• Title/Summary/Keyword: Thickness effect

Search Result 6,567, Processing Time 0.046 seconds

Double-layered Polymer Electrolyte Membrane based on Sulfonated Poly(aryl ether sulfone)s for Direct Methanol Fuel Cells (직접 메탄올 연료전지용 술폰화 폴리아릴에테르술폰 이중층 고분자 전해질 막의 제조 및 특성)

  • Hong, Young-Taik;Ko, Ha-Na;Park, Ji-Young;Choi, Jun-Kyu;Kim, Sang-Un;Kim, Hyung-Joong
    • Membrane Journal
    • /
    • v.19 no.4
    • /
    • pp.291-301
    • /
    • 2009
  • Double-layered polymer electrolyte membranes were prepared from two different sulfonated poly(aryl ether sulfone) copolymers by the two-step solution casting method for direct methanol fuel cells (DMFC). Sulfonation degrees were adjusted 10% (SPAES-10) and 50% (SPAES-50) by controlling monomer ratios, and the weight ratios of SPAES-10 copolymer were varied in the range of 5~20% to investigate the effect of thickness of coating layers on the membranes. Proton conducting layers were fabricated from SPAES-50 solutions of N-methyl-2-pyrrolidone (NMP) by a solution casting technique, and coating layers formed on the semiliquid surface of the conducting layer by pouring of SPAES-10-NMP solutions onto. It was found that double-layered polymer electrolyte membrane could significantly reduce the methanol crossover through the membrane and maintain high proton conductivities being comparable to single-layered SPAES-50 membrane. The maximum power density of membrane-electrolyte assembly (MEA) at the condition of $60^{\circ}C$ and 2 M methanol-air was $134.01\;mW/cm^2$ for the membrane prepared in the 5 wt-% of SPAES-10 copolymer, and it was corresponding to the 105.5% of the performance of the commercial Nafion 115 membrane.

Thermal Stability of Ti-Si-N as a Diffusion Barrier (Cu와 Si간의 확산방지막으로서의 Ti-Si-N에 관한 연구)

  • O, Jun-Hwan;Lee, Jong-Mu
    • Korean Journal of Materials Research
    • /
    • v.11 no.3
    • /
    • pp.215-220
    • /
    • 2001
  • Amorphous Ti-Si-N films of approximately 200 and 650 thickness were reactively sputtered on Si wafers using a dc magnetron sputtering system at various $N_2$/Ar flow ratios. Their barrier properties between Cu (750 ) and Si were investigated by using sheet resistance measurements, XRD, SEM, RBS, and AES depth profiling focused on the effect of the nitrogen content in Ti-Si-N thin film on the Ti-Si-N barrier properties. As the nitrogen content increases, first the failure temperature tends to increase up to 46 % and then decrease. Barrier failure seems to occur by the diffusion of Cu into the Si substrate to form Cu$_3$Si, since no other X- ray diffraction intensity peak (for example, that for titanium silicide) than Cu and Cu$_3$Si Peaks appears up to 80$0^{\circ}C$. The optimal composition of Ti-Si-N in this study is $Ti_{29}$Si$_{25}$N$_{46}$. The failure temperatures of the $Ti_{29}$Si$_{25}$N$_{465}$ barrier layers 200 and 650 thick are 650 and $700^{\circ}C$, respectively.ely.

  • PDF

Development of EM Wave Absorber for Increasing Communication Range in RFID System (RFID 시스템의 통신 거리 증대를 위한 전파흡수체 개발)

  • Park, Soo-Hoon;Kim, Dong-Il;Yoon, Sang-Gil;Yoo, Gun-Suk;Jeong, In-Seong
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
    • /
    • v.20 no.3
    • /
    • pp.222-229
    • /
    • 2009
  • In this paper, we designed and fabricated the EM wave absorbers for preventing the reduction of the communication range when RFID Tag is approached to a metal plate. The EM wave absorber samples were fabricated with difference composition ratios of Amorphous metal powder and CPE, the absorption abilities of which were simulated by substituting different thicknesses of the EM wave absorbers. Then the EM wave absorbers are manufactured based on the simulated results. By using the EM wave absorbers, we have confirmed the improvement effect of RFID tag antenna and the increase of communication range of RFID system. As a result, it was cleary shown that the communication range of RFID system is improved by adopting the EM wave absorber with the composition ratio of Amorphous metal powder:CPE=80:20 wt.% and the thickness of 4 mm. Thus, it was confirmed that the proposed EM wave absorber can increase the communication range of RFID system from 0.8 m to 5.2 m in UHF band.

