• Title/Summary/Keyword: Toxic gases

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A Study of Bore Evacuator Gas Flow Analysis (제연기 개스유동 해석에 관한 연구)

  • 강국정
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1996.11a
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    • pp.1083-1087
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    • 1996
  • Bore evacuator which have circular structure of cylindrical form is located at tube, and its function is to evacuate toxic gases generated during firing intervals. Between bore evacuator and bore interior, gas flow field is developed through the nozzles, and the charging and discharging process is formed. By these flow cycle(charging and discharging) the evacuation effect can be generated. This report contains an analyses and results consideration about bore evacuator flowfield.

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Consequence Analysis of Toxic Gases Generated by Fire of Lithium Ion Batteries in Electric Vehicles (전기자동차 내 리튬이온전지 화재로 발생하는 독성가스의 위험성 분석)

  • Oh, Eui-young;Min, Dong Seok;Han, Ji Yun;Jung, Seungho;Kang, Tae-sun
    • Journal of the Korean Institute of Gas
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    • v.23 no.1
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    • pp.54-61
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    • 2019
  • As the market for portable electronic devices expands, the demand for Lithium Ion Battery (LIB) is also increasing. LIB has higher efficiency than other secondary batteries, but there is a risk of explosion / fire due to thermal runaway reaction. Especially, Electric Vehicles (EV) equipped with a large capacity LIB cell also has a danger due to a large amount of toxic gas generated by a fire. Therefore, it is necessary to analyze the risk of toxic gas generated by EV fire to minimize accident damage. In this study, the flow of toxic gas generated by EV fire was numerically analyzed using Computational Fluid Dynamic. Scenarios were established based on literature data and EV data to confirm the effect distance according to time and exposure standard. The purpose of this study is to analyze the risk of toxic gas caused by EV fire and to help minimize the loss of life and property caused by accidents.

A Study on Semi Quantitative Risk Analysis for Air Separation Unit using a GRA(Generic Risk Analysis) Method (GRA(Generic Risk Analysis) 기법을 이용한 공기분리시설에 대한 준 정량적 위험성 평가에 관한 연구)

  • Shin, Jung-Soo;Byun, Hun-Soo
    • Journal of the Korean Institute of Gas
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    • v.17 no.1
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    • pp.56-66
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    • 2013
  • The gas production plants supply the inert gas to production plants for maintaining safe operation and also supply combustible, flammable, explosive and toxic gases as functions of basic materials needed for producing chemical goods. In addition, gas plants need to be safe and reliable operation because they are operated under high temperature, high pressure, cryogenic and catalytic reactions. As these plants have a complex process in operation, there has been a risk that major industrial accidents such as a fire, explosion and toxic gas released, also risks of asphyxiations by inert gases and burns caused by high temperature and cryogenic substances. This study is to carry out the semi quantitative risk assesment method which is the generic risk analysis (GRA). This method is applied to air separation unit(ASU) to identify its initial risk, safety barriers, residual risk and elements important for safety(EIS). The result of this study, suggested the management tools and procedures of implementation for EIS management.

Combustive Characteristic and Toxic Gases Generation of Interior Materials -The focus for resist-carpet, resist-after-tretment plywood, sofa leather- (내장재의 연소 및 독성가스 발생 특성 -방염 카페트, 방염 후처리 합판, 쇼파 내자를 중심으로-)

  • 김일수;류경옥
    • Fire Science and Engineering
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    • v.12 no.2
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    • pp.43-59
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    • 1998
  • It was studied a compared estimation of the fire risk of the three kinds of the interior materials, such as a resist carpet, a resist-after-treatment plywood and sofa leather. Toxic gases, CO, CO2, NOx, SO2, HCN, HCI were detected during the combustion of the samples. A resist-carpet was more combustible than the resist-after-treatment plywood and sofa leather in the combustion characteristics and has a blow-up-combustion of combustion in all the samples. The generation of CO reached the lethal doses in minute after the combustion was begun. NOx and So2 were detected not more than each of the lethal doses, while HCN was detected in the carpet 20.6 times than the sofa leather, and 4.6 times than the resist-after-treatment plywood. HCI was detected in the carpet 4.48 times than the sofa leather and 2.47 times than the resist-after-treatment plywood. It is conclusion that the carpet was the highest in the fire risk among the three kinds of the interior materials.

