• Title/Summary/Keyword: Trace analysis

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Water distribution system contamination source estimation based on trace analysis (Trace Analysis 기능을 활용한 상수도 관망 내 오염물 유입 지점 추정)

  • Shin, Geumchae;Lee, Seungyub
    • Proceedings of the Korea Water Resources Association Conference
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    • 2022.05a
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    • pp.184-184
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    • 2022
  • 지난 2019년 인천시, 서울시 문래동, 포항시 등에서 발생한 수질사고로 인해 국민의 상수도에 대한 신뢰도가 최악의 상황에 있으며, 이후로도 깔따구 유충이 발견되는 등 상수도 관망 내 체계적인 수질 관리 및 빠르고 정확한 수질 사고 발생 지점의 추정이 중요해 지고 있는 실정이다. 오염물 유입 추정은 수리학적 사고로 고려되는 누수와는 달리 상대적으로 그 지점 추정이 어렵다. 대게의 경우 수리해석을 진행하여 유량과 유향을 파악한 뒤 계측 지점에서부터 동일 시간대로 역으로 흐름을 거슬러 올라가며 확률상 높은 지점을 추정하는 것이 일반적인 방법이다. 본 연구에서는 범용 수리해석 프로그램인 EPANET2.2에 내장된 Trace Analysis (이후 trace 분석) 옵션을 사용한 오염물 유입 지점 추정 방법론을 소개한다. 본 연구에서는 방법론의 검증을 위해 오염물 유입지점은 한 곳으로 가정하였다. 해당 방법론은 먼저 절점별 trace 분석을 실시하여 모든 지점에서 수질 관측 지점까지 물이 도달하는데 소요되는 시간을 산정한다. 해당 시간과 오염물 관측 데이터와의 비교를 통해 유입 확률이 높은 지점을 추출한다. 이를 위해 실측 데이터가 필요하며, 결과는 지점별 확률로 나타난다. 모의 결과 1개의 수질 관측 지점으로도 개략적인 지점을 선정할 수 있는 것으로 나타났다. 다만, 수질 관측 지점의 수에 따라 분석 결과의 정확도가 향상한다. 마지막으로 유입 지점 추정 확률이 낮은 경우, 유입 지점 추정 확률을 향상시킬 수 있는 추가 수질 분석 지점을 결정하였다. 본 연구에서 소개한 방법론은 향후 수질 사고 발생 시 최초 확산 방지를 위한 격리 지점 선정에 근거를 제시할 수 있을 것으로 기대하며, 나아가 수질 관측 지점을 결정 및 대응 방안 수립 가이드라인으로 활용할 수 있을 것이다.

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Introduction of Clean Techniques for Trace Metal Analysis in Seawater (해수 중의 미량금속 분석을 위한 청결기술의 소개)

  • Kim, Kyung-Tae;Kim, Eun-Soo;Ra, Kong-Tae;Moon, Deok-Soo;Kim, Hyeon-Ju
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.15 no.2
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    • pp.157-164
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    • 2009
  • The metals such as Al, Ag, Au, Cu, Cd, Co, Fe, Ni, Pb, Zn, etc are present at very low concentration in seawater and are classified as so-called trace metals. Whiles some of them are used in metabolism of living organism as a micronutrient, they may show toxic effects on organisms in case of a limited threshold concentration of them Plenty of studies on trace metals have been performed bemuse trace metals have a persistent influence and an adverse effect on marine environment and ecosystem. For long years, when the concentration of trace metals in natural waters such as seawater and fresh water are measured with high precision and accuracy, some systematic errors have been recognized to be present in measurements. Since 1975 in US and European countries, the measured concentration of trace metals in seawater have been found to be lower by factors of 10-1,000 than the previous data of trace metals measurements and the vertical profiles of the measurements have been shown to reflect well-known biological, physical and geochemical processes. These results are attributed to great advances in analytical instrumentation and methodology for trace metals measurements. Precautions against the contamination of samples are required to be taken in the process of sampling, storage, and analysis of samples. However, in Korea, erroneous data of trace metals with regard to ocean and marine environment related survey and investigations are reported The lock of exact understanding and information regarding precautions in sampling, storage and analysis of samples lead to the deterioration of data quality, especially in the analysis of trace metals. The major procedures to obtain the accurate data of trace metals in natural waters are introduced for applying to the study and assessment of marine environments.

