• Title/Summary/Keyword: Toxic chemical management

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Current Status of Recycling of LED Waste (LED 폐자원의 재활용 현황)

  • Lee, Duk-Hee;Shin, Dongyoon;Kim, Tae-Hyung;Lee, Chan-Gi;Park, Kyung-Soo;Lee, Ki Woong;Lee, Jaeryeong
    • Resources Recycling
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    • v.28 no.2
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    • pp.14-22
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    • 2019
  • Development of technology makes LED an economical option because of lower energy consumption and better environmental impact. Because higher consumer demand the LED market is expanding rapidly due to its environment-friendly advantages. Expansion of LED application, development of various fusion technologies, the emergence of new markets, and the large-scale expansion of markets would lead to a large volume of e-waste generation with valorization potential. Currently, most of the generated waste being that landfilled and incinerated due to the absence of technology and management system. In this paper, we review the current status of LED waste recycling and analyzes the available recycling technologies.

Insecticidal Efficacy of Porteresia coarctata (Roxb.) on Bio-chemical Alteration of Spodoptera litura (Fab.)

  • Bhattacharyya Atanu;Goswami Arunava;Dihidar Shankar;Adhikari Sujit;Banerjee Sudip Kumar;Talapatra Soumendra Nath;Barik Bikas Ranjan;Bhattacharya Subir Kumar;Chandra Asit Kumar
    • International Journal of Industrial Entomology and Biomaterials
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    • v.14 no.1
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    • pp.9-13
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    • 2007
  • Hexane extract of Porteresia coarctata (Roxb.) exhibits a toxic effect on the tissues of Spodoptera litura (F) while fed at the dose of 1000 and 2000 ppm thoroughly mixing with castor leaves (Ricinus communis L) after dissolving in DMSO at late fourth instar whereas only DMSO treated castor leaves were fed to control group. The larvae were put to rear at $28^{\circ}C{\pm}1^{\circ}C$, $76{\pm}4%$ R.H. under 12 L + 12 D photoperiodic regime. In test group insects substantial reduction of protein and DNA content was marked in fat body and midgut tissues compared to DMSO treated control group. The significant biochemical alterations in the midgut tissues and fat body of test group insects indicate the insecticidal property of the said plant extract that could be tested in facilitating the phenomenal stride in Integrated Pest Management.

Selection of Low Toxic Pesticides and Residual Toxicity to Cotesia glomerata (배추나비고치벌 (Cotesia glomerata)에 대한 저독성 약제 및 잔류독성)

  • Choi, Byeong-Ryeol;Lee, Si-Woo;Park, Hyung-Man
    • Korean journal of applied entomology
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    • v.46 no.2
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    • pp.251-259
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    • 2007
  • For the development of integrated pest management system by harmonizing biological and chemical control, some experiments wee carried out to select low toxic pesticides against natural enemies. and their residual toxicity were evaluated. Leaf dipping method, body dipping method, and diet treatment method were set up for the toxicity evaluation against Cotesia glomerata adults. We had tested 46 different pesticides (31 insecticides, 11 fungicides, 4 herbicides) at recommending concentration commonly used to control diamond back moth, disease and up-land weeds in chinese cabbage field. Twenty three insecticides, eleven fungicides, and four herbicides were shown to be low toxic to C. glomerata adults in the treatment of body dipping. After insecticide spraying at recommending dose on the chinese cabbage, we examined residual effect of insecticides by introducing natural enemies on different days. Safety interval for the introduction of C. glomerata adults was established according to the residual toxicity of pesticides. Safe insecticides for the introduction of C. glomerata adults at one day after treatment (DAT) were thiacloprid, acephate, chlorfenapyr, clothianidin and at 3 DAT were imidacloprid, deltamethrin, thiamethoxam, dimethylvinphos, emamectin benzoate.

Evaluation of Low Toxic and Residual Toxicity of Pesticides Registrated on Sweet Pepper Greenhouse to Orius strigicollis (으뜸애꽃노린재 성충에 대한 착색단고추에 등록된 농약의 저독성 및 잔류독성 평가)

