• Title/Summary/Keyword: Thermal-degradation

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Evaluation of Radiation Degradation or Crosslinked Polyethylene using TGA (TGA를 이용한 가교폴리에틸렌의 방사선 열화 평가)

  • Lee, Chung;Kim, Ki-Yup;Ryu, Boo-Hyung;Lim, Kee-Joe
    • Journal of the Korean Society of Safety
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    • v.18 no.2
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    • pp.50-55
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    • 2003
  • Radiation degradation of crosslinked polyethylene(XLPE) was investigated using thermogravimetric analysis(TGA), The results of TGA were compared with FT-IR, melting temperature, oxidation induction time, and elongation at break on the XLPE exposed by $\gamma$-ray. 5% decomposition temperature of $\gamma$-ray irradiated XLPE showed similar tendencies with the case of elongation at break. Both properties agreed below 1000 KGy, however, did not show any remarkable characteristics above 1000 kGy, these properties can be useful to evaluate the radiation degradation of XLPE for only low irradiated region. Above 1000 kGy, the thermal decomposition activation energy showed decreased, on the contrary, increasing below 1000 kGy. Compared with FT-IR spectrum of irradiated XLPE, it was confirmed that the oxidation reaction was still occurring below 1000 kGy. Radiation degradation of XLPE was dependent upon the irradiation doses, TGA can be a useful tool to evaluate the degradation.

Effects of Zeolites on Thermal Stability of Poly(vinyl chloride) (폴리염화비닐(PVC)의 열안정성에 제올라이트가 미치는 영향)

  • Xu, Jiayou;Liang, Qinghua;Xian, Xiumei;Li, Kaidan;Liu, Jie
    • Polymer(Korea)
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    • v.39 no.1
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    • pp.1-5
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    • 2015
  • The effects of zeolite on the thermal stability of poly(vinyl chloride) (PVC) were investigated by the static thermal stability test, pyrolysis experiment and ultraviolet spectrum. The results showed that the porous zeolite could absorb hydrogen chloride (HCl), which suppressed the catalysis of HCl on thermal degradation of PVC, thus improved the thermal stability of PVC. The oxidizing acid which was loaded on zeolite had oxidated on the double bond that formed during the dehydrochlorination of PVC. This process could prohibit the growth of the conjugated polyene and improved the color of PVC. Hence, zeolite might be possible to come up with a high performance thermal stabilizer.

A Study on Evaluation of Thermal Shock Damage of Metal Matrix Composite using Ultrasonics (초음파를 이용한 금속복합재료의 열충격 손상 평가 연구)

  • 강문필;이준현
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.04a
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    • pp.31-37
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    • 2000
  • Metal matrix composites(MMCs) are rapidly becoming one of the strongest candidates for structural materials for many high temperature application. Among the high temperature environment, thermal shock is known to cause significant degradation in most MMC system. Therefore, the nondestructive evaluation on thermal shock damage behavior of SiC/A16061 composite has been carried out using ultrasonic surface and SH-waves. For this study, Sic fiber reinforced metal matrix composite specimens fabricated by a squeeze casting technique were thermally cycled in the temperature range 25~$400^{\circ}C$ up to 1000 cycles. Three point bend test was conducted to investigate the effect of thermal shock damage on mechanical properties. The relationship between thermal shock damage behavior and the change of ultrasonic velocity and attenuation were discussed by considering SEM observation of fracture surface.

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THIN-FILM-COATED DETECTORS FOR NEUTRON DETECTION

  • McGregor Douglas S.;Gersch Holly K.;Sanders Jeffrey D.;Klann Raymond T.;Lindsay John T.
    • Journal of Radiation Protection and Research
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    • v.26 no.3
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    • pp.167-175
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    • 2001
  • Semiconductor diode detectors coated with neutron reactive material are presently under investigation for various uses, such as remote sensing of thermal neutrons, fast neutron counting, and thermal neutron radiography. Theory indicates that single-coated devices can yield thermal neutron efficiencies from 4% to 11 %, which is supported by experimental evidence. Radiation endurance measurements indicate that the devices function well up to a limiting thermal neutron fluence of $10^{13}/cm^2$, beyond which noticeable degradation occurs. Thermal neutron contrast images of step wedges and simple phantoms, taken with dual in-line pixel devices, show promise for thermal neutron imaging detectors.

