• International Journal of Safety
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• v.11 no.1
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• pp.15-18
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• 2012

Because of development of printing technology, toner cartridge particle becomes smaller and more dangerous. And sometimes we had incidents with dust explosion of toner cartridge particle at recycling facilities in Japan. Therefore we studied on hazard of toner particle relating with dust explosion. We found that toner particle is so dangerous compared with most organic solids, even though it does not belong to hazardous materials in the UN regulation and the Japanese Fire Service Law.

• 정보저장시스템학회:학술대회논문집
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• 2005.10a
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• pp.75-80
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• 2005

Study for toner adhesion is known as an important role in electrophotography. In this research, a centrifugal detachment method was used to measure the adhesion force of several hundred particles simultaneously and to determine its sensitivity to particle size. For uncharged toner particles, we estimated the van der Waals force based on the centrifugal farce experiments. Then for charged toner particles, the centrifugal force experiments were carried out. The difference between the results for charged toner particles and the results for uncharged toner particles was compared with the image force calculated from a model which assumed that the toner charge was located at the center of the particle. In the calculations, experimental data obtained by E-SPART (Electrical- Single Particle Aerodynamic Relaxation Time) analyzer were used. The adhesion force of micro-sized toner particles deposited on the DR surface was found to be approximately 1${\~}$3 nN.

• Transactions of the Society of Information Storage Systems
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• v.2 no.2
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• pp.105-110
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• 2006

Study for toner adhesion is 3non as an important role in electrophotography. In this research, a centrifugal detachment method was used to measure the adhesion force of several hundred particles simultaneously and to determine its sensitivity to particle size. For uncharged toner particles, we estimated the van der Waals force based on the centrifugal force experiments. Then for charged toner particles, the centrifugal force experiments were carried out. The difference between the results for charged toner particles and the results for uncharged toner particles was compared with the image force calculated from a model which assumed that the toner charge was located at the center of the particle. In the calculations, experimental data obtained by E-SPART (Electrical-Single Particle Aerodynamic Relaxation Time) analyzer were used. The adhesion force of micro-sized toner particles deposited on the DR surface was found to be approximately $1{\sim}3$ nN.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.36 no.2
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• pp.24-32
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• 2004

Toner used in xerographic printing process is hydrophobic powder with low surface energy. The toner ink film fused on paper surface can be efficiently detached from a fiber surface during pulping, but it does not fragment again into fine toner particles. Ink agglomerates that result have too large particle size to be deinked by flotation. The purpose of this study is to enhance toner agglomeration using 1-octadecanol for improving the toner removal by screening. The effect of pH, pulping temperature, and 1-octadecanol on toner agglomeration and removal by screening was investigated using image analysis methods. Results showed that the size of toner agglomerates increased substantially when pulping was carried out at high temperature under acidic condition. When toner agglomerates showed spherical shape, the particle removal efficiency of screening was improved.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.22 no.1
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• pp.93-97
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• 2009

We analyzed voltage characteristics of toner particle type display according to particle layers and cell gap between two electrodes and ascertained the aging effects by measuring the response time of particles with and without aging process. The threshold/driving/breakdown voltage is proportional to layers of toner particles and cell gap and the response time at driving voltage is faster than that of threshold and breakdown voltage because of different q/m of color and black particles. The analysis of response time is a method of estimation of optical characteristics, driving voltage and particle lumping and these results are promoted by aging process. We use the laser and photodiode to measure response time and optical properties. It has not been studied and reported to analyze the relationship of response time, threshold/driving/breakdown voltage, lumping phenomena, cell gap, and aging process for toner particle type display.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.33 no.2
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• pp.58-67
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• 2001

