• Title/Summary/Keyword: Thin Face

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Oxide perovskite crystals type ABCO4:application and growth

  • Pajaczkowska, A.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06a
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    • pp.258-292
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    • 1996
  • In the last year great interest appears to YBCO thin films preparation on different substrate materials. Preparation of epitaxial film is a very difficult problem. There are many requirements to substrate materials that must be fullfilled. Main problems are lattice mismatch (misfit) and similarity of structure. From paper [1] or follows that difference in interatomic distances and angles of substrate and film is mire important problem than similarity of structure. In this work we present interatomic distances and angle relations between substrate materials belonging to ABCO4 group (where A-Sr or Ca, B-rare earth element, C-Al or Ga) of different orientations and YBCO thin films. There are many materials used as substrates for HTsC thin films. ABCO4 group of compounds is characterized by small dielectric constants (it is necessary for microwave applications of HTsC films), absence of twins and small misfit [2]. There most interesting compounds CaNdAlO4, SrLaAlO4 and SrLaGaO4 were investigated. All these compounds are of pseudo-perovskite structure with space group 14/mmm. This structure is very similar to structure of YBCO. SLG substrate has the lowest misfit (0.3%) and dielectric constant. For preparation of then films of substrates of this group of compound plane of <100> orientation are mainly used. Good quality films of <001> orientations are obtained [3]. In this case not only a-a misfit play role, but c-3b misfit is very important too. Sometimes, for preparation of thin films substrates of <001> and <110> orientations were manufactured [3]. Different misfits for different YBCO faces have been analyzed. It has been found that the mismatching factor for (100) face is very similar to that for (001) face so there is possibility of preparation of thin films on both orientations. SrLaAlO4(SLA) and SrLaGaO4(SLG) crystals of general formula ABCO4 have been grown by the Czochralski method. The quality of SLA and SLG crystals strongly depends on axial gradient of temperature and growth and rotation rates. High quality crystals were obtained at axial gradient of temperature near crystal-melt interface lower than 50℃/cm, growth rate 1-3 mm/h and the rotation rate changing from 10-20pm[4]. Strong anisotropy in morphology of SLA and SLG single crystals grown by the Czochralski method is clearly visible. On the basics of our considerations for ABCO4 type of the tetragonal crystals there can appear {001}, {101}, and {110} faces for ionic type model [5]. Morphology of these crystals depend on ionic-covalent character of bonding and crystal growth parameters. Point defects are observed in crystals and they are reflected in color changes (colorless, yellow, green). Point defects are detected in directions perpendicular to oxide planes and are connected with instability of oxygen position in lattice. To investigate facets formations crystals were doped with Cr3+, Er3+, Pr3+, Ba2+. Chromium greater size ion which is substituted for Al3+ clearly induces faceting. There appear easy {110} faces and SLA crystals crack even then the amount of Cr is below 0.3at.% SLG single crystals are not so sensitive to the content of chromium ions. It was also found that if {110} face appears at the beginning of growth process the crystal changes its color on the plane {110} but it happens only on the shoulder part. The projection of {110} face has a great amount of oxygen positions which can be easy defected. Pure and doped SLA and SLG crystals measured by EPR in the<110> direction show more intensive lines than in other directions which allows to suggest that the amount of oxygen defects on the {110} plane is higher. In order to find the origin of colors and their relation with the crystal stability, a set of SLA and SLG crystals were investigated using optical spectroscopy. The colored samples exhibit an absorption band stretching from the UV absorption edge of the crystal, from about 240 nm to about 550 m. In the case of colorless sample, the absorption spectrum consists of a relatively weak band in the UV region. The spectral position and intensities of absorption bands of SLA are typical for imperfection similar to color centers which may be created in most of oxide crystals by UV and X-radiation. It is pointed out that crystal growth process of polycomponent oxide crystals by Czochralski method depends on the preparation of melt and its stoichiometry, orientation of seed, gradient of temperature at crystal-melt interface, parameters of growth (rotation and pulling rate) and control of red-ox atmosphere during seeding and growth (rotation and pulling rate) and control of red-ox atmosphere during seeding and growth. Growth parameters have an influence on the morphology of crystal-melt interface, type and concentration of defects.

