• 대한화학회지
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• 제55권5호
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• pp.835-841
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• 2011

Corrosion inhibition of mild steel by nevirapine, an antiretroviral has been investigated using potentiodynamic polarization, electrochemical impedance spectroscopy technique and weight loss methods. The experimental results suggested, nevirapine is a good corrosion inhibitor for mild steel in 1M hydrochloric acid medium and the inhibition efficiency increased with increase in inhibitor concentration. The kinetic parameters for corrosion process and thermodynamic parameters for adsorption process were calculated and discussed. The adsorption of the inhibitor on the surface of mild steel followed Langmuir adsorption isotherm.

• Journal of Oral Medicine and Pain
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• 제25권1호
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• pp.9-28
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• 2000

The purpose of this article, the first part of series, is to describe the general theory applicable to various chromatographic procedures. History of chromatography, separation of matters, classification of chromatography, underlying principles of separation in chromatography, covering resolution, column efficiency, column selectivity, and capacity factor, movement of solute in chromatographic phase, including elution development, displacement development, and frontal analysis, were discussed. Mathematical description of plate theory and thermodynamic viewpoint of retention were emphasized.

• 오토저널
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• 제3권3호
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• pp.49-57
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• 1981

A cycle simulation of 4 cycle spark ignition engine using methanol-water blend as a fuel has been developed for study of prediction of power, specific fuel consumption, mean effective pressure and thermal efficiency. One-dimensional flow model for intake process and thermodynamic model for combustion process were selected. After, performance test was made with conventional engine which was modified in consideration of fuel properties. And computational results by simulation have been compared with experimental results. As the agreement between computational and experimental results was good, prediction of engine performance by was possible.

• 품질경영학회지
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• 제12권1호
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• pp.31-34
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• 1984

The industrial sector is the largest energy consumer, accounting for 44% of the total energy consumption of Korea in 1981. Energy conservation in the industrial processes is one of the most important strategies to the energy conservation to the nation. This paper introduces principles of energy conservation which is the maximum thermodynamic efficiency in energy use. Two important factors considered are how much heat is available and how good is the heat available (the quality of energy).

• Bulletin of the Korean Chemical Society
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• 제16권5호
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• pp.454-458
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• 1995

Inhibiting action of semicarbazide, thiosemicarbazide, sym. diphenylcarbazide towards corrosion of zinc in hydrochloric acid has been investigated. The rate of corrosion depends on the nature of the inhibitor and its concentration. The values of inhibition efficiency from, weight loss, thermometric measurements are in good agreement with those obtained from polarization studies. From the polarization studies, the inhibitors used act as mixed absorption type inhibitors, increased adsorption resulting from an increase in the electron density at the reactive C=S and C=O groups and N-atoms. The thermodynamic parameters of adsorption obtained using Bockris-Swinkels adsorption isotherm reveal a strong interaction of these carbazides on zinc surface.

• 한국재료학회지
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• 제28권2호
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• pp.75-81
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• 2018

An ultra-high temperature ceramic, tantalum carbide, has received much attention for its favorable characteristics: a superior melting point and chemical compatibility with carbon and other carbides. One drawback is the high temperature erosion of carbon/carbon (C/C) composites. To address this drawback, we deposited TaC on C/C with silicon carbide as an intermediate layer. Prior to the TaC deposition, the $TaCl_5-C_3H_6-H_2$ system was thermodynamically analyzed with FactSage 6.2 and compared with the $TaCl_5-CH_4-H_2$ system. The results confirmed that the $TaCl_5-C_3H_6-H_2$ system had a more realistic cost and deposition efficiency than $TaCl_5-CH_4-H_2$. A dense and uniform TaC layer was successfully deposited under conditions of Ta/C = 0.5, $1200^{\circ}C$ and 100 torr. This study verified that the thermodynamic analysis is appropriate as a guide and prerequisite for carbide deposition.

• 에너지공학
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• 제23권1호
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• pp.75-80
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• 2014

지난 최근 몇 년 동안 내연기관 엔진의 여러 가지 타입의 성능, 효율, 배기가스 특성을 잘 설명해 줄 수 있는 흥미있는 수학적인 모델이 다양하게 제시되고 있다. 이러한 다양한 양상의 엔진 작동의 모의실험에 있어서 주요한 요소가 엔진 연소 과정의 모델이다. 연소모델은 주로 세 가지 분류로 세분화 되어지고 있다. 즉, 제로 차원적, 유사 차원적, 다차원 모델로 나눌 수 있다. 제로 차원모델은 열역학 제1법칙에 근거하여 만들어졌고, 시간은 단지 독립 변수이다. 본 연구는 제로 차원 모델에 의하여 스파크 점화 기관의 연소 특성을 제시하려는 그 목적이 있다.

• 한국수소및신에너지학회논문집
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• 제5권2호
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• pp.91-98
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• 1994

In this study hydrogen gas and oxygen gas are used to make a pollution-free engine which is a closed system with the components such as a combustor, two turbines, a radiator and a compressor. One of the two turbines produces main power, and the other is used to drive a compressor to compress unburned gases and to return them to the combustor. Some of the water from the radiator is pumped to cool down the internal wall of the combustor and to be used as a working fluid which expands from liquid state to vapor state to get more expansion work. The possibility of operating the whole system is checked by the thermodynamic analysis to make the closed engine system. The calculations in the thermal analysis are based on the Brayton cycle and the Rankine cycle. The closed system in this study shows similar efficiency as usual internal combustion engines, but it produces water only without air pollution such as $NO_x$ and soot.

• 한국수소및신에너지학회논문집
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• 제25권2호
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• pp.200-208
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• 2014

This paper presents thermodynamic performance analysis of organic Rankine cycle (ORC) using low temperature heat source in the form of sensible energy and using liquefied natural gas (LNG) as heat sink to recover the cryogenic energy of LNG. LNG is able to condense the working fluid at a very low condensing temperature in a heat exchanger, which leads to an increased power output. Based on the mathematical model, a parametric analysis is conducted to examine the effects of eight different working fluids, the turbine inlet pressure and the condensation temperature on the system performance. The results indicate that the thermodynamic performance of ORC such as net work production or thermal efficiency can be significantly improved by the LNG cold energy.

• 대한설비공학회지:설비저널
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• 제33권3호
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• pp.50-57
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• 2004

This article reviews absorption cooling R＆D in Europe from the viewpoint of fundamentals, cycle development and applications. The review contains information on R＆D, predominantly of public projects in the field of sorption cooling. We report on research which is performed in Europe with some stress on Germany. There is progress in fundamentals, thermodynamic cycle design, and also applications. In the fundamentals part the discussion about thermodynamics, working pairs, and heat and mass transfer is reflected. Today's discussion on thermodynamic cycles is not very strong. Main focus is on special solid sorption cycles, compression­sorption hybrids, and open cycles, In the applications part the chilling business is the main issue. Some interest is given to the improvement of efficiency on and the adaptation to low temperature waste heat use, but the stress is on the use of solar energy as heat source. The area of heat pumping for heating purposes is less prominent but not at all negligible. Finally, industrial heat pumping involves the reverse cycle (heat transformer, heat pump type Ⅱ) also, but there is no significant activity.