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Study of the Fire Risk of Occupants During Pilotis Space Fires (필로티 공간의 화재 시 재실자의 위험성에 관한 연구)

  • Choi, Seung-Bok;Choi, Doo-Chan;Choi, Don-Mook
    • Fire Science and Engineering
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    • v.30 no.5
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    • pp.144-150
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    • 2016
  • An apartment house with a pilotis that raises the architectural volume and provides a space for circulation is becoming popular. With the popularity of pilotis in apartment houses, people also have a keen interest in the potential fire risk at the pilotis. As residents can only access their apartment house through the pilotis, there is a risk to the occupants if there is fire there. Therefore, this study evaluated the pilotis fire cases of urban multifamily housing to conduct a Fire Dynamics Simulator (FDS) and Fire Evacuation Simulation (FES). Through these two simulation methods, it is possible to validate the riskiness of fire at an apartment with a pilotis. The study identified that the toxic gases and flame spread out to the pilotis within hundred seconds after ignition. In addition, the toxic gases and flame also reach the second floor within three seconds and the entire building within 735 seconds if the entrance doors at the pilotis are opened. On the other hand, the FES simulation results showed that it also takes about approximately 609 seconds to excavate from the apartment house with a pilotis. Therefore, this research shows that an apartment house with a pilotis can ensure the building occupants' lives and their safety if there is fire.

[Retracted]Gas Mask Removal Efficiency of CO, HCl, HCN, and SO2 Gas Produced by Fire ([논문철회]화재용 방독면의 CO, HCl, HCN, SO2 연소생성물 제거효율)

  • Kong, Ha-Sung;Gong, Ye-Som;Kim, Sang-Heon
    • Fire Science and Engineering
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    • v.29 no.4
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    • pp.57-60
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    • 2015
  • The removal efficiencies by elastic fire gas mask of toxic gases CO, HCl, HCN, and $SO_2$ produced by a fire have a key role in saving lives. The elastic fire gas mask comprises a visible window, elastic hood, gas purification canister, and air vent. It does not have hair or neck thongs, which makes it easy to use and put on quickly. This research examined the removal efficiency of toxic gases by such a mask. The removal efficiencies for CO with a background concentration of 2505.0 ppm were 99.99 and 99.98% after 3.5 and 8.5 min, respectively. The residual CO concentration was drastically increased after 8.5 min. The removal efficiencies for HCl, HCN, and $SO_2$ with background concentrations of 1003.0, 399.0, and 100.3 ppm, respectively, were 100% after 20 min.

Development and Evaluation of Differential Pressure Type Mass Flow Controller for Semiconductor Fabrication Processing (반도체 공정용 차압식 질량 유량 제어 장치의 개발 및 성능 평가)

  • Ahn, Jin-Hong;Kang, Ki-Tai;Ahn, Kang-Ho
    • Journal of the Semiconductor & Display Technology
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    • v.7 no.3
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    • pp.29-34
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    • 2008
  • This paper describes the fabrication and characterization of a differential pressure type integrated mass-flow controller made of stainless steel for reactive and corrosive gases. The fabricated mass-flow controller is composed of a normally closed valve and differential pressure sensor. A stacked solenoid actuator mounted on a base-block is utilized for precise and rapid control of gas flow. The differential pressure flow sensor consisting of four diaphragms can detect a flow rate by deflection of diaphragm. By a feedback control from the flow sensor to the valve actuator, it is possible to keep the flow rate constant. This device shows a fast response less than 0.3 sec. Also, this device shows accuracy less than 0.1% of full scale. It is confirmed that this device is not attacked by toxic gas, so the integrated mass-flow controller can be applied to advanced semiconductor processes which need fine mass-flow control corrosive gases with fast response.

