• 한국대기환경학회지
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• 제16권5호
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• pp.469-476
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• 2000

This study was performed to understand the behavior and source characteristics of particulate trace metals in Daegu area. To do this, total of 84 samples had been collected from January to December 1999. TSP (total suspended particulate matter) and PM-10(particulate matter with aerodynamic diameters less 10${\mu}{\textrm}{m}$) were collected by filters on portable air sampler, and in TSP and PM-10 were analyzed by ICP(Inductively Coupled Plasma Spectrometer) after preliminary treatment. The results were follow as: first, annul means of TSP and PM-10 concentration were 123 and 69$\mu\textrm{g}$/㎤ respectively. The concentration of TSP adn PM-10 were highest in winter season compared to other seasons. Second, the concentration of Al, Fe, Mn were higher in TSP than in PM-10, indicating that these metals are generally associate with natural contributions. Third, a hierarchical clustering technique was used to group 9 metals. The results from the cluster analysis of TSP and PM-10 shows a similar clustering pattern : Fe, Al in a group and the rest of the metals such as Ni, Cr, As, Mn, Cd, Pb, Zn in the other group. One group of metal such as Fe, Al is associated with natural sources such as soil and dust. The other is closely related to urban anthropogenic sources such as fuel combustion, incineration, and refuse burning, Finally, using Al as a reference element, enrichment factors were used for identifying the major particulate contributors. The enrichment factors of Al. Fe<10 (standard value of enrichment factor) were considered to have a significant dust and soil source and termed nonenriched. Ni, Cr, As, Mn, Cd, Pb, Zn》10 is enriched and has a significant which is contributed by athropogenic sources.

• 한국가금학회지
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• 제20권1호
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• pp.11-15
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• 1993

Environmental measurements were made in 10 broiler confinement houses in order to characterize dust contaminants. Particles were collected by filters on nine stages Anderson Air Sampler, The obtained results were summarized as follows ; 1. The concentrations of the total suspended particles(TSP) were 7.584 mg/$m_3$~11.589mg/$m_3$ in 10 day old broiler houses and 15.836 mg/$m_3$~22.471 mg/$m_3$ in 30 day old broiler houses. 2. The concentrations of the coarse particles were 4.974 mg/$m_3$~18.981 mg/$m_3$ in 10 broiler confinement houses. Therefore, it was found that the coarse particles contributed to TSP between 65.6% and 85.0%. 3. The dust levels were higher in 30 day old broiler houses with TSP averaging about 19.341 mg/$m_3$ than 9.491 mg/$m_3$ in 10 day old broiler houses. In view of the above results , It was concluded that domestic broiler houses need artificial ventilation system.

• 한국대기환경학회지
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• 제6권2호
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• pp.155-160
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• 1990

During the period from Mar. 1985 to Feb. 1988, airborne particulate matters were collected and size fractionated by the ANdersen high volume air sampler in Seoul. The concentrations of several heavy metals (Pb, Cu, Zn, Fe, Mn) and benzo(a)pyrene were determined to investigate the size distributions and seasonal variations. And with respect to seven components in the total suspended particulate (TSP), the factor analysis was performed for three groups such as the coarse particles (> 2 $\mu$m), fine particles (< $\mu$m) and TSP. As a result of factor analysis by using the varimax method, the chemical components in the TSP were able to characterize with two principal factors. The first factor, F1 was considered to be a factor indicating the contribution of natural sources and the second factor, F2 was a factor indicating the degree of artificial sources. Each components in the TSP was divided into two main groups of components originated from soil and/or road dust and pollutants originated from automobiles and/or human work.

• 한국축산시설환경학회지
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• 제12권3호
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• pp.115-122
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• 2006

본 연구는 터널환기 무창육계사의 계사내부의 위치별 먼지 농도 분포와 배기홴에서 배출된 먼지의 확산범위를 알아보고자 수행하였으며 결과는 다음과 같다. 1. 입기구 방향의 계사 1/4 지점의 먼지농도는 TSP의 경우 $301.0{\sim}1,366.0\;{\mu}g/m^3$으로 입기구의 위치에 따라 차이가 있었다. 2. 터널홴 앞 3m 지점에서는 TSP $2065.8{\sim}3,092.2\;{\mu}g/m^3$, PM 2.5 $27.6{\sim}36.3\;{\mu}g/m^3$, PM 1.0 $8.3{\sim}11.3\;{\mu}g/m^3$으로 입기구에 비하여 증가하였다. 3. 배기홴으로부터 3m의 지점의 먼지 배출량은 TSP $354.8{\sim}574.8\;{\mu}g/m^3$으로 매우 높았으며 PM10 $94.4{\sim}156.2\;{\mu}g/m^3$, PM2.5 $14.6{\sim}18.0\;{\mu}g/m^3$, PM1.0 $6.0{\sim}6.4\;{\mu}g/m^3$ 이었다. 4. 배기홴으로부터 50m 떨어진 지점에서의 분진농도는 TSP $25.1\;{\mu}g/m^3$, PM10 $8.8\;{\mu}g/m^3$, PM2.5 $5.6\;{\mu}g/m^3$, PM1.0 $4.9\;{\mu}g/m^3$으로 매우 낮은 분진농도를 보였다. 5. 입기구와 배기구 간 분진농도의 차이는 TSP의 경우 입기구에서 $317.9\;{\mu}g/m^3$인데 비하여 배기구는 $2,678.5\;{\mu}g/m^3$로 8.42배 높았으며 PM10 7.4배, PM2.5 3.4배, PM1.0 1.6배 높았다. 6. 배기홴으로부터 거리별 분진의 배출농도는 3m 지점에서 $446.6\;{\mu}g/m^3$ 이었으나 20 m 지점에서는 $156.3\;{\mu}g/m^3$로 34.9% 수준이었고 PM10 34.9%, PM2.5 48.7%, PM1.0 86.8% 수준이었다.

