• 제목/요약/키워드: Toxic Gas

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Characterization of Toxic Pollutants in Ash and Flue Gas from Gasification Incinerator of Waste Tires (폐타이어 건류 소각에서 발생되는 재와 배기 가스에서의 독성 오염 물질의 정량)

  • Koo, Ja Kong;Seo, Young Hwa;Kim, Seok Wan;Yoo, Dong Joon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.13 no.1
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    • pp.213-220
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    • 1993
  • The problem of disposing of huge quantities of used tires is of growing concern to every country. As an economical solid waste management, a gasification followed by incineration process was applied to scrap tires to recover heat and to reduce waste volume for final landfill disposal. The gasification temperature, combustible and non-combustible gasified products and possibly produced air pollutants were predicted by changing equivalent mole ratios of carbon to oxygen by a chemical equilibrium model. For a risk assessment of ash toxic pollutants including heavy metals and toxic organics were thoroughly analyzed. Gasification bottom ash contained much more toxic organic compounds than fly ash, whereas fly ash contained higher concentration of heavy metals such as Pb and Cd. Pretreatment or secure landfill technology is suggested for a safe management of ash produced from the gasification incinerators.

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A Study of Bore Evacuator Gas Flow Analysis (제연기 개스유동 해석에 관한 연구)

  • 강국정
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1996.11a
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    • pp.1083-1087
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    • 1996
  • Bore evacuator which have circular structure of cylindrical form is located at tube, and its function is to evacuate toxic gases generated during firing intervals. Between bore evacuator and bore interior, gas flow field is developed through the nozzles, and the charging and discharging process is formed. By these flow cycle(charging and discharging) the evacuation effect can be generated. This report contains an analyses and results consideration about bore evacuator flowfield.

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A Study on the Characteristics of Electro-Polishing and Utility Materials for Gas Transitting (Gas 이송용 Utility Materials의 전해연마 특성에 관한 연구)

  • An, Se-Won;Lee, Jong-Hyung;Park, Moo-Soo
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.3 no.3
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    • pp.52-57
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    • 2004
  • Many kinds of gases, such as erosion gas, dilution gas, and toxic gas have been used in manufacturing process of LCD at semiconductor. In order to increase accumulation rate of manufacturing process, high degree of purity in these gases and minimized metalllic dust are required. All wetted stainless steel surface must be 316L electro-polished with $0254{\mu}m$ in average. Based on the AES analysis, Cr/Fe 11 and $Cr_2O_3$ thickness $25{\AA}$ are measured Molybdenum and silicon contaminants which is characteristic of stainless steel and oxygen were found on the surface.

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Simple Bluetooth Wireless Multi-gas Measurement System (간단한 블루투스 무선다중가스센서 계측시스템)

  • Kim, Chul min;Kim, Doyoon;Kim, Yeonsu;Kim, Gyu-tae
    • Journal of the Semiconductor & Display Technology
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    • v.19 no.2
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    • pp.51-54
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    • 2020
  • To develop gas-distinguishing sensor system, it is highly required to integrate multiple sensors for effective detection of a single targeted gas or mixture of gases. In addition, it is important to collect the reliable data from individual sensors into one integrated measuring device. Collecting the data of toxic gases on the spot should be done without inhalation. We suggest simple wirelessly running system for data collection that guarantees both reliability of data sources and safety. Here, we made a multi-gas measuring instrument(device) combined with Bluetooth module which provides a safe and precise big data accumulation system.

Humidity Dependence Removal Technology in Oxide Semiconductor Gas Sensors (산화물 반도체 가스 센서의 습도 의존성 제거 기술)

  • Jiho Park;Ji-Wook Yoon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.4
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    • pp.347-357
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    • 2024
  • Oxide semiconductor gas sensors are widely used for detecting toxic, explosive, and flammable gases due to their simple structure, cost-effectiveness, and potential integration into compact devices. However, their reliable gas detection is hindered by a longstanding issue known as humidity dependence, wherein the sensor resistance and gas response change significantly in the presence of moisture. This problem has persisted since the inception of oxide semiconductor gas sensors in the 1960s. This paper explores the root causes of humidity dependence in oxide semiconductor gas sensors and presents strategies to address this challenge. Mitigation strategies include functionalizing the gas-sensing material with noble metal/transition metal oxides and rare-earth/rare-earth oxides, as well as implementing a moisture barrier layer to prevent moisture diffusion into the gas-sensing film. Developing oxide semiconductor gas sensors immune to humidity dependence is expected to yield substantial socioeconomic benefits by enabling medical diagnosis, food quality assessment, environmental monitoring, and sensor network establishment.

Removal Characteristics of Gaseous Contaminants by a Wet Scrubber with Different Packing Materials (충진제의 종류에 따른 습식 스크러버의 가스상 물질 제거특성)

  • Han, Bang-Woo;Kim, Hak-Joon;Kim, Yong-Jin;Han, Kyeong-Soo
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.6
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    • pp.744-751
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    • 2007
  • Wet scrubber is widely used to remove toxic gaseous contaminants in various industries such as semi-conductor industry, display manufacturing industry and so on. In this study, to optimize a packed bed scrubber as one of typical wet scrubber size while keeping its performance, four different packing materials were investigated at different air flow rates, liquid-gas ratios and pH values. Ammonia, hydrochloric acid and hydrofluoric acid were used as test gases to characterize the scrubber performance. Gas removal efficiency increased as the packing size decreased, which resulted in the increase of specific surface area. The increase of air flow rate led to the decrease of gas removal efficiency, while the increase of liquid-gas ratio led to the increase of gas removal efficiency. For the case of $NH_3$ gas, lower pH, and for the cases of HCl and HF, higher pH contributed to higher gas removal efficiency. Gas removal efficiency of a wet scrubber increased in the order of HCl < $NH_3$ < HF according to its water solubility.

