• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.23 no.2
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• pp.161-167
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• 2009

Organic insulating materials which are utilized as insulating materials for the low voltage show unique carbonization characteristics when they are carbonized by a leakage current. Therefore the use of the carbonization characteristics makes it possible to examine the electrical fire which is caused by a leakage current flowing on the surface of the organic insulating material. In order to understand such carbonization characteristics, in this paper, experiments have been done to carbonize typical organic insulating materials such as phenol resin, PVC, and acrylic resin, and the carbonization patterns and the IR absorption spectrum of specimens have been analyzed. According to the analysis of the carbonization patterns, the phenol resin shows the so-called 'spider-leg' carbonization pattern due to a thermosetting property. In contrast to the phenol resin, the thermoplastic property makes it difficult to observe a clear carbonization pattern to verify carbonizing causes on the surfaces of PVC and acrylic resins. In this case, the IR absorption spectrum can be analyzed to examine the specimen carbonized by a leakage current. The analysis result shows that absorption peaks appear at the wave numbers of $3,400[cm^{-1}]$ and $1,618[cm^{-1}]$, which can be an important factor to verify the carbonizing causes.

• Macromolecular Research
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• v.17 no.10
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• pp.739-745
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• 2009

N,N'-(bicyclo[2,2,2]oct-7-ene-tetracarboxylic)-bis-L-amino acids 3a-g were synthesized by the condensation reaction of bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic dianhydride 1 with two equimolars of Lalanine 2a, L-valine 2b, L-leucine 2c, L-isoleucine 2d, L-phenyl alanine 2e, L-2-aminobutyric acid 2f and L-histidine 2g in an acetic acid solution. Seven new poly(amide-imide)s PAIs 5a-g were synthesized through the direct polycondensation reaction of seven chiral N,N'-(bicyclo[2,2,2]oct-7-ene-tetracarboxylic)-bis-L-amino acids 3a-g with bis(3-amino phenyl) phenyl phosphine oxide 4 by two different methods: direct polycondensation in a medium consisting of N-methyl-2-pyrrolidone (NMP)/triphenyl phosphite (TPP)/calcium chloride ($CaCl_2$/pyridine (py), and direct polycondensation in a tosyl chloride (TsCl)/pyridine (py)/N,N-dimethylformamide (DMF) system. The polymerization reaction produced a series of flame-retardant and thermally stable poly(amide-imide)s 5a-g with high yield. The resulted polymers were fully characterized by FTIR, $^1H$ NMR spectroscopy, elemental analyses, inherent viscosity, specific rotation and solubility tests. Data obtained by thermal analysis (TGA and DTG) revealed that the good thermal stability of these polymers. These polymers can be potentially utilized in flame retardant thermoplastic materials.

• Composites Research
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• v.31 no.3
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• pp.83-87
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• 2018

An object in the Low Earth Orbit (LEO) is affected by many environmental conditions unlike earth's surface such as, Atomic oxygen (AO), Ultraviolet Radiation (UV), thermal cycling, High Vacuum and Micrometeoroids and Orbital Debris (MMOD) impacts. The effect of all these parameters have to be carefully considered when designing a space structure, as it could be very critical for a space mission. Polybenzimidazole (PBI) is a high performance thermoplastic polymer that could be a suitable material for space missions because of its excellent resistance to these environmental factors. A thin coating of PBI polymer on the carbon epoxy composite laminate (referred as CFRP) was found to improve the energy absorption capability of the laminate in event of a hypervelocity impact. However, the overall efficiency of the shield also depends on other factors like placement and orientation of the laminates, standoff distances and the number of shielding layers. This paper studies the effectiveness of using a PBI coating on the front bumper in a multi-shock shield design for enhanced hypervelocity impact resistance. A thin PBI coating of 43 micron was observed to improve the shielding efficiency of the CFRP laminate by 22.06% when exposed to LEO environment conditions in a simulation chamber. To study the effectiveness of PBI coating in a hypervelocity impact situation, experiments were conducted on the CFRP and the PBI coated CFRP laminates with projectile velocities between 2.2 to 3.2 km/s. It was observed that the mass loss of the CFRP laminates decreased 7% when coated by a thin layer of PBI. However, the study of mass loss and damage area on a witness plate showed CFRP case to have better shielding efficiency than PBI coated CFRP laminate case. Therefore, it is recommended that PBI coating on the front bumper is not so effective in improving the overall hypervelocity impact resistance of the space structure.