Healing Effects of Ginsenoside Rg1 on Experimental Open Wound in Rat (흰쥐의 외과적 창상에 대한 Ginsenoside Rg1의 치료효과)

  • Lim, Ae-Kyoung;Kim, Kil-Soo;Park, Su-Jung;Hong, Joo-Heon;Choi, Hyang-Ja;Kim, Dae-Ik
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.39 no.10
    • /
    • pp.1452-1458
    • /
    • 2010
  • This study was performed to investigate the effect of ginsenoside Rg1 treatment on wound healing using SD rats by generating four full-thickness skin wounds on the dorsum. In the Rg1-treated groups (5,000 and 10,000 ppm), area of wounds and macroscopic inflammatory signs were significantly decreased compared to control group throughout the experimental period in a concentration dependent manner. Histological appearance after 20 days of treatment with Rg1 revealed the formation of epithelial layer, hair follicles and progressive angiogenesis and an increase in collagen and granulation as compared to control group. Rg1 treatment resulted in the increased expression of the vascular endothelial growth factor (VEGF) mRNA and reduced expression of transforming growth factor beta (TGF-$\beta$) mRNA in wounded skin compared to control group. The expression levels of VEGF and TGF-$\beta$ mRNA in the Rg1-treated groups were similar to those of Fucidin(R) ointment-treated group. These results suggested that Rg1 should be helpful for the promotion of wound healing.

Finite Element Analysis for the Contact Stress of Ultra-high Molecular Weight Polyethylene in Total Knee Arthroplasty (전 슬관절 치환 성형술에 사용되는 초고분자량 폴리에틸렌 삽입물의 접촉응력에 관한 유한요소해석)

  • Jo, Cheol-Hyeong;Choe, Jae-Bong;Choe, Gwi-Won;Yun, Gang-Seop;Gang, Seung-Baek
    • Journal of Biomedical Engineering Research
    • /
    • v.20 no.1
    • /
    • pp.37-44
    • /
    • 1999
  • Because of bone resorption, wear of ultra-high molecular weight polyethylene(UHMWPE) in total knee arthroplasty has been recognized as a major factor in long-term failure of knee implant. The surface damage and the following harmful wear debris of UHMWPE is largely related to contact stress. Most of the previous studies focused on the contact condition only at the articulating surface of UHMWPE. Recently, contact stress at the metal-backing interface has been implicated as one of major factors in UHMWPE wear. Therefore, the purpose of the is study is to investigate the effect of the contact stress for different thickness, conformity friction coefficient, and flexion degree of the UHMWPE component in total knee system, considering the contact conditions at both interfaces. In this study, a two-dimensional non-linear plane strain finite element model was developed. The results showed that the maximum value of von-Mises stress occurred below the articulating surface and the contact stress was lower for the more conforming models. All-polyethylene component showed lower stress distribution than the metal-backed component. With increased friction coefficient on the tibiofemoral contact surface, the maximum shear stress increased about twofold.

  • PDF

Beneficial Effect of Collagen Peptide Supplement on Anti-aging Against Photodamage (콜라겐 펩타이드의 피부 광노화 예방 효과)

  • Kim, Jeong-Kee;Lee, Ji-Hae;Yang, Mi-Sook;Seo, Dae-Bang;Lee, Sang-Jun
    • Korean Journal of Food Science and Technology
    • /
    • v.41 no.4
    • /
    • pp.441-445
    • /
    • 2009
  • Recent research has revealed that hydrolyzed collagen peptides have beneficial effects in various diseases such as osteoarthritis and human rheumatoid arthritis and also play a protective role in skin by improving the activity of antioxidants. In this study, we investigated the effects of a novel mixture (AP-CPM01) containing collagen peptides and elastin peptides on photoaged hairless mice skin both in vivo and in vitro. To evaluate the effects of AP-CPM01 on UVBinduced skin wrinkle formation in vivo, the hairless mice were exposed to UVB irradiation and orally administered the AP-CPM01 at 333 mg/kg per day for 10 weeks. The effects on skin appearance and epidermal thickness were measured using bioengineering and histochemical methods. In addition, the influence of AP-CPM01 on collagen metabolism in human skin fibroblasts was also investigated. The skin of mice in the AP-CPM01 treated group had better appearance and less wrinkling than that of mice in the control group. In the human fibroblast cells, the amount of de novo procollagen synthesis was increased after AP-CPM01 treatment, reflecting that AP-CPM01 can induce de novo procollagen synthesis and reduce UVB-induced skin wrinkle formation. These results suggest that AP-CPM01 is a potent candidate for antiphotoaging functions.

Effect of Reflow Number and Surface Finish on the High Speed Shear Properties of Sn-Ag-Cu Lead-free Solder Bump (리플로우 횟수와 표면처리에 따른 Sn-Ag-Cu계 무연 솔더 범프의 고속전단 특성평가)

  • Jang, Im-Nam;Park, Jai-Hyun;Ahn, Yong-Sik
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.16 no.3
    • /
    • pp.11-17
    • /
    • 2009
  • The drop impact reliability comes to be important for evaluation of the life time of mobile electronic products such as cellular phone. The drop impact reliability of solder joint is generally affected by the kinds of pad and reflow number, therefore, the reliability evaluation is needed. Drop impact test proposed by JEDEC has been used as a standard method, however, which requires high cost and long time. The drop impact reliability can be indirectly evaluated by using high speed shear test of solder joints. Solder joints formed on 3 kinds of surface finishes OSP (Organic Solderability Preservation), ENIG (Electroless Nickel Immersion Gold) and ENEPIG (Electroless Nickel Electroless Palladium Immersion Gold) was investigated. The shear strength was analysed with the morphology change of intermetallic compound (IMC) layer according to reflow number. The layer thickness of IMC was increased with the increase of reflow number, which resulted in the decrease of the high speed shear strength and impact energy. The order of the high speed shear strength and impact energy was ENEPIG > ENIG > OSP after the 1st reflow, and ENEPIG > OSP > ENIG after 8th reflow.

