• Title/Summary/Keyword: Ti-Fe-Si

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Microstructure and Mechanical Properties of Rapidly Solidified Powder Metallurgy Al-Fe-V-Si-X Alloys

  • Genkawa, Takuya;Yamasaki, Michiaki;Kawamura, Yoshihito
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1041-1042
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    • 2006
  • High heat-resistant Al-Fe-V-Si and Al-Fe-V-Si-X rapidly solidified powder metallurgy (RS P/M) alloys have been developed under well-controlled high purity argon gas atmosphere. The $Al_{90.49}Fe_{6.45}V_{0.68}Si_{2.38}$ (at. %) RS P/M alloy exhibited high elevated-temperature strength exceeding 300 MPa and good ductility with elongation of 6 % at 573 K. Reduction of $H_2O$ partical pressure in P/M processing atmosphere led to improvement in mechanical properties of the powder-consolidated alloys under elevated-temperature service conditions. Ti addition to the Al-Fe-V-Si conduced to enhancement of the strength at room temperature. The tensile yeild strength and ultimate strenght were 545 MPa and 722 MPa, respectively.

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Mineralchemie der Klinopyroxen vom tephritischen Gesteine im Kaiserstuhl, BRD (카이져슈튤에서 산출되는 테프라이트질 화산암내의 단사휘석에 관한 광물화학적 고찰)

  • Kim, Jin-Seop;Keller, Jorg
    • Journal of the Mineralogical Society of Korea
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    • v.2 no.2
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    • pp.100-106
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    • 1989
  • Die Titan-Augite sind die dominierenden Einsprenglings- und Grundmassephasen in allen tephritischen Gesteinen im Kaiserstuhl. Mg-Werte ($Mg/Mg+Fe^{2+}+Mn$) der Pyroxene schwanken von 60-85. Der FATS- und TITS-Anteil nimmt von phonolithischem Basanit und -Tephrit zum fraktionierten phonolithischen Tephrit hin ab. Die Kpx der einzelnen Gesteinsgruppen zeigen auch einen Fraktionier-ungstrend, der durch Abnahme von Si und Zunahme von Al vom phonolithischen Basanit und -Tephrit zum fraktionierten phonolithischen Tephrit gekennzeichnet ist. Der in Alkaligesteinen gewohnlich auftretende $gr{\ddot{u}}ne$ Kern der Px ist Fe-reicher und $Ti-{\ddot{a}}rmer$ als der $hellbra{\ddot{u}}nliche$-farblose Rand. Die $gr{\ddot{u}}nen$ Kerne weisen $gegen{\ddot{u}}ber$ den $hellbr{\ddot{a}}unlichen$ Randern $h{\ddot{o}}here$ $Na/Fe^{+3}$-Verhaltnisse auf.

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The Dielectric Properties of $Bi_4Ti_3O_{12}$ Ferroelectric Thin Films Doping Neodymium (Neodymium이 첨가된 $Bi_4Ti_3O_{12}$ 강유전체 박막의 유전 특성)

  • Kwon, Hyun-Yul;Nam, Sung-Pill;Lee, Sang-Heon;Bae, Seon-Gi;Lee, Young-Hie
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.1829-1831
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    • 2005
  • Ferroelectric $Bi_{3.25}Nd_{0.75}Ti_3O_{12}$(BNdT) thin films were proposed for capacitor of FeRAM. The BNdT thin films were grown on Pt/Ti $SiO_2/P-Si(100)$ substrates by the RF magnetron sputtering deposition. The dielectric properties of the BNdT were investigated by varying post-annealing temperatures. Increasing post-annealing temperature, the (117) peak was increased. An increase of rod type grains of BNdT films with increasing post-annealing temperature was observed by the Field Emission Scanning Electron Microscopy(FE-SEM). The dielectric constant and dielectric loss of the BNdT thin films with post-annealing temperature of $700^{\circ}C$ were 418 and 0.37, respectively.

