• Applied Chemistry for Engineering
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• v.30 no.1
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• pp.81-87
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• 2019

In this study, synthetic methods and physical properties for a new class of glycidyl azide polymer (GAP) were investigated for energetic thermoplastic elastomers (ETPE). Four kinds of GAP copolymer polyols were synthesized by introducing nucleophiles such as azide, alkoxide and alkyl amine into poly(epichlorohydrin) (PECH). The GAP copolymer synthetic reaction can be evaluated as an environmental benign and efficient synthetic method due to the simultaneous one-step reaction using two kinds of nucleophiles and the complete consumption of sodium azide. The relative stoichiometric substitution ratio analysis and the progress of reaction were checked and monitored by inverse gated decoupled $^{13}C$ NMR and Fourier transform infrared (FT-IR) spectroscopy. The glass transition temperature and molecular weight were measured by differential scanning calorimetry (DSC) and gel permeation chromatography (GPC) analysis. The synthesized poly($GA_{0.8}-butoxide_{0.2}$), poly($GA_{0.7}-n-butylamine_{0.3}$), poly($GA_{0.7}-dipropylamine_{0.3}$) and poly($GA_{0.7}-morpholine_{0.3}$) had a glass transition temperature ranged from -39 to $-26^{\circ}C$.

• Journal of Welding and Joining
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• v.16 no.2
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• pp.48-56
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• 1998

This study was performed to find the best bonding conditions by comparing mechanical properties in thermoplastic resin of polyethylene (PE) and polyamide (PA) adhesion. Following results were obtained from the tests with varying welding time and welding pressure. Satisfactory adhesion was executed in ultrasonic welding for the same materials of PE and PA. The best welding conditions were found to be welding time of 1 second, welding pressure of 250kPa for PE-PE weding, 2 second and 350kPa for PA-PA welding. Welding time and welding pressure end to increase with the increase of materials strength. Dissimilar materials were adhered when adhesion and ultrasonc welding were performed simultaneously. The observation of the structure of ultrasonic welding area with microscope showed differenticated structures between well adhered region and badly adhered region.

• Macromolecular Research
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• v.10 no.6
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• pp.365-368
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• 2002

Thermoplastic polyurethanes (TPUs) with different hard segment length has been prepared from a fixed molar ratio of poly(tetramethylene ether glycol), 4,4'-diphenylmethane diisocyanate, and 1,4-butanediol by different polymerization procedures. Results reveal that the on-set temperature of endotherms ( $T_{cc}$ ) due to the crystallization of hard segments by cooling the TPUs from melt and the peak temperature of endotherms due to the melting of hard segments ( $T_{mh}$ ) by heating the TPUs increased and levelled off with increasing the hard segment length of TPUs. It has also been observed that soft segment glass transition temperature ( $T_{gs}$ ) of TPU decreased slightly with increasing the hard segment length, which explains less mixing of soft segments and hard segments. In tensile measurement of TPUs, strain hardening is observed with increasing the hard segment length, which is attributed to the strain induced crystallization of soft segments.

• Korea-Australia Rheology Journal
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• v.12 no.1
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• pp.77-81
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• 2000

Rheological behavior of thermoset/thermoplastic blends of epoxy/polyethersulphone (PES) was monitored during curing of the epoxy resin. During the isothermal curing of the mixture, a fluctuation in viscosity just before the abrupt viscosity increase was observed. This fluctuation is found to be due to the phase separation of PES from the matrix epoxy resin during the curing. The experimentally observed viscosity fluctuation is simulated with a simple two phase suspension model in terms of the increase in domain size. The viscosity profiles obtained experimentally at different isothermal curing temperatures are in good agreement with the predictions from the simple model taking into account the viscosity change due to the growth of PES domain and the network formation of the epoxy matrix.

