• Title/Summary/Keyword: Thermal-degradation

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Surface properties of epoxy/glass Eber composites by environmental conditions (사용 환경조건에 따른 Epoxy/Glass Fiber 복합재료의 표면특성)

  • 임경범;이백수;황명환;김윤선;유도현;이덕출
    • Journal of the Korean Vacuum Society
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    • v.9 no.3
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    • pp.279-284
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    • 2000
  • In order to analysis the degradation process of epoxy/glass fiber for outdoor condition, FRP laminate was exposed to high temperature and water. Then the degradation process was evaluated by comparing contact angle, surface potential decay, and surface resistivity. For the change of wettability, the contact angle of thermal-treated specimen with the high temperature of $200^{\circ}C$ increased. But that of water-treated specimen decreased. The characteristic of surface potential decay shows the tendency of the remarkable decrease on water-treated specimens, but increase on thermal-treated specimen compared with untreated one. Also, for the surface resistivity, it shows the same trend compared with the change of contact angle.

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Using Lamb Waves to Monitor Moisture Absorption in Thermally Fatigued Composite Laminates

  • Lee, Jaesun;Cho, Younho
    • Journal of the Korean Society for Nondestructive Testing
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    • v.36 no.3
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    • pp.175-180
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    • 2016
  • Nondestructive evaluation for material health monitoring is important in aerospace industries. Composite laminates are exposed to heat cyclic loading and humid environment depending on flight conditions. Cyclic heat loading and moisture absorption may lead to material degradation such as matrix breaking, debonding, and delamination. In this paper, the moisture absorption ratio was investigated by measuring the Lamb wave velocity. The composite laminates were manufactured and subjected to different thermal aging cycles and moisture absorption. For various conditions of these cycles, not only changes in weight and also ultrasonic wave velocity were measured, and the Lamb wave velocity at various levels of moisture on a carbon-epoxy plate was investigated. Results from the experiment show a linear correlation between moisture absorption ratio and Lamb wave velocity at different thermal fatigue stages. The presented method can be applied as an alternative solution in the online monitoring of composite laminate moisture levels in commercial flights.

Changes in physicochemical characteristics of cation exchange resins by high dose gamma irradiation

  • Seung Joo Lim;Wang Kyu Choi;Mansoo Choi
    • Nuclear Engineering and Technology
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    • v.56 no.5
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    • pp.1777-1780
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    • 2024
  • Chemical and thermal characteristics of cation exchange resins were examined after irradiation of gamma rays. The degradation of cation exchange resins was mainly observed at doses of up to 500 kGy, whereas the balance between degradation and cross-linking reactions was sustained at 700 kGy. While the carbon content decreased significantly up to a maximum dose of 500 kGy, it showed an increase at higher doses. Conversely, the oxygen content exhibited a decrease in contrast to the carbon content. The continuous reduction in sulfur content was attributed to the decomposition of sulfonic groups. Gamma-ray irradiation caused a decrease in the initiation temperature of sulfonic groups and PS-DVB, but unlike the chemical properties of cation exchange resins due to gamma-ray irradiation, the thermal properties of resins remained unaffected.

Thermo-Mechanical Reliability of Lead-Free Surface Mount Assemblies for Auto-Mobile Application (무연 솔더가 적용된 자동차 전장부품 접합부의 열적.기계적 신뢰성 평가)

  • Ha, Sang-Su;Kim, Jong-Woong;Chae, Jong-Hyuck;Moon, Won-Chul;Hong, Tae-Hwan;Yoo, Choong-Sik;Moon, Jeong-Hoon;Jung, Seung-Boo
    • Journal of Welding and Joining
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    • v.24 no.6
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    • pp.21-27
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    • 2006
  • This study was focused on the evaluation of the thermo-mechanical board-level reliability of Pb-bearing and Pb-free surface mount assemblies. The composition of Pb-bearing solder was a typical Sn-37Pb and that of Pb-free solder used in this study was a representative Sn-3.0Ag-0.5Cu in mass %. Thermal shock test was chosen for the reliability evaluation of the solder joints. Typical $Cu_6Sn_5$ intermetallic compound (IMC) layer was formed between both solders and Cu lead frame at the as-reflowed state, while a layer of $Cu_3Sn$ was additionally formed between the $Cu_6Sn_5$ and Cu lead frame during the thermal shock testing. Thickness of the IMC layers increased with increasing thermal shock cycles, and this is very similar result with that of isothermal aging study of solder joints. Shear test of the multi layer ceramic capacitor(MLCC) joints was also performed to investigate the degradation of mechanical bonding strength of solder joints during the thermal shock testing. Failure mode of the joints after shear testing revealed that the degradation was mainly due to the excessive growth of the IMC layers during the thermal shock testing.

