• Composites Research
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• v.19 no.2
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• pp.28-34
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• 2006

[ $Cu-TiB_2$ ] metal matrix composites with various weight fractions of $TiB_2$ were fabricated by combination of manufacturing process, SPS (self-propagating high-temperature synthesis) and SPS (spark plasma sintering). The feasibility of $Cu-TiB_2$ composites for welding electrodes and sliding contact material was investigated through experiments on the tensile properties, hardness and wear resistance. To obtain desired properties of composites, composites are designed according to reinforcement's shape, size and volume fraction. Thus proper modeling is essential to predict the effective material properties. The elastic moduli of composites obtained by FEM and tensile test were compared with effective properties from the original Eshelby model, Eshelby model with Mori-Tanaka theory and rule-of-mixture. FEM result showed almost the same value as the experimental modulus and it was found that Eshelby model with Mori-Tanaka theory predicted effective modulus the best among the models.

• Journal of the Korean Ceramic Society
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• v.21 no.4
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• pp.349-354
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• 1984

The purpose of present study is to find the structure crystallization mechanism and physical properties in $TiO_2$ containing lead zinc borosilicate glass system. The experiments such as differential thermal analysis infrared spectral analysis. X-ray diffraction analysis and thermal expansion measurements have been done. Differential thermal analysis of coarse and fine glass powder showed bulk nucleating mechanism for high $TiO_2$ containing glasses and surface nucleation mechanism for low $TiO_2$ containing glasses. The prepared glasses crystallized to crystalline mixture of PbO.2ZnO. $B_2O_3$ .4PbO.2ZnO.$5B_2O_3$and 2PbO.ZnO.$B_2O_3$ when heat-treated in the range of 480 and 51$0^{\circ}C$ and crystallized to PbTiO3 when heat-treated at $600^{\circ}C$. Obtained crystalline phase of $PbTiO_3$ in glass matrix strongly affects to thermal expansion coefficient and the value of crystallized glass varied 68.0 to $107.1{\times}10-7$/$^{\circ}C$ depending on the amount of $TiO_2$added. Infrared spectral analysis showed that [$BO_3$] triangle and [$BO_3$] tetrahedral units were coexisted in the glass with high content of PbO.

• Journal of the Korean institute of surface engineering
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• v.31 no.3
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• pp.157-164
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• 1998

Effects of alloying elements on the pitting behavior of Ti-Al intermetalic compounds in the electrolytic soution containing Cl- were investigated through electrochemical tets and corrosion morphologies. Corrosion potential increased in the case of Cr addition to Ti-48%Al, whereas it decreased in the case of Si and B addition. The simultaneous addition of Cr and Si increased passive current density and decrosion corrosion potential. The passive current density of N addtion was higher than that of B addition in H2SO4 solution. With the addition of alloying elements, The pitting resistance decreased in order of TiAl>TiAlSi>TiAlN>TiAlB>TiAlCr and whin siumultaneous addition, it decreased in order of TiAlCrSi>TiAlCrBN>TiAlCrrN. The surface merohology after pitting test showed that the TiAl coataining Si had for fewer pits than that containing Cr and N simultaneously.

• Proceedings of the KIEE Conference
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• 2007.07a
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• pp.1303-1304
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• 2007

The composites were fabricated, respectively, using 61[vol.%]SiC-39[vol.%]$TiB_2$ and using 61[vol.%]SiC-39[vol.%]$ZrB_2$ powders with the liquid forming additives of 12[wt%] $Al_{2}O_{3}+Y_{2}O_{3}$ by hot pressing annealing at $1650[^{\circ}C]$ for 4 hours. Reactions between SiC and transition metal $TiB_2$, $ZrB_2$ were not observed in this microstructure. ${\beta}{\rightarrow}{\alpha}$-SiC phase transformation was occurred on the SiC-$TiB_2$ and SiC-$ZrB_2$ composite. The relative density, the flexural strength and Young's modulus showed the highest value of 98.57[%], 226.06[Mpa] and 86.38[Gpa] in SiC-$ZrB_2$ composite at room temperature respectively. The electrical resistivity showed the lowest value of $7.96{\times}10^{-4}[{\Omega}{\cdot}cm]$ for SiC-$ZrB_2$ composite at $25[^{\circ}C]$. The electrical resistivity of the SiC-$TiB_2$ and SiC-$ZrB_2$ composite was all positive temperature coefficient resistance (PTCR) in the temperature ranges from $25[^{\circ}C]$ to $700[^{\circ}C]$. The resistance temperature coefficient of composite showed the value of $6.88{\times}10^{-3}/[^{\circ}C]$ and $3.57{\times}10^{-3}/[^{\circ}C]$ for SiC-$ZrB_2$ and SiC-$TiB_2$ composite in the temperature ranges from $25[^{\circ}C]$ to $700[^{\circ}C]$.

