• 에너지공학
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• 제22권2호
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• pp.120-127
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• 2013

본 연구는 예혼합 연소시스템에 적용할 직교류 엇갈림 배열 열교환기의 열전달 및 압력강하 특성 검토를 목적으로 한다. 따라서 비예혼합화염보다 화염길이가 짧고 당량비 조절을 통해 NOx 및 CO 배출을 제어할 수 있는 예혼합방식의 버너 앞에 모듈로 구성된 열교환기를 설치한 후 당량비를 변화시킬 때 NOx와 CO의 배출특성을 검토하였다. 또한 열교환기의 모듈 변화에 대한 유용도, 엔트로피 생성량 및 압력강하를 계산하였고 엑서지 로스를 검토하여 열교환기의 성능을 분석하였다.

• 한국수소및신에너지학회논문집
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• 제15권2호
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• pp.144-151
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• 2004

The effect of the cobalt content on the thermodynamic and, heat and mass transfer properties of the $MmNi_{5-y}B_{y-z}C_z(y=0.5{\sim}1.5,\;z=0.5)$hydrogen storage alloys has been studied systematically. The P-C isotherms curves show that with increasing cobalt content in the alloys, the plateau pressure of the hydrogen absorption and desorption and enthalpy(${\Delta}H$) increases steeply and the plateau region becomes flat, while entropy(${\Delta}S$) decreases. Also at the constant cobalt content the hydrogen transfer rate decreases with the reaction temperature, while the initial reaction kinetics increases. But the initial reaction with hydrogen completes within 1min, although the reaction proceeds about 30minutes thereafter.

• 에너지공학
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• 제22권1호
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• pp.44-50
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• 2013

본 연구의 목적은 예혼합방식의 버너 앞에 소형 열교환기를 설치한 후 당량비를 변화시킬 때 NOx와 CO의 배출특성을 검토하고 열교환기 유용도와 엔트로피 생성수를 실험결과를 바탕으로 계산한 것이다. 실험결과 당량비가 증가할수록 화염온도가 높아지면서 열전달율은 상승한다. 배기가스 오염물질량과 유용도를 고려할 경우 본 실험범위에서의 적정 운전당량비는 0.75이다. 유용도를 증가시키고 엔트로피 생성량을 줄이기 위해서는 연소가스의 열전달량을 증가시켜야 하며 따라서 열교환기 면적을 증가시키는 것이 필요하다고 판단된다.

• 대한의용생체공학회:학술대회논문집
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• 대한의용생체공학회 1990년도 춘계학술대회
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• pp.47-50
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• 1990

In this study, the degree of spectral transfer to lower frequency caused by accumulation of Latic acid inside the muscle is estimated the convintional dip analysis, zero-crossing method and FFT method have intrinsic errors and estimation problems in case of severe noise. The new spectral analysis method using "$2^{nd}$ order Maximum Entropy Method" was applied to estimate mean frequency and we confirmed that this new method yields fast and reliable estimation over the FFT method.

• 한국수자원학회논문집
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• 제36권2호
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• pp.263-271
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• 2003

습윤지수는 TOPMODEL, THALES 등의 수문모형에서 유역수문과정을 기술하는 지표로서 사용되며, 습윤지수의 계산방법과 한계성에 대한 많은 연구가 보고되고 있다. 임의유역에 대한 습윤지수 분포함수는 사용되어지는 흐름분배 알고리즘에 의존하게 되므로, 적절한 알고리즘의 선정과 알고리즘간의 비교가 필요하다. 본 연구에서는 엔트로피 개념을 이용하여 수치고도모형내의 정보가 각 흐름분배 알고리즘에 의해 습윤지수 분포함수로 도출되는 과정에서, 각 흐름분배 알고리즘에 따른 정보이동량을 해석하고 실측된 지표토양수분과의 상관성 검토를 통한 기존흐름분배 알고리즘들의 고찰을 시도하였다. Holmgren의 구배멱급수 알고리즘과 SDFAA 알고리즘은 습윤지수의 정보량 최대화를 위해 가장 적절한 알고리즘으로 판명되었다.