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Thermal Decomposition Energy of Liquid Crystalline Epoxy (열경화성 액정 에폭시 수지의 열분해 활성화에너지)

  • Seung Hyun Cho
    • Composites Research
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    • v.37 no.1
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    • pp.1-6
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    • 2024
  • A liquid crystalline thermosetting epoxy was synthesizes with DGE-DHMS and 1-Methyl Imidazole. To investigate thermal stability, activation energies for thermal decomposition were calculated via Flynn-Wall-Ozawa method and Kissinger method with the data obtained from TGA analysis. The result showed that there were no differences in thermal decomposition behavior between liquid crystalline phases and isotropic phase and also the same thermal decomposition mechanism was applied to the entire process.

Analysis and Improvement of Reliability in IGZO TFT for Next Generation Display

  • Fujii, Mami;Fuyuki, Takashi;Jung, Ji-Sim;Kwon, Jang-Yeon;Uraoka, Yukiharu
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.326-329
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    • 2009
  • We investigated the degradation of $In_2O_3-Ga_2O_3$-ZnO (IGZO) thin-film transistors (TFTs), which is promising device for driving circuits of nextgeneration displays. We performed the electronic stress test by applying gate and drain voltage. We discussed the degradation mechanism by thermal analysis and device simulation.

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Quality Deterioration Suppressing Effects of pH Regulators during Heat Treatment of Concentrated Blueberry Puree (농축 블루베리 퓌레 열처리 시 pH 조절제의 품질 저하 억제 효과)

  • Lee, In Gyeong;Min, Seo Cheol;Kim, Hee Sun;Han, Gwi Jung;Kim, Myung Hwan
    • Korean journal of food and cookery science
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    • v.32 no.5
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    • pp.549-558
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    • 2016
  • Purpose: In this study, we aimed to minimize quality degradation of concentrated blueberry puree by thermal treatment at $90^{\circ}C$ for 5 min, with citric acid (CA) and acidic sodium metaphosphate (ASM) as pH modifiers. Methods: The color values, redness a, anthocyanin contents, DPPH radical scavenging, elastase inhibition and tyrosinase inhibition activities were evaluated for quality parameters of concentrated blueberry puree. Results: The highest values of color value, redness a, anthocyanin contents, DPPH radical scavenging, elastase inhibition and tyrosinase inhibition activities were 1% CA+0.5% ASM followed by 1% CA and control. The quality parameters of concentrated blueberry puree were significantly different between control and 1% CA+0.5% ASM treatment (p<0.05). Conclusion: During thermal treatment, quality degradation of concentrated blueberry puree was reduced by 1% CA+0.5% ASM treatment, which is expected for new acidulants.

Assessment of temperature effect in structural health monitoring with piezoelectric wafer active sensors

  • Kamas, Tuncay;Poddar, Banibrata;Lin, Bin;Yu, Lingyu
    • Smart Structures and Systems
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    • v.16 no.5
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    • pp.835-851
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    • 2015
  • This paper presents theoretical and experimental evaluation of the structural health monitoring (SHM) capability of piezoelectric wafer active sensors (PWAS) at elevated temperatures. This is important because the technologies for structural sensing and monitoring need to account for the thermal effect and compensate for it. Permanently installed PWAS transducers have been One of the extensively employed sensor technologies for in-situ continuous SHM. In this paper, the electro-mechanical impedance spectroscopy (EMIS) method has been utilized as a dynamic descriptor of PWAS behavior and as a high frequency standing wave local modal technique. Another SHM technology utilizes PWAS as far-field transient transducers to excite and detect guided waves propagating through the structure. This paper first presents how the EMIS method is used to qualify and quantify circular PWAS resonators in an increasing temperature environment up to 230 deg C. The piezoelectric material degradation with temperature was investigated and trends of variation with temperature were deduced from experimental measurements. These effects were introduced in a wave propagation simulation software called Wave Form Revealer (WFR). The thermal effects on the substrate material were also considered. Thus, the changes in the propagating guided wave signal at various temperatures could be simulated. The paper ends with summary and conclusions followed by suggestions for further work.