• Composites Research
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• v.14 no.1
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• pp.1-7
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• 2001

In this study, damage evaluation of glass fiber reinforced thermoplastic composites was investigated with acoustic emission method. Specimens of 1.7mm thickness laminate were made from PET and 7 layers o171ass fabrics. Notch and impact loading were added to the specimen and normal tensile test and tensile test with the dead load were carried out. AE signal was measured as the functions of notch ratio to the width0 and impact energy in order to find out the correlation between fracture mode and AE parameters. The result has shown that low amplitude of AE signal was due to the microcrack of matrix and its growth, whereas the amplitude in the mid range was the response to the delamination and interfacial separation. In the range of high amplitude above 90dB. the fracture of glass fabric was found. Tensile strength decreased with increasing notch ratio to the width and impact energy because of tile effect or delamination, the cracking of matrix and stress concentration. In proportion to the size of damaged area. AE signal showed its wider range of frequency and energy as well as increased number of hits.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2002.05a
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• pp.227-234
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• 2002

With the increasing environmental consideration and stricter regulations, gasification of waste is considered to be more attractive technology than conventional incineration for energy recovery as well as material recycling. The experiment for combustible waste mixed with plastic and cellulosic materials was performed in the fixed bed gasifier to investigate the gasification behavior with the operating conditions. Waste pelletized with a diameter of 2~3cm and 5cm of length was gasified at the temperature range of 1100~145$0^{\circ}C$. It was shown that the composition of H$_2$ was in the range of 30~40% and CO 15~30% depending upon oxygen/waste ratio. Casification of waste due to thermoplastic property from mixed plastic melting and thermal cracking shows a prominent difference from that of coal or coke. It was desirable to maintain the top temperature up to foot to ensure the mass transfer and uniform reaction through the packed bed. As the bed height was increased, the formation of H$_2$ and CO was increased whilst $CO_2$ decreased by the char-$CO_2$ reaction and plastic cracking. From the experimental results, the cold gas efficiency was around 61% and heating values of product gases were in the range of 2800~3200㎉/Nm3.

• Composites Research
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• v.12 no.4
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• pp.55-61
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• 1999

Interfacial shear strength (IFSS) of poly(arylene ether phosphine oxide) (PEPO) coated carbon fibers was evaluated via microdroplet test and compared with results obtained from carbon fibers coated with poly(arylene ether sulfone) (PES), Udel$^{\circledR}$ P-1700 and Ultem$^{\circledR}$ 1000. Interfacial adhesion between thermoplastics and uncoated carbon fibers was also measured in order to understand the adheion mechanism. PEPO coated carbon fibers showed the highest IFSS, followed by PES, Udel and Ultem coated fibers. A similar trend was observed for thermoplastic/uncoated fibers. SEM analysis indicated that only PEPO coated fiber exhibited cohesie failure in the vinylester resin, while others showed failure at or near the interface of polymer coating and vinylester resin. The enhanced interfacial adhesion by PEPO coating could be attributed to the strong interaction of P = 0 moiety to the fiber as well as to the vinylester resin.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2012.03a
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• pp.18-18
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• 2012

전 세계적으로 이산화탄소 배출량 저잠을 위해 모든 산업분야에서 연구개발의 중점을 두고 있다. 그의 일환으로 자동차 산업에서는 EU규제에 따라 리사이클이 가능한 소재 개발이 요구되고 있으며, 그중 많은 양이 사용되고 있는 PU Foam의 대체 재료 개발이 시급한 실정이다. 기존 자동차의 흡음재로 주로 사용되고 있는 PU Foam 소재는 통기성이 부족할 뿐만 아니라 연소 시 인체에 유해한 HCN Gas를 발생시키고, 한번 성형된 부품은 Recycle 및 Re-Use가 불가능하다는 단점이 있다. 또한 장시간 사용시 황변 발생과 악취가 발생하는 등으로 최근 대두되고 있는 자동차 내장재 감성품질 향상 측면에 한계를 나타내고 있다. 이러한 Low Melting 성능을 가지는 PET 부직포 소재의 한계를 극복하기 위하여 저융점 성능의 Elastic Fiber의 개발과 함께 고탄성 복합부직포 소재의 개발을 통해 높은 변형률과 우수한 복원력을 나타내는 환경친화형 열가소성 탄성체(Thermoplastic Elastomer) 개발을 추진하고 있다. 고탄성 복합부직포는 자동차 내장재 성형 시 열을 가하더라도 Elastomer 자체의 탄성 발현을 통해 초기의 Bulky성을 유지할 수 있으며, Recycle 및 Re-use가 가능하여 환경 친화적인 측면에서도 큰 장점을 갖고 있다. 자동차용 흡음 내장재뿐만 아니라 각종 수송용 차량의 경량화 및 쾌적성 향상을 위한 용도로써 자동차 내장용 PU Foam의 57% 이상을 차지하고 있는 Seat Cushion재 등의 대체가 가능하며, 다양한 산업분야에서 사용되고 있는 PU Foam의 대체로 다양한 용도 전개가 가능할 것으로 예상된다. 본 연구에서는 PU Foam의 대체 재료로 각광받고 있는 Elastic PET를 개발하여 자동차 내장재로의 적용 가능성을 검토하였다.

