• 한국세라믹학회지
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• 제48권2호
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• pp.160-167
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• 2011

Plasma sprayed ceramic coatings inherently contain pores and usually also cracks. Post-treatment of the plasma sprayed coatings is a way to close the connected pores and cracks. In this study, post-sealing treatment in plasma sprayed $Al_2O_3$ coatings was employed to overcome the reduction of coating properties. $Al_2O_3$ plasma thermal spray coating was made on aluminum alloys plate, $CrO_3$ post coating and heat treatment at $550^{\circ}C$ was carried out in order for final $Cr_2O_3$ to be saturated through phase transformation. Chromia sealing began at the fine defect in coated microstructure, while larger pores were permeated later. The increase in concentration and treatment frequency of sealing solution resulted in the decrease of porosity of coating layer, while cracks occurred partially after the third treatment. After twice treatment of 10M $CrO_3$ solution, microhardness and breakdown voltage of $Al_2O_3$ coatings were found to increase by ${\fallingdotseq}$ 50% and ${\fallingdotseq}$ 390% respectively than without post-treatment.

• 한국세라믹학회지
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• 제34권1호
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• pp.88-94
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• 1997

플라즈마 용사법(plasma spray method)으로 제작된 상용 가스 터빈 연소기의 finned segment의 열차폐용 코팅계, ZrO2-8wt%Y2O3 top coat/Ni-26Cr-5Al-0.5Y bond coat/Hastelloy X superalloy 기판에서 NiCrAlY bond coat의 산화 거동과 열피로 파괴에 대하여 조사하였다. 생성된 bond coat의 주산화물은 NiO, CrO2, Al2O3였다. ZrO2/bond coat계면에서 생성된 산화물의 분포는 고온에서의 사용 전에 이 계면 아래에 얇은 층의 Al2O3가없는 곳에서는 NiO 산화층 및에 Cr2O3와 Al2O3가 혼합된 형태를 나타내었다. 열피로에 의해 박리된 시편의 파면을 관찰한 결과, 파괴는 주로 ZrO2/산화층 계면보다 세라믹층내로 약간 치우쳐서 일어나지만, 산화층 내에서도 약간 일어남을 알 수 있었다.

• 한국표면공학회지
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• 제48권6호
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• pp.260-268
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• 2015

The thermal barrier coating (TBC) for inner wall of liquid-fuel rocket combustor consists of NiCrAlY as bonding layer and $ZrO_2$ as a top layer. In most case, the plasma spray coating is used for TBC process and this process has inherent possibility of cracking due to large difference in thermal expansion coefficients among bonding layer, top layer and metal substrate. In this paper, we suggest crack-free TBC process by using a precise electrodeposition technique. Electrodeposited Ni-P/Cr double layer has similar thermal expansion coefficient to the Cu alloy substrate resulting in superior thermal barrier performance and high temperature oxidation resistance. We studied the effects of phosphorous concentrations (2.12 wt%, 6.97 wt%, and 10.53 wt%) on the annealing behavior ($750^{\circ}C$) of Ni-P samples and Cr double layered electrodeposits. Annealing temperature was simulated by combustion test condition. Also, we conducted SEM/EDS and XRD analysis for Ni-P/Cr samples. The results showed that the band layers between Ni-P and Cr are Ni and Cr, and has no formed with heat treatment. These band layers were solid solution of Cr and Ni which is formed by interdiffusion of both alloy elements. In addition, the P was not found in it. The thickness of band layer was increased with increasing annealing time. We expected that the band layer can improve the adhesion between Cr and Ni-P.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.490.1-490.1
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• 2014

The ZnO nanowire (NW)-based nanogenerators (NGs) can have rectifying current and potential generated by the coupled piezoelectric and semiconducting properties of ZnO by variety of external stimulation such as pushing, bending and stretching. So, ZnO NGs needed to enhance durability for stable properties of NGs. The durability of the metal electrodes used in the typical ZnO nanogenerators(NGs) is unstable for both electrical and mechanical stability. Indium tin oxide (ITO) is used as transparent flexible electrode but because of high cost and limited supply of indium, the fragility and lack of flexibility of ITO layers, alternatives are being sought. It is expected that carbon nanotube and Ag nanowire conductive coatings could be a prospective replacement. In this work, we demonstrated transparent flexible ZnO NGs by using CNT/Ag nanowire hybrid electrode, in which electrical and mechanical stability of top electrode has been improved. We grew vertical type ZnO NW by hydrothermal method and ZnO NW was coated with hybrid silicone coating solution as capping layer to enhance adhesion and durability of ZNW. We coated the CNT/Ag nanowire hybrid electrode by using bar coating system on a capping layer. Power generation of the ZnO NG is measured by using a picoammeter, a oscilloscope and confirmed surface condition with FE-SEM. As a results, the NGs using the CNT/Ag NW hybrid electrode show 75% transparency at wavelength 550 nm and small change of the resistance of the electrode after bending test. It will be discussed the effect of the improved flexibility of top electrode on power generation enhancement of ZnO NGs.

