• Title/Summary/Keyword: Toxic gases

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Characterization of inorganic materials in industrial waste and RDF using SEM-EDS (SEM-EDS를 이용한 산업단지폐기물과 고형연료의 무기 성분 규명)

  • Jeong, Moon-Heon;Lee, Ju-Ho;Yoo, Jeong-Kun;Lee, Gang-Woo;Shon, Byung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.10
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    • pp.2786-2793
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    • 2009
  • Recently, the development and spread of the new recyclable energy becomes urgent because of the depletion of fossil fuel and strengthening the environmental regulation. To recovery from the waste out of the many new recyclable energies has been proved as the most favorable when the potential value of energy source is compared. The RDF from the waste has been approved as the most economical method out of the other methods. However, the toxic gases (HCl, Dioxin etc) and heavy metals generated during the burning of the industrial wastes have been pointed out as problems. The PVC, alkali metal chloride, and alkaline earth metal chloride are major materials for emitting the chlorine and chlorine compounds have the problem such as the erosion on the heat collection device. This research has analyzed the heavy metal components containing in the industrial waste, and the concentration of Cl and S in the industrial waste generated in B industrial complex are slightly high than that of the A industrial complex. The results can be used to discuss the origin of inorganic components in industrial waste and utilized as a base data to improve the performance of the RDF as fuel.

Development of a monolithic apparatus for degasing aluminum continuous casting molten metal (알루미늄 연속주조 용탕의 탈 가스 일체화 장치 개발)

  • 이용중;김태원;김기대;류재엽;이형우
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2004.10a
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    • pp.145-149
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    • 2004
  • It is necessary for managing a perfect process for degasing aluminum molten metal according to the increase of a grade of aluminum and its alloy products. There are some methods that have been used to manage a degasing process in recent years, such as an injection method that uses aluminum molten metal powder and chemicals supplier and input method that supplies argon and nitrogen, or chlorine gas by using a gas blow-tube. However, these methods show some problems, and it shows that it is a difficult process to handle. pollution due to the producing a lot of toxic gases like chlorine and fluoride gas. irregular effects, and lowering work efficiency due to the excessive processing time. The problems that are the most fatal are the producing a lot of sludge due to the reaction of aluminum molten metal with chemicals. loss of metals, and decreasing the life of refractory materials. In order to solve these problems. this paper develops a technology that is related to aluminum continuous casting molten metal and monolithic degasing apparatus. A degasing apparatus developed in this study improved the exist ing methods and prevented environmental pollution wi th smokeless. odor less, and harmlessness by using a new method that applies argon and nitrogen gas in which the methods used in the West and Japan are eliminated. The developed method can significantly reduce product faults that are caused by the production of gas and oxidation because it uses a preprocessed molten metal with chemicals. In addition. the amount of the produced sludge can also be reduced by 60-80% maximum compared with the existing methods. Then. it makes it possible to minimize the loss of metals. Moreover. the molten metal processing and settling time is also shortened by comparing it with the existing methods that are applied by using chemicals. In addition, it does much to improve the workers' health, safety and environment because there is no pollution. The improvement of productivity and prevent ion effects of disaster from the results of the development can be summarized as follows. It will contribute to the process rationalization because it does not have any unnecessary processes that the molten metal will be moved to an agitator by using a ladle and returned to process for degasing like the existing process due to the monolithic configuration. There are no floating impurities due to the oxidation caused by the contact with the air as same as the existing process. In addition. it can protect the blending of precipitation impurities. Because it has a monolithic configuration. it can avoid the use of additional energy to compensate the temperature decreasing about 60t that is caused by the moving of molten metal. It is not necessary to invest an extra facilities in order to discharge the gas generated from a degasing process by using an agitator. The working environment can be improved by the hospitable air in the factory because the molten metal is almost not exposed in the interior of the area.

