• Title/Summary/Keyword: Top Coating

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Fabrication and Characterization of La2Zr2O7/YSZ Double-Ceramic-Layer Thermal Barrier Coatings Fabricated by Suspension Plasma Spray (서스펜션 플라즈마 용사법을 이용한 La2Zr2O7/YSZ 2층세라믹 열차폐코팅의 제조와 특성평가)

  • Kwon, Chang-Sup;Lee, Sujin;Lee, Sung-Min;Oh, Yoon-Suk;Kim, Hyung-Tae;Jang, Byung-Koog;Kim, Seongwon
    • Journal of the Korean institute of surface engineering
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    • v.48 no.6
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    • pp.315-321
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    • 2015
  • Rare-earth zirconates, such as $La_2Zr_2O_7$ and $Gd_2Zr_2O_7$, have been investigated as one of the candidates for replacing conventional yttria-stabilized zirconia (YSZ) for thermal barrier coating (TBC) applications at higher turbine inlet temperatures. In this study, double-ceramic-layer (DCL) TBCs of YSZ 1st layer and $La_2Zr_2O_7$ top coat layer are fabricated by suspension plasma spray with serial liquid feeders. Microstructures, hardness profiles, and thermal durability of DCL-TBCs are also characterized. Fabricated DCL-TBCs of YSZ/$La_2Zr_2O_7$ exhibit excellent properties, such as adhesion strength (>25 MPa) and electrical thermal fatigue (~1429 cycles), which are comparable with TBCs fabricated by atmospheric plasma spray.

Optical Properties of Color Conversion Lens for White LED Using B2O3-Bi2O3-ZnO Glass (B2O3-Bi2O3-ZnO계 유리를 이용한 백색 LED용 색변환 렌즈의 광 특성)

  • Chae, Yoo-Jin;Lee, Mi-Jai;Kim, Jin-Ho;Hwang, Jong-Hee;Lim, Tae-Young;Jeong, Hee-Suk;Lee, Young-Sik;Kim, Deuk-Jung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.8
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    • pp.614-619
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    • 2013
  • Recently, remote phosphor is reported for white LED enhancing of phosphor efficiency compared with conventional phosphor-based W-LED. In this study, Remote phosphor was produced by screen printing coating on glass substrate with phosphor contents rated paste and heat treatment. The paste consists of phosphor, lowest softening glass frit and organic binders. Remote phosphor can be well controlled by varying the phosphor content rated paste. After mounting remote phosphor on top of blue LED chip, CCT, CRI, and luminance efficiency were measured. The measurement results showed that CCT, CRI, and luminance efficiency were 6,645, 68, and 1,16l m/W in phosphor 80 wt.% remote phosphor sintered at $600^{\circ}C$.

A Study on Development and Construction Methods of the Inorganic Floor Finishing Material of Hazardous Material Storage Facilities (위험물 저장시설의 무기질 바닥마감재와 이를 이용한 시공방법에 관한 연구)

  • Oh, Dong-Seok;Yu, Chul-Hee;Kim, Byung-Duk;Kim, Heum;Park, Sang-Min
    • Journal of the Korean Institute of Gas
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    • v.18 no.4
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    • pp.35-43
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    • 2014
  • Usage of the inorganic floor finishing material can be advantageous to overcome some problems of traditional organic-based floor finishing material used for hazardous material storage facilities. A spark can be produced by physical impact between the flooring and the flooring disposal equipment while removing the existing flooring. In order to prevent a fire hazard, which may be caused the spark, it is feasible that a construction can be implemented without removing the existing flooring. Moreover, the top coating material containing an antistatic agent is effective to prevent secondary damage caused by static electricity after finishing the construction of the flooring. Therefore, the inorganic floor finishing material of the this study is expected to be beneficial for safety management and economical aspect for inspectors.

Synthesis of Silica Membranes on a Porous Stainless Steel by Sol-Gel Method and Effect of Preparation Conditions on Their Permselectivity

  • Lee, Dong-Wook;Nam, Seung-Eun;Sea, Bong-Kuk;Ihm, Son-Ki;Lee, Kew-Ho
    • Bulletin of the Korean Chemical Society
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    • v.25 no.9
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    • pp.1371-1378
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    • 2004
  • A porous stainless steel (SUS) as a substrate of silica composite membranes for hydrogen purification was used to improve mechanical strength of the membranes for industrial application. The SUS support was successfully modified by using submicron Ni powder, $SiO_2$ sols with particle size of 500 nm and 150 nm in turns. Silica top layer was coated on the modified supports under various preparation conditions such as calcination temperature, dipping time and repeating number of dipping-drying process. The calcination temperature for proper sintering was between H ttig temperature and Tamman temperature of the coating materials. Maximum hydrogen selectivity was investigated by changing dipping time. As repeating number of dipping-drying process increased, permeances of nitrogen and hydrogen were decreased and $H_2/N_2$ selectivity was increased due to the reduction of non-selective pinholes and mesopores. For the silica membrane prepared under optimized conditions, permeance of hydrogen was about $3\;{\times}\;10^{-5}\;cm^3{\cdot}cm^{-2}{\cdot}s^{-1}{\cdot}cmHg^{-1}$ combined with $H_2/N_2$ seletivity of about 20.