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Trace elements analysis in some medicinal plants using graphite furnace-atomic absorption spectroscopy

  • Anal, Jasha Momo H.;Chase, Petevino
    • Environmental Engineering Research
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    • v.21 no.3
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    • pp.247-255
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    • 2016
  • Ten trace elements (Mg, Ca, V, Cr, Mn, Fe, Cu, Zn, Mo, and Cd) were determined in seven traditionally used wild medicinal plants of the Nagas in the North-East India viz Cynoglossum furcatum Wallich, Elsholtzia blanda Bentham, Lycopodium cernuum Linnaeus, Potentilla fulgens Wallich ex Hooker, Swertia macrosperma C.B. Clarke, Thalictrum foliolosum DC and Valeriana jatamansi Jones. Plant samples were dried, weighed, digested and analyzed for their mineral distribution level ranging from trace to major elements by graphite furnace-atomic absorption spectroscopy. All the medicinal herbs studied were found to contain the ten elements analyzed. The elemental concentration is given in mg/kg. Mg and Ca are present in high concentrations in both the roots and leaves of the plant samples. Among trace transition metals Fe had the highest concentration, followed by Mn, Cr, Cu, V, Zn, and Mo. Analysis showed that the toxic Cd element was at a lower concentration and is within the permissible limit of FAO/WHO, California standards and United States Pharmacopeia Limit for Nutritional Supplements.

Trace Metals of Ambient TSP in Daegu Area (대구지역 총 부유분진중 중금속)

  • 이찬형
    • Journal of Environmental Health Sciences
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    • v.29 no.1
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    • pp.67-73
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    • 2003
  • This study was carried out to characterize the behavior and sources of particulate trace metal in Daegu city. TSP (Total Suspended Particulate matter) was collected by filters on High Volume Air Sampler from the four areal (reference, residential, commercial, industrial area). The moult were analyzed by AAS after preliminary treatment. The average centration trend of trace metals contained in TSP was shown as follows : Fe > Cu > Pb > Mn > Ni > Cr > Cd. The trace metals showed the highest concentration in the industrial area. This study showed the seasonal variation of trace metals. Fe and Mn showed high concentration in spring, whereas Cr, Ni, Cd and Pb showed high concentration in winter. Also this study showed the regional variation of trace metals. The order of the average concentration of trace metals was : industrial > commercial > residential > reference area. Using Mn as a reference element, the enrichment factor analysis were used for identifying the trace element contributors. The enrichment factors of Cr, Fe < 10 were considered to have a significant dust and soil source and termed nonenriched. Pb, Cd, Cu >>10 were enriched and had a significant fraction which was contributed by anthropogenic sources.

Trace Elements Deficiency and the Diagnostic Usefulness of Hair Mineral Analysis in Children with Chronic Gastrointestinal Disease (만성 소화기 질환 환아에서 미량원소 결핍과 모발 검사의 유용성)

  • Hong, Jea-Na;Lee, Jung-Hwa;Lee, Ran;Shin, Jee-Youn;Ko, Jae-Sung;Seo, Jeong-Kee
    • Pediatric Gastroenterology, Hepatology & Nutrition
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    • v.11 no.2
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    • pp.122-129
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    • 2008
  • Purpose: Patients with chronic gastrointestinal disease are at risk for trace element deficiency due to impaired absorption and gastrointestinal loss. The aim of this study was to evaluate the trace element status of patients with gastrointestinal disease by blood and hair analysis, and to determine the usefulness of hair mineral analysis for diagnosing trace element deficiency not detected by a blood test. Methods: An analysis of hair minerals was performed and compared with blood mineral analysis in 13 patients with chronic gastrointestinal disease. The concentration of each element in the hair and blood was compared in the subgroups based on parenteral nutritional support or clinical symptoms. Results: Almost all patients had trace element deficiency. The trace elements deficient in the blood or hair analysis included zinc, selenium and copper. The hair zinc concentration was significantly lower in the group receiving parenteral nutritional support. The hair selenium concentration was statistically associated with the clinical symptoms of hair loss, brittle hair and loss of hair pigmentation. Conclusion: The results of this study suggest that patients with chronic gastrointestinal disease should receive adequate zinc and selenium replacement to avoid trace element deficiency especially when treated with long-term parenteral nutrition. Hair mineral analysis is useful as a complementary tool for the detection of a trace element deficiency.