• Carbon letters
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• v.5 no.1
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• pp.1-5
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• 2004

The effects of fiber surface-treatment and sizing on the dynamic mechanical properties of unidirectional and 2-directional carbon fiber/nylon 6 composites by means of dynamic mechanical analysis have been investigated in the present study. The interlaminar shear strengths of 2-directional carbon/nylon 6 composites sized with various thermosetting and thermoplastic resins are also measured using a short-beam shear test method. The result suggests that different surface-treatment levels onto carbon fibers may influence the storage modulus and tan ${\delta}$ behavior of carbon/nylon 6 composites, reflecting somewhat change of the stiffness and the interfacial adhesion of the composites. Dynamic mechanical analysis and short-beam shear test results indicate that appropriate use of a sizing material upon carbon fiber composite processing may contribute to enhancing the interfacial and/or interlaminar properties of woven carbon fabric/nylon 6 composites, depending on their resin characteristics and processing temperature.

• Composites Research
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• v.29 no.5
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• pp.243-248
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• 2016

Although thermoset carbon fiber composite bipolar plates not only have high mechanical properties but also high corrosion resistance in acid environment, high manufacturing cost and low bulk electrical conductivity are the biggest obstacle to overcome. In this research, thermoplastic polymer is employed for the matrix of carbon composite bipolar plate to increase both the manufacturing productivity and bulk electric conductivity of the bipolar plate. In order to increase the electrical conductivity and strength, plain type carbon fabric rather than chopped or unidirectional fibers is used. Also nano particles are embedded in the thermoplastic matrix to increase the bulk resistance of the bipolar plate. The area specific resistance and the mechanical strength of the developed bipolar plate are measured with respect to the environmental temperature and stack compaction pressure.

• Composites Research
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• v.37 no.2
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• pp.68-75
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• 2024

Polypropylene (PP), a thermoplastic resin with excellent mechanical, thermal, chemical, and water resistance properties, has been attracting attention due to its economic efficiency and recyclability. However, repeated processing of thermoplastic resins can lead to property degradation, and the point at which quality degradation occurs varies depending on the processing conditions. In this study, we evaluated the performance changes of composite materials with repeated processing by blending PP resin with various additives and conducting extrusion and injection processes repeatedly. In addition, we evaluated the mechanical properties of composite materials to evaluate the effect of MFI value change during repeated processing on fiber impregnation in composite material processing.

• Journal of the Korean Society of Visualization
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• v.5 no.1
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• pp.3-8
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• 2007

We present simple methods for fabricating high aspect-ratio polymer nanostructures on a solid substrate by rigiflex lithography with tailored capillarity and adhesive force. In the first method, a thin, thermoplastic polymer film was prepared by spin coating on a substrate and the temperature was raised above the polymer's glass transition temperature ($T_g$) while in conformal contact with a poly(urethane acrylate) (PUA) mold having nano-cavities. Consequently, capillarity forces the polymer film to rise into the void space of the mold, resulting in nanostructures with an aspect ratio of ${\sim}4$. In the second method, very high aspect-ratio (>20) nanohairs were fabricated by elongating the pre-formed nanostructures upon removal of the mold with the aid of tailored capillarity and adhesive force at the mold/polymer interface. Finally, these two methods were further used to fabricate micro/nano hierarchical structures by sequential application of the molding process for mimicking nature's functional surfaces such as a lotus leaf and gecko foot hairs.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2004.10a
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• pp.88-91
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• 2004

In this study, a number of natural fiber henequen reinforced polymer matrix composites were successfully fabricated by means of a compression molding technique using chopped henequen fibers surface-treated with different electron beam irradiation (EBI) dosages, thermoplastic poly(butylene succinate), thermosetting unsaturated polyester and phenolic resins. Their interfacial and thermal characteristics were studied in terms of interfacial shear strength, fracture surface, dynamic mechanical properties, dimensional stability, and thermal stability using single fiber microbonding test, SEM, DMA, TMA, and TGA. The results show that their interfacial and thermal properties significantly depend on the intensity of EBl treatment on the natural fiber surface.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.23 no.2
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• pp.127-132
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• 2014

Micro/nano-injection molding is one of the main processing techniques for polymer micro-fabrication. Most of the difficulties encountered in polymer micro-molding are caused by the demolding, rather than the filling of molds. Therefore, studying the demolding process is vitally important for manufacturing polymer replicas. The most important parameters are the thermal stress, friction and adhesion forces, and mechanical strength of the resist. In this research, we determinedthe effects of the processing conditions on the ejection force for cases involving two common thermoplastic polymers. The results showed that the processing conditions noticeably influenced the ejection force.