• Title/Summary/Keyword: Toughening

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Sintered properties of silicon carbide prepared by using the alumina and yttria-coated SiC powder (알루미나 및 이트리아로 코팅된 분말을 사용하여 제조한 탄화규소의 소결물성)

  • Um, Ki-Young;Kim, Hwan;Kang, Hyun-Hee;Lee, Jong-Kook
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.4
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    • pp.645-650
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    • 1998
  • Alumina- and yttria-coated SiC powder was prepared by the surface-induced precipitation method, and sintered properties of silicon carbide prepared from this powder were investigated. After a well dispersion of SiC powders in the aqueous solution of $Al_2(SO_4)_3$ and $Y_2(SO_4)_3$, the mixed precursors of aluminum hydroxide, aluminum carbonate, yttrium hydroxide, and yttrium carbonate were precipitated on the surfaces of SiC particles through the hydrolysis reaction of urea. SiC specimens with alumina and yttria exhibit, 97.8% of theoretical density after the sintering at $1900^{\circ}C$ for 2 hrs. During annealing at $2000^{\circ}C$, $\beta$longrightarrow$\alpha$ phase transformation of SiC had taken place and resulted with a rodlike microstructure. Toughness of sintered SiC was enhanced by crack deflection around the rodlike grains. In case of annealing less than that of 3 hr, the fracture toughness of SiC was slightly improved with increasing the amount of sintering aid. However, annealed specimens for a long time showed constant fracture toughness even though the amount of sintering aid increased. It is resulted that the main factor for toughening in annealed SiC for a long time is the pullout effect of rodlike grains during the propagation of cracks, and the amount of sintering aids is less effective on the fracture toughness of SiC.

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Enhancement of Compatibility and Toughening of Commingled Packaging Film Wastes (혼합 폐포장 필름의 상용성 증진과 강인화)

  • Jeon Byeong-Hwan;Yoon Hogyu;Hwang Seung-Sang;Kim Jungahn;Hong Soon-Man
    • Polymer(Korea)
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    • v.29 no.2
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    • pp.127-134
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    • 2005
  • The relationships among mechanical properties, rheological properties, and morphology by reactive extrusion based on commingled pckaging film wastes contains polypropylene (PP) pckaging film system [PP/polyethylene (PE)/aluminum (Al)/poly(ethylene terephthalate) (PET)] and Nylon packaging film system[Nylon/PE/linear-low density polyethylene (LLDPE)] were investigated to improve the compatibility and toughness of these wastes using various compatibilizers such as ethylene vinylacetate (EVA), styrene-ethylene/butylene-styrene triblock copolymer (SEBS), styrene-ethylene/butylene-styrene-graft-maleic anhydride copolymer (SEBS-g-MA), polyethylene-graft-maleic anhydride (PE-g-MA), polypropylene-graft-maleic anhydride (PP-g-MA) , polyethylene-graft-acrylic acid (PE-g-AA) and polypropylene-graft-acrylic acid (PP-g-AA). Compared with simple melt blend system, the blends showed improvement of about $50\%$ increase in physical properties when SEBS and EVA were added. However, SEBS-g-MA thermoplastic elastomer which is highly reactive with amine terminal group of nylon, resulted in about $200\%$ increase in impact strength. This compatibilization effect resulted from the increase of interfacial adhesion and the reduction of domain size of dispersed phase in PP/Nylon blend system.

Effect of Tetragonal $ZrO_2$ Addition on the Mechanical Properties of $\alpha$-Alumina/La-\beta-Aluminate $Composite (정방정 $ZrO_2$의 첨가가 $\alpha$-Alumina/La-\beta-Aluminate $ 복합체의 기계적 성질에 미치는 영향)

  • Suk-Won Kang;Hai-Doo Kim;Shin Kim;Soo-Young Lee;Dong-Soo Park
    • Journal of the Korean Ceramic Society
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    • v.31 no.5
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    • pp.513-519
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    • 1994
  • Alumina composite was fabricated by introducing tetragonal ZrO2 in alumina composite of $\alpha$-alumina reinforced with in-situ formed La-$\beta$-aluminate (LaAl11O18). The powder mixture of composition (100-x)[88 Al2O3+(La2O3+11 Al2O3)]+x vol% ZrO2 was prepared with x from 0 to 40. Dense composites fabricated by hot-pressing exhibited bending strength up to 1200 MPa. The gain growth inhibiting effect of ZrO2 grains and La-$\beta$-aluminate platelets, and possibly the stress-induced phase transformation of ZrO2 have resulted in the high bending strength. The fracture toughness of the composite also increased up to 8.5 MPa.m1/2. The enhancement in toughness can be explained by transformation and microcrack toughening of ZrO2 and by crack deflection and bridging of La-$\beta$-aluminate platelets and ZrO2.