A Dual Integer Register File Structure for Temperature - Aware Microprocessors (온도 인지 마이크로프로세서를 위한 듀얼 레지스터 파일 구조)

  • Choi, Jin-Hang;Kong, Joon-Ho;Chung, Eui-Young;Chung, Sung-Woo
    • Journal of KIISE:Computer Systems and Theory
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    • v.35 no.12
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    • pp.540-551
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    • 2008
  • Today's microprocessor designs are not free from temperature as well as power consumption. As processor technology scales down, an on-chip circuitry increases power density, which incurs excessive temperature (hotspot) problem. To tackle thermal problems cost-effectively, Dynamic Thermal Management (DTM) has been suggested: DTM techniques have benefits of thermal reliability and cooling cost. However, they require trade-off between thermal control and performance loss. This paper proposes a dual integer register file structure to minimize the performance degradation due to DTM invocations. In on-chip thermal control, the most important functional unit is an integer register file. It is the hotspot unit because of frequent read and write data accesses. The proposed dual integer register file migrates read data accesses by adding an extra register file, thus reduces per-unit dynamic power dissipation. As a result, the proposed structure completely eliminates localized hotspots in the integer register file, resulting in much less performance degradation by average 13.35% (maximum 18%) improvement compared to the conventional DTM architecture.

Performance Evaluation of Selective Coatings for Solar Thermal Collectors (태양열 집열기에 사용될 선택흡수막의 성능 평가)

  • Lee, Kil-Dong
    • Journal of the Korean Solar Energy Society
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    • v.32 no.4
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    • pp.43-50
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    • 2012
  • Metal-metal oxide (M-M oxide) cermet solar selective coatings with a double cermet layer film structure were deposited on the Al-deposited glass substrate by using a directed current (DC) magnetron sputtering technology. M oxide (CrO and ZrO) was used as the ceramic component in the cermets, and Cr and Zr used as the metallic components. In addition, black Cr (Cr-$Cr_2O_3$ cermet) solar selective coatings were deposited on the Ni-plated Cu substrate by using a electroplating method for comparison. The thermal stability tests were carried out for performance evaluation of solar coatings. Reflectance measurements were used to evaluate both solar absorptance(${\alpha}$) and thermal emittance (${\epsilon}$) of the solar coatings before and after thermal testing by using a spectrometer. Optical properties of optimized cermet solar coatings were ${\alpha}{\simeq}0.94-0.96$ and ${\epsilon}{\simeq}0.1$ ($100^{\circ}C$). The results of thermal stability test of M-M oxide solar coatings showed that the Cr-CrO cermet solar selective coatings were more stable than the Zr-ZrO cermet selective coatings at temperature of both $400^{\circ}C$ in air and $450^{\circ}C$ in vacuum. The black Cr solar selective coatings were degraded in air at temperature of $400^{\circ}C$. The main optical degradation modes of these coatings were diffusion of metal atoms, and oxidation.

Thermal Properties of Poly($\varepsilon$-Caprolactone)/Multiwalled Carbon Nanotubes Composites

  • Kim, Hun-Sik;Chae, Yun-Seok;Choi, Jae-Hoon;Yoon, Jin-San;Jin, Hyoung-Joon
    • Advanced Composite Materials
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    • v.17 no.2
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    • pp.157-166
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    • 2008
  • In this study, multiwalled carbon nanotubes (MWCNTs) were compounded with the poly($\varepsilon$-caprolactone) (PCL) matrix at the solution state using chloroform. For homogeneous dispersion of MWCNTs in polymer matrix, oxygen-containing groups were introduced on the surface of MWCNTs. The mechanical properties of the PCL/MWCNTs composites were effectively increased due to the incorporation of MWCNTs. The composites were characterized using scanning electron microscopy in order to obtain information on the dispersion of MWCNT in the polymeric matrix. In case of 1.2 wt% of MWCNTs in the matrix, strength and modulus of the composite increased by 12.1% and 164.3%, respectively. In addition, the dispersion of MWCNTs in the PCL matrix resulted in substantial decrease of the electrical resistivity of the composites as the MWCNTs loading was increased from 0 to 2.0 wt%. Furthermore, thermal stability of the PCL and PCL/MWCNTs-COOH composites were investigated using the data acquired from the thermogravimetric analysis. The detailed kinetics of the thermal degradation of the composites was investigated by analyzing their thermal behavior at different heating rates in a nitrogen atmosphere. Activation energy of thermal degradation was determined by using the equations proposed by Kissinger and Flynn-Wall-Ozawa. The apparent activation energy of PCL/MWCNTs-COOH composite was considerably higher than that of neat PCL.