An Organic Electrophosphorescent Device Driven by All-Organic Thin-Film Transistor using Polymeric Gate Insulator

  • Pyo, S.W.;Shim, J.H.;Kim, Y.K.
    • Journal of Information Display
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    • v.4 no.2
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    • pp.1-6
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    • 2003
  • In this paper, we demonstrate that the organic electrophosphorescent device is driven by the organic thin film transistor with spin-coated photoacryl gate insulator. It was found that electrical output characteristics in our organic thin film transistors using the staggered-inverted top-contact structure showed the non-saturated slope in the saturation region and the sub-threshold nonlinearity in the triode region, where we obtained the maximum power luminance that was about 90 $cd/m^2$. Field effect mobility, threshold voltage, and on-off current ratio in 0.45 ${\mu}m$ thick gate dielectric layer were 0.17 $cm^2/Vs$, -7 V, and $10^6$ , respectively. In order to form polyimide as a gate insulator, vapor deposition polymerization process was also introduced instead of spin-coating process, where polyimide film was co-deposited by high-vacuum thermal evaporation from 4,4'-oxydiphthalic anhydride (ODPA) and 4,4'-oxydianiline (ODA) and cured at 150${\sqsubset}$for 1hr. It was also found that field effect mobility, threshold voltage, on-off current ratio, and sub-threshold slope with 0.45 ${\mu}m$ thick gate dielectric films were 0.134 $cm^2/Vs$, -7 V, and $10^6$ A/A, and 1 V/decade, respectively.

Fabrication of Stretchable Ag Nanowire Electrode and its Electrochromic Application (신축성있는 Ag 나노와이어 전극의 제조 및 전기변색 응용)

  • Lee, Jin-Young;Han, Song-Yi;Nah, Yoon-Chae;Park, Jongwoon
    • Korean Journal of Materials Research
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    • v.29 no.2
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    • pp.87-91
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    • 2019
  • We report on stretchable electrochromic films of poly(3-hexylthiophene) (P3HT) fabricated on silver nanowire (AgNW) electrodes. AgNWs electrodes are prepared on polydimethylsiloxane (PDMS) substrates using a spray coater for stretchable electrochromic applications. On top of the AgNW electrode, poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) is introduced to ensure a stable resistance over the electrode under broad strain range by effectively suppressing the protrusion of AgNWs from PDMS. This bilayer electrode exhibits a high performance as a stretchable substrate in terms of sheet resistance increment by a factor of 1.6, tensile strain change to 40 %, and stretching cycles to 100 cycles. Furthermore, P3HT film spin-coated on the bilayer electrode shows a stable electrochromic coloration within an applied voltage, with a color contrast of 28.6 %, response time of 4-5 sec, and a coloration efficiency of $91.0cm^2/C$. These findings indicate that AgNWs/PEDOT:PSS bilayer on PDMS substrate electrode is highly suitable for transparent and stretchable electrochromic devices.

The Study and Conservation of Woven Cigarette Inserts (담배 사은품 실크 인서트(Silk Inserts)에 관한 연구와 보존처리)

  • Lee, Young-Joo
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.3 s.151
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    • pp.447-457
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    • 2006
  • The purpose of this study is to document and preserve an unidentified textile purchased at a flea market. This study object is important because it is one of the very rare silk insert series from 1930s which were created for commercial use(as inclusion in cigarette packages). The investigation was conducted by researching the limited publications that discuss silk inserts, visiting many sites on the internet that offer such inserts for sale or catering to the collectors of these silk inserts, and especially visiting the collection of silk inserts, named the J.R. Burdick Collection, at the Metropolitan Museum of Art, New York. Several pieces matched the patches used in the study piece. But Buidick's description on time frame(1912-1915) did not indicate the full range of production of silk inserts. After the identification of object, the conservation treatment was carefully done using adhesives. The results of this study can be summarized as follows; 1. The silk inserts of the study object were included as promotions by some company owned by the American Tobacco Company, probably at some time between 1934 and 1939. 2. The initial stage in the conservation treatment was mechanical surface cleaning using a vacuum cleaner. After vacuuming, humidification was conducted to reduce creases in the top of the object. The damaged areas were backed with stabiltax coated with a solution of Elvace 45675 since the fiber of this object was too deteriorated. 3. Adhesive treatments using Elvace showed satisfactory results: flexibility, strength, no damaging effects on the study object, removability without damaging the object.

