• 제목/요약/키워드: Toxic gases

검색결과 224건 처리시간 0.025초

반도체 산업 공정가스의 혼화성에 따른 반응성 고찰 (Reactivity Considerations with Miscibility of Process Gases in Semiconductor industry)

  • 이근원
    • 한국가스학회지
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    • 제20권4호
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    • pp.15-24
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    • 2016
  • 반도체 산업에서 많은 종류의 화학물질 사용으로 인한 독성물질 누출과 화학물질간의 혼화에 따른 화재 폭발 등에 의한 화학사고의 위험성이 증가하고 있다. 화학물질의 혼화에 따른 반응성을 평가하는데 실험적 방법이 가장 신뢰성 있지만, 모든 화학물질을 실험을 통하여 평가하는 것은 시간적, 비용적인 제한이 있다. 본 연구에서는 반도체 산업에서 주로 사용되는 공정가스의 위험성 추정하기 위해 미국 NOAA(National Oceanic and Atmospheric Administration)과 EPA에서 개발한 CRW(Chemical Reactivity Worksheet) 3.0 프로그램을 사용하여 공정가스의 반응성을 고찰하였다. 이들 연구 결과는 반도체산업의 공정가스의 혼화성에 따른 반응성 정보와 저장캐비닛의 가스 실린더 보관에 관한 KOSHA 기술지침 작성에 필요한 기초자료를 제시하고자 하였다.

Octa-dodecyloxy Copper-Phthalocyanine LB막 제작에 관한 연구 (A study on the preparation and characterization of Octa-dodecyloxy Copper-Phthalocyanine LB films)

  • 구자룡;이한성;김영관;손병청;김정수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 춘계학술대회 논문집
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    • pp.150-153
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    • 1997
  • Langmuir-Blodgett(LB) technique is one of the ways of fabricating organic ultra-thin films. It is well known that It has the advantage to control the alignment and orientation of the molecules in the films. Metallo-phthalocyanines(MPcs) are sensitive to electron affinitive toxic gaseous molecules, such as NO$_2$, NO, SO$_2$. MPcs are thermal, optical, mechanical, chemical stable. Therefore, it is interesting to prepare phthalocyanine LB films containing copper as a chemical sensor for NO$_2$ and SO$_2$ gas and test their sensitivity to these toxic gases. In this study, thin films of Octa-dodecylosy copper-phthalocyanine were prepared by LB technique. $\pi$-A isotherm, transfer ratio, UV-VIS. spectroscopy of these films were investigated. Also current-voltage(I-V) characteristics of these was auto investigated.

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Octa-dodecyloxy Tin-Phthalocyanine LB막 제작에 관한 연구 (A study on the preparation and characterization Octa-dodecyloxy Tin-Phthaucyanine LB films)

  • 이명호;신현만;김영관;손병청;김정수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1997년도 춘계학술대회 논문집
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    • pp.146-149
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    • 1997
  • It is well known that the metallo-phthalocyanines(MPcs) are sensitive to toxic gaseous molecules, such as NO$_2$, NO, SO$_2$. MPcs are thermally, optica1ly, mechanically and chemically stable. Therefore, it is interesting to prepare phthalocyanine LB films containing tin as a chemical sensor for NO$_2$ and SO$_2$ gas and test their sensitivity to these toxic gases. Frist, in this study, ultra thin films of Octa-dodecyloxy tin-phthalocyanine were prepared on various substrates by LB technique. Langmuir-Blodgett(LB) technique is one of the ways of fabricating organic thin films. It has the advantage to control the alignment and orientation of the molecules in the films. $\pi$-A isotherm and transfer ratio of tin-phthalocyanine derivative. UV-VIS. spectroscopy were investigated. Also intrinsic current-voltage(1-V) characteristics of these films was investigated.

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철도차량용 재료의 독성성분 정량화 향상기법 연구 (The improvement of quantification method of toxic gas components from the materials of the railway vehicle)

  • 이철규;정우성;이덕희;이관섭;박지영
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2007년도 추계학술대회 논문집
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    • pp.1314-1317
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    • 2007
  • This study is on the fire resistance evaluation method, expecially on the toxicity of smoke gases generated from the fire, of materials for railway car and structures. Until now, Although international standard related to the quantifying evaluation method of smoke gas is provided but the specific procedure is not contained. On this reason, Test results of toxicity show deviation with the different technique being applied. For now, In advanced railway country, various instrument, like ion chromatography and etc., is used but FT-IR is recommended due to its lots of advantages. while FT-IR has a lot of strong points but still has some problems like water vapor interferences. In this paper, To improve credibility and repeatability of FT-IR it contains some technical solutions in quantifying the 8 toxic components.