A Study on Thermal Cycle Characteristics of Solid Oxide Fuel Cell (고체 산화물 연료전지의 열사이클 따른 성능 열화 특성 연구)

  • Kim, Eung-Yong;Song, Rak-Hyun;Jeon, Kwang-Sun;Shin, Dong-Ryul;Kang, Thae-Khapp
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1312-1314
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    • 1998
  • SOFC system is often subject to thermal cycle condition during normal start/stop, shutdown, and emergence state. Under the thermal cycle condition of heating and cooling, the SOFC components expand or shrink, which produces thermal stress and thermal shock. The SOFC performance is degraded by the thermal factors. To protect SOFC system from the thermal degradation, the optimum thermal condition must be clarified. In this study, to examine the thermal cycle characteristics, we fabricated single cells of planar SOFC with an area of $5{\times}5cm$. The electrolyte and PEN were tested under thermal cycle conditions in the range of$ 2-8^{\circ}C/min$. After thermal cycle test. crack creation of the components were examined using ultraviolet apparatus. No crack in the electrolyte and PEN were observed. The single cell system with alumina frame were also tested under thermal cycle conditions of 2, 3, $4^{\circ}C/min$. The single cell was fractured at the thermal cycle of 3 and $4^{\circ}C/min$ and the optimum condition of the thermal cycle to be found below $2^{\circ}C/min$.

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Thermal Fatigue Degradation Behavior of Ni-Ti Shape Memory Alloy (Ti-Ni 형상기억합금의 열피로열화 거동)

  • 박영철;조용배;오세욱
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.11
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    • pp.2913-2921
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    • 1994
  • In SMA(shape memory alloy), the degradation by fatigue is one of the most important problems to be overcome, when SMA is used for robot-actuator material. The actuator is operated repeatitively for long time and its repeating operation develops the fatigue degradation of SMA. The fatigue degradation changes the transformation temperature and deformation behavior and results in inaccurate operation control of robot. Accordingly, the changing behavior of transformation temperature and deformation which results from repeating operation is to be investigated in advance and the scheme to resolve those problems have to be made for the design of actuator. In this study, the fatigue tests were carried out on SMA specimens prepared to have different condition of aging time and pre-strain with the direct-current heating-cooling method, which was a general method of operation in robot actuators. The behavior of transformation temperature and deformation were examined and analyzed in each specimen and the study was performed to establish the optimistic manufacturing condition of SMA against the fatigue degradation.

Evaluation of 1Cr-1Mo-0.25V Steel Degradation Using Magnetic Barkhausen Noise (Magnetic Barkhausen Noise를 이용한 1Cr-1Mo-0.25V강의 열화도 평가)

  • Lee, J.M.;Ahn, B.Y.;Nam, Y.H.;Nahm, S.H.;Lee, S.S.;Lee, O.S.
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.250-255
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    • 2001
  • It is inevitable to evaluate the life of turbine rotor because the operating periods of power plants need to be extended. The magnetic methods utilizing Magnetic Barkhausen noise curve were applied to detect the degradation caused by thermal aging. The Magnetic property of material depends on the domain dynamics and it is affected by the microstructure of material. Therefore the magnetic property is very sensitive to the microstructure change of the material. It is, thus, very useful to detect the state of degradation of varying materials. The test specimen made of 1Cr-1Mo-0.25V steel was used widely for turbine rotor material, and seven kinds of specimens with different degradation levels were prepared by the isothermal heat treatment at $630^{\circ}C$. With the increase of degradation, BHN was decreased. The result was compared with coercive force and vickers hardness.

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