Microwave-assisted TS-1 Membrane for the Separation of Ethylbenzene from Xylene Mixture (마이크로웨이브로 제조된 TS-1 Membrane을 이용한 혼합 자일렌에서의 에틸벤젠 고순도화)

  • Jeon, Yu-Kwon;Lee, Gi-Cheon;Chu, Young-Hwan;Choi, Seong-Hwan;Seo, Young-Jong;Shul, Yong-Gun
    • Membrane Journal
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    • v.22 no.2
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    • pp.120-127
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    • 2012
  • In this study, separation of ethylbenzene from mixed xylene was performed by using TS-1 zeolite membrane. TS-1 zeolite membranes were prepared by microwave synthesis and changing the reaction temperature. MFI-type TS-1 membranes are synthesized on alumina tubes by functional coating using 3-chloropropyltrimethoxysilane (3CP-TMS). On top surface of interlayer, nano TS-1 crystals were seeded. To form interlayer, microwave-assisted growth of TS-1 zeolite was carried out and thin zeolite layers were produced. All of the prepared membranes are tested to separate ethylbenzene from mixed xylene at different operating temperatures. TS-1 membrane with zeolite seed synthesized at $170^{\circ}C$ compared to 120, $140^{\circ}C$ shows the best ethylbenzene separation at the operation temperature of $200^{\circ}C$ from ternary mixed xylene containing certain composition of ethylbenzene/p-xylene/m-xylene. (separation factor : 2.64, ethylbenzene flux : 1703.0 mol/$m^2{\cdot}s{\cdot}Pa$).

Study on the Separation of N2/SF6 Mixture Gas Using Polyimide Hollow Fiber Membrane (폴리이미드 중공사 막을 이용한 N2/SF6 혼합기체 분리에 관한 연구)

  • Kim, Dae-Hoon;Kim, Guang-Lim;Jo, Hang-Dae;Park, Jong-Soo;Lee, Hyung-Keun
    • Korean Chemical Engineering Research
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    • v.48 no.5
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    • pp.660-667
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    • 2010
  • In this research polyimide, Matrimid 5218, hollow fiber membrane was used to recover sulfur hexafluoride($SF_6$) which is one of the six greenhouse gases from $N_2/SF_6$ mixture gas. Fibers were spun from using dry-wet phase inversion method. The module was manufactured by fabricating fibers after surface coating with silicone elastomer. The scanning electron microscopy(SEM) studies showed that the produced fibers typically had an asymmetric structure; a dense top layer supported by a sponge-like substructure. The developed module had a permeance of 0.78-1.36 GPU for $N_2$ with $N_2/SF_6$ selectivity of 2.44-5.08 at various pressure and temperature. For recovery of $SF_6$, a membrane module and 10 vol.% $SF_6$ from $N_2/SF_6$ mixture gas was used. The effects of various operating condition such as pressure, temperature, and retentate side flow rate were tested. When pressure and temperature were increased and retentate flow rate was decreased, the $SF_6$ purity in recovered gas was increased up to 37.5 vol.% with decreasing recovery ratio. When retentate flow rate was increased pressure and temperature was decreased, the $SF_6$ recovery ratio in retentate side was increased up to 89% with decreasing the $SF_6$ purity in retentate side.

Design Analysis of Hydraulic Excavator since 1990 (1990년대 유압굴삭기 조형 분석에 관한 연구)

  • 윤진필;문무경
    • Archives of design research
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    • v.13 no.4
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    • pp.233-242
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    • 2000
  • The traditional image of hydraulic excavator started to change in two ways since 1990. First, post-heavy equipment's visual image was new waves to traditional image of heavy, strong, and wild. They are the negative aspect that excavators have. Another movement of getting rid of its negative image can be found in late-heavy equipment, which was intended to adapt traditional and positive, but off negative images. In 1990s, the design trend is moving from warm/hard to warm/soft, and KOBELCO can be exceptional example that went even further, gone up to cool-soft image. KOBELCO specially aimed 'post- excavator image' strategy, which has been successful. Image of cabin as a human space changed little bit further than outside image. Each company tried to differentiate the design of cabin focusing on its safety. Following paragraphs show specific trend of image change in form, colour, texture, and the composition. Major visual image change in form tries to follow the image of cars and home appliances which are showing the movement from tough and hard image to soft one. Structural change on local image shows the movement from angular edge to edgeless and the movement of cabin's pillar C placed to back of the equipment with gentle inclination. All of these movements are the result of effort to improve traditional excavator's negative image, that top structure is assembled separately, to positive ones. Today's tendency about its color becomes important to apply two different colour styles. Each style has brightness and tone comparison. As an enormous power convey system, it was in common that its brightness comparison was useful because of the alarm of its damage possibility. However, as its colour control and its design have been emphasized gradually, the tone comparison takes a part in an important role, too. As an example, there is an occasion that these comparisons are compromised simultaneously. In the respect of its image creation, its texture treatments make the tendency of being the same as passenger cars. It is caused from its development of the manufacture techniques of from the fabrication method in small business to the press method in big firm. Further, it is also because of its improvement of painting & coating skills. It may prohibit the reflection effect from solar rays. In the point of view of its visual images, it is recognized the prominent tendency that its composition has been gradually decreased. Lots of windows and the frames tends dark-colour as a whole. It is more preferred to have one colour image, but except KOBELCO and HITACHI. As well, there is another high-tendency to improve its standard treatments, especially for its corner and texture treatments.

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