• 한국광물학회지
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• 제24권3호
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• pp.225-234
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• 2011

2009년 3월 17일 채집된 황사 총시료(TSP)의 개별 입자에 대하여, 고분해 주사전자현미경 및 에너지분산 X선 분광분석을 이용한 광물학적 특성 및 혼합상태 분석을 실시하였다. 황사 입자들 중, 석영, 사장석, K-장석, 각섬석, 흑운모, 백운모, 녹니석, 방해석 등은 비교적 조립질 입자로 산출되며, 이들 입자는 앓은 극미립 일라이트질 점토광물 층으로 피복되어 있다. 극미립 점토광물 입자들은 또한 개별 점토 덩어리를 형성한다. 조립질 방해석 외에 나노섬유 방해석들이 개별적으로 또는 집합체로 큰 입자를 피복하거나 점토광물과 함께 덩어리를 형성한다. 입자의 주 광물에 따라 광물학적 분류를 실시하고 빈도를 구하였다. 이번 TSP의 단일입자 광물학적 특성 및 혼합상태는 기존의 $PM_{10}$ 분석 결과와 거의 차이가 없었다.

• 한국대기환경학회지
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• 제10권4호
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• pp.233-244
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• 1994

The phenomenon of yellow sand (dust clouds) occurred in Korea during the spring of 1993 and 1994 is studied in detail. In total 6 cases including 15 days of yellow sand were observed in 1993 and the annual number of these events was found to increased. Examinations in this study include meteorological charts satellite imagery, pilot reports (PIREP) of Korea Air Force, and air concentrations of total suspended particulates(TSP). We present on estimation of total atmospheric loadings based on the observation and theory. According to the PIREP, in general the dust clouds travelled in the lower troposphere up to the level 5km. The visibility within the clouds was in the range of 3-8km The area covered by yellow sand in an event exceeded 0.4 M $\textrm{km}^2$ . According to trajectory analyses, dust clouds invaded Korea in April and May 1993 were landed in the sink area after 2~4 days travelling for 2,000~3,000km from a source region. Estimates of total atmospheric loadings of a dust cloud for April 23~24 in 1993 were 1.5 M ton. In addition, 7 dust storms were also reported in synoptic observations in NW China and Mongolia during the spring in 1994. The yellow sand was not reported with meteorological observations in Korea, however pilots reported significant dust clouds over the Yellow Sea on 8 and 13 April and 20 May 1994.

• 한국환경보건학회지
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• 제29권1호
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• pp.67-73
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• 2003

This study was carried out to characterize the behavior and sources of particulate trace metal in Daegu city. TSP (Total Suspended Particulate matter) was collected by filters on High Volume Air Sampler from the four areal (reference, residential, commercial, industrial area). The moult were analyzed by AAS after preliminary treatment. The average centration trend of trace metals contained in TSP was shown as follows : Fe > Cu > Pb > Mn > Ni > Cr > Cd. The trace metals showed the highest concentration in the industrial area. This study showed the seasonal variation of trace metals. Fe and Mn showed high concentration in spring, whereas Cr, Ni, Cd and Pb showed high concentration in winter. Also this study showed the regional variation of trace metals. The order of the average concentration of trace metals was : industrial > commercial > residential > reference area. Using Mn as a reference element, the enrichment factor analysis were used for identifying the trace element contributors. The enrichment factors of Cr, Fe < 10 were considered to have a significant dust and soil source and termed nonenriched. Pb, Cd, Cu >>10 were enriched and had a significant fraction which was contributed by anthropogenic sources.

• 한국축산시설환경학회지
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• 제13권2호
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• pp.97-104
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• 2007

