society
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• 제12권4호
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• pp.441-444
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• 1991

The intramolecular proton transfers of 2-hydroxy-4,5-naphthotropone in room temperature solutions are studied using static and time-resolved absorption and emission spectroscopy. Dual normal and tautomer fluorescence is observed in ethanol solution, while only the tautomer fluorescence is observed in cyclohexane solution. The fluorescence lifetimes and quantum yields in ethanol and cyclohexane solutions indicate that in hydrocarbon solvents, rapid intersystem crossing competes with proton transfer in the first excited singlet state. Transient absorption spectra and kinetics indicate that proton transfer also undergoes in the first triplet state with a transfer time of ∼ 3 ns. No transient absorption from the tautomer ground state indicates a rapid back proton transfer in the ground state.

• Structural Engineering and Mechanics
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• 제67권2호
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• pp.165-173
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• 2018

A simple predicted model using a modified Shear-lag method was used to represent the moisture absorption effect on the stiffness degradation for $[0/90]_{2s}$ composite laminates with transverse cracks and under flexural loading. Good agreement is obtained by comparing the prediction model and experimental data published by Smith and Ogin (2000). The material properties of the composite are affected by the variation of temperature and moisture absorption. The transient and non-uniform moisture concentration distribution give rise to the transient elastic moduli of cracked composite laminates. The hygrothermal effect is taken into account to assess the changes in the normalised axial and flexural modulus due to transverse crack. The obtained results represent well the dependence of the stiffness properties degradation on the cracks density, moisture absorption and operational temperature. The composite laminate with transverse crack loaded in axial tension is more affected by the hygrothermal condition than the one under flexural loading. Through this theoretical study, we hope to contribute to the understanding of the moisture absorption on the composite materials with matrix cracking.

• Bulletin of the Korean Chemical Society
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• 제35권3호
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• pp.851-857
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• 2014

Carotenoids, natural antenna pigments in photosynthesis share a symmetric backbone of conjugated polyenes. Contrary to the symmetric and almost planar geometries of carotenoids, excited state structure and dynamics of carotenoids are exceedingly complex. In this paper, recent infrared and visible transient absorption measurements and excitation dependent dynamics of 8'-apo-${\beta}$-caroten-8'-al and 7',7'-dicyano-7'-apo-${\beta}$-carotene will be reviewed. The recent visible transient absorption measurements of 8'-apo-${\beta}$-caroten-8'-al in polar and nonpolar solvents will also be introduced to emphasize the complex excited-state dynamics and unsolved problems in the $S_2$ and $S_1$ excited states.