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Scaled model tests for improvement and applicability of the transverse smoke control system on tunnels (횡류식 제·배연 시스템의 개선 및 적용성 분석을 위한 모형실험 연구)

  • Kim, Hyo-Gyu;Baek, Doo-San;Kim, Jae-Hyun;Lee, Seong-Won;Yoo, Ji-Oh
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.22 no.5
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    • pp.563-574
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    • 2020
  • Currently, road tunnels and railroad tunnels are building smoke control systems to emit toxic gases and smoke from fires. Among the various smoke control systems, the transverse smoke control system has the disadvantage that air supply or exhaust is performed on only half of the cross-section, rather than air supply or exhaust on the entire cross-section of the tunnel as air is supplied or exhausted by partitioning the wind path. Therefore, this study analyzed the effect of exhaustion through numerical analysis and scaled model tests on the zoning smoke control system, which improved the limitations of the transverse smoke control system. As a result of the scaled model test, the transverse ventilation system exhibited a 25.6% smoke control rate based on the state where no smoke was controled, and zoning smoke control system showed a smoke control rate of 40.8%. In addition, as a result of numerical analysis, it was found that transverse ventilation system did not control fire smoke spreading from the tunnel and continued to spread. On the other hand, zoning smoke control system was found to be smoke controled within a certain section due to the air curtain effect and the flue gas effect.

Simultaneous Reduction of CH4 and NOx of NGOC/LNT Catalysts for CNG buses (CNG 버스용 NGOC/LNT 촉매의 CH4와 NOx의 동시 저감)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.6
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    • pp.167-175
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    • 2018
  • Natural gas is a clean fuel that discharges almost no air-contaminating substances. This study examined the simultaneous reduction of $CH_4$ and NOx of NGOC/LNT catalysts for CNG buses related to the improvement of the $de-CH_4/NOx$ performance, focusing mainly on identifying the additive catalysts, loading of the washcoat, stirring time, and types of substrates. The 3wt. % Ni-loaded NGOC generally exhibited superior $CH_4$ reduction performance through $CH_4$ conversion, because Ni is an alkaline, toxic oxide, and exerts a reducing effect on $CH_4$. A excessively small loading resulted in insufficient adsorption capacity of harmful gases, whereasa too high loading of washcoat caused clogging of the substrate cells. In addition, with the economic feasibility of catalysts considered, the appropriate amount of catalyst washcoat loading was estimated to be 124g/L. The NOx conversion rate of the NGOC/LNT catalysts stirred from $200^{\circ}C$ to $550^{\circ}C$ for 5 hours showed 10-15% better performance than the NGOC/LNT catalysts mixed for 2 hours over the entire temperature range. The NGOC/LNT catalysts exhibitedapproximately 20% higher $de-CH_4$ performance on the ceramic substrates than on the metal substrates.

The Background and Direction of R&D Project for Advanced Technology of Wastewater Treatment and Reuse (하.폐수 고도처리 기술개발사업 추진배경과 개발방향)

  • Kim, Ji-Tae;Hwang, Hae-Young;Hong, Byung-Pyo;Byun, Hong-Sik
    • Membrane Journal
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    • v.21 no.3
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    • pp.277-289
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    • 2011
  • Since 1980s, wastewater treatment facilities in Korea have been rapidly expanded by 90 percent as the government invested them continuously. Considering social and environmental factors such as the needs of alternative water resources for water shortages, energy saving and new energy production sources for decrease of greenhouse gases, and the demand for the improvement of the water quality in rivers and lakes, advanced technologies in wastewater treatment are essential in the 21st century. In this aspect, new conceptual technology is systematically combined with the advanced treatment technology such as the control and treatment technology of hazardous and toxic material, customized reusing skill, and energy saving/recovery technology. The new R&D project for advanced technology of wastewater treatment and reuse will focus on these advanced technologies which will improve the water quality and foster the competitiveness in world environmental markets, building a solid foundation particularly in the market of developing countries. The project will be divided up into high quality reusing of wastewater, energy self-sufficiency, and integrated management system. It will be carried out for five years, 2011~2015, as Phase I.