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Study on the Surface Properties of Arc Ion Plated Ti-Al-Cr-N Thin Layers (아크 이온 증착된 Ti-Al-Cr-N 도포층의 표면 물성 연구)

  • Gang, Bo-Gyeong;Choe, Yong;Gwon, Sik-Cheol;Zang, Shi-Hong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.05a
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    • pp.125-125
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    • 2015
  • Ti-Al-Cr-N thin layer was prepared on Fe-Si thin sheet by arc ion plating to improve corrosion and mechanical properties. The compositions ratios of Fe : Cr : Al : Ti : Si : N of the thin layers at $500^{\circ}C$ was 1.24 : 0.56 : 36.82 : 32.72 : 0.59 : 28.07 [wt.%], respectively. The higher arc ion plating temperature was, the higher corrosion resistance and nano-hardness were observed due to chromium content. Corrosion potential and corrosion rate in artificial sea water of the coating layer were in the range of $-39mV_{SHE}$ and $2mA/cm^2$, respectively. Passivity was not observed in the artificial sea water. Nano-hardnesses of the thin layers was increased by adding Cr from 23.6 to 25.8 [GPa]. The friction coefficients and fatigue limits of the layers were 0.388, 0.031, respectively.

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Sintering of TiB2 with Polycarbosilane (Polycarbosilane 첨가에 의한 TiB2의 소결)

  • Lee, Kwang-Jung;Kang, Shin-Hyuk;Kim, Deug-Joong
    • Journal of the Korean Ceramic Society
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    • v.42 no.8 s.279
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    • pp.588-592
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    • 2005
  • The effect of SiC additive on the densification behavior and microstructural change of $TiB_2$ ceramics was investigated. The infiltration and direct mixing with polycarbosilane (PCS), which was converted to SiC by pyrolysis during sintering, were used for the addition of SiC. The addition of Fe enhanced the densification of $TiB_2$, but which resulted in exaggerated grain growth. However, the addition of PCS enhanced the densification and suppressed the exaggerated grain growth of $TiB_2$. Moreover, the addition of PCS using direct mixing was more effective for suppress of grain growth as compare to the addition of PCS using infiltration.

Ferroelectric, Leakage Current Properties of BiFeO3/Pb(Zr0.52Ti0.48)O3 Multilayer Thin Films Prepared by Chemical Solution Deposition (Chemical Solution Deposition 방법을 이용한 BiFeO3/Pb(Zr0.52Ti0.48)O3 다층박막의 전기적 특성에 대한 연구)

  • Cha, J.O.;Ahn, J.S.;Lee, K.B.
    • Journal of the Korean Vacuum Society
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    • v.19 no.1
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    • pp.52-57
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    • 2010
  • $BiFeO_3/Pb(Zr_{0.52}Ti_{0.48})O_3$(BFO/PZT) multilayer thin films have been prepared on a Pt/Ti/$SiO_2$/Si(100) substrate by chemical solution deposition. BFO single layer, BFO/PZT bilayer and multilayer thin films were studied for comparison. X-ray diffraction analysis showed that the crystal structure of all films was multi-orientated perovskite phase without amorphous and impurity phase. The leakage current density at 500 kV/cm was reduced by approximately four and five orders of magnitude by bilayer and multilayer structure films, compared with BFO single layer film. The low leakage current density leads to saturated P-E hysteresis loops of bilayer and multilayer films. In BFO/PZT multlayer film, saturated remanent polarization of $44.3{\mu}C/cm^2$ was obtained at room temperature at 1 kHz with the coercive field($2E_c$) of 681.4 kV/cm.

