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Preparation of Silica Nanoparticles via Two-Step Process Utilizing Mixed Chlorosilane Residues

  • Su, Yonghong;Xu, Bugang;Cai, Jixiang;Chen, Liang;Huang, Bing
    • Journal of the Korean Ceramic Society
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    • v.55 no.6
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    • pp.562-569
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    • 2018
  • We propose an economic and facile method for the preparation of silica nanoparticles through a two-step process utilizing chlorosilane residues. Mixed chlorosilane residue was alcoholized with absolute ethanol as a first step to form tetraethoxysilane (TEOS). The TEOS was then utilized as a silicon source to synthesize silica nanoparticles in a sol-gel method. The alcoholysis process was designed and optimized utilizing the Taguchi experimental design method and the yield of TEOS was as high as 82.2% under optimal synthetic conditions. Similarly, the Taguchi method was also utilized to study the effects of synthesis factors on the particle size of silica nanoparticles. The results of statistical analysis indicate that the concentration of ammonia has a greater influence on particle size compared to the mass fractions of TEOS and polyethylene glycol (4.6% and 9.7%). The purity of the silica particles synthesized in our experiments is high, but the specific surface area and pore volume are small.

Electrical Charateristics of Step-down Piezoelectric Transformer

  • Shin Hoonbum;Ahn HyungKeun;Han Deuk-Young
    • Proceedings of the KIPE Conference
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    • 2001.10a
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    • pp.47-51
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    • 2001
  • In this paper, we have explained electrical characteristics of a step-down Rosen type piezoelectric transformer for AC-adapter. When the electric voltage is applied to the driving piezoelectric vibrator polarized in the longitudinal direction, then output voltage is generated at the generating piezoelectric vibrator polarized in the thickness direction due to the piezoelectric effects. From the piezoelectric direct and converse effects, symbolic expressions between the electric inputs and outputs of the step-down piezoelectric transformer have derived with an equivalent circuit model. With the symbolic expressions, load and frequency characteristics have discussed through simulation. Output voltage and current from a 11-layered and a 13-layered piezoelectric transformers were measured under the various conditions of loads and frequencies. First we measured resonant frequency from impedance curve and got equivalent impedance value of the piezoelectric transformer from admittance plot. It was shown from experiments that output voltage has increased and resonant frequency has changed according to various resistor loads. Output current has decreased inversely proportional to changing of loads. Moreover, the measured values of output voltage and current are well agreed with the simulated values of the proposed equivalent circuit model.

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Comparison of the Estimation-Before-Modeling Technique with the Parameter Estimation Method Using the Extended Kalman Filter in the Estimation of Manoeuvring Derivatives of a Ship (선박 조종미계수 식별 시 모델링 전 추정기법과 확장 Kalman 필터에 의한 계수추정법의 비교에 관한 연구)

  • 윤현규;이기표
    • Journal of the Society of Naval Architects of Korea
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    • v.40 no.5
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    • pp.43-52
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    • 2003
  • Two methods which estimate manoeuvring derivatives in the model of hydrodynamic force and moment acting on a manoeuvring ship using sea trial data were compared. One is the widely used parameter estimation method by using the Extended Kalman Filter (EKF), which estimates state variables of linearized state space model at every instant after dealing with the coefficients as the augmented state variables. The other one is the Estimation-Before-Modeling (EBM) technique, so called the two-step method. In the first step, hydrodynamic force of which dynamic model is assumed the third-order Gauss-Markov process is estimated along with motion variables by the EKF and the modified Bryson-Frazier smoother. Then, in the next step, manoeuvring derivatives are identified through the regression analysis. If the exact structure of hydrodynamic force could be known, which was an ideal case, the EKF method would be regarded as being more superior compared to the EBM technique. However the EBM technique was more robust than the EKF method from a realistic point of view where the assumed model structure was slightly different from the real one.