Experimental and CFD Study on the Exhaust Efficiency of a Smoke Control Fan in Blind Entry Development Sites (맹갱도 굴진 작업공간내 방재팬의 화재연 배기효율에 관한 현장실험 및 CFD 연구)

  • Nguyen, Vanduc;Kim, Dooyoung;Hur, Wonho;Lee, Changwoo
    • Tunnel and Underground Space
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    • v.28 no.1
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    • pp.38-58
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    • 2018
  • The ventilation system plays a crucial role in underground mine safety. The main objective of the ventilation system is to supply sufficient air to dilute the contaminated air at working places and consequently provide tenable environment during the normal operation, while it also should be capable of controlling the fire propagation and facilitate rescue conditions in case of fire in mines. In this study, a smoke control fan was developed for the auxiliary ventilation as well as the fire smoke exhaust. It works as a free-standing auxiliary fan without tubing to dilute or exhaust the contaminated air from the working places. At the same time, it can be employed to extract the fire smoke. This paper aims to examine the smoke control efficiency of the fan when combined with the current ventilation system in mines. A series of the site experiments and numerical simulations were made to evaluate the fan performance in blind entry development sites. The tracer gas method with SF6 was applied to investigate the contaminant behavior at the study sites. The results of the site study at a large-opening limestone mine were compared with the CFD analysis results with respect to the airflow pattern and the gas concentration. This study shows that in blind development entry, the most polluted and risky place, the smoke fan can exhaust toxic gases or fire smoke effectively if it is properly combined with an additional common auxiliary fan. The venturi effect for smoke exhaust from the blind entry was also observed by the numerical analysis. The overall smoke control efficiency was found to be dependent on the fan location and operating method.

Experimental Study on Moisture Content According to Addition of Surfactants (계면활성제 첨가에 따른 함수율에 관한 실험적 연구)

  • Kim, Nam-Kyun;Rie, Dong-Ho
    • Fire Science and Engineering
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    • v.29 no.2
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    • pp.79-83
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    • 2015
  • The fire accident is a representative type of disaster that can largely impact on business. Therefore, precautionary measures and rapid initial response is very important when a disaster occurs. The storage of porous combustibles is inevitable in coal yard, plywood processing industry, and others that are currently operating. Initial fire fighting of fire and identifying the ignition point in such a porous combustible storage space are so difficult that if the initial response is failed, being led to deep-seated fire, surface fire is likely to result in secondary damage. In addition, deep-seated fire can cause personal injuries and property damage due to a large amount of toxic gases and reignition. Therefore damage reduction measures is required around the storage space to handle a porous flammable. Improving the penetration performance of the concentration of the surfactant is carried out as underlying study, which is about an deep-seated fire extinguishing efficiency augmentation when using wetting agents. The porous materials used in the experiments is radiata pine wood flour, which occupies more than 75% of the domestic wood market. Fire fighting water is selected as Butyl Di Glycol (BDG), which is being used for infiltration extinguishing agent, and the experiment was carried out by producing a standard solution. The experiment was carried out on the basis of the Deep-Seated Fire Test of NFPA 18. The amount of watering, porous material to the internal amount of penetration, and runoff measurement out of the porous material was conducted. According to experimental results, as the surface tension is reduced, the surfactant concentration macroscopic penetration rate decreases, but infiltration to a porous material is shown to have growth characteristics.

Study on the Growth Environment of 'Gangwha-mugwort' Through the Climatological Characteristic Analysis of Gangwha Region (강화지역의 기후특성 분석을 통한 '강화약쑥'의 생육 환경 연구)