• 한국표면공학회지
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• 제30권4호
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• pp.272-280
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• 1997

The Thermal Barrier Coation(TBC) to improve the that barrier and wear resistant propenrty in high temperature ofthe aircraftength between the accumlation of the aircraft engine and the automobile engine has usually the two layer structure. One is a creamic top layer for heat insulation and the other is a metal bond layer to facilitate the bond strength between the top ceramic layer and the substrate. But, the coated layers should be peeled off because of the accumulation of the thermal stress by the differance of the thermal expantion coefficient between metal and ceramics in a hrat cyclic environment. In this study, the intermediate layer by plasm spray process was introduced to reduce the thermal stress. The powders of plasm spray coating were the Yttria Stabilized Zirconia (YSZ), the Magnesia Stabillized Zirconia(MSZ) and NiCrAlY. the intermediate layer was sprayed with the powders of the bond cast for the purpose of test were executed. The high temperature wear resistance tends to decreasnceee wear and thermal shock test were exeucuted. The high temperature were resistance of the YSZ TBC is better that of the MSZ TBC. The wearrsistance tends to decrease accoring to incresing the temperature between $400^{\circ}C$to $600^{\circ}C$. The thermal shock life of the 3 layer TBC with YSZ top casting was the most outstanding thermal shock rsisstasnce. This means that the intermediate layer should play an importnat roll to alleviate the diffrerence of the thermal expansion coef frcients between metallic layer and cermics layer.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 하계학술대회 논문집 A
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• pp.107-109
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• 1998

This paper presents mechanical analysis of gas turbine generator (113MVA, $3{\phi}$, 2P, 0.9PF, F class, 3600rpm, 60Hz, 13.8kV, 4.72kA, Air-Cooling) field coil deformation. Rotor end coil deformation is only appeared on turbine end but collector end coil is normal. Expansion direction of end coil is tangential not axial. Deformation appears more severe at top turn. Retaining ling is expanded by centrifugal force of coil and itself. In case friction coefficient between coil top surface and retaining ring insulation inner surface is small, coil end length ${\ell}$ does not change. However, in case friction coefficient big condition, coil end is expanded ${\Delta}{\ell}$ due to start and stop. Deformation is assumed about 30mm by watching photograph inner surface of retaining ring is coated by Teflon at manufacturing condition. Usually Teflon coating insulation surface is small friction coefficient. It's value 0.08${\sim}$0.15. However it's value exceeds more than 0.297. Since top turn deformation appears. The distortion and subsequent failure have occurred because of the lack of a sufficient slip-plane between the top field coil conductors and the inside surface of the retaining ring insulation on the turbine end of the field-winding.

• Current Optics and Photonics
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• 제5권5호
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• pp.500-505
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• 2021

We demonstrated a wide-fan-angle flat-top irradiance pattern with a very narrow linewidth by using an aspheric lens and a long-pitch reflective diffraction grating. First, we numerically designed a diffraction-based linear beam homogenizer. The structure of the Al diffraction grating with an isosceles triangular shape was optimized with 0.1-mm pitch, 35.5° slope angle, and 0.02-mm radius of the rounding top. According to the numerical results, the linear uniformity of the irradiance was more sensitive to the working distance than to the shape of the Al grating. The designed Al grating reflector was fabricated by using a conventional mold injection and an Al coating process. A uniform linear irradiance of 405-nm laser diode with a 100-mm flat-top length and 0.176-mm linewidth was experimentally demonstrated at 140-mm working distance. We believe that our proposed linear beam homogenizer can be used in various potential applications at a precise inspection system such as three-dimensional morphology scanner with line lasers.