  • Choi, Byeong-Ryeol;Park, Hyung-Man;Kim, Jeong-Hwan;Lee, Si-Woo
    • Korean journal of applied entomology
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    • v.46 no.3
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    • pp.415-423
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    • 2007
  • For the development of integrated pest management system by harmonizing biological and chemical control, some experiments were carried out to select low toxic pesticides and to evaluate residual toxicity to natural enemies. Leaf dipping method and body dipping method were set up for evaluating toxicity to minute pirate bug, Orius strigicollis adult. We had tested 52 kinds of pesticides (33 insecticides, 19 fungicides) commonly used to control greenhouse insects, mites, and disease pests to natural enemies at the recommended concentration. Fourteen insecticides by body dipping method, 12 insecticides by leaf dipping method and 19 fungicides were selected as low toxic pesticides to O. strigicollis adult. After insecticide spraying at recommending dose on the sweet pepper plant, we examined residual effect of insecticides by introducing natural enemies on different days. Safety interval for introduction of O. strigicollis adult was established according to residual toxicity of pesticides. Safety insecticides at one day after treatment were pyraclofos, methomyl, thiodicarb, esfenvalerate bifenthrin, alpha-cypermethrin, etofenprox, fenvalerate, imidacloprid, acetamiprid, abamectin, emamectin benzoate, spinosad, indoxacarb. However, residual toxicity of nee-nicotinoids last up to 21 days to O. strigicollis adults.

Study on Exposed Piping with High Risk of Fire (화재 위험성이 높은 노출배관 사용에 관한 연구)

  • Kim, Yeob-Rae;Baek, Dong-Hyun
    • Fire Science and Engineering
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    • v.29 no.4
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    • pp.61-66
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    • 2015
  • PVC pipe has excellent corrosion resistance and chemical resistance and is broadly used. However there are no regulations regarding exposed piping material in buildings. There is growing concern about the vulnerability of piping to fires and generating toxic gas. Exposed piping should be made of incombustible materials to prevent spreading of toxic gas and to minimize damage to life and property in case of fire. Many big structures are being built, and concerns regarding damage by fire are continuously growing. In these circumstances, we should reinforce fire safety standards for buildings and heighten safety consciousness to become a well-developed country. For these reasons, we investigated the materials used for exposed piping and the standards of well-developed countries to enhance safety. We tried to figure out the alternatives by examining the actual conditions of each region's buildings. Based on the use of incombustible materials for exposed piping in each region, we tried to enhance the effectiveness for safety by suggesting revisions for related laws and regulations.

Developing Trends of the Chiral Drug Separation and Analysis Technology by using Molecular Recognition (분자인식 기법에 의한 키랄 의약품 분리 분석기술 개발동향)

  • Park, Gyung Hee;Lee, Yo-Han;Chang, Sang Mok;Kim, Woo-Sik;Kim, Jong-Min
    • Clean Technology
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    • v.22 no.2
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    • pp.75-81
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    • 2016
  • As the quality of life has improved, the desire for the safety and quality of the foods and drugs has been gradually increasing. For safety and quality management in foods, drugs, health management, agriculture, environmental conservation, and the industrial fields, the demand for quickly and accurately measuring various chemicals has been increasing. As well, the desire for self-diagnosis of one's own health state and self-examining the safety of environment has been gradually increasing. Optical Isomers can have very different physiological effects on human beings. One isomer can exhibit desirable pharmacological, pharmacodynamic, pharmacokinetic and physiological properties, while the other isomer can exhibit undesirable and toxic properties toward living organisms, especially human beings. And they can exhibit different activities in chemical and biotechnological processes. Although the majority of commercially available drugs are now both synthetic and chiral materials, a most chiral drugs are still marketed as racemic drugs. Thus, to avoid possible undesirable side effects from chiral drugs, more effective methods for separating and recognizing chiral compounds are urgently needed. In this report, we investigated the overall developing trends of the chiral drug separation and analysis technology by using molecular recognition.

The Concentration Distribution and Source Identification of Polychlorinated Biphenyls in River Sediment (하천 퇴적물 중 PCBs 농도분포 및 발생원 해석)

  • Jin, Ronghu;Oh, Jung-Keun;Kim, Jong-Guk;Kim, Kyoung-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.11
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    • pp.995-1000
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    • 2010
  • To investigate the relationship between polychlorinated byphenyls (PCBs) sources and concentration level in sediment, total 63 sediment samples with three-time sampling at one site were measured at 21 sites in Nakdong River. As a result of analysis, total concentrations and toxic equivalent (TEQ) concentration of Dioxin-like PCBs were ranged from 3.0 to 6,600 pg/g-dry with a mean value of 440 pg/g-dry and

A Study on the Improvement of the System to Reduce Damage on Ammonia Chemical Accident (암모니아 화학사고 피해를 줄이기 위한 제도개선 연구)

