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유기물과 석회 처리 수준이 토양의 Trichloroethylene 흡착에 미치는 영향 (The Effect of Organic Matter and Lime Treatment on Trichloroethylene Adsorption by Soil)

  • 이군택;류순호;이민효
    • 한국토양환경학회지
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    • 제1권1호
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    • pp.11-17
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    • 1996
  • 본 실험은 산업 현장에서 광범위하게 사용하고 있는 유기용제인 Trichloroethylene (TCE)이 저장탱크누출, 작업장에서의 취급 부주의, 매립지 침출수 유출 등을 통해 토양과 지하수를 오염시킬 우려가 있는 물질이므로 토양내에서의 TCE의 흡착성향을 파악하기 위하여 본 연구를 수행하였다. 이를위해 토양의 유기물 함량과 석회 시용량을 달리하여 TCE에 대한 Freundlich 등온흡착식 상수 k와 n을 결정하였다. 유기물함량은 sewage sludge cake을 0ton/ha, 50ton/ha, 100ton/ha 수준으로 처리하고 S1, S2, S3라 명명하였다. 석회는 2ton/ha, 4ton/ha, 6ton/ha, 10ton/ha. 수준으로 처리하였다. sewage sludge cake을 수준별로 처리한 실험에서 구한 Freundlich 등온흡착식은 다음과 같다. (단, TCE 처리 농도범위가 0.5~2.5ng/g soil 일 경우임) S1 : x/m = 0.393 $C^2$, S2 : x/m = 0.436 $C^2$, S3 : x/m = 0.636 $C^2$위 식에서 보듯이 k값이 sewage sludge cake 처리수준이 증가할수록 0.393, 0.436, 0.636으로 증가하므로 TCE 처리농도가 같다면 sewage sludge cake 처리수준이 높은 토양일수록 TCE에 대한 흡착효율이 좋았다. 반면 석회시용 수준이 증가할수록 토양의 pH는 증가하였고 TCE 흡착능력은 감소하였다.

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The Estimation of Emission Factor of N2O and CH4 by Measurement from Stacks in the Waste Incinerators and Cement Production Plants

  • Choi, Sang-Min;Im, Jong-Kwon;Hong, Ji-Hyoung;Lee, Sue-Been;Zoh, Kyung-Duk
    • 한국환경보건학회지
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    • 제33권3호
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    • pp.217-226
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    • 2007
  • The purpose of this study is to estimate the emission factor of $non-CO_2$ global warming gases such as $N_2O$ and $CH_4$ by measuring concentrations from stacks of waste incinerators and cement production plants. Based on the established monitoring methods, $N_2O$ concentration measured from stacks in incinerator were between 0.62 and $40.60\;ppm_v$ (ave. $11.50\;ppm_v$). The concentration of $N_2O$ was dependent on the incinerator types. However, the concentrations of $CH_4$ gas were between 2.65 and $5.68\;ppm_v$ (ave. $4.22\;ppm_v$), and did not show the dependency on the incinerator types. In the cement production plant, the concentration ranges of $N_2O$ from the stack were from 6.90 to $10.80\;ppm_v$ (ave. $8.60\;ppm_v$), and $CH_4$ were between 1.80 and $2.20\;ppm_v$ (ave. $2.60\;ppm_v$). Using measured concentrations, the emission amounts of $N_2O$ and $CH_4$ from stacks per year were calculated. The results were is 4.2 ton $N_2O/yr$ in the incinerators, and 53.7 ton $N_2O/yr$ in the cement facilities. The big difference is from the flow rate of flue gas in the cement facilities compared to the incinerators. By the same reason, the $CH_4$ emission amounts in cement plant and incinerator was found to be 339 ton $CO_2/yr$ and 34.1 ton $CO_2/yr$, respectively. Finally, the emission factor of $N_2O$ in the incinerators were calculated using the measured concentration and the amount of incinerated wastes, and was $42.5\sim799.1\;g/ton$ in kiln and stoker type, $11.9\sim79.9\;g/ton$ in stoker type, 90.1 ton/g in rotary kiln type, 174.9 g/ton in fluidized bed type, and 63.8 g/ton in grate type, respectively. Also, the emission factors of $CH_4$ were found to 65.2-91.3 g/ton in kiln/stoker type, 73.9-122 g/ton in stoker type, 109.5 g/ton rotary kiln, and 26.1 g/ton in fluidized bed type. This result indicates that the emission factor in incinerators is strongly dependent on the incinerator types, and matched with result of IPCC (International Panel on Climate Change) guideline.

