• Bulletin of the Korean Chemical Society
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• 제31권2호
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• pp.365-371
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• 2010

The multiconfiguration molecular mechanics (MCMM) algorithm was used to generate potential and vibrationally adiabatic energy surfaces for excited-state tautomerization in the 1:1 7-azaindole:$H_2O$ complex. Electronic structures and energies for reactant, product, transition state were computed at the CIS/6-31G(d,p) level of theory. The potential and vibrationally adiabatic energies along the reaction coordinate were generated step by step by using 16 high-level Shepard points, which were computed at the CIS/6-31G(d,p) level. This study shows that the MCMM method was applied successfully to make quite reasonable potential and adiabatic energy curves for the excited-state double proton transfer reaction. No stable intermediates are present in the potential energy curve along the reaction coordinate of the excited-state double proton transfer in the 1:1 7-azaindole:$H_2O$ complex, indicating that these two protons are transferred concertedly. The change in the bond distances along the reaction coordinate shows that two protons move very asynchronously to make an $H_3O^+$-like moiety at the transition state.

• 한국위성정보통신학회논문지
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• 제10권3호
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• pp.73-77
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• 2015

본 논문에서는 반복 복호 과정에서 연판정 정보값들의 변화로 인하여 성능이 개선되는 상황을 분석하기 위하여 사용되는 EXIT(extrinsic information transfer) 차트를 LDPC 부호와 터보 부호에 대하여 생성하는 기법을 소개하고, EXIT 차트 생성과정에서 비트 오류를 제외하였을 경우 나타나는 효과에 대해 살펴보기로 한다. 본 논문에서 제시된 시뮬레이션을 이용한 EXIT 챠트 생성 기법은 매우 간단한 방법으로 반복 복호를 사용하는 오류정정부호의 정보흐름을 파악할 수 있는 효율적인 방법이다. 시뮬레이션 결과 분석을 통하여 비트 오류를 제외할 경우 지나치게 정보량이 높은 구간에서만 EXIT 챠트가 생성된다는 사실을 확인할 수 있었다.

• Journal of Advanced Marine Engineering and Technology
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• 제15권3호
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• pp.57-65
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• 1991

The quenching of steels by water is one of the important problems in engineering for the applications of heat treatment or continuous casting process, but the fundamental researches by the theoretical approaches have not been satisfactorily improved yet. The very rapid cooling problems by the thermal conduction including the latent heat of phase transformation in steel and the transient boiling heat transfer of water on the surface of the steel covering from $850^{\circ}C$ to $20^{\circ}C$ are the key problems of heat treatment. The present quenching experiments are performed for the cylindrical specimens of carbon steel, S45C of diameters (12-30). Nonlinear transient heat conduction and transient boiling heat transfer problem of water on the surface of specimens is analyzed by the numerical method of inverse heat conduction problem. The conditions for the calculation are that the initial temperature of specimens is $820^{\circ}C$ and the cooling water in bath are $20^{\circ}C$,$40^{\circ}C$,$60^{\circ}C$,$80^{\circ}C$,$95^{\circ}C$ with no agitation.

• 열처리공학회지
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• 제23권5호
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• pp.249-256
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• 2010

Water jet impingement cooling has been widely used in a various engineering applications; especially in cooling of hot steel plate of steelmaking processes and heat treatment in hot metals as an effective method of removing high heat flux. The effects of cooling water temperature on water jet impingement cooling are primarily investigated for hot steel plate cooling applications in this study. The local heat flux measurements are introduced by a novel experimental technique that has a function of high-temperature heat flux gauge in which test block assemblies are used to measure the heat flux distribution during water jet impingement cooling. The experiments are performed at fixed flow rate and fixed nozzle-to-target spacing. The results show that effects of cooling water temperature on the characteristics of jet impingement heat transfer are presented for five different water temperatures ranged from 5 to $45^{\circ}C$. The local heat flux curves and heat transfer coefficients are also provided with respect to different boiling regimes.

• Biotechnology and Bioprocess Engineering:BBE
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• 제7권1호
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• pp.16-20
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• 2002

Parameter estimations were made for the reversed-phase adsorption of perillyl alcohol (POH), a potent anti-cancer agent, on octadecylsilyl-silica gel (ODS). The average particle diameter of ODS was about $15\;{\mu}m$, and the particles were packed in the column $(3.9\;\times\;300mm)$. The mobile phase used was a mixture of acetonitrile and water, in which the acetonitrile ranged between 50 and $70\;(v/v\;\%)$. The first absolute moment and the second central moment were determined from the chromatographic elution curves by moment analysis. Experiments were carried out using POH solutions within the linear adsorption range. The fluid-to-particle mass transfer coefficient was estimated using the Wilson-Geankoplis equation. The axial dispersion coefficient and the intra particle diffusivity were determined from the slope and intercept of a plot of H vs $1/u_0$, respectively. The contributions of each mass-transfer step were axial dispersion, fluid-to-particle mass transfer, and intraparticle diffusion.