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Initial growth mode of ultra-thin Al films on a W(110) surface at high temperatures

  • Choi, Dae Sun;Park, Mi Mi
    • Applied Science and Convergence Technology
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    • v.24 no.6
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    • pp.228-231
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    • 2015
  • We investigated the adsorption structures and the initial growth mode of ultra-thin Al films on a W(110) surface at a high temperature. When Al atoms were adsorbed on the W(110) at the substrate temperature of 1100 K and with coverage of 0.5ML, Al atoms formed a p($2{\times}1$) double-domain structure. When the coverage was 1.0 ML, the double domain of a hexagonal structure (fcc(111) face) rotated ${\pm}5^{\circ}$ from the [100] direction of the W(110) surface and another distorted hexagonal structure were found. Low-energy electron diffraction results along with ion scattering spectroscopy results showed that the Al atoms followed the Volmer-Weber growth mode at a high temperature.

Studios on the Thin Rubber Coated Fabrics. (part 3) Physical properties of the Surface and Back Coated Fabrics with Rubber (박막(薄膜) Rubber Coated Fabrics에 관(關)한 연구(硏究) (제3보(第3報)) 각종(各種) 원반(原反)에 천연(天然) 및 합성(合成)고무를 양면(兩面) 도포(塗布)했을 때의 물리적성능(物理的性能)에 대(對)하여)

  • Kim, Joon-Soo;Lee, Myung-Whan;Yum, Hong-Chan;Lee, Chin-Bum;Rhim, Kwang-Kew
    • Elastomers and Composites
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    • v.2 no.1
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    • pp.31-36
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    • 1967
  • As a series of the studies of thin rubber coated fabrics, the experiments were concentrated on the investigation of the physical properties of the surface and back coated fabrics with natural and synthetic rubber. Cotton poplin and nine other cotton shootings were used as a base fabric and both sides of fabric, face and back, were coated by means of topping or spreading process. The physical properties of finished material were broadly investigated especially in view of the quality requirements of the poncho.

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A Study of Permanent Form System by Thin Precast Concrete Panel (박판 프리캐스트 콘크리트 영구거푸집 시스템 연구(I))

  • 정문영;남기룡;서치호;김윤일
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.04a
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    • pp.451-459
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    • 1997
  • Current domestic building market is in the face of a tise in construction cost as a result of labor cost and materials problems, so improvements for productivity are doing their best for finding a way out of the difficulties. But the most of technical of from work is just considered the basic role and shape. As for environment protection, the utilization of waste concrete is important. But many of studies were interesting on the resource recycling for structural concrete. The purpose of this study is the development of thin precast form using recycled aggregate and the assembling systems for permanent form by cast-in-place.

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Duplication of Koryo Tripitaka (Taejang′kyong) by Copper Electroforming (전주공정을 이용한 팔만대장경 동판제작)

  • 김인곤;강경봉;이재근;오명현
    • Journal of the Korean institute of surface engineering
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    • v.37 no.1
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    • pp.22-27
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    • 2004
  • Copper electroforming process has been applied to duplicate Koryo Tripitaka (Taejang'kyong), wooden printing block. Thin copper replica printing plates of 1 mm thickness was successfully manufactured from the printing face (54.5${\times}$25.5 cm) of wooden printing plate. Major processes are (1) silicon rubber replication of the master (2) silvering on silicon rubber (3) copper electroforming (4) separation of copper from the silicon mandrel (5) final coloring by brass plating and trimming. This process has various Potential applications in making thin metallic objects such as plaques, statues, bust and hollow metal objects for jewelry.

Improvement of CMP and Cleaning Process of Large Size OLED LTPS Thin Film Using Oscar Type Polisher (Oscar형 연마기를 이용한 대면적 OLED용 LTPS 박막의 CMP 처리 및 세정 공정 개선)

  • Shim, Gowoon;Lee, Hyuntaek;Song, Jongkook
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.4
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    • pp.71-76
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    • 2022
  • We evaluated and developed a 6th generation large-size polisher in the type of face-up and Oscar. We removed the hillocks of the low temperature poly-silicon (LTPS) thin film with this polisher. The surface roughness of LTPS was lowered from 7.9 nm to 0.6 nm after CMP(chemical mechanical polishing). The thickness of the LTPS is measured through reflectance in real time during polishing, and the polishing process is completed according to this thickness. The within glass non-uniformity (WIGNU) was 6.2% and the glass-to-glass non-uniformity (GTGNU) was 2.5%, targeting the LTPS thickness of 400Å. In addition, the residual slurry after the CMP process was removed through the Core Flow PVA Brush and alkaline chemical.