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Simple Spot Method of Image Analysis for Evaluation of Highly Marbled Beef

  • Irie, M.;Kohira, K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.4
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    • pp.592-596
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    • 2012
  • The simple method of evaluating highly marbled beef was examined by image analysis. The images of the cross section at the 6 to 7th rib were obtained from 82 carcasses of Wagyu cattle. By using an overall trace method, the surrounding edges of the longissimus thoracis and three muscles were traced automatically and manually with image analysis. In a spot method, 3 to 5 locations (2.5 or 3.0 cm in diameter) for each muscle were rapidly selected with no manual trace. The images were flattened, binarized, and the ratio of fat area to muscle area was determined. The correlation coefficients for marbling between different muscles, and between the overall trace and the spot methods were 0.55 to 0.81 between different muscles and 0.89 to 0.97, respectively. These results suggested that the simple spot method is speedy and almost as useful as the overall trace method as a measuring technique for beef marbling in loin muscles, especially for highly marbled beef.

Trace Element in the Indian Ocean: Current Research Trends and Future Needs (인도양에서 미량원소 연구 동향 및 향후 연구 방향)

  • Kim, Intae
    • Ocean and Polar Research
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    • v.43 no.4
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    • pp.335-352
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    • 2021
  • Trace elements in the ocean have been known as essential micronutrients for the primary production of phytoplankton and the growth of marine organisms. The GEOTRACES program beginning in the mid-2000 provided a new understanding of the distribution, origin and behavior of trace elements in the ocean, together with the establishment of both clean seawater sampling and trace element analysis techniques. The Indian Ocean, one of the major oceans, is relatively the least explored area, despite playing an important role in global climate variability. Although trace element observations have recently been conducted in the Indian Ocean by Japanese-and Indian scientists, relatively not much study has been done compared to the Atlantic, Pacific and Polar Regions. Recently, together with the launch of R/V Isabu, a 5,000-ton grade large- and comprehensive research vessel, the observations of trace elements has been conducted in the Indian Ocean for the first time in Korea since 2018. In this paper, we introduce the key results of currently conducted GEOTRACES expedition in the Indian Ocean to present future trace element research directions in the Indian Ocean, and also reviewed the preliminary results in the Indian Ocean studies from Korea. In the 2020s, new Indian Ocean GEOTRACES projects are planned around European countries, and it is time for Korea to prepare for the next phase of the trace element study in the Indian Ocean in line with these international trends.

Effect of Soil Factors on Crop Uptake of Toxic Trace Elements (독성미량원소의 작물흡수에 대한 토양인자의 영향)

  • Park, Mi Jeong;Ji, WonHyun;Koh, IlHa;Lee, Sang-Hwan
    • Journal of Soil and Groundwater Environment
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    • v.23 no.5
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    • pp.37-44
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    • 2018
  • Soil trace elements and their bioaccumulation in agricultural products have attracted widespread concerns, yet the crop uptake characteristics of trace elements in different soil-plants systems have been rarely investigated. Experiments were carried out to investigate the effect of soil properties on trace element concentrations in cabbage and radish. Soil pH and total organic matter were major factors influencing trace elements transfer from soil to vegetables. Inclusion of other soil properties in the stepwise regression analysis improved the regression models for predicting trace element concentrations. Consideration of other soil properties should be taken into account for more precise prediction of trace element concentrations in the two vegetables, which could help quantitatively evaluate the ecologic risk of toxic trace elements accumulation in crops.