MOW (Mixed Office Waste) mainly consisted of photocopied paper is being recycled to produce tissue or fine paper products. Toner particles that are fused and set on paper surface in photocopying process turns into large and plate-shaped particles after repulping which prevents them to be removed effectively in flotation deinking. The immediate purpose of this study is to find the effective deinking technology that increases the recycling potential of photocopied papers for manufacturing tissue and fine paper products. In this study the effects of pulping temperature and the type of hydrophobic groups of nonionic surfactants on the deinking efficiency of photocopied paper has been investigated. Particle size distribution of the toner particles after pulping and flotation, brightness, yield and ash removal were investigated. The size of toner particles after pulping increased as the pulping temperature was increased. When pulping at the low temperature finer toner particles were generated, however, greater amount of toner particles was found to attach to the fiber. When the pulping temperature was greater than Tg of the toner, the amount of coarse hairy particles increased. When nonionic surfactants with a double bond in hydrophobic groups were used, toner removal efficiency, brightness and ash removal were increased. As the addition level of surfactant was increased, yield decreased rather sharply without improving brightness.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.22 no.1
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• pp.86-92
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• 2009

We fabricated the charged particle type display using opposite-charged two toner particles. The particles were composed of polymer, colorant($TiO_2$, carbon black) and external additives(nano-sized silica and so on). In fabrication process we controlled the putting layers of this toner particles on the inner panel. To get the effect of number of layers ($1{\sim}3$), we measured the threshold, driving and breakdown voltages, reflectivity, viewing angle, and color characteristics using RT-300 anisotropic scattering system. We ascertained that these voltages are increased with increasing of layers of particles. Cell gap between electrodes must be enlarged with increment of layers and the size of particles. The lumping phenomena of particles at near of the rib observed by optical system with same CIE values.

• Korean Chemical Engineering Research
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• v.51 no.5
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• pp.628-633
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• 2013

Carbon black was surface-modified to prepare styrene-based suspension polymerized toner with excellent carbon black dispersibility inside toner particles. Carbon black was oxidized first to introduce hydroxyl groups on the surfaces, then esterification between the hydroxyl groups and carboxyl groups of organic acids (oleic acid, palmitic acid, acrylic acid) was followed to obtain organically surface-modified carbon black. The surface-modification of carbon black was confirmed by FTIR. Apparent carbon black dispersibility in the monomer mixture of the binder resin was tested and the particle size of dispersed carbon black was measured by particle size analyzer. Optical micrographs showed that carbon black dispersibility inside toner particles was improved considerably when the carbon black surfacemodified with oleic acid was used. The polymerized toner prepared with the carbon black surface-modified with oleic acid showed ideal particle size and size distribution as a toner.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.22 no.2
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• pp.169-173
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• 2009

We studied driving characteristics according to the ratio of mass and charging (m/q) value for charged toner particles with black and yellow color in charged particle type display panel. After biasing rectangle pulse to the transparency electrodes of putted panel with toner particles, its response time and contrast ratio are simultaneously measured using a laser as a optical source, photodiode as a detector and reflective system. As a results, contrast ratio is largest at the shortest response time region which is different to the particle because of m/q. We proposed relational equation for response time, m/q, cell gap and biasing voltage. It has not been studied and reported to analyze the relationship of response time, biasing voltage, lumping phenomena, cell gap, and contrast ratio for toner particle type display.

• Textile Coloration and Finishing
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• v.15 no.6
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• pp.8-17
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• 2003

In order to investigate the possibility of PVA particle as toner, PVA/PVAc particle was manufactured. Fine spherical PVAc particle with emulsifier SDS(sodium Dodecyl Sulfate) and initiator V-50(2,2'- azo bis(2-amidinopropane) dihydrochloride) was manufactured by emulsion polymerization. And then, the PVAc was carried with surface saponification. PVA/PVAc skin core structured particle was obtained under optimum saponification condition. PVA skin side in manufactured PVA/PVAc particles was dyed with 1:2 metal complex type C. I. Acid Yellow 235 and then the dyed PVA particles were observed with a optical microscope. Under given polymerization condition such as SDS concentration, $1.62\times{10}^{-2} \;mol/lH_2O$, V-50 concetration, $3.7\times{10}^{-3}\;mol/lH_2O$ and temperature $50^\circ{C}$ , the high molecular weight of PVAc with Pn 13,900 and PVA with Pn 3,400 was produced. The particle distribution of obtained PVAc microspheres was appeared highly at 60 and $100\mu{m}$, respectively.