• Journal of the Korean Ceramic Society
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• v.35 no.7
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• pp.665-670
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• 1998

Ferroelectric anomaly in PbO-{{{{ { {B }_{2 }O }_{3 } }}-{{{{ {TiO }_{3 } }}-BaO glasses which is observed in DAT measurements was in-vestigated together with the effect of BaO content on the shift of Cuire temperature. The temperature where the ferroelectric anomaly apperars on cooling in DTA decreased in proportion with increasing BaO content,. For as-crystallized samples the ferroelectric anomaly was not observed on heating but on cooling whilist for powder samples leached chemically from the crystallized samples both endothermic and ex-otehrmic peaks were observed. This fact suggests that the appearance of the ferroelectric anomaly in DAT largely depends on glassy phases surrounding individual {{{{ {PbTiO }_{3 } }} crystals rather than effects of grain size and crystallinity.

• Journal of the Korean Ceramic Society
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• v.36 no.7
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• pp.767-772
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• 1999

The effect of B2O3 addition on the sintering behavior dielectric and ferroelectric properties of Ba0.7Sr0.3TiO3 ceramics were investigated. The sample with 0.5wt% B2O3 was sintered under 115$0^{\circ}C$. The dielectric and ferroelectric properties of BST with 0.5wt% B2O3 was as good as BST without B2O3 sintered at 135$0^{\circ}C$ and its dielectric loss was even better When B2O3 was added over 1.0wt% the overdoped B2O3 remained in the specimens and formed a second phase which degraded the sintering behaivor dielectric properties of BST.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2003.11b
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• pp.300-304
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• 2003

수용성 안료인 RhB를 대상으로 GF/C에 고정한 $TiO_2$와 유동층 반응기를 이용하여 제거실험을 수행한 결과 다음과 같은 결론을 얻었다. 1. 고정화 $TiO_2$의 경우도 분말을 이용한 것과 같이 최적 광촉매 투입량이 나타났으며, 최적 투입량은 40.0 g/L이었고, 분말 $TiO_2$를 이용하는 광촉매 반응의 초기속도식과 같이 Langmuir - Hinshelwood 식으로 표현될 수 있었다. 분말 $TiO_2$를 이용한 경우보다 초기반응속도는 2.3배 느렸으나, 고정화 $TiO_2$의 경우 연속공정이 가능하고 촉매회수 공정이 필요하지 않으므로 반응속도만 더 높일 수 있으면 현장적용 가능성이 높다고 사료되었다. 2. 고정화 $TiO_2$의 최소유동을 위한 공기 공급량은 4 L/min, 최대 반응속도는 5 L/min에서 나타나 고정화 $TiO_2$를 충진한 유동층 반응기의 최적 공기 공급량은 최소유동화 속도 부근인 것으로 사료되었다.

• Journal of the Korean Chemical Society
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• v.46 no.3
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• pp.179-186
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• 2002

A molecular orbital analysis based on the extended Huckel calculations has been carried out to study the OH bond activation of water on the $TiO_2$(110) surface. $H_2O$ binds with its axis perpendicular to the surfac on top of the five-coordinate $Ti^{4+}$ atom via its $3a_1$ orbital. In this bonding situation, the two-coordinated bridging $O^{2-}$ atom ($O_b$, basic site) on $TiO_2$(110) is too distant from an H atom of water to form hydrogen-bondig interactions with water that facilitate O-H bond cleavage. It has been elucidated that the O-H bond is appreciably weakened when the water molecule is tilted to give a hydrogen bond with the $O_b$ atom. This mechanism includes mutual transfer of electron density from the $3a_1$ orbital of the water molecule to the $Ti^{4+} 3d_{z2}$ orbital and from the $O_b$ P orbitals to the $2b_1$ of the adsorbed water molecule This should result in lengthening of the O-H bond in the surface complex and the subsequent dissociation into the fragments OH and H.

• Journal of the Korean Society for Heat Treatment
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• v.27 no.4
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• pp.169-174
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• 2014

The effect of varying amounts of graphite and $TiB_2$ on the electrical conductivity of composite bipolar plates was systematically studied. In this study, Titanium diboride ($TiB_2$) which has a high electrical conductivity, was selected as a filler and a additive material instead of conventional graphite. For proper distribution of the filler and matrix materials, ball milling using alumina balls was conducted for 1h, and then the hot press method was applied for the preparation of composite samples. The results showed a rapid increase in the electrical conductivity of composite bipolar plates at the critical filler content. However, $TiB_2$ and graphite composite bipolar plates showed similar increases in the electrical conductivity even though $TiB_2$ has a higher electrical conductivity than graphite. In addition, it was also found that a small addition of $TiB_2$ to graphite filler could be very effective for increasing the electrical conductivity and flexural strength of the composite bipolar plate.

• Applied Biological Chemistry
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• v.35 no.4
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• pp.294-299
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• 1992

In order to examine the effect of $TiO_2$ on photosterilization of microorganism. Proper content of $TiO_2$, illumination time, wave length specificity and cell concentration were investigated for photosterilization of E. coli, B. subtilis and S. cerevisiae. The amount of $TiO_2$ for photosterilization of E. coli was effective in the range of $5{\sim}20\;mg%$. The sterilization time was reduced when the low wave length below 400 nth was not cut off by glass, but the catarizing effect of $TiO_2$ was similar to overall wave length. The photosterilization effects by $TiO_2$ addition was recognized among S. cerevisiae, E. coli and B. subtilis in that order. The photosterilization time of S. cerevisiae was considerably reduced at $10^4/ml$ cell concentration compared to $10^5/ml$.