  • Lee, Joo Chan;Jeon, Byeong Han;Kim, Hyun Sub
    • Journal of the Society of Disaster Information
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    • v.18 no.2
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    • pp.306-313
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    • 2022
  • Purpose: The purpose of this study is suggested to improve upon current existing methods of ammonia chemical accident prevention and damage reduction. Method: Ammonia is one of the most common toxic substances that causes frequent chemical accidents. And it was selected as leakage materials according to statistics on chemical accident. Based on actual cases of chemical accidents, CARIS modeling was used to compare the damage impact range of Ammonia and HCl and Cl. Also, find out problems with the current systems. Result: As a result of find out the range of accident influence that spreads to the surroundings when an ammonia chemical accident, it was longer than the range of influence of hydrochloric acid and shorter than that of chlorine. In addition, it was found that when chemical accident by ammonia, hydrochloric acid, or chlorine, there are apartments and schools, which can have an effect. Conclusion: It is decided that it is necessary to determine whether or not chemical accident prevention management plans and statistical investigations are submitted for workplaces dealing with ammonia, and detailed guidelines and reviews are necessary. In addition, it is judged that it is necessary to establish a DB for ammonia handling plants, and it is considered that information sharing and joint inspection among related organizations should be pursued.

Heavy Metals of Landfilled Biomass and Their Environmental Standard, Including CCA-treated Wood for Eco-housing Materials (방부처리 목재를 포함한 토양매립 바이오메스의 중금속 함량과 안전성 문제)

  • Lim, Kie-Pyo;Lee, Jong-Tak;Bum, Jung-Won
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.4
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    • pp.37-45
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    • 2006
  • Recently, wood-framed houses has been built in the Korea for pension. Wood is good material for human healthy, while the construction lumbers are treated with preservative such as CCA (chromated copper arsenate), which contain some toxic elements for human body. However, if the waste woody biomass treated with various heavy metals, which has been collected from house construction or demolition, was fired in the field, and incinerated or landfilled after mass collection, such components will result in the toxic air pollutants in the burning or land fills, and spreaded into other areas. So the careful selection of wood and chemicals are required in advance for house construction, in particular, for environment-friendly housings. Therefore, this study was carried out to determine the content of toxic heavy metals in woody materials such as domestic hinoki and imported hemlock treated with CCA for housing materials, and the post-treated wood components such as organic fertilizer, sludge, dry-distilled charcoal and carbonized charcoal, to be returned finally into soil. The results are as follows. 1) The chemical analysis of toxic trace elements in various solid biomass required accurate control and management of laboratory environment, and reagents and water used, because of the error of data due to various foreign substances added in various processing and transporting steps. So a systematic analyzers was necessary to monitor the toxic pollutants of construction materials. 2) In particular, the biomass treated with industrial biological or thermal conditions such as sludge or charcoals was not fully dissolvable after third addition of $HNO_3$ and HF. 3) The natural woody materials such as organic fertilizer, sludge. and charcoals without any treatment of preservatives or heavy metal components were nontoxic in landfill because of the standard of organic fertilizers, even after thermal or biological treatments. 4) The CC A-treated wood for making the construction wood durable should not be landfilled, because of its higher contents of toxic metals than the criterion of organic fertilizer for agriculture or of natural environment. So the demolished waste should be treated separately from municipal wastes.

Size, Shape, and Crystal Structure of Silica Particles Generated as By-products in the Semiconductor Workplace (반도체 작업환경 내 부산물로 생성되는 실리카 입자의 크기, 형상 및 결정 구조)

  • Choi, Kwang-Min;Yeo, Jin-Hee;Jung, Myung-Koo;Kim, Kwan-Sick;Cho, Soo-Hun
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.25 no.1
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    • pp.36-44
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    • 2015
  • Objectives: This study aimed to elucidate the physicochemical properties of silica powder and airborne particles as by-products generated from fabrication processes to reduce unknown risk factors in the semiconductor manufacturing work environment. Materials and Methods: Sampling was conducted at 200 mm and 300 mm semiconductor wafer fabrication facilities. Thirty-two powder and airborne by-product samples, diffusion(10), chemical vapor deposition(10), chemical mechanical polishing(5), clean(5), etch process(2), were collected from inner chamber parts from process and 1st scrubber equipment during maintenance and process operation. The chemical composition, size, shape, and crystal structure of silica by-product particles were determined by using scanning electron microscopy and transmission electron microscopy techniques equipped with energy dispersive spectroscopy, and x-ray diffractometry. Results: All powder and airborne particle samples were composed of oxygen(O) and silicon(Si), which means silica particle. The by-product particles were nearly spherical $SiO_2$ and the particle size ranged 25 nm to $50{\mu}m$, and most of the particles were usually agglomerated within a particle size range from approximately 25 nm to 500 nm. In addition, the crystal structure of the silica powder particles was found to be an amorphous silica. Conclusions: The silica by-product particles generated from the semiconductor manufacturing processes are amorphous $SiO_2$, which is considered a less toxic form. These results should provide useful information for alternative strategies to improve the work environment and workers' health.