Fabrication and Photocatalytic Activity of TiO2 Nanofibers Dispered with Silica Nanoparticles (SiO2 나노입자가 분산된 TiO2 나노섬유의 제작 및 광촉매 특성 분석)

  • Choi, Kwang-Il;Lee, Woohyoung;Beak, Su-Wung;Song, Jinho;Lee, Sukho;Lim, Cheolhyun
    • Korean Chemical Engineering Research
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    • v.52 no.5
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    • pp.667-671
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    • 2014
  • In this study, we suggest a facile method to control conditions of single component independently when preparing consisting two-component metal oxides nanofiber by simply dispersing nanoparticles in precursor solution. The well dispersed $SiO_2$ nanoparticles in $TiO_2$ nanofibers were successfully synthesized through a simple electrospinning process. The as-synthesized nanodfibers were investigated via FE-SEM, XRD and EDS for structural studies, furthermore, the analysis of UV-VIS and photocatalytic activity were carried out for demonstrate the effect of $SiO_2$ nanoparticles dispersed in $TiO_2$ nanofibers. As a result, $TiO_2$ nanofibres dispersed with $SiO_2$ nanoparticles have enhanced photocatalytic activity than that of $TiO_2$ nanofibres only. In this strategy, the introduction of $SiO_2$ nanoparticles in $TiO_2$ nanofibers were attribute to enlarge absorption in the visible region (380~440 nm). Additionally, $Br{\o}nsted$ acid sites generated in each metal oxide of Ti and Si increase OH radicals efficiently as well as it limit recombination loss by holding photogenerated electrons for high efficient photocatalytic activity.

A review on thermohydraulic and mechanical-physical properties of SiC, FeCrAl and Ti3SiC2 for ATF cladding

  • Qiu, Bowen;Wang, Jun;Deng, Yangbin;Wang, Mingjun;Wu, Yingwei;Qiu, S.Z.
    • Nuclear Engineering and Technology
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    • v.52 no.1
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    • pp.1-13
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    • 2020
  • At present, the Department of Energy (DOE) in Unite State are directing the efforts of developing accident tolerant fuel (ATF) technology. As the first barrier of nuclear fuel system, the material selection of fuel rod cladding for ATFs is a basic but very significant issue for the development of this concept. The advanced cladding is attractive for providing much stronger oxidation resistance and better in-pile behavior under sever accident conditions (such as SBO, LOCA) for giving more coping time and, of course, at least an equivalent performance under normal condition. In recent years, many researches on in-plie or out-pile physical properties of some suggested cladding materials have been conducted to solve this material selection problem. Base on published literatures, this paper introduced relevant research backgrounds, objectives, research institutions and their progresses on several main potential claddings include triplex SiC, FeCrAl and MAX phase material Ti3SiC2. The physical properties of these claddings for their application in ATF area are also reviewed in thermohydraulic and mechanical view for better understanding and simulating the behaviors of these new claddings. While most of important data are available from publications, there are still many relevant properties are lacking for the evaluations.

Electrochemical Behaviors of PEO-treated Ti-6Al-4V Alloy in Solution Containing Zn and Si Ions

  • Hwang, In-Jo;Choe, Han-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.160-160
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    • 2017
  • Commercially pure titanium (Cp-Ti) and Ti alloys (typically Ti-6Al-4V) display excellent corrosion resistance and biocompatibility. Although the chemical composition and topography are considered important, the mechanical properties of the material and the loading conditions in the host have, conventionally. Ti and its alloys are not bioactive. Therefore, they do not chemically bond to the bone, whereas they physically bond with bone tissue. The electrochemical deposition process provides an effective surface for biocompatibility because large surface area can be served to cell proliferation. Plasma electrolyte oxidation (PEO) enables control in the chemical composition, porous structure, and thickness of the TiO2 layer on Ti surface. Silicon (Si) in particular has been found to be essential for normal bone and cartilage growth and development. Zinc (Zn) plays very important roles in bone formation and immune system regulation, and is also the most abundant trace element in bone. The objective of this work was to study on electrochemical behaviors of PEO-treated Ti-6Al-4V Alloy in solution containing Zn and Si ions. The morphology, the chemical composition, and the microstructure analysis of the sample were examined using FE-SEM, EDS, and XRD. The potentiodynamic polarization and AC impedance tests for corrosion behaviors were carried out in 0.9% NaCl solution at similar body temperature using a potentiostat. The promising results successfully demonstrated the immense potential of Si/Zn-TiO2 coatings in dental and biomaterials applications.

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