• 오토저널
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• 제7권1호
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• pp.24-34
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• 1985

The study of unsteady gas exchange processes in the inlet and exhaust systems of the single-cylinder 4-stroke cycle spark ignition engine is presented in this paper. The generalized method of characteristics including friction, heat transfer, change of flow area and entropy gradients was used for solving the equations defining the gas exchange process. The path line calculation was also conducted to allow for calculation of the gas composition and entropy change along the path lines, and of the variable specific heat due to the change of temperature and composition. As the result of the simulation, the properties at each point in the inlet and exhaust pipe, pressure and temperature in the cylinder, and charging efficiency were obtained. Pumping loss and residual gas fraction were also computed. The effect of engine speed, exhaust and inlet pipe length on the pumping loss and charging efficiency were studied showing that the results were in agreement with what has been known from experiments.

• 설비공학논문집
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• 제7권1호
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• pp.30-41
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• 1995

The present paper investigated irreversibilities and energy flow of a vapor compression refrigerator. The entropy generation and the available energy dissipation in components of the system were analyzed by using experimental data. It was shown that the dissipated available energy in the compressor including electric motor was much more than those in other components. The effects of the pressure drop and heat loss on irreversibilities in the condenser and the evaporator were small in comparison with heat transfer.

• Bulletin of the Korean Chemical Society
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• 제6권1호
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• pp.23-29
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• 1985

The charge-transfer complexing properties of 1-methyl nicotinamide (MNA), an acceptor, and adenine, a donor, were investigated in water and SDS micellar solutions in relation to the intramolecular interaction in nicotinamide adenine dinucleotide ($NAD^+$). The spectral and thermodynamic parameters of MNA-indole and methyl viologen-adenine complex formations were determined, and the data were utilized to evaluate the charge-transfer abilities of MNA and adenine. The electron affinity of nicotinamide was estimated to be 0.28 eV from charge-transfer energy $of{\sim}300$ nm for MNA-indole. The large enhancement of MNA-indole complexation in SDS solutions by entropy effect was attributed to hydrophobic nature of indole. The complex between adenine and methyl viologen showed an absorption band peaked near 360 nm. The ionization potential of adenine was evaluated to be 8.28 eV from this. The much smaller enhancement of charge-transfer interaction involving adenine than that of indole in SDS solutions was attributed to weaker hydrophobic nature of the donor. The charge-transfer energy of 4.41 eV (280 nm) was estimated for nicotinamide-adenine complex. The spectral behaviors of $NAD^+$ were accounted to the presence of intramolecular interaction in $NAD^+$, which is only slightly enhanced in SDS solutions. The replacement of nicotinamide-adenine interaction in $NAD^+$ by intermolecular nicotinamide-indole interaction in enzyme bound $NAD^+$, and guiding role of adenine moiety in $NAD^+$ were discussed.

• 대한기계학회논문집
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• 제8권6호
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• pp.564-568
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• 1984

본 연구에서는 실제 동력 발생장치에 사용되는 사이클은 장치의 크기를 고려 한 파라미터의 선정이 필요하며, 여기서는 열전달에 의한 비가역성을 고려할 때의 열 기관 사이클을 출력에 중점을 두어 해석하고자 한다. 그리고 비가역성에 의한 엔트 로피 생성량과 출력과의 관계도 살펴볼 것이다.

• Bulletin of the Korean Chemical Society
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• 제5권3호
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• pp.121-126
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• 1984

The charge transfer complex formations between indole derivatives and methylviologen were investigated spectroscopically. In aqueous solutions near room temperature, the order of complex stability was tryptamine < tryptophan < indole < indole acetate, which is the reverse order of the magnitude of molar absorptivities. This was interpreted as involvement of contact charge transfer. The decrease of enthalpy of complex formation (-${\Delta}$H) was highest in tryptamine, and lowest in indole acetate. ${\Delta}$H and entropy of complex formation (${Delta}$S) varied nearly in a linear fashion with isokinetic temperature $242^{\circ}$K. These results were attributed to the hydration-dehydration properties of the side chains in indole derivatives. Except indole acetate, the complex formations were greatly enhanced by the addition of sodium dodecyl sulfate(SDS). However, the direct relationship between the enhanced complex formation and SDS micelle formation was not found. The enhanced charge transfer interaction inSDS solutions was attributed to the increased ${\Delta}$S by interaction between methylviologen and SDS in premicellar level. The order of complex stability in SDS solutions was indole acetate < tryptophan < trypamine < indole, which reflects the hydrophobicity of indole derivatives as well as electrostatic interaction between indole derivatives and methylviologen associated with SDS.