Quantitative Analysis on the Structure of Hambaek Syncline (정량적(定量的) 해석(解析)에 의(依)한 함백향사(咸白向斜) 구조(構造) 연구(硏究))

  • Park, Rin Sik;Min, Kyung Duck
    • Economic and Environmental Geology
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    • v.13 no.3
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    • pp.141-158
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    • 1980
  • A geologic structure could be formed through various processes, because there are a number of factors which control the deformation of the Earth's crust. In geology, we could call it geological epistemology to describe exactly a geologic structure, and call it geological logics to infer logically the deforming process through which the geologic structure had been formed. Degree of legitimacy of geological logics depends upon the degree of exactness of geological epistemology. This study described quantitatively 3-dimensional Hambaek Syncline through computer analysis, and examined qualitatively into its deforming mechanism based on the results of 3-dimensional analysis of the structure. Input data for the computer analysis are dips and dip directions of bedding planes of the structure. The Hambaek Syncline disclose a minor fold group of NE-SW or NNE-SSW trend and a large scale fold of E-W trend. The conclusions of this study are as follows: (1) The fold of E-W trend is primary fold $(F_1)$ and the minor fold group of NE-SW or NNE-SSW trend secondary fold $(F_2)$. (2) Hambaek Syncline is cylindrical type fold. (3) Apparent axial trace of Hambaek syncline does not coincide with true axial trace. The apparent axial trace is $N70^{\circ}-80^{\circ}W$ in Gohan and Sabuk area, and changes to $N70^{\circ}-80^{\circ}E$ in the westward of the area, while the true axial trace is $N40^{\circ}-70^{\circ}W$ in the former, and $N60^{\circ}-80^{\circ}E$ in the latter area. (4) Westward dipping of axial plane of the minor fold group of NE-SW or NNE-SSW trend can be attributed to simple shear movements along overthrusts. (5) Angle between axial trace and the directional trace of the maximum principal compressive stress $({\sigma}_1)$ may not be perpendicular each other. The angle between them is governed by the following factors; 1) the plunge of fold axis 2) the dip of axial surface 3) cylindrisity (6) The mean axial trace of Hambaek Syncline $(F_1)$ is $N45.6^{\circ}W$, and the directional trace of ${\sigma}_1$ is $N52.4^{\circ}E$ (7) The mean axial trace of the minor fold group of NE-SW or NNE-SSW trend $(F_2)$ is $N21^{\circ}E$, and the directional trace of ${\sigma}_1$ is $N22^{\circ}W$.

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Trace Element Analysis by Neutron Activastion Analysis in the Human Cancer Tissue (폐암조직에서 중성자 방사화 분석법을 이용한 미량 원소 분석)

  • Lim, Sang-Moo;Zo, Jae-Il;Shim, Young-Mog;Chung, Young-Ju;Cho, Seung-Yeon;Chung, Yong-Sam
    • The Korean Journal of Nuclear Medicine
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    • v.27 no.1
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    • pp.104-111
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    • 1993
  • Trace elements are important components in the biological system, as a structural material and metabolic controller. Neutron activation analysis (NAA) with high neutron flux and high energy resolution Ge (Li) detector coupled to multichannel analyzer (MCA) has been one of the most accurate method for the determination of ultra-trace level components, and is applicable to biological material. In human body, the NAA can be used for quantitation of trace elements in various organs and tissue with endocrinological and metabolic disease and industrial metal poisoning. In this study, Triga Mark III nuclear reactor in Korea Atomic Research Institute was used for quantitation of trace eleement in human lung cancer tissues by neutron activation analysis. In the squamous cell carcinoma tissues, Br, Hg, La, Sb, Sc, Cl, Fe and I content were lower than normal lung tissues, and K, Rb and Se content were higher. In the adenocarcinoma tissues, Fe, Au, La, Sc and Zn content were lower than normal lung tissues, and Rb, Co and Se content were higher. Rb content was higher in the adenocarcinoma tissues than in the squamous cell carcinoma tissues. Fe and Na content were higher in the squamous cell carcinoma tissues than in the adenocarcinoma tissues.

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