• 대한기계학회논문집A
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• 제34권4호
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• pp.475-480
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• 2010

가스터빈 블레이드는 터빈 가동 시 발생하는 고온화염으로부터 블레이드를 보호하고, 구조물의 표면 온도를 안전한 수준으로 낮추기 위하여 블레이드 표면에 열차폐 코팅(TBC; Thermal barrier coating)을 하여 사용하고 있다. 본 논문에서는 가스터빈 1단 블레이드에 적용되는 코팅 방식을 이용하여 코인형 시험편을 제작하였고 열화 온도 및 유지 시간의 변화에 따른 코팅 계면 산화물의 성장 거동을 분석하였다. 코팅 단면에 대하여 코팅 계면 산화물의 두께와 마이크로 비커스 경도를 측정하여 열화 특성을 평가 하였다. 또한 성분분석을 통하여 미세조직의 변화를 관찰함으로써 열차폐 코팅의 열적 열화특성을 평가하였다.

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 2001년도 춘계학술발표논문집
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• pp.79-79
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• 2001

백판지는 포장용기로 사용되기 때문에 인쇄적성 이외에 다양한 후가공적성이 요구 된다. V Varnish Coating도 이러한 후가공적성 중의 하나로서 국내 인쇄소에서는 기계 코팅으로 불리 우며, 목적은 표면에 고분자수지 피막을 입힘으로써 인쇄물의 광택을 높여서 상품가치를 높이고 수운침투와 같은 외부환경의 변화로부터 상품을 안전하게 보관하기 위함이다. arnish C Coating은 인쇄기의 마지막 Unit에서 인쇄와 동일한 방식으로 진행되는데, 코팅액의 배합은 인쇄소와 인쇄물에 따라 상이하다. 본 연구는 Varnish Coating(OI하 기계코팅) 광택향상을 통 한 품질개선 목적으로 수행되었다. 기계 코팅의 특 성 을 파 악 하 기 위 해 서 Gas Chromatography / Mass Spectrometer와 FT -IR Sp e ectrometer를 사용하여 성문운석을 실시해본 결과 코팅액으로 사용되는 광택바니스는 아크 랄과 페놀수지를 툴루엔 계열의 용매에 녹인 용액이고, 흐$\mid$석제로 쓰이는 인쇄바니스는 스티 렌수지를 동일한 용매에 녹인 용액으로 조사되었다. 기계코팅광택 저하현상의 원인파악을 위해서 도공층의 공극구조를 Mercury Porosimeter를 이용하여 파악한 결과 기공의 부피가 상 대적으로 크게 나타났다. 위의 결과를 토대로 기계코팅광택 저하는 코팅액이 과도한 기공부피를 갖는 도공층 내부 로 대부분 홉수되고 표면에 적은 양만이 잔류하기 때문으로 판단하고 해결방안은 도공층의 기공부피를 줄이는 쪽으로 정하였다. Mayor Coater와 QC를 이용하여 Coating Color Formula t tion 번경실힘을 진행하여 도공지 물성을 분석하였다. 그 결과 Double Coating의 Top Color에 서 강력한 상호작용을 하는 Protein과 콜레이를 감량 하고 경질탄산칼숨을 배제하여 기공의 부피를 줄인 경우 기계코팅광택 향상효과가 두드러지게 나타났다. 이러한 Lab 실험을 바탕으로 결정된 Color Formulation에 대한 현장실험을 진행하였고 Lab 평가 및 실인쇄 평가 결과 원하는 수준의 기계코팅광택 향상을 얻을 수 있었다. 몇 차례의 현장실험과 Long-Run Test한 제품들에 대한 물성을 문석한 결과 기계코팅굉택은 인쇄 광택과 같은 경향을 나타냈으며 실협실적으로 간단하게 측정되는 물성 중에서 Air Permeability와 강한 음의 상관관계롤 보였다.

• 한국환경과학회지
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• 제30권3호
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• pp.219-234
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• 2021

Industrial emissions, mainly from industrial complexes, are important sources of ambient Volatile Organic Compounds (VOCs). Identification of the significant VOC sources from industrial complexes has practical significance for emission reduction. VOC samples were collected from July 2019 to June 2020. A Positive Matrix Factorization (PMF) receptor model was used to evaluate the VOC sources in the area. Four sources were identified by PMF analysis, including coating-1, coating-2, printing, and vehicle exhaust. The coating-1 source was revealed to have the highest contribution (41.5%), followed by coating-2 (23.9%), printing (23.1%), and vehicle exhaust (11.6%). The source showing the highest contribution was coating emissions, originating from the northwest to southwest of the sample site. It also relates to facilities that produce auto parts. The major components of VOC emissions from the coating facilities were toluene, m,p-xylene, ethylbenzene, o-xylene, and butyl acetate. Industrial emissions should be the top priority to meet the relevant control criteria, followed by vehicular emissions. This study provides a strategy for VOC source apportionment from an industrial complex, which is helpful in the development of targeted control strategies.