Development of an Optical Waveguide Loss Measuring System using an Rectangular Glass Probe

  • Choi, Young-Kyu
    • Journal of Sensor Science and Technology
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    • v.10 no.1
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    • pp.71-79
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    • 2001
  • The use of a glass-plate probe of rectangular shape is proposed for the measurement of transmission loss in optical waveguides. The light-collecting window is of a thin, rectangular shape and is perpendicular to the light streak, while the conventional fiberglass probe has a small circular face. This transversely elongated form results in a grate improvement of mechanical tolerance for the probe movement in the vortical as well as in the transverse direction. A theoretical investigation also presents a reasonable agreement with the experiments.

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Structural and Morphological Changes of Co Nanoparticles and Au-10at.%Pd Thin Film Studied by in Situ Heating in a Transmission Electron Microscope

  • Ji, Yoon-Beom;Park, Hyun Soon
    • Applied Microscopy
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    • v.47 no.3
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    • pp.208-213
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    • 2017
  • The microstructural changes in Co nanoparticles and an Au-10at.%Pd thin film have been investigated using an in situ heating holder with a micro-electro-mechanical system (MEMS). In Co nanoparticles, two phases (face-centered cubic and hexagonal close-packed crystal structures) were found to coexist at room temperature and microstructures at temperatures, higher than $1,000^{\circ}C$, were observed with a quick response time and significant stability. The actual temperature of each specimen was directly estimated from the changes in the lattice spacing (Bragg-peak separation). For the Au-10at.%Pd thin film, at a set temperature of $680^{\circ}C$, the actual temperature of the sample was estimated to be $1,020^{\circ}C{\pm}123^{\circ}C$. Note that the specimen temperature should be carefully evaluated because of the undesired effects, i.e., the temperature non-uniformity due to the sample design of the MEMS chip, and distortion due to thermal expansion.

Development of zirconia hair cutter for biocompability (생체친화형 지르코니아 헤어커터 개발)

  • Kim, Jeong-Sik;Kim, Kwang-Hee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.6
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    • pp.2612-2617
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    • 2013
  • This study aims to develop hair cutter with zirconia($ZrO_2$) material whose machinability, corrosion resistance, wear resistance and bio-compatibility are excellent by comparing iron hair cutter. Ultra-thin zirconia cutter with the thickness of 0.253mm is manufactured through the optimization of design, molding, sintering, grinding and grinding process. With observation result of cutter specimen by use of scanning electron microscope(SEM), formability and process of cutting face are shown to be good. It is also evaluated with sufficient merchantability by cutting test results. The cutter process technology of thin zirconia can be utilized at the development of high value-added beauty appliances like razor, beauty-razor and eye brows-razor for woman by use of study result.

Improved interfacial stress analysis of a plated beam

  • Hao, Sheng-Wang;Liu, Yan;Liu, Xiao-Dan
    • Structural Engineering and Mechanics
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    • v.44 no.6
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    • pp.815-837
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    • 2012
  • A plated beam is strengthened by bonding a thin plate to the tension face; it often fails because of premature debonding of the thin plate from the original beam in a brittle manner. A sound understanding of the mechanism of such debonding failure is very important for the effective use of this strengthening technique. This paper presents an improved analytical solution for interfacial stresses that incorporates multiple loading conditions simultaneously, including prestress, mechanical and thermal loads, and the effects of adherend shear deformations and curvature mismatches between the beam and the plate. Simply supported beams bonded with a thin prestressing plate and subjected to both mechanical and thermal loading were considered in the present work. The effects of the curvature mismatch and adherend shear deformations of the beam and plate were investigated and compared. The main mechanisms affecting the distribution of interfacial stresses were analyzed. Both the normal and shear stresses were found to be significantly influenced by the coupled effects of the elastic moduli with the ratios $E_a/E_b$ and $E_a/E_p$.