  • Ahn, Joong-Bae;Hur, Ji-Na;Jung, Hae-Gon;Park, Jong-Ho
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.14 no.2
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    • pp.71-78
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    • 2012
  • Eupatilin, one of representative medical components of mugwort, can be efficiently extracted from the 'Gangwha Sajabalssuk'. The Eupatilin content may depend on environmental factors such as soil and regional climate in addition to a genetic factor and Gangwha region has a profitable environmental condition for the mugwort growth. In this study, the climatological characteristics of Gangwha was analyzed in order to find the environmental condition of mugwort containing high Eupatilin in term of atmospheric, oceanographic and land variables. The climate of Gangwha is characterized by the relatively low daily temperature and large diurnal variation with plenty of solar radiation, long sunshine duration and less cloudiness. According to our correlation analysis, the long sunshine duration and the large diurnal temperature variation are highly correlated with the Eupatilin contents. The result implies that Gangwha has the favorable conditions for the cultivation and the habitat of the high-Eupatilin concentrated mugwort. Because of the sea surrounding Gangwha Island with low salinity and moderate wind, the salt contained in sea breeze is relatively low compared to other regions. Furthermore, Gangwha has clean atmospheric environment compared to other regions because the concentrations of toxic gases harmful to crop growth such as nitrogen dioxide ($NO_2$), sulfite gas ($SO_2$) and fine dust (PM-10) are lower in the air. The ozone ($O_3$) concentration is moderate and within the level of natural production. It is also found that moderately coarse texture or fine loamy soils known as good for water drainage and for the growth and cultivation of the 'Gangwha-mugwort' are distributed throughout the areas around mountainous districts in Gangwha, coinciding with those of mugwort habitat.

Properties of quasi-noncombustible ultra-lightweight geopolymer (준불연 초경량 지오폴리머의 물성)

  • Kim, Yootaek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.3
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    • pp.132-139
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    • 2019
  • EPS (expanded polystyrene) is one of the most used building materials for insulation that is favored by its excellent heat insulation, economical efficiency and lightweight characteristics. However, EPS is vulnerable to the fire and producing large amount of toxic gases in case of fire. Therefore, ultra-lightweight geopolymer which can replace EPS is fabricated by using IGCC (integrated gasification combined cycle) fused slag and Si sludge as raw materials and the possibility of replacement on ultra-lightweight geopolymer for EPS as an insulation building material was evaluated in this study. Ultra-lightweight geopolymer can be fabricated with the pulverized IGCC fused slag having low carbon content and density, compressive strength, thermal conductivity were $0.064g/cm^3$, 0.04 MPa, and 0.072 W/mK, respectively. The thermal conductivity of ultra-lightweight geopolymer is 1.5~2.0 times higher than that of EPS suggested in the KS M 3808; however, the thermal conductivity value of geopolymer is meaningful and competitive to that of EPS in the market. Therefore, ultralightweight geopolymer can be applicable to the building material for thermal insulation purpose and have an enough possibility to replace EPS in the future because it is not only much safer than EPS in case of fire but also it can be fabricate by using waste materials from the industry.

Research Trends on Improvement of Physicochemical Properties of Sulfonated Hydrocarbon Polymer-based Polymer Electrolyte Membranes for Polymer Electrolyte Membrane Fuel Cell Applications (고분자 전해질 막 연료전지 응용을 위한 탄화수소계 고분자 전해질 막의 물성 향상에 관한 연구동향)

  • Inhyeok, Hwang;Davin, Choi;Kihyun, Kim
    • Membrane Journal
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    • v.32 no.6
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    • pp.427-441
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    • 2022
  • Polymer electrolyte membrane (PEM) serving as a separator that can prevent the permeation of unreacted fuels as well as an electrolyte that selectively transports protons from the anode to the cathode has been considered a key component of polymer electrolyte membrane fuel cell (PEMFC). The perfluorinated sulfonic acid-based PEMs, represented by Nafion®, have been commercialized in PEMFC systems due to their high proton conductivity and chemical stability. Nevertheless, these PEMs have several inherent drawbacks including high manufacturing costs by the complex synthetic processes and environmental problems caused by producing the toxic gases. Although numerous studies are underway to address these drawbacks including the development of sulfonated hydrocarbon polymer-based PEMs (SHP-PEMs), which can easily control the polymer structures, further improvement of PEM performances and durability is necessary for practical PEMFC applications. Therefore, this study focused on the various strategies for the development of SHP-PEMs with outstanding performance and durability by 1) introducing cross-linked structures, 2) incorporating organic/inorganic composites, and 3) fabricating reinforced-composite membranes using porous substrates.