본 연구는 변형된 사이클론식 먼지포집기를 이용하여 계사의 먼지농도를 낮추고자 먼지포집기를 개발하였으며 무창육계사에서의 먼지 저감효과를 알아보고자 경기 화성 소재 육계농장의 무창계사에서 시험을 수행하였으며 그 결과는 다음과 같다. 1. 시험계사의 환기량은 2주령시 $0.014{\sim}0.015cmm$ 이었으며 5주령시에는 $0.158{\sim}0.181cmm$이었다. 암모니아가슬 농도는 1주령시 $13{\sim}16\;ppm$, 2주령시 $20{\sim}24ppm$이었으며 $CO_2$ 농도는 1주령시 400-500ppm이었으며 2주령 시 $1,000{\sim}2,000ppm$이었다. 2. 먼지포집기의 기계별 1주간 먼지포집량은 1주령시 104.1g, 2주령시 274.7g, 3주령시 388.6g으로 증가하다가 4주령에는 감소하였다. 3. 먼지포집기의 주령별 먼지 포집효율은 TSP의 경우 먼지포집기를 통과하기전 $3,111.7{\sim}8,745.2\;{\mu}g/m^3$로 높았으나 먼지포집기를 통과하고 난 후 $530.8{\sim}2,264.4\;{\mu}g/m^3$로 낮아져 $54.2{\sim}82.9%$의 효율을 보였으나 PM1.0의 경우 통과전 $15.2{\sim}39.0\;{\mu}g/m^3$에서 통과 후 $11.9{\sim}34.9\;{\mu}g/m^3$로 $7.6{\sim}33.8%$의 낮은 포집효율을 보였다. 4. 대조구의 경우 1주령시 TSP 농도는 $1,387.6\;{\mu}g/m^3$, 4주령시 $4,210.1\;{\mu}g/m^3$으로 높았으나 먼지포집기가 설치된 시험구의 경우 1주령시 $876.3\;{\mu}g/m^3$, 4주령시 $2,535.3\;{\mu}g/m^3$으로 $36.8{\sim}39.8%$의 먼지 저감효과가 있었다. 그러나 PM2.5, PM1.0의 경우 $11.4{\sim}39.8%$의 낮은 먼지저감 효과가 있었다. 5. 대조구의 경우 폐사율은 4.06%이었으나 시험구는 3.13%으로 낮아졌으며 출하체중도 대조구는 1.658kg인데 비하여 시험구는 1.742kg으로 높았다.

• Safety and Health at Work
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• 제14권2호
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• pp.215-221
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• 2023

Background: There is little information about the airborne hazardous agents released during the heat treatment when manufacturing a welding material. This study aimed to evaluate the airborne hazardous agents generated at welding material manufacturing sites through area sampling. Methods: concentration of airborne particles was measured using a scanning mobility particle sizer and optical particle sizer. Total suspended particles (TSP) and respirable dust samples were collected on polyvinyl chloride filters and weighed to measure the mass concentrations. Volatile organic compounds and heavy metals were analyzed using a gas chromatography mass spectrometer and inductively coupled plasma mass spectrometer, respectively. Results: The average mass concentration of TSP was 683.1±677.4 ㎍/m³, with respirable dust accounting for 38.6% of the TSP. The average concentration of the airborne particles less than 10 ㎛ in diameter was 11.2-22.8×10⁴ particles/cm³, and the average number of the particles with a diameter of 10-100 nm was approximately 78-86% of the total measured particles (<10 ㎛). In the case of volatile organic compounds, the heat treatment process concentration was significantly higher (p < 0.05) during combustion than during cooling. The airborne heavy metal concentrations differed depending on the materials used for heat treatment. The content of heavy metals in the airborne particles was approximately 32.6%. Conclusions: Nanoparticle exposure increased as the number of particles in the air around the heat treatment process increases, and the ratio of heavy metals in dust generated after the heat treatment process is high, which may adversely affect workers' health.

• 분석과학
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• 제21권4호
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• pp.304-315
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• 2008

한라산 1100 고지에서 채취한 대기 부유분진의 조성은 인위적 기원의 성분들이 가장 높고, 다음으로 해양 기원 성분과 토양 기원 성분들이 높은 함량을 나타내었다. 계절별로는 봄철에 토양 성분인 nss-$Ca^{2+}$, Al, Fe, Ca 성분의 농도가 크게 증가하였고, 인위적 기원의 $NH{_4}^+$, $K^+$, nss-$SO{_4}^{2-}$은 6월에 가장 높은 농도를 보였다. 반면에 $NO{_3}^-$은 봄철에 nss-$Ca^{2+}$과 함께 농도가 상승하였고, 이는 중국으로부터 장거리 이동에 의한 영향으로 추정된다. 황사와 비황사 때의 농도를 비교해 본 결과, 황사 때에 nss-$Ca^{2+}$, Al, Ca, Fe 농도가 7.2~9.5배 증가하였고, nss-$SO{_4}^{2-}$과 $NO{_3}^-$은 각각 1.3, 3.8배 정도 더 증가한 것으로 확인되었다. 요인분석법으로 분진성분의 발생기원을 조사해 본 결과, 한라산 1100 고지 부유분진은 토양의 영향을 가장 많이 받고, 다음으로 인위적 영향과 해염 영향을 많이 받고 있는 것으로 추정된다. 역궤적분석에 의해 분진 성분의 유입경로를 조사한 결과, 공기덩어리가 중국대륙을 거쳐 제주지역으로 이동한 북서풍 계열의 풍향일 때 주요 인위적 기원의 성분과 토양 성분의 농도가 상승하고, 공기가 북태평양을 거쳐 제주지역으로 유입되었을 때 이들 성분들의 농도가 상대적으로 감소하는 경향을 보였다.