생산자조직 내 자원순환형 농업시스템 구축사례와 시사점 (Case Study on the Directions for Establishment of Resource Cycling Agricultural System Focused on Farmer's Organization)

  • 허승욱
    • 한국유기농업학회지
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    • 제19권4호
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    • pp.463-474
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    • 2011
  • The objectives of this study were to establish of resource cycling agricultural system focused on farmer's organization. Case is selected as the farming corporation for the regional agriculture considering the amount of sowing by-products and livestock by-products generated. As a result, generation of fertilizer ingredient depend on feces and urine of Korean native cattle is estimated nitrogen 7.7 ton, phosphoric acid 2.9 ton, and potassium 4.9 ton. On the other hand, generation of fertilizer ingredient demand in cultivated acreage is estimated nitrogen 42.4 ton, phosphoric acid 14.3 ton, and potassium 17.0 ton. Therefore, optimum livestock numbers is estimated 1,867 cattle and it means 1,468 cattle can be raise additionally. In order to complete the resource cycling agricultural system, it should be establish nutrient management system at all of organization level and achieve improvements in regional resource supply. Both economic value of organic fertilizer and the resource cycling system linked market system is considered to develop resource cycling level.

매립장의 반입쓰레기 성상변화에 따른 다짐밀도 조사연구 (The Investigation Study of Compaction Density by Waste Composition Change in Landfill Site)

  • 정병길;최영익;김정권
    • 한국환경과학회지
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    • 제17권4호
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    • pp.397-403
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    • 2008
  • The purpose of this study is to investigate weighted compaction density according to a leading density in truck, a compaction density of solid waste and composition ratios of solid waste fur calculation of a capacity of the landfill sites. The experiments for calculations of in-place density at landfill site have been conducted in S landfill site at B City. The size of vessel for measuring the compaction density was $1m^3(1m{\times}1m{\times}1m)$. The experiment tests have been carried out methods (1 time for bulldozer and 4 times for compactor) that do contain all of specification at the landfill site. Average of the loading density at the landfill site was $0.264\;ton/m^3$ ($0.113{\sim}0.487\;ton/m^3$). When the loading density for each compositions was compared, the composition of the highest average loading density ($0.474\;ton/m^3$) was miscellaneous wastes. The composition of the lowest average loading density ($0.120 ton/m^3$) was general solid waste. The reported results indicated that the compaction density at the landfill site was $0.538\;ton/m^3$, which was calculated with weighted incoming ratios of compositions. The ranges of the density for each composition were from $0.021\;ton/m^3$ to $0.221\;ton/m^3$. When the compaction density for each composition was compared, the composition with the highest average compaction density ($0.221\;ton/m^3$) was miscellaneous wastes. The composition with the lowest average compaction density ($0.021\;ton/m^3$) was general solid wastes.

한국의 축산물 물발자국 산정 (Estimation of Water Footprint for Livestock Products in Korea)

  • 이상현;최진용;유승환;김영득;신안국
    • 한국농공학회논문집
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    • 제57권2호
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    • pp.85-92
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    • 2015
  • Since the consumption of the livestock products increased for the past 10 years in Korea, the water use for live animals has become more important in terms of water savings. Therefore, the index connecting water use and livestock products consumption should be required for sustainable water management, and water footprint concept could be suggested as the index. The aim of this study is to estimate the water footprint for livestock products; beef cattle, swine, and broiler chicken. The water footprint for livestock products is divided into direct and indirect water. The direct water includes the drinking and servicing water, and the indirect water includes the water for the cultivation of feed crops. The water footprint of beef cattle was calculated to $17,023.1m^3/ton$, and direct water was $91.2m^3/ton$, and indirect water was $16,931.9m^3/ton$. The water footprint of swine was calculated to $4,235.8m^3/ton$, and direct water was $129.7m^3/ton$, and indirect water was $4,106.0m^3/ton$. The water footprint of broiler chicken was calculated to $2,427.7m^3/ton$, and direct water was $7.6m^3/ton$, and indirect water was $2,420.1m^3/ton$. Also, we compared the water footprint to water demand of water vision 2020 which is the main report for national water management. The water vision 2020 reported only direct water for live animal, but the water footprint includes the direct and indirect water. Therefore, the water footprint could be applied to various fields relating water and food.

