• Title/Summary/Keyword: Thermally stimulated current

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Effects of copolymer on electrical conduction characters in polythylene (폴리에틸렌의 도전특성에 미치는 공중합의 영향)

  • 이규철;이종호;류근민
    • Electrical & Electronic Materials
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    • v.4 no.1
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    • pp.12-18
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    • 1991
  • 각종 monomer를 공중합시킨 고분자 필름의 X선 유기 TSC(thermally-stimulated current)를 측정하고 polyethylene(PE)의 절연성능 개선의 관점에서 공중합 monomer의 영향에 대하여 검토하였다. PE의 X선 유기 TSC 피이크는 결정화도가 높을 수록 고온측으로 이동하였다. X선 유기 TSC에서 피이크는 공중합에 의하여 Br 및 F원자가 0.2~0.4eV의 전자 trap이 도입된 것으로 생각된다.

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A Study on the Calculation of Escape Frequency Factor using TSC Equation (열자격전류식을 이용한 이탈주파수인자 계산에 관한 연구)

  • 김기준;김상진;전동근
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.11a
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    • pp.135-138
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    • 1995
  • This paper presents a method to calculate the escape frequency factor and its verification from TSC(Thermally Stimulated Current) equation and cures. To apply calculation method of ν using asymptotic estimation, it utilized two sets of TSC data with 1K interval. This method enables one to get the exact value of ν and activation energy at the same time by using computer programming. So, it regards their calculation method as a useful process to obtain the value of physical behavior.

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A effect on the high field conduction and carrier traps in polythylene (폴리에틸렌의 고전계 전기전도 및 캐리어 트랩에 미치는 공중합의 효과)

  • 유근민;이종호;이규철
    • Electrical & Electronic Materials
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    • v.6 no.1
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    • pp.50-54
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    • 1993
  • 각종 monomer를 공중합시킨 PE의 고전계 전기전도와 X선 유기 TSC(X-ray induced thermally stimulated current)를 측정하고 공중합 monomer의 영향에 대하여 검토하였다. 할로겐을 함유한 공중합 PE에서 고전계 전기전도가 억제되는 것을 관찰하였다. 또 할로겐을 함유하는 monomer를 공중합시킨 PE의 X선 유기 TSC에서는 공중합에 의한 전자 trap은 약 0.4eV정도로 평가된다. 이들 시료에서 절연 파괴 강도가 상승한 것은 전자 트랩이 전자의 전계가속을 억제하여 고전계 전기전도를 억제시키고 절연파괴강도를 향상 시킨 것으로 추측된다.

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Pyroelectricity of Drawn Poly(vinylidenefluoride) Films

  • 조재환;김상용
    • Proceedings of the Korean Fiber Society Conference
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    • 1988.06a
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    • pp.34-34
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    • 1988
  • The pyroelectricity of poly(vinylidenefluoride) films prepared by varying the draw ratio and the poling field was investigated. As the draw ratio and the electric field on poling of the drawn samples increased, so did the pyroelectric coefficient. But the effect of electric field on the pyroelectricity was greater than that of draw ratio. The pyroelectric and piezoelectric activities could be explained by the polarization using the thermally stimulated current. The relation between pyroelectric coefficient and piezoelectric stress constant showed a good linearity.

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Numerical Analysis of Thermally stimulated current of Ionic Space charge Polarijation by Hopping Model (Hopping 모델에 의한 이온 공간전하분극 숙련재전류의 수치해석)

  • 김의균;국상훈
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1990.10a
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    • pp.91-94
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    • 1990
  • The behavior of charged particle in dielectrics have a many effects on characteristics of the insulating materials. In this paper, numerical analysis method by hopping model was investigated application of TSC. As the results, there was a difference between characteristics of TSC by dipole polarization. Physical constant of movable ion corresponding to the experimental results was evaluated and also. Numerical calculations of unsaturated TSC and I-V characteristics were carried out by was of hopping model.

Optimization Technique for Forming Electret Using Finite Element Method (유한요소법을 이용한 일렉트렛트 형성의 최적화 기법)

  • Park, Geon-Ho
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2019.07a
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    • pp.337-338
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    • 2019
  • 본 연구에서는 열자격전류의 측정을 통해 얻은 데이터를 유한요소법을 이용하여 일렉트렛트 형성에 깊은 관련이 있는 대전 과정에 관한 시뮬레이션을 수행하였는데, 전극의 에지효과로 인한 전계의 집중 현상을 확인하였고 일렉트렛트의 불균일한 대전 상태 여부를 검증한 후 최적 설계를 도출하여 각종 센서재료의 적용에 기여할 것으로 사료된다.