A Study on a Compensation of Decoded Video Quality and an Enhancement of Encoding Speed

  • Sir, Jaechul;Yoon, Sungkyu;Lim, Younghwan
    • Journal of the Korea Computer Graphics Society
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    • v.6 no.3
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    • pp.35-40
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    • 2000
  • There are two problems in H.26X compression technique. One is compressing time in encoding process and the other is degradation of the decoded video quality due to high compression rate. For transferring moving pictures in real-time, it is required to adopt massively high compression. In this case, there are a lot of losses of an original video data and that results in degradation of quality. Especially degradation called by blocking artifact may be produced. The blocking artifact effect is produced by DCT-based coding techniques because they operate without considering correlation between pixels in block boundaries. So it represents discontinuity between adjacent blocks. This paper describes methods of quality compensation for H.26x decoded data and enhancing encoding speed for real-time operation. Our goal of the quality compensation is not to make the decoded video identical to a original video but to make it perceived better through human eyes. We suggest an algorithm that reduces block artifact and clears decoded video in decoder. To enhance encoding speed, we adopt new four-step search algorithm. As shown in the experimental result, the quality compensation provides better video quality because of reducing blocking artifact. And then new four-step search algorithm with $MMX^{TM}$ implementation improves encoding speed from 2.5 fps to 17 fps.

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Variation of Residual Welding Stresses in Incoloy 908 Conduit during the Jacketing of Superconducting Cables

  • Lee, Ho-Jin;Kim, Ki-Baik;Nam, Hyun-Il
    • Progress in Superconductivity and Cryogenics
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    • v.5 no.1
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    • pp.71-75
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    • 2003
  • The conduit fer superconducting cable is welded and plastically deformed during the jacketing process to make the CICC (Cable-in-Conduit-Conductors) fer a fusion magnet. The jacketing process of KSTAR (Korea Superconducting Tokamak Advanced Research) conductors is composed of several sequential steps such as rounding, welding, sizing, and square-rolling. Since the welded zone in Incoloy 908 conduit is brittle and easy to have flaws, there may be a possibility of stress corrosion cracking during the heat treatment of coil when both the induced tensile residual stress and the concentration of oxygen in the furnace are sufficiently high. The steps of the jacketing process were simulated using the finite element method of the commercial ABAQUS code, and the stress distribution in the conduit in each step was calculated, respectively. Furthermore, the variations of residual welding stresses through the steps of the jacketing process were calculated and analyzed to anticipate the possibility of the stress corrosion cracking in the conduit. The concentrated high tensile residual welding stresses along the welding bead decrease by the plastic deformation of the following sizing step. The distribution in residual stresses in the conductor for magnet coil is mainly governed by the last step of square-rolling.

Phosphorylation of Elongation Factor-2 And Activity Of Ca2+/Calmodulin-Dependent Protein Kinase III During The Cell Cycle

  • Suh, Kyong-Hoon
    • BMB Reports
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    • v.33 no.2
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    • pp.103-111
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    • 2000
  • Phosphorylation of the eukaryotic elongation factor 2 (eEF-2) blocks the elongation step of translation and stops overall protein synthesis. Although the overall rate of protein synthesis in mitosis reduces to 20% of that in S phase, it is unclear how the protein translation procedure is regulated during the cell cycle, especially in the stage of peptide elongation. To delineate the regulation of the elongation step through eEF-2 function, the changes in phosphorylation of eEF-2, and in activity of corresponding $Ca^{2+}$/calmodulin (CaM)-dependent protein kinase III (CaMK-III) during the cell cycle of NIH 3T3 cells, were determined. The in vivo level of phosphorylated eEF-2 showed an 80% and 40% increase in the cells arrested at G1 and M, respectively. The activity of CaMK-III also changed in a similar pattern, more than a 2-fold increase when arrested at G1 and M. The activity change of the kinase during one turn of the cell cycle also demonstrated the activation at G1 and M phases. The activity change of cAMP-dependent protein kinase (PKA) was reciprocal to that of CaMK-III. These results indicated: (1) the activity of CaMK-III was cell cycle-dependent and (2) the level of eEF-2 phosphorylation followed the kinase activity change. Therefore, the elongation step of protein synthesis might be cell cycle dependently regulated.