  • PDF

Assesment of Zeolite, Montmorillonite, and Steel Slag for Interrupting Heavy Metals Release from Contaminated Marine Sediments for Capping Thickness of Reactive materials (오염된 해양퇴적물에서 중금속 용출 차단을 위한 제올라이트, 몬모릴로나이트, 제강슬래그의 적용성 평가)

  • Kang, Ku;Kim, Young-Kee;Park, Seong-Jik
    • Journal of Navigation and Port Research
    • /
    • v.39 no.4
    • /
    • pp.335-344
    • /
    • 2015
  • This study aims to assess the effectiveness of zeolite, montmorillonite, and steel slag as capping materials to block the release of heavy metals from marine sediment depending on their depths. The results showed that all capping materials used this study were not effective in interrupting release of As. Zeolite had negative effect on the block of Cr release but it was significantly reduced to 5 cm by montmorillonite capping. In contrast to As and Cr, Cd, Ni, and Pb were not released even from uncapped sediments. Cu and Zn were the heavy metals those were most significantly influenced by the capping conditions. Cu release from marine sediments were effectively blocked by more than 1 cm depth of montmorillonite and more than 3 cm depth of zeolite. All capping materials were found to be effective in interrupting release of Zn from marine sediments. It was concluded that the zeolite, montmorillonite, and steel slag could be used as a potential capping material for interrupting the release of Cr, Cu, and Zn from the contaminated marine sediments.

The Changes of Depositional Landforms in the Downstream Reach of Cha-Cheon (차천(車川) 하류 구간의 퇴적지형 변화)

  • Yu, Tai-Il
    • Journal of the Korean association of regional geographers
    • /
    • v.12 no.3
    • /
    • pp.352-363
    • /
    • 2006
  • The purpose of this paper is to analyze changes in the depositional landform in the channel of Cha-cheon, a branch stream of Nakdong river(main stream) since the artificial straight channel has been constructed in 1973. The results of analyses are as follow. First, the Cha-cheon has flooded over one time in a year, and flowed backward over three times annually, according to analyze the data of the Hyeonpoong Gauging Station of rainfall and water level during a decade(1993$\sim$2002). Second, the flood plain within the artificial straightened channel has a nearly plain profile between the small dike and last riffle(point A). Deposits thickness of flood plain reduce gradually toward upstream. Third, grain size distribution of the flood plain deposits(0$\sim$20cm) within the artificial straightened channel has a coarsening trend in downstream reach of C point. It implies that the backward flow of Nakdong river(the main stream of Cha-cheon) make effect on the depositional mechanism of lowest reach in Cha-cheon. Finally, the result of analyzing grain size distribution of the flood plain deposits(0$\sim$20cm) within the artificial straightened channel implies that the c-point is the boundary between the vertical deposition of suspended load due to the backward flow of Nakdong river and the deposition of bed load supplied from hillslope of Cha-cheon basin.

  • PDF

The Properties and Production of Hand-Made Paper Made from Various Plant Fibers (식물섬유 수초지의 제조와 물성에 대한 연구)

  • Lee, Hye-Ja;Lim, Hee-Jung;Bae, Hyun-Young;Mo, Tae-Wha;Yoo, Hye-Ja;Han, Young-Sook
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.32 no.9
    • /
    • pp.1366-1375
    • /
    • 2008
  • This studies were carried out in order to develope environmentally-friendly fiber materials and substitute resources of Paper mulberry. Various plant fibers such as New Zealand flax, Indian mallow, Kuzu vine and Yucca were used as raw materials of hand-made papers. We rotted these 4 kinds of plant fibers and removed non-cellulose. After rotting, the pulping rate(%) and the length of fibers in pulps were measured. The physical characteristics of papers made of various plants fiber were investigated and the probabilities of practical use were considered. The results were as follow: The non-cellulose contents of plant fibers were $30{\sim}40%$ and those contents must be lower down to 8% to be able to manufacture the hand made papers. The lignin in pulps were removed almost and the hemicellulose were partially removed to reach up to appropriate level of the pulp rates and fiber lengths. The more hemicellulose removed, the finer fiber thickness were and rapidly the lower Hanji tensile strength were. But the tear strength of these plants of hand-made papers do not decreased so much as tensile strength. So the property of 4 types of plant fibers might be of great advantages to make hand-made papers. Both tensile and tear strengths of Hanji of New Zealand flax, Indian mallow, Kuzu vine and Yucca were higher than Paper mulberry hand-made paper. When 30% of mulberry paper were mixed, the mixing effect showed maximum. Because of the functions of all plant fiber hand-made papers showed better than those of Paper mulberry hand-made paper, 4 types of plant fibers could be substitute Paper mulberry.