• 한국산학기술학회논문지
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• 제16권5호
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• pp.3596-3601
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• 2015

진동해머에 의해 시공되는 말뚝의 거동을 분석할 목적으로 개발된 기존의 프로그램을 개선하고자 하였다. 진동해머-말뚝-지반으로 구성되는 진동시스템의 기존 지배방정식에 지반저항의 댐핑효과와 클러치마찰력을 추가하였다. 또한, 개발된 해석기법의 하중전이곡선을 모사하는 수정 Ramberg-Osgood 모델의 매개변수를 재산정하여 해석기법을 개선하고자 하였다. 수정된 프로그램에 의한 해석결과를 현장시험결과와 비교해 볼 때 시간에 따른 말뚝의 변위 및 하중전이거동이 현장시험결과에 좀 더 유사하였다. 개발된 프로그램에 의한 말뚝 관입깊이별 관입속도를 상용 프로그램에 의한 결과 및 현장시험결과와 비교해 볼 때 상용프로그램보다 훨씬 더 현장시험결과에 가까웠다.

• Bulletin of the Korean Chemical Society
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• 제16권6호
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• pp.511-515
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• 1995

Since much studies have been performed concerning the electrochemical behaviors and the practical applications of PB based devices, little has yet reported to investigate the best condition for the preparation for PB thin films. As considered some factors(peak shape, peak current, and peak separation) from the i-V curves, the optimal condition in the film growth were investigated under various immersion solutions. An electron-transfer processes of Fe2+/Fe3+ and Fe(CN)63-/4- redox couples were considered by measuring the observed currents as a function of the rotation velocity. The standard heterogeneous electron-transfer rates for these films and bare Au disc electrode in 10-3 M Fe2+/Fe3+ solution, applied at +0.65 V vs. SCE, were 6.14 × 10-3 and 7.78 × 10-3 cm/s, respectively, obtained using a rotating disc electrode. In case of the addition of potassium ion, the rate constants for these Fe2+/Fe3+ system on thin films of PB and bare electrode were given a little high values. The electron transfer rate for 10-3 M Fe(CN)63-/4- were 4.55 × 10-3 and 6.84 × 10-3 cm/s, respectively. The conductivity as directly determined during obtained the voltammogram, was 2.2 × 10-7 (Ω·cm)-1. This value is similar magnitude to that calculated from bulk sample.

• 한국태양에너지학회 논문집
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• 제33권4호
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• pp.51-58
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• 2013

A study on power performance testing of a wind turbine which has no met-mast at a distance of 2~4 rotor diameter was carried out using the Nacelle Transfer Function, NTF, according to IEC 61400-12-2. The wind data for this study was measured at HanKyoung wind farm of Jeju Island. The NTF was modeled using the correlation between wind speeds from the met-mast and from the wind turbine nacelle within 2~4 rotor diameter from the met-mast. The NTF was verified by the comparison of estimated Annual Energy Productions, AEPs, and binned power curves. The Nacelle Power Curve, NPC, was derived from the nacelle wind speed data corrected by NTF. The NPC of wind turbine under test and the power curve offered by the turbine manufacturer were compared to check whether the wind turbine is properly generating electricity. Overall the NPC was in good agreement with the manufacturer's power curve. The result showed power performance testing for a wind turbine which has no met-mast at a distance of 2~4 rotor diameter was successfully carried out in compliance with IEC 61400-12-2.

• 한국광학회지
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• 제2권4호
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• pp.203-208
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• 1991

모드동기된 아르곤 이온 레이저를 여기광원으로 사용한 시간상관 단일광자 계수장치를 이용하여 에틸렌글리콜 용매 내에서 Rhodamine 6G에서 Malachite Green으로의 비복사 에너지전달과정을 연구하였다. 측정된 donor의 형광소멸곡선을 full-fitting 방법으로 분석 처리하여 acceptor 농도의 변화에 따른 환산농도와 임계전이거리를 구했다. donor의 농도가 acceptor의 농도 보다 클때는 donor-donor의 원거리 쌍극자 모멘트에 의한 에너지 이주 효과를 고려해야하며 Forster 모델 보다 Huber 모델이 더 적절하였다.

• Journal of Power Electronics
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• 제19권5호
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• pp.1235-1247
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• 2019

Zero-Voltage-Switching (ZVS) operation for a Wireless Power Transfer (WPT) system can be achieved by designing a ZVS controller. However, the performance of the controller in some industrial applications needs to be designed tightly. This paper introduces a ZVS controller design method for WPT systems. The parameters of the controller are designed according to the desired performance based on the closed loop dominant pole placement method. To describe the dynamic characteristics of the system ZVS angle, a nonlinear dynamic model is deduced and linearized using the small signal linearization method. By analyzing the zero-pole distribution, a low-order equivalent model that facilitates the controller design is obtained. The parameters of the controller are designed by calculating the time constant of the closed-loop dominant poles. A prototype of a WPT system with the designed controller and a five-stage multistage series variable capacitor (MSVC) is built and tested to verify the performance of the controller. The recorded response curves and waveforms show that the designed controller can maintain the ZVS angle at the reference angle with satisfactory control performance.