• Particle and aerosol research
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• v.12 no.3
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• pp.51-56
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• 2016

Due to recent development in nanotechnology and increasing usage and production of nanomaterials, numerous studies related to environment, sanitation and safety handling of nanoparticle are being conducted. Since nanoparticles can be easily absorbed into human bodies through breathing process, based on their toxic substances and their large specific surface, these particles can cause serious health damage. Therefore, to reduce nanoparticle emissions, nanofiltration technology is becoming a serious issue. Filtration is a separation process during which a fluid passes through a barrier by removing the particles from the stream. Barrier filters can be made of various materials and shapes. One of the most common type of barrier filter is the fibrous filter. Fibrous filters are divided in two types: nonwoven and woven fabrics. Polypropylene is a thermoplastic material, used as a base material for melt blown nonwoven fabric. In this study, we examined filtration property of KCl nanoparticles with a mean particle diameter of 75 nm using multilayer meltblown filter samples. These experiments verify that the penetration of nanoparticle in the filter correlate with pressure drop; the meltblown layer MB1 has the greatest effect on dust collection efficiency of the filter. Among all tested samples, dust collection efficiency of 2-layer filter was best. However, when considering the overall pressure drop and dust collection efficiency, the 4-layer filter has the highest quality factor for particles smaller than 70 nm.

• Fashion & Textile Research Journal
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• v.15 no.2
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• pp.294-301
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• 2013

Sustainable fashion & textile is more than eco fashion & textile with the concepts for the next generation's happiness, prosumer value, and community responsibility. This study considers methods to enhance fashion and textile industry sustainability in accordance to clothing types (material, product life and washing properties) and to investigate company strategies. Company strategies are of redesign with stock, volunteering & measuring trash amount, participation by evaluation stores, clerk environment education, hiring QC specialist and reinforcing partnerships. For the case of daily innerwear, throwing away and recycling is more efficient for the environment than laundering in the consumer use stage; subsequently, we recommend the use of polypropylene fiber (a cheap and an eco-friendly material) for this item that can be recycled and reformed after use. For the case of single layer clothing (such as sportswear, blouse or pants) we recommend the use of thermoplastic materials with welding or fuse assembling technology instead of a sewing method of seams as well as the recycle design that is simply melted and reformed into new clothing without an after use dissembling process. Secondhand use or resale is suitable for denim/jean items if the clothing has a storytelling or private history tag. Lastly, module-type jacket or coat shows the variety of styles with one clothing worn w/o collar or sleeve details and changed into vest/coat; in addition, it is possible to add or partly tear off some jacket/coat fibers of the felt material to reform it into a new design.

• Composites Research
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• v.28 no.5
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• pp.249-253
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• 2015

This paper reports a study on a method for achieving lightweight thermoplastic laminate composites referred to as tow spreading technology. Thickness of an unspread 12 K carbon fiber tow is reduced by increasing the tow width from 7 mm to 20 mm. The polypropylene (PP) film was used to stabilize and impregnate the spread tow, covering it into a partially consolidated prepreg: 12 K carbon fiber spread tow/PP. Laminates were fabricated from the spread tow prepreg and control laminate composites were produced from unspread tow prepreg consisting of 12 K carbon fiber and PP. The void content, tensile and flexural properties of the composite laminates were investigated. Consequently, the spread tow laminate composite exhibited lower void content and improved mechanical properties.