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Production of high dissolved O2/O3 with rotating wheel entraining gas method for environmental application

  • Li, Haitao;Xie, Bo;Hui, Mizhou
    • Advances in environmental research
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    • v.2 no.1
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    • pp.1-8
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    • 2013
  • There is a significant demand to make various dissolved gases in water. However, the conventional aeration method shows low gas mass transfer rate and gas utilization efficiency. In this study, a novel rotating wheel entraining gas method was developed for making high dissolved $O_2$ and $O_3$ in water. It produced higher concentration and higher transfer rate of dissolved $O_2$ and $O_3$ than conventional bubble aeration method, especially almost 100% of gas transfer efficiency was achieved for $O_3$ in enclosed reactor. For application of rotating wheel entraining gas method, aerobic bio-reactor and membrane bio-reactor (MBR) were successfully used for treatment of domestic and pharmaceutical wastewater, respectively; and vacuum ultraviolet $(VUV)/UV+O_3/O_2$ reactors were well used for sterilization in air/water, removal of dust particles and toxic gases in air, and degradation of pesticide residue and sterilization on fruits and vegetables.

Effect of CeO2 Addition on De-CH4 and NOx Performance (CH4와 NOx 저감 성능에 관한 CeO2 첨가의 영향)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.9
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    • pp.473-479
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    • 2017
  • Due to environmental pollution, hazards of the human body, and global warning, changes in the power train of automobiles are intensifying, and the market forelectronic vehicles is rising. Also, in order to meet the stricter emission regulations forautomobiles with internal combustion engines based on fossil fuel, the proportion of after-treatments for vehicles and vessels is increasing gradually. The objective of this study is to investigate the effectsfrom additive ceric oxide ($CeO_2$) loading amounts to improve the methane ($CH_4$) and nitric oxide (NOx) abatement ability of the natural gas oxidation catalysts(NGOC) reducing toxic gases emitted from compressed natural gas (CNG) buses. Three kinds of NGOC were prepared under the following conditions: fresh and $700^{\circ}C$ for 12hr thermal aging, and the reduction performance of toxic gases was evaluated. Fresh $1Pt-3Pd-1Rh-3MgO-6CeO_2/(Al+Z)$ NGOC containing 6wt% $CeO_2$ had the highest dispersivity of palladium (Pd) with high selectivity to $CH_4$ and improved harmful gas reduction performance. The NGOC with 6wt% $CeO_2$ loaded the least decreased in the dispersivity of the noble metal, and showed the highest reduction of harmful gases due to the thermal durability of $CeO_2$.

Emission of Carbon Monoxide and Carbon Dioxide Gases during Fire Tests of Specimens Treated with Phosphorus-Nitrogen Additives (인-질소 첨가제로 처리된 시험편의 연소 시에 발생하는 일산화탄소와 이산화탄소 생성)

  • Chung, Yeong-Jin
    • Applied Chemistry for Engineering
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    • v.26 no.5
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    • pp.609-614
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    • 2015
  • This study was to investigate the production of combustion toxic gases of pinus rigida specimens treated with pyrophosphoric acid (PP)/4ammonuium ion ($4NH_4{^+}$), methylenepiperazinomethyl-bis-phosphonic acid (PIPEABP) and PIPEABP/$4NH_4{^+}$. Each pinus rigida plates was painted in three times with 15 wt% in the aqueous solution followed by drying the species at room temperature. Emission of combustion toxic gases was examined by the cone calorimeter (ISO 5660-1). First-time to peak mass loss rate (1st-$TMLR_{peak}$) treated with chemicals was delayed upto 66.7~250.0% compared to those of untreated specimens. For test pieces treated with the chemicals, the emission of peak carbon monoxide ($CO_{peak}$) values of 0.0136~0.0178% and peak carbon dioxide ($CO_{2\;peak}$) value of 0.04432~0.3648% were obtained, which were higher than those for the virgin plate. In particular, oxygen emission is much higher than the level of 15% which can be fatal to humans. Therefore, the resulting risk could be eliminated. However it is supposed that the combustion-toxicities were partially increased compared to those of virgin plate.