전전환 논에서 우분시용이 토양화학성 및 Silage 옥수수의 수량과 품질에 미치는 영향 (Effects of Cattle Manure Application on the Soil Properties , Yield Performance and Quality of Silage Corn Cultivated on Paddy land)

  • 진현주;양종성;김정갑;정의수
    • 한국초지조사료학회지
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    • 제16권1호
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    • pp.81-86
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    • 1996
  • Silage wm(cv, Gwanganok) was cultivated during 1991-1994 on paddy land as a rotational cropping system of rice, to evaluate the effect of cattle manure application on the soil characteristics, yield performance and quality of com plant. The treatments used in this study were non-fertilizer, NPK standard in chemical fertilizer(N:$P_2O_5$ : $K_2O$= 200 : 150 : 150 kg/ha), cattle manure 20.40, 60 and 80 ton/ha Application of cattle manure improved soil pH, organic matter, available phosphate and exchangeable cations in the soils. During the experiment, soil pH was improved from 4.7 in the chemical fertilizer application(control) to 5.4-5.6 in the application of cattle manure, and available $P_2O_5$ wntent was increased from 72.2 ppm(contro1) to 340.2 ppm(cattle manure 80 ton/ha). Application of cattle manure increased plant growth, plant height and stalk diameter, and silage yields. Dry matter yields were produced 15.88 ton(chemical fertilizer), 20.11 ton(cattle manure 40 ton) and 21.22 ton/ha(cattle manure 80 ton/ha). However, no signicant yield differences were observed between cattle manure 40, 60 and 80 tonlha Productions of total digestible nutrients(TDN) and net energy for lactation(NEL) were also increased under cattle manure application. From the abobe results, the proper application amount of cattle manure was 40 tonha in this experiment.

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서울지역 대형연소시설에서의 질소산화물 배출계수 산정 (The Evaluation of NOx Emission Factor from Large Combustion Facilities in Seoul)

  • 조기찬;최종욱;박후경;유병태
    • 환경위생공학
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    • 제15권4호
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    • pp.78-83
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    • 2000
  • The emission factor of nitrogen oxides(NOx) was evaluate to clarify the characteristics of NOx emitted from seven large combustion facilities in seoul area. The emission factors of NOx at A-1 and A-2 facilities of internal combustion engine were 66.957kgNOx/ton and 20.913kgNOx/ton, respectively. The emission factor of A-1 facility was higher than that of A-2 facility even same internal combustion engine, because A-1 facility adopted SCR(selective catalystic reactor) for reduction of NOx emission factor of A-2, A-4, and A-7 power generation boiler facilities were 4.300kgNOx/ton, 2.460kgNOx/ton and 1.796kgNOx/ton, respectively. The capacity of A-2 facility was about two times than that of A-4 and A-7. These emission factors were lower than those at facilities in other areas of korea, because of using low NOx burner of power generation boiler. The emission factors of NOx at A-3 and A-6 incinerator facilities were 0.147kgNOx/ton and 0.221kgNOx/ton which were lower than other facilities, respectively, because these facilities incinerate municipal solid waste of low heating value and uwe SCR for reducing NOx concentration.

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Organic carbon distribution and cycling in the Quercus glauca forest at Gotjawal wetland, Jeju Island, Korea

  • Han, Young-Sub;Lee, Eung-Pill;Park, Jae-Hoon;Lee, Seung-Yeon;Lee, Soo-In;You, Young-Han
    • Journal of Ecology and Environment
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    • 제42권2호
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    • pp.60-69
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    • 2018
  • Background: This study was conducted from March 2011 to February 2013 in order to evaluate the ecosystem value by examining the organic carbon distribution and cycling in the Quercus glauca forest, evergreen oak community at Seonheul-Gotjawal, Jeju Island. Results: The amount of organic carbon distribution was $124.5ton\;C\;ha^{-1}$ in 2011 and $132.63ton\;C\;ha^{-1}$ in 2012 for aboveground biomass. And it was $31.13ton\;C\;ha^{-1}$ in 2011 and $33.16ton\;C\;ha^{-1}$ in 2012 for belowground biomass. In total, the amount of organic carbon distribution in plants was 155.63 and $165.79ton\;C\;ha^{-1}$ in 2011 and 2012, respectively. In 2011 and 2012 respectively, the amount of organic carbon distribution was 3.61 and $6.39ton\;C\;ha^{-1}$ in the forest floor and it was 78.89 and $100.71ton\;C\;ha^{-1}$ in the soil. As shown, most carbon was distributed in plants. Overall, the amount of organic carbon distribution of the Q. glauca forest was $238.13ton\;C\;ha^{-1}$ in 2011 and $272.89ton\;C\;ha^{-1}$ in 2012. In 2011, the amount of organic carbon fixed in plants through photosynthesis (NPP) was $14.22ton\;C\;ha^{-1}\;year^{-1}$ and the amount of carbon emission of soil respiration was $16.77ton\;C\;ha^{-1}\;year^{-1}$. The net ecosystem production (NEP) absorbed by the Q. glauca forest from the atmosphere was $5ton\;C\;ha^{-1}\;year^{-1}$. Conclusions: The carbon storage value based on such organic carbon distribution was estimated about $23.81mil\;won\;ha^{-1}$ in 2011 and $27.29mil\;won\;ha^{-1}$ in 2012, showing an annual increment of carbon storage value by $3.48mil\;won\;ha^{-1}$. The carbon absorption value based on such NEP was estimated about $500,000won\;ha^{-1}\;year^{-1}$.