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Exploratory Study on Consumer Attitude toward the SSM Regulation Law (유통산업발전법 개정에 따른 소비자 반응 탐색연구)

  • Nam, Se-Hyun;Cho, Yoon-Ki;Yoo, Jeong-Seok;Kim, Dong-Tae
    • Journal of Distribution Science
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    • v.11 no.10
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    • pp.47-53
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    • 2013
  • Purpose - Six months have passed since the amendment of the SSM regulation law; however, as yet, there is no confirmed research or report on the effects of this amendment, which are indefinite. Further, there have been no attempts to study the effects of the SSM regulation law from the consumers' viewpoint, which is important because consumers are the main agents that are greatly influenced by the amendment law. Therefore, this study aims to investigate the consumers' attitude toward the SSM regulation law as well as the effects of the SSM regulation law on the changes in purchase behavior. Research design, data, and methodology - This study was initiated from four research problems that are linked to consumer reaction to the SSM regulation law. Research problem 1: What is the consumers' reaction (perception, attitude, and perceived fairness) to the SSM regulation law? Research problem 2: How do the consumers' reactions to the SSM regulation law differ by consumers' characteristics? Research problem 3: Could the SSM regulation law change a consumer's purchase behavior? Research problem 4: Is it necessary to amend the SSM regulation law? This study collected the data through the interview and survey of housewives for the purpose of solving the research problems. The interview was conducted as a pilot study for the field survey. We interviewed three housewives, who were: an employed housewife, a full-time homemaker, and a manager of a housewife club, respectively. We then conducted a field survey of 232 housewives who were housewife club members or elementary school parents in Chunghcheong-do. Results - We verified the reliability and validity of the data, and analyzed it to solve the research problems. The main findings of this study were as follows. First, consumers still have a positive attitude toward large discount chains and SSM, which has been the case since the law was introduced. Second, perceived risk of consumers associated with traditional markets and small neighborhood shops was low. Third, consumers think that amendments of the SSM regulation law are important, and they positively assess the satisfaction, necessity, and propriety of the law. Fourth, although the SSM regulation law caused inconvenience to consumers, this law did not have any influence on the usage frequency and the use-behavior of large discount chains. Finally, consumers reacted very negatively to the toughening up of the SSM regulation law. Conclusions - In short, consumers still have a positive attitude toward the SSM regulation law. However, this act did not have any influence on the use-behavior of large discount chains (General Super Market). Thus, policy making authorities require active communication and promotions to enhance the effect of the SSM regulation law. This study was of the nature of exploratory research, which did not focus on hypothesis testing, but on finding solutions to the research problems. Therefore, this study is no more than a simple data analysis. Future studies should attempt to investigate the actual effects of the SSM regulation law, on the basis of sufficient literature review and real sales data.

The study of fractural behavior of repaired composite (수리된 복합 레진 수복물의 파괴 거동에 관한 연구)

  • Park, Sang-Soon;Nam, Wook;Eom, Ah-Hyang;Kim, Duck-Su;Choi, Gi-Woon;Choi, Kyoung-Kyu
    • Restorative Dentistry and Endodontics
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    • v.35 no.6
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    • pp.461-472
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    • 2010
  • Objectives: This study evaluated microtensile bond strength (${\mu}TBS$) and short-rod fracture toughness to explain fractural behavior of repaired composite restorations according to different surface treatments. Materials and Methods: Thirty composite blocks for ${\mu}TBS$ test and sixty short-rod specimens for fracture toughness test were fabricated and were allocated to 3 groups according to the combination of surface treatment (none-treated, sand blasting, bur roughening). Each group was repaired immediately and 2 weeks later. Twenty-four hours later from repair, ${\mu}TBS$ and fracture toughness test were conducted. Mean values analyzed with two-way ANOVA / Tukey's B test ($\alpha$= 0.05) and correlation analysis was done between ${\mu}TBS$ and fracture toughness. FE-SEM was employed on fractured surface to examine the crack propagation. Results: The fresh composite resin showed higher ${\mu}TBS$ than the aged composite resin (p < 0.001). Mechanically treated groups showed higher bond strength than non-mechanically treated groups except none-treated fresh group in ${\mu}TBS$ (p < 0.05). The fracture toughness value of mechanically treated surface was higher than that of non-mechanically treated surface (p < 0.05). There was no correlation between fracture toughness and microtensile bond strength values. Specimens having high KIC showed toughening mechanism including crack deviation, microcracks and crack bridging in FE-SEM. Conclusions: Surface treatment by mechanical interlock is more important for effective composite repair, and the fracture toughness test could be used as an appropriate tool to examine the fractural behavior of the repaired composite with microtensile bond strength.

Hybrid Nanostructure-dependent Mechanical Properties and Crystallization Behaviors of Polypropylene/Clay Nanocomposites (폴리프로필렌/점토 나노복합체의 하이브리드 나노구조에 따른 기계적 성질 및 결정화거동 변화)

  • Choi, Ki-Woon;Lee, Han-Sup;Kang, Bok-Choon;Yang, Hoi-Chang
    • Polymer(Korea)
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    • v.34 no.4
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    • pp.294-299
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    • 2010
  • Clay-loaded polypropylene (PP) nanocomposites were fabricated via melt-compounding of two molecular weight ($M_w$) PPs (140 and 410 kg/mol) and octadecylammine-treated clay (C18MMT), with the assistance of maleic anhydride-grafted PP(PP-MAH), respectively, at $170^{\circ}C$ and $190^{\circ}C$. At both melt-compounding temperatures, the low-$M_w$ PP tends to easily diffuse into silicate layers, especially in the presence of the mobile PP-MAH, resulting in a marked increase in silicate layer spacing (above 58 $\AA$), when compared to 27 $\AA$ in the high-$M_w$ PP-based system. Due to relatively lower melt-viscosity of the low-$M_w$ PP-based system, however, there existed quasi-stacked clay aggregates with a thickness of 60~80 nm, while the high-$M_w$ PP-based nanocomposites showed relatively homogeneous dispersion of clays. The different morphologies are mainly related to changes in the viscoelastic properties of PPs, dependent on the processing temperature and their $M_{w}s$. The slight differences in nanocomposites induce discernible crystallization and mechanical behaviors. High-$M_w$ PP-based nanocomposites containing 1~3 wt% C18MMT showed improvement in both tensile strength and modulus, while maintaining the inherent ductility of pure PP.