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The Effect of Single Wall Carbon Nanotubes on the Dipole Orientation and Piezoelectric Properties of Polymeric Nanocomposites

  • Kang, Jin-Ho;Park, Cheol;Gaik Steven J.;Lowther Sharon E.;Harrison Joycelyn S.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.245-245
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    • 2006
  • Recent studies of single wall carbon nanotube (SWNT)/polyimide nanocomposites indicate that these materials have a potential to provide the combination of structural integrity and sensing/actuation capability. This study shows the effect of the SWNT type and concentration on the dipole orientation and piezoelectric properties of the electroactive polymide nanocomposites using a thermally stimulated current (TSC) spectroscopy. These nanocomposites exhibit very thermally stable piezoelectric properties up to $150^{\circ}C$. This presentation will highlight the dipole orientation and electroactive characteristics of the SWNT/polyimide nanocomposites and discuss their potential multifunctional aerospace applications.

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The Characteristics of Termally Stimulated Current for Epoxy Composites : The effects of Curing Agents and Fillers (에폭시 복합재료의 열자격전류(TSC) 특성: - 경화제와 충진제의 영향)

  • Wang, Jong-Bae;Park, Jun-Bum;Lee, Joon-Ung;Kim, Hong-Chul
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.1162-1164
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    • 1993
  • The Thermally Stimulated Current(TSC) spectroscopy has been applied to study the influence of the structual cahange and interface on the electrical properties of epoxy composites. Three DGEBA-MeTHPA matrix model samples mixed different ratios and silica($SiO_2$) filled sample and silaln treating-filled sample has been studied. Above room temperature, the relaxation mode $\alpha$ peak associated with Tg has been located at $110^{\circ}C$. Below glass transition temperature(Tg), three relaxation modes are observed in all samples: a $\beta$ mode situated at $10^{\circ}C$, a $\gamma$ mode located at $-40^{\circ}C$ and a $\delta$ mode appeared in $-120^{\circ}C$. The analysis of its fine structure indicates that constitution of elementary processes is characterized by the activation energy and relaxation time. Also the dielectric relaxation properties have been investigated to compare the the change of the molecular structure and motion to the relaxation properties and conduction mechanism in TSC spectra.

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A study on the Electrical Properties of Polypropylene Film (폴리플로필렌 박막의 전기적 특성에 관한 연구)

  • Lee, Joon-Ung;Kim, Wang-Kon;Kim, Bong-Heup
    • Elastomers and Composites
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    • v.21 no.2
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    • pp.121-128
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    • 1986
  • Studies has been carried out on the characteristics of thermally stimulated current for polypropylene in the temperature range of $293[^{\circ}K]{\sim}403[^{\circ}K]$. The main peak observed at $366[^{\circ}K]$, as may be $\beta$ peak in conventional nomination, is believed to be depolarization current originated from the relaxation of "CO" group in monomer structure. The activation energy for the observed peak has been concluded to be in the range of $0.6{\sim}0.7[(eV]$ at $360[^{\circ}K]$ by the initial rise method. Furthermore, the initial density of carriers were calculated about $10^{22}/m^3$

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The Charge decay characteristics of Polymer surface by Corona discharge (코로나 하전한 고분자의 표면전하감쇄)

  • Lee, B.S.;Kim, Y.B.;Park, J.K.;Kim, J.S.;Lee, J.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1995.07c
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    • pp.1156-1158
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    • 1995
  • Charge decay, thermally stimulated current(TSC), charging and discharging currents(I) are measured for negatively corona-charged polymers. In this study, we will make an experiment in charge decay on polymer surface, TSC, polarity effect and the others in order to analysis it's mechanism. Especially polyvinylidene fluoride(PVDF) film is the best functional material which has been so far. Therefore, It's worthy of notice to investigate it's characteristic. And then some other functional polymers will be focused on. An experimental result was missed out for the shortage of setting. So, this thesis will be explained on the theory and direction of reseach hereafter.

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