공간정보를 활용한 도심지 토사유실 위험도 평가 (The evaluation of Soil Erosion Risk of Urban Area based on Geospatial Information)

  • 이근상
    • 지적과 국토정보
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    • 제45권2호
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    • pp.57-70
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    • 2015
  • 최근 기후변화에 따른 집중호우로 토사유실이 심각해지고 있다. 이러한 토사유실은 산사태, 수질, 농경지 생산성 저하 등의 주요 원인이 되고 있다. 따라서 토사유실 모델링에 매우 민감하게 작용하는 DEM, 토양도 그리고 토지피복도와 같은 공간정보를 활용하여 토사유실에 영향을 주는 주요 원인지역을 찾는 것이 매우 중요하다. 본 연구에서는 RUSLE 모형을 이용하여 토사유실량을 평가하였다. 완산구에서는 효자 4동과 평화2동의 토사유실량이 각각 10,869ton/yr과 10,477ton/yr으로 높게 나타났으며 덕진구에서는 우아2동의 토사유실량이 17,603ton/yr으로 높게 나타났다. 또한 토사유실 잠재성 평가에 이용되는 단위 토사유실량 분석결과, 완산구에서는 효자1동과 평화1동이 각각 $1,485.7ton/km^2$$1,297.0ton/km^2$로 높게 나타났으며, 완산구에서는 인후3동의 단위토사유실량이 $2,557.7ton/km^2$으로 가장 높게 나타났다. 따라서 본 연구에서 도출한 성과는 도심지 토사유실 및 토석류 위험도를 예측하고 대비하는데 활용할 수 있을 것으로 기대된다.

Microbubble Flotation에 의한 고품위(高品位) 석탄생산(石炭生産) 기술(技術) 개발(開發) (Development of Microbubble Flotation Technique for the Production of High Grade Coal)

  • 한오형;박신웅;김병곤
    • 자원리싸이클링
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    • 제21권4호
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    • pp.44-52
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    • 2012
  • 본 연구에서는 고정탄소 20.68%의 석탄으로부터 고품위 석탄 생산의 가능성을 확인하고자 한다. 또한, 광물학적, 물리, 화학적인 방법과 단체분리도의 특성을 파악하여 청정 석탄 기술의 처리과정에서 회분의 함량을 감소하는 데 목적이 있다. 본 연구에서 일반부선과 미립자 처리에 적합한 microbubble column 부선을 적용하여 기포제, 포수제, 억제제의 종류와 첨가량의 변화와 분쇄시간, 공기주입량, 급광량에 따른 영향을 확인하였다. 먼저 광액농도 20%, 포수제 DMU 101 + DDA(100mL/ton), 기포제 pine oil(200mL/ton), 억제제 sodium silicate(1 kg/ton)의 실험조건으로 일반부선을 실시한 결과, 회분제거율 81.55%, 회수율 70.23%를 얻을 수 있었고, 광액농도 5%, 분쇄시간 5분, collector DMU 101 + DDA(100 mL/ton), 기포제 AF65(5.4 L/ton), 억제제 AF65 (5.4 L/ton), 세척수(360 mL/min.)와 공기주입량(1,197 mL/min.)의 조건으로 microbubble column 부선을 실시한 결과, 회분제거율 83.85%, 회수율 70.42%를 얻을 수 있었다.