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Identification of First-order Plus Dead Time Model from Step Response Using HS Algorithm (HS 알고리즘을 이용한 계단응답으로부터 FOPDT 모델 인식)

  • Lee, Tae-Bong
    • Journal of Advanced Navigation Technology
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    • v.19 no.6
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    • pp.636-642
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    • 2015
  • This paper presents an application of heuristic harmony search (HS) optimization algorithm for the identification of linear continuous time-delay system from step response. Identification model is first-order plus dead time (FOPDT), which describes a linear monotonic process quite well in most chemical processes and HAVC process and is often sufficient for PID controller tuning. This recently developed HS algorithm is conceptualized using the musical process of searching for a perfect state of harmony. It uses a stochastic random search instead of a gradient search so that derivative information is unnecessary. The effectiveness of the identification method has been demonstrated through a number of simulation examples.

High Gain Soft switching Bi-directional Converter for Eco-friendly Vehicle HDC (친환경 자동차 HDC를 위한 고승압 소프트스위칭 양방향 컨버터)

  • Oh, Se-Cheol;Park, Jun-Sung;Kwon, Min-Ho;Choi, Se-Wan
    • The Transactions of the Korean Institute of Power Electronics
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    • v.17 no.4
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    • pp.322-329
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    • 2012
  • This paper proposes a non-isolated bidirectional soft-switching converter with high voltage for high step-up/down and high power applications. Compared to the conventional boost converter the proposed converter can achieve approximately doubled voltage gain using the same duty cycle. The voltage ratings of the switch and diode are reduced to half, which result in the use of devices with lower $R_{DS(ON)}$ and on drop leading to reduced conduction losses. Also, voltage ratings of the passive components are reduced, and therefore the total energy volume is reduced to half. Further, the switch is turned on with ZVS in the CCM operation which results in negligible surge caused leading to reduced switching losses. The validity of the proposed converter is proved through a 10kW prototype.

Detection and Location of Cable Fault Using Improved SSTDR (개선된 SSTDR을 이용한 케이블 고장 검출과 위치 계산)

  • Jeon, Jeong-Chay;Kim, Jae-Jin;Choi, Myeong-Il
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.9
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    • pp.1583-1589
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    • 2016
  • This paper proposes an improved spread spectrum time domain reflectometry (ISSTDR) using time-frequency correlation and reference signal elimination method in order to have more accurate fault determination and location detection than conventional (SSTDR) despite increased signal attenuation due to the long distance to cable fault location. The proposed method has a two-step process: the first step is to detect a peak location of the reference signal using time-frequency correlation analysis, and the second step is to detect a peak location of the correlation coefficient of the reflected signal by removing the reference signal. The proposed method was validated through comparison with existing SSTDR methods in open-and short-circuit fault detection experiments of low voltage power cables. The experimental results showed that the proposed method can detect correlation coefficients at fault locations accurately despite reflected signal attenuation so that cable faults can be detected more accurately and clearly in comparison to existing methods.

A research on the tunnel insulator pollution characteristic in Korea Railroad (철도 터널구간 애자류 오염도 분석에 관한 연구)

  • Jeon, Yong-Joo;Lee, Tea-Hoon;Choi, Kyoung-Il;Lee, Shi-Bin;Han, Sang-Gil
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1169_1170
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    • 2009
  • This paper introduces insulator pollutant accumulate pattern in the tunnel of korea railroad. To accomplish this goal, effective sample collecting method was proposed for the first step. Dust at the surface was collected directly. Distilled water and brush was used while collecting. Through this method dust is easily and accurately collected. The second step is pollutant analysis. Several analyze item is selected such as quantity, conductivity, contact angle, Optical Microscope(OM), IR, Equivalent Salt Deposit Density(ESDD), and ICP-AES. The third step, best represent tunnel was selected considering location, length and natural surroundings. Also to consider the difference at inside the tunnel, several bracket insulators were selected along to the location. To make the result precise, above procedure was repeated several times at the same target. Finally relation among type of train, numbers of movement, surroundings, length will be considered in combination with the pollution. With this result pollute map for KORAIL could be accomplished and inspect period will be optimized case by case.

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