Evaluation of 0ff-gas Characteristics in Vitrification Process of ion-Exchange Resin

  • Park, S. C.;Kim, H. S.;K. H. Yang;C. H. Yun;T. W. Hwang;S. W. Shin
    • Nuclear Engineering and Technology
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    • v.33 no.1
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    • pp.83-92
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    • 2001
  • The properties of off-gas generated from vitrification process of ion-exchange resin were characterized. Theoretical composition and flow rate of the off-gas were calculated based on chemical composition of resin and it's burning condition inside CCM. The calculated off-gas flow rate was 67.9Nm$^3$/h at the burning rate of 40kg/h. And the composition of off-gas was avaluated as $CO_2$(41.4%), steam(40.0%), $O_2$(13.3%), NO(3.6%), and SO$_2$(1.6%) in order. Then, actual flow rate and composition of off-gas were measured during pilot-scale demonstration tests and the results were compared with theoretical values. The actual flow rate of off-gas was about 1.6 times higher than theoretical one. The difference between theoretical and actual flow rates was caused by the in-leakage of air to the system, and the in-leakage rate was evaluated as 36.3Nm$^3$/h. Because of continuous change in the combustion parameters inside CCM, during demonstration tests, the concentration of toxic gases showed wide fluctuation. However, the concentration of CO, a barometer of incompleteness of combustion inside CCM, was stabilized soon. The result showed quasi-equilibrium state was achieved two hours after feeding of resin.

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A method of human error management in chemical process industries (화학공정산업의 인적오류 제어 방법)

  • Jo Young-Do;Park Kyo-Shik;Park Heui-Joon
    • Journal of the Korean Institute of Gas
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    • v.7 no.2 s.19
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    • pp.42-47
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    • 2003
  • To prevent major accident from toxic gas release, explosion, or fire in chemical processes, it needs dynamic control of human error with mechanical failure. Although most of major accidents occur with a coupling of human error and mechanical failure, numbers of researches have studied human error and mechanical reliability independently, but no where cross each other, to reduce the risk in the process. This work focuses on the coincidence of human error and mechanical failure for management of human error, and on some important performance shaping factors to propose a method for improving safety effectively of the process industries.

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Pyrolysis oil refining by Fly-ash absorption (Fly-ash 흡착기법을 이용한 열분해유 정제)

  • Im, EunJung;Kim, SungHyun;Chun, ByungHee;SunWoo, Hwan;Jeong, IckCheol
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.222-222
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    • 2011
  • Plastic product is increasing by the growth of its demand and most of refused plastics are incinerated or reclaimed. However, the refused plastic is not easily decomposed and has the environmental problem with its various toxic gas in case of incineration. Therefore, many countries such as USA, Japan, Germany and other developed industrial countries as well as Korea are interested in studying the recyclable resource of refused plastic. The macromolecular waste pyrolysis has the advantage of collecting of raw materials in high price and can at least get fuel gas or oil with high heat capacity. It also discharges low waste gas and low toxic gas including SOx, NOx and HCl heavy metals. However, pyrolyzed oil includes enough excess unsaturated hydrocarbons to form tar, which can cause the nozzle of engines to plug when pyrolyzed oil is used as fuel. Activated carbon was proven to have prominent adsorption capability among the other adsorbents that were mainly composed of carbon. This study examined the possibility of application in activated charcoal of its solid formation by analysing the feature of pyrolysis which is one of the chemical recycling methods and getting chemical analysis of the product and activated energy. Analyze the element of the oil produced by pyrolysis using GC-MS. The experiment of tar adsorption using fly-ash showed that fly-ash improved the optical intensity of pyrolyzed oil and decreased oxygen compounds in the pyrolyzed oil.

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IN VITRO STUDY ON THE CYTOTOXICITY OF THE DIFFERENTLY STERILIZED DEMINERALIZED BONE POWDER (멸균방법에 따른 탈회동종골의 세포독성 여부에 관한 실험적 연구)

  • Woo, Ki-Sun;Yim, Chang-Joon;Kim, Se-Won;Kim, Jong-Yeo
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.19 no.3
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    • pp.287-299
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    • 1997
  • Procurement, cutting, cleansing, freezing, freeze-drying, and demineralization of the allogeneic bone must be made under the germ-free stable condition without bacterial and/or viral contamination. Even thought the bone is procured under the germ free condition, we must have confidence on disinfection of all the solutions that come in contact with tissue during the whole procedure. Lots of antibacterial agents have been introduced for chemical sterilization. Recently ethylene oxide gas sterilization or radiation sterilization is frequently selected as a secendary sterilization procedure. The biological and biochemical response of the graft material differs with the type and concentration of the sterilizing agents, and various toxic reactions have been reported due to the graft material itself and the substance released by the chemicals. The authors conducted the Millipore filter test to observe the toxic effect on L929 fibroblasts according to the effect on activity of succinate dehydrogenase, during the secondary sterilization of the demineralized allogeneic bone powder with irradiation or ethylene oxide gas. The result were as follows : 1. Around the copper disk, positive control group, 10mm diameter discoloration was observed. 2. As same as the negative control group, the disk showed no discoloration. 3. The demineralized allogeneic bone which was sterilized with ethylene oxide gas or irradiation showed no cytotoxicity. 4. From this results, it is suggested that treatment with ethylene oxide gas or irradiation should be effective to sterilize the deminineralized allogeneic bone.

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