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반도체공정의 Tubing 내 잔여가스제거 지적결정시스템 (Intelligent Decision System for Purging a Residual Gas inside Tubing in Semiconductor Process)

  • 임사환;허용정;최성주;이종락
    • 반도체디스플레이기술학회지
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    • 제5권4호
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    • pp.23-27
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    • 2006
  • Semiconductor industry has been dramatically developed with the information era of 21C, and the trend now is to consider that the technology of management system of the computer utility that has a high efficiency is important. This study investigated the intelligent decision system for residual gas purge process to effectively remove the residual gas in the tube after replacing the cylinder that is used for the gas cabinet or BSGS(Bulk Specialty Gas Supply System) of the semiconductor process. It was suggest from this study that it is possible to decide the type, frequency and volume of purge gas using various toxic gases which is necessary for each process. Also, this result will be utilized for operating the system, increasing the efficiency of management and saving energy.

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동물성 기포제의 희석농도에 따른 기포콘크리트의 특성 (Properties of Foamed Concrete according to Dilution Concentrations of Animality Protein Foaming Agent)

  • 임정준;이상수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2019년도 추계 학술논문 발표대회
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    • pp.77-78
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    • 2019
  • Organic insulating materials can cause fatal toxic gases when burned, which can lead to human injury. As a combustible material, the risk of fire spreading is great. Therefore, there is a need for a study on the lightweight cured body for the non-combustible inorganic insulation to replace the flammable organic insulation. This study aims to examine the properties of lightweight foamed concrete according to the dilution concentration of animal foaming agent which forms a closed void when foaming as a part of the experiment to examine the utility of the lightweight foamed concrete as an insulating material. Bubbles occupy a large volume of lightweight foam concrete and have a great influence on the properties. Therefore, the stability of the bubble is very important, and as a result of the experiment, it is determined that 3% of the smallest vesicles are prepared at the proper dilution concentration.

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Green SCM 도입 및 적용 방안에 관한 연구 (A Study on Introduction and Application of Green SCM)

  • 이공섭
    • 대한안전경영과학회지
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    • 제14권4호
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    • pp.79-83
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    • 2012
  • This study analyzes introduction state of Green SCM technology in domestic and overseas area and suggests how to reduce greenhouse gases of logistics in the future. Thus, introduction state of Green SCM was reviewed by building and integrating logistic-related informatization systems such as WMS and TMS. And how to apply the system to track toxic substance in supply chain was performed to manage toxic substance. Therefore, it will be necessary to develop a device to display and collect vehicle condition & log through OBD-II, which is widely adopted, and hardware to measure, collect, and monitor carbon dioxide emission and power consumption of fixed facilities.

Toxicological Study for Blood Cyanide and Carboxyhemoglobin Levels in the Fire- related Fatalities

  • Baeck, Seung-Kyung;Kim, Dong-Woo;Kim, Sun-Chun;Park, Woo-Yong;Jin, Kwang-Ho;Chung, Young-Ho;Park, Yun-Shin;Seo, Joong-Seok
    • 대한약학회:학술대회논문집
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    • 대한약학회 2003년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.1
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    • pp.170.2-170.2
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    • 2003
  • The most common cause of death in fires is the inhalation of noxious gases rather than thermal injury. Carbon monoxide is well-known toxic component in fire atmospheres. However, the importance of hydrogen cyanide(HCN) as a toxic agent in the fire related fatalities(FRF) is under discussion. HCN is known to be produced in fires involving by the pyrolysis of polyacrylonitril (PAN) and other nitrogen-containing polymer. (omitted)

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Octa(2-ethyhexyloxy) copper-phthalocyanine의 LB막 제작에 관한 연구 (Study on the preparation Of Octa(2-ethyhexyloxy) copper-phthalocyanine LB film)

  • 임준석;김영관;김정수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1995년도 추계학술대회 논문집
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    • pp.228-231
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    • 1995
  • Phthalocyanine have a good sensitivity to the toxic gases like NO$_2$. Also its properties of good chemical and thermal suability give a potential to superiors gas sensing system. Depositioni of Octa(2-ethyhexyloxy) Copper Phthalocyanine is confirmed by transfers ratio, UB